skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Dynamic Screening and Slow Cooling of Hot Carriers in Lead Halide Perovskites

Authors:
 [1];  [1]; ORCiD logo [1]
  1. Department of ChemistryColumbia University New York NY 10027 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1491924
Grant/Contract Number:  
N00014‐18‐1‐2080; DE‐SC0010692
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Name: Advanced Materials Journal Volume: 31 Journal Issue: 47; Journal ID: ISSN 0935-9648
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Joshi, Prakriti Pradhan, Maehrlein, Sebastian F., and Zhu, Xiaoyang. Dynamic Screening and Slow Cooling of Hot Carriers in Lead Halide Perovskites. Germany: N. p., 2018. Web. doi:10.1002/adma.201803054.
Joshi, Prakriti Pradhan, Maehrlein, Sebastian F., & Zhu, Xiaoyang. Dynamic Screening and Slow Cooling of Hot Carriers in Lead Halide Perovskites. Germany. doi:10.1002/adma.201803054.
Joshi, Prakriti Pradhan, Maehrlein, Sebastian F., and Zhu, Xiaoyang. Mon . "Dynamic Screening and Slow Cooling of Hot Carriers in Lead Halide Perovskites". Germany. doi:10.1002/adma.201803054.
@article{osti_1491924,
title = {Dynamic Screening and Slow Cooling of Hot Carriers in Lead Halide Perovskites},
author = {Joshi, Prakriti Pradhan and Maehrlein, Sebastian F. and Zhu, Xiaoyang},
abstractNote = {},
doi = {10.1002/adma.201803054},
journal = {Advanced Materials},
number = 47,
volume = 31,
place = {Germany},
year = {2018},
month = {9}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/adma.201803054

Citation Metrics:
Cited by: 8 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Femtosecond hot‐carrier energy relaxation in GaAs
journal, November 1987

  • Schoenlein, R. W.; Lin, W. Z.; Ippen, E. P.
  • Applied Physics Letters, Vol. 51, Issue 18
  • DOI: 10.1063/1.98651

Charge Carriers in Hybrid Organic–Inorganic Lead Halide Perovskites Might Be Protected as Large Polarons
journal, November 2015


Hot-carrier cooling and photoinduced refractive index changes in organic–inorganic lead halide perovskites
journal, September 2015

  • Price, Michael B.; Butkus, Justinas; Jellicoe, Tom C.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9420

Local Polar Fluctuations in Lead Halide Perovskite Crystals
journal, March 2017


Dynamic disorder, phonon lifetimes, and the assignment of modes to the vibrational spectra of methylammonium lead halide perovskites
journal, January 2016

  • Leguy, Aurélien M. A.; Goñi, Alejandro R.; Frost, Jarvist M.
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 39
  • DOI: 10.1039/C6CP03474H

Recent progress in relaxor ferroelectrics with perovskite structure
journal, January 2006


Intrinsic Charge Transport across Phase Transitions in Hybrid Organo-Inorganic Perovskites
journal, May 2016


Hybrid organic—inorganic perovskites: low-cost semiconductors with intriguing charge-transport properties
journal, January 2016

  • Brenner, Thomas M.; Egger, David A.; Kronik, Leeor
  • Nature Reviews Materials, Vol. 1, Issue 1
  • DOI: 10.1038/natrevmats.2015.7

Efficiency of hot‐carrier solar energy converters
journal, May 1982

  • Ross, Robert T.; Nozik, Arthur J.
  • Journal of Applied Physics, Vol. 53, Issue 5
  • DOI: 10.1063/1.331124

Room-Temperature Coherent Optical Phonon in 2D Electronic Spectra of CH 3 NH 3 PbI 3 Perovskite as a Possible Cooling Bottleneck
journal, June 2017

  • Monahan, Daniele M.; Guo, Liang; Lin, Jia
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 14
  • DOI: 10.1021/acs.jpclett.7b01357

Temperature-Dependent Charge-Carrier Dynamics in CH 3 NH 3 PbI 3 Perovskite Thin Films
journal, September 2015

  • Milot, Rebecca L.; Eperon, Giles E.; Snaith, Henry J.
  • Advanced Functional Materials, Vol. 25, Issue 39
  • DOI: 10.1002/adfm.201502340

Ultralow thermal conductivity in all-inorganic halide perovskites
journal, July 2017

  • Lee, Woochul; Li, Huashan; Wong, Andrew B.
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 33
  • DOI: 10.1073/pnas.1711744114

Metal halide perovskites for energy applications
journal, May 2016


Quantization of Multiparticle Auger Rates in Semiconductor Quantum Dots
journal, February 2000


Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009

  • Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
  • Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
  • DOI: 10.1021/ja809598r

Exceeding the Shockley–Queisser limit in solar energy conversion
journal, January 2013

  • Nelson, Cory A.; Monahan, Nicholas R.; Zhu, X. -Y.
  • Energy & Environmental Science, Vol. 6, Issue 12
  • DOI: 10.1039/c3ee42098a

Direct Observation of Dynamic Symmetry Breaking above Room Temperature in Methylammonium Lead Iodide Perovskite
journal, October 2016


Trap-Free Hot Carrier Relaxation in Lead–Halide Perovskite Films
journal, May 2017

  • Bretschneider, Simon A.; Laquai, Frédéric; Bonn, Mischa
  • The Journal of Physical Chemistry C, Vol. 121, Issue 21
  • DOI: 10.1021/acs.jpcc.7b03992

Phonon Speed, Not Scattering, Differentiates Thermal Transport in Lead Halide Perovskites
journal, August 2017


Breaking the phonon bottleneck in nanometer quantum dots: Role of Auger-like processes
journal, January 1995


Optical phonons in methylammonium lead halide perovskites and implications for charge transport
journal, January 2016

  • Sendner, Michael; Nayak, Pabitra K.; Egger, David A.
  • Materials Horizons, Vol. 3, Issue 6
  • DOI: 10.1039/C6MH00275G

Screening in crystalline liquids protects energetic carriers in hybrid perovskites
journal, September 2016


Slow hot carrier cooling in cesium lead iodide perovskites
journal, October 2017

  • Shen, Qing; Ripolles, Teresa S.; Even, Jacky
  • Applied Physics Letters, Vol. 111, Issue 15
  • DOI: 10.1063/1.4991993

The Evolution of Quantum Confinement in CsPbBr 3 Perovskite Nanocrystals
journal, April 2017


Hot-phonon effects in bulk GaAs
journal, September 1987


Lead halide perovskites: Crystal-liquid duality, phonon glass electron crystals, and large polaron formation
journal, October 2017

  • Miyata, Kiyoshi; Atallah, Timothy L.; Zhu, X. -Y.
  • Science Advances, Vol. 3, Issue 10
  • DOI: 10.1126/sciadv.1701469

Acoustic-optical phonon up-conversion and hot-phonon bottleneck in lead-halide perovskites
journal, January 2017

  • Yang, Jianfeng; Wen, Xiaoming; Xia, Hongze
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14120

Phonon anharmonicity, lifetimes, and thermal transport in CH 3 NH 3 PbI 3 from many-body perturbation theory
journal, December 2016


Transport Dynamics of a Large Acoustic Polaron in One Dimension
journal, December 1983


Long-Lived Hot Carriers in Formamidinium Lead Iodide Nanocrystals
journal, May 2017

  • Papagiorgis, Paris; Protesescu, Loredana; Kovalenko, Maksym V.
  • The Journal of Physical Chemistry C, Vol. 121, Issue 22
  • DOI: 10.1021/acs.jpcc.7b02308

Low electron-polar optical phonon scattering as a fundamental aspect of carrier mobility in methylammonium lead halide CH 3 NH 3 PbI 3 perovskites
journal, January 2016

  • Filippetti, A.; Mattoni, A.; Caddeo, C.
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 22
  • DOI: 10.1039/C6CP01402J

Light-induced picosecond rotational disordering of the inorganic sublattice in hybrid perovskites
journal, July 2017


Mechanical properties of A Pb X 3 ( A = Cs or CH 3 NH 3 ; X = I or Br) perovskite single crystals
journal, October 2015

  • Rakita, Yevgeny; Cohen, Sidney R.; Kedem, Nir Klein
  • MRS Communications, Vol. 5, Issue 4
  • DOI: 10.1557/mrc.2015.69

Role of Dielectric Drag in Polaron Mobility in Lead Halide Perovskites
journal, October 2017


Direct observation of mode-specific phonon-band gap coupling in methylammonium lead halide perovskites
journal, September 2017


Electron Dynamics at the ZnO (101̅0) Surface
journal, July 2008

  • Tisdale, William A.; Muntwiler, Matthias; Norris, David J.
  • The Journal of Physical Chemistry C, Vol. 112, Issue 37
  • DOI: 10.1021/jp802455p

Perovskite Materials for Light-Emitting Diodes and Lasers
journal, May 2016

  • Veldhuis, Sjoerd A.; Boix, Pablo P.; Yantara, Natalia
  • Advanced Materials, Vol. 28, Issue 32
  • DOI: 10.1002/adma.201600669

Competition Between Hot-Electron Cooling and Large Polaron Screening in CsPbBr 3 Perovskite Single Crystals
journal, December 2017

  • Evans, Tyler J. S.; Miyata, Kiyoshi; Joshi, Prakriti P.
  • The Journal of Physical Chemistry C, Vol. 122, Issue 25
  • DOI: 10.1021/acs.jpcc.8b00476

Interplay between organic cations and inorganic framework and incommensurability in hybrid lead-halide perovskite CH 3 NH 3 PbBr 3
journal, September 2017


Thermal Conductivity of CH 3 NH 3 PbI 3 and CsPbI 3 : Measuring the Effect of the Methylammonium Ion on Phonon Scattering
journal, February 2017

  • Kovalsky, Anton; Wang, Lili; Marek, Gage T.
  • The Journal of Physical Chemistry C, Vol. 121, Issue 6
  • DOI: 10.1021/acs.jpcc.6b12231

Hot-phonon effects in femtosecond luminescence spectra of electron-hole plasmas in CdS
journal, August 1995


Quantifying Polaron Formation and Charge Carrier Cooling in Lead-Iodide Perovskites
journal, May 2018

  • Bretschneider, Simon A.; Ivanov, Ivan; Wang, Hai I.
  • Advanced Materials, Vol. 30, Issue 29
  • DOI: 10.1002/adma.201707312

Lattice Dynamics and Central-Mode Phenomena in the Dielectric Response of Ferroelectrics and Related Materials
journal, January 2004


Phonon–Electron Scattering Limits Free Charge Mobility in Methylammonium Lead Iodide Perovskites
journal, December 2015

  • Karakus, Melike; Jensen, Søren A.; D’Angelo, Francesco
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 24
  • DOI: 10.1021/acs.jpclett.5b02485

Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter‐wave spectroscopy
journal, December 1987

  • Poglitsch, A.; Weber, D.
  • The Journal of Chemical Physics, Vol. 87, Issue 11, p. 6373-6378
  • DOI: 10.1063/1.453467

Ultrafast Imaging of Carrier Cooling in Metal Halide Perovskite Thin Films
journal, January 2018


Exploring Anomalous Polarization Dynamics in Organometallic Halide Perovskites
journal, January 2018

  • Ahmadi, Mahshid; Collins, Liam; Puretzky, Alexander
  • Advanced Materials, Vol. 30, Issue 11
  • DOI: 10.1002/adma.201705298

Infrared dielectric constant of gallium arsenide
journal, December 1996

  • Moore, W. J.; Holm, R. T.
  • Journal of Applied Physics, Vol. 80, Issue 12
  • DOI: 10.1063/1.363818

Semiconductor excitons in new light
journal, July 2006

  • Koch, S. W.; Kira, M.; Khitrova, G.
  • Nature Materials, Vol. 5, Issue 7
  • DOI: 10.1038/nmat1658

Large polarons in lead halide perovskites
journal, August 2017

  • Miyata, Kiyoshi; Meggiolaro, Daniele; Trinh, M. Tuan
  • Science Advances, Vol. 3, Issue 8
  • DOI: 10.1126/sciadv.1701217

Extended carrier lifetimes and diffusion in hybrid perovskites revealed by Hall effect and photoconductivity measurements
journal, August 2016


Thermally Activated Exciton Dissociation and Recombination Control the Carrier Dynamics in Organometal Halide Perovskite
journal, June 2014

  • Savenije, Tom J.; Ponseca, Carlito S.; Kunneman, Lucas
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 13
  • DOI: 10.1021/jz500858a

Improved Understanding of the Electronic and Energetic Landscapes of Perovskite Solar Cells: High Local Charge Carrier Mobility, Reduced Recombination, and Extremely Shallow Traps
journal, September 2014

  • Oga, Hikaru; Saeki, Akinori; Ogomi, Yuhei
  • Journal of the American Chemical Society, Vol. 136, Issue 39
  • DOI: 10.1021/ja506936f

Ultrafast carrier thermalization in lead iodide perovskite probed with two-dimensional electronic spectroscopy
journal, August 2017

  • Richter, Johannes M.; Branchi, Federico; Valduga de Almeida Camargo, Franco
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/s41467-017-00546-z

Dielectric Response: Answer to Many Questions in the Methylammonium Lead Halide Solar Cell Absorbers
journal, May 2017

  • Anusca, Irina; Balčiūnas, Sergejus; Gemeiner, Pascale
  • Advanced Energy Materials, Vol. 7, Issue 19
  • DOI: 10.1002/aenm.201700600

Dynamics of hot carrier cooling in photo-excited GaAs
journal, September 1979


Ultra-Low Thermal Conductivity in Organic–Inorganic Hybrid Perovskite CH 3 NH 3 PbI 3
journal, July 2014

  • Pisoni, Andrea; Jaćimović, Jaćim; Barišić, Osor S.
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 14
  • DOI: 10.1021/jz5012109

GIGANTEA is a co-chaperone which facilitates maturation of ZEITLUPE in the Arabidopsis circadian clock
journal, February 2017


Persistent Energetic Electrons in Methylammonium Lead Iodide Perovskite Thin Films
journal, November 2016

  • Niesner, Daniel; Zhu, Haiming; Miyata, Kiyoshi
  • Journal of the American Chemical Society, Vol. 138, Issue 48
  • DOI: 10.1021/jacs.6b08880

Screening of hot-carrier relaxation in highly photoexcited semiconductors
journal, February 1981


Tetragonal CH 3 NH 3 PbI 3 is ferroelectric
journal, June 2017

  • Rakita, Yevgeny; Bar-Elli, Omri; Meirzadeh, Elena
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 28
  • DOI: 10.1073/pnas.1702429114

Making and Breaking of Lead Halide Perovskites
journal, January 2016

  • Manser, Joseph S.; Saidaminov, Makhsud I.; Christians, Jeffrey A.
  • Accounts of Chemical Research, Vol. 49, Issue 2
  • DOI: 10.1021/acs.accounts.5b00455

Dynamical Origin of the Rashba Effect in Organohalide Lead Perovskites: A Key to Suppressed Carrier Recombination in Perovskite Solar Cells?
journal, April 2016

  • Etienne, Thibaud; Mosconi, Edoardo; De Angelis, Filippo
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 9
  • DOI: 10.1021/acs.jpclett.6b00564

Charge transport in hybrid halide perovskites
journal, November 2017


Barrier to recombination of oppositely charged large polarons
journal, February 2018


Molecular disorder and translation/rotation coupling in the plastic crystal phase of hybrid perovskites
journal, January 2016


Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells
journal, March 1961

  • Shockley, William; Queisser, Hans J.
  • Journal of Applied Physics, Vol. 32, Issue 3, p. 510-519
  • DOI: 10.1063/1.1736034

Slow Cooling of Hot Polarons in Halide Perovskite Solar Cells
journal, October 2017


Relaxing with relaxors: a review of relaxor ferroelectrics
journal, April 2011


Electron–phonon coupling in hybrid lead halide perovskites
journal, May 2016

  • Wright, Adam D.; Verdi, Carla; Milot, Rebecca L.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms11755

Ferroelectric large polarons
journal, April 2018


Structural Phase- and Degradation-Dependent Thermal Conductivity of CH 3 NH 3 PbI 3 Perovskite Thin Films
journal, March 2016

  • Guo, Zhi; Yoon, Seog Joon; Manser, Joseph S.
  • The Journal of Physical Chemistry C, Vol. 120, Issue 12
  • DOI: 10.1021/acs.jpcc.6b00513

CH 3 NH 3 PbI 3 perovskites: Ferroelasticity revealed
journal, April 2017


Photoinduced Giant Dielectric Constant in Lead Halide Perovskite Solar Cells
journal, June 2014

  • Juarez-Perez, Emilio J.; Sanchez, Rafael S.; Badia, Laura
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 13
  • DOI: 10.1021/jz5011169

Hot carrier cooling mechanisms in halide perovskites
journal, November 2017


Long-range hot-carrier transport in hybrid perovskites visualized by ultrafast microscopy
journal, April 2017


Observation of a hot-phonon bottleneck in lead-iodide perovskites
journal, October 2015