Controlling catalytic activity and selectivity for partial hydrogenation by tuning the environment around active sites in iridium complexes bonded to supports
Abstract
Enveloping atomically dispersed supported iridium with the choice of ionic liquid molecular sheaths and supports controls the catalytic performance.
- Authors:
-
- Department of Chemical and Biological Engineering, Koç University, Sariyer 34450, Istanbul, Turkey, Koç University TÜPRAŞ Energy Center (KUTEM)
- Department of Materials Science and Engineering, University of California, Davis, USA
- Department of Chemical Engineering, University of California, Davis, USA
- SSRL, SLAC National Accelerator Laboratory, Menlo Park, USA
- Publication Date:
- Research Org.:
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1491267
- Alternate Identifier(s):
- OSTI ID: 1505424
- Grant/Contract Number:
- Consortium for Operando and Advanced Catalyst Characterization; AC02-76SF00515; FG02-04ER15513; 113M552
- Resource Type:
- Published Article
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Name: Chemical Science Journal Volume: 10 Journal Issue: 9; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Babucci, Melike, Fang, Chia-Yu, Perez-Aguilar, Jorge E., Hoffman, Adam S., Boubnov, Alexey, Guan, Erjia, Bare, Simon R., Gates, Bruce C., and Uzun, Alper. Controlling catalytic activity and selectivity for partial hydrogenation by tuning the environment around active sites in iridium complexes bonded to supports. United Kingdom: N. p., 2019.
Web. doi:10.1039/C8SC05287E.
Babucci, Melike, Fang, Chia-Yu, Perez-Aguilar, Jorge E., Hoffman, Adam S., Boubnov, Alexey, Guan, Erjia, Bare, Simon R., Gates, Bruce C., & Uzun, Alper. Controlling catalytic activity and selectivity for partial hydrogenation by tuning the environment around active sites in iridium complexes bonded to supports. United Kingdom. https://doi.org/10.1039/C8SC05287E
Babucci, Melike, Fang, Chia-Yu, Perez-Aguilar, Jorge E., Hoffman, Adam S., Boubnov, Alexey, Guan, Erjia, Bare, Simon R., Gates, Bruce C., and Uzun, Alper. Wed .
"Controlling catalytic activity and selectivity for partial hydrogenation by tuning the environment around active sites in iridium complexes bonded to supports". United Kingdom. https://doi.org/10.1039/C8SC05287E.
@article{osti_1491267,
title = {Controlling catalytic activity and selectivity for partial hydrogenation by tuning the environment around active sites in iridium complexes bonded to supports},
author = {Babucci, Melike and Fang, Chia-Yu and Perez-Aguilar, Jorge E. and Hoffman, Adam S. and Boubnov, Alexey and Guan, Erjia and Bare, Simon R. and Gates, Bruce C. and Uzun, Alper},
abstractNote = {Enveloping atomically dispersed supported iridium with the choice of ionic liquid molecular sheaths and supports controls the catalytic performance.},
doi = {10.1039/C8SC05287E},
journal = {Chemical Science},
number = 9,
volume = 10,
place = {United Kingdom},
year = {Wed Feb 27 00:00:00 EST 2019},
month = {Wed Feb 27 00:00:00 EST 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C8SC05287E
https://doi.org/10.1039/C8SC05287E
Other availability
Cited by: 31 works
Citation information provided by
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Web of Science
Figures / Tables:
Table 1: Summary of EXAFS fit parameters characterizing samples prepared by adsorption of Ir(CO)2(acac) on metal oxides having various electron-donor characteristics (quantified by the their corresponding PZC values)a
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Works referenced in this record:
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005
- Ravel, B.; Newville, M.
- Journal of Synchrotron Radiation, Vol. 12, Issue 4
Isolated Metal Active Site Concentration and Stability Control Catalytic CO 2 Reduction Selectivity
journal, February 2015
- Matsubu, John C.; Yang, Vanessa N.; Christopher, Phillip
- Journal of the American Chemical Society, Vol. 137, Issue 8
Homogeneity of Surface Sites in Supported Single-Site Metal Catalysts: Assessment with Band Widths of Metal Carbonyl Infrared Spectra
journal, September 2016
- Hoffman, Adam S.; Fang, Chia-Yu; Gates, Bruce C.
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 19
Catalysis by Supported Single Metal Atoms
journal, November 2016
- Liu, Jingyue
- ACS Catalysis, Vol. 7, Issue 1
Nature of the metal-support interface in supported metal catalysts: Results from X-ray absorption spectroscopy
journal, January 1992
- Koningsberger, D. C.; Gates, B. C.
- Catalysis Letters, Vol. 14, Issue 3-4
Tuning selectivity in catalysis by controlling particle shape
journal, January 2009
- Lee, Ilkeun; Delbecq, Françoise; Morales, Ricardo
- Nature Materials, Vol. 8, Issue 2
Particle Size Effects in the Catalytic Electroreduction of CO 2 on Cu Nanoparticles
journal, May 2014
- Reske, Rulle; Mistry, Hemma; Behafarid, Farzad
- Journal of the American Chemical Society, Vol. 136, Issue 19
Synthesis of a molecularly defined single-active site heterogeneous catalyst for selective oxidation of N-heterocycles
journal, April 2018
- Zhang, Yujing; Pang, Shaofeng; Wei, Zhihong
- Nature Communications, Vol. 9, Issue 1
Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit
journal, October 2015
- Lucci, Felicia R.; Liu, Jilei; Marcinkowski, Matthew D.
- Nature Communications, Vol. 6, Issue 1
Gold Atoms Stabilized on Various Supports Catalyze the Water–Gas Shift Reaction
journal, November 2013
- Flytzani-Stephanopoulos, Maria
- Accounts of Chemical Research, Vol. 47, Issue 3
Size-dependent catalytic activity of supported metal clusters
journal, November 1994
- Xu, Z.; Xiao, F. -S.; Purnell, S. K.
- Nature, Vol. 372, Issue 6504
Thermally stable single atom Pt/m-Al2O3 for selective hydrogenation and CO oxidation
journal, July 2017
- Zhang, Zailei; Zhu, Yihan; Asakura, Hiroyuki
- Nature Communications, Vol. 8, Issue 1
Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis
journal, April 2013
- Yang, Xiao-Feng; Wang, Aiqin; Qiao, Botao
- Accounts of Chemical Research, Vol. 46, Issue 8
Electronic Metal-Support Interactions in Single-Atom Catalysts
journal, March 2014
- Hu, Pingping; Huang, Zhiwei; Amghouz, Zakariae
- Angewandte Chemie International Edition, Vol. 53, Issue 13
Tuning Catalytic Selectivity: Zeolite- and Magnesium Oxide-Supported Molecular Rhodium Catalysts for Hydrogenation of 1,3-Butadiene
journal, September 2012
- Yardimci, Dicle; Serna, Pedro; Gates, Bruce C.
- ACS Catalysis, Vol. 2, Issue 10
Single-atom catalysis of CO oxidation using Pt1/FeOx
journal, July 2011
- Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng
- Nature Chemistry, Vol. 3, Issue 8
Single-Site Zeolite-Anchored Organoiridium Carbonyl Complexes: Characterization of Structure and Reactivity by Spectroscopy and Computational Chemistry
journal, July 2015
- Martinez-Macias, Claudia; Chen, Mingyang; Dixon, David A.
- Chemistry - A European Journal, Vol. 21, Issue 33
Crystal structure of (acetylacetonato) (dicarbonyl)iridium(I)
journal, June 2009
- Zherikova, K. V.; Kuratieva, N. V.; Morozova, N. B.
- Journal of Structural Chemistry, Vol. 50, Issue 3
Selective Hydrogenation of 1,3-Butadiene to 1-Butene by Pd(0) Nanoparticles Embedded in Imidazolium Ionic Liquids
journal, August 2005
- Umpierre, Alexandre P.; Machado, Giovanna; Fecher, Gerhard H.
- Advanced Synthesis & Catalysis, Vol. 347, Issue 10
Two- and Three-Dimensional [IrSi] Networks in the Silicides Sm3Ir2Si2, HoIrSi, and YbIrSi
journal, August 2001
- Mishra, Ratikanta; Hoffmann, Rolf-Dieter; Pöttgen, Rainer
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 627, Issue 8
Low-temperature carbon monoxide oxidation catalysed by regenerable atomically dispersed palladium on alumina
journal, September 2014
- Peterson, Eric J.; DeLaRiva, Andrew T.; Lin, Sen
- Nature Communications, Vol. 5, Issue 1
Tuning the Selectivity of Single-Site Supported Metal Catalysts with Ionic Liquids
journal, September 2017
- Babucci, Melike; Fang, Chia-Yu; Hoffman, Adam S.
- ACS Catalysis, Vol. 7, Issue 10
Ligand Effects in SCILL Model Systems: Site-Specific Interactions with Pt and Pd Nanoparticles
journal, April 2011
- Sobota, Marek; Happel, Markus; Amende, Max
- Advanced Materials, Vol. 23, Issue 22-23
Isostructural Zeolite-Supported Rhodium and Iridium Complexes: Tuning Catalytic Activity and Selectivity by Ligand Modification
journal, August 2015
- Martinez-Macias, Claudia; Serna, Pedro; Gates, Bruce C.
- ACS Catalysis, Vol. 5, Issue 10
Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts
journal, July 2013
- Cargnello, M.; Doan-Nguyen, V. V. T.; Gordon, T. R.
- Science, Vol. 341, Issue 6147
Catalyst Architecture for Stable Single Atom Dispersion Enables Site-Specific Spectroscopic and Reactivity Measurements of CO Adsorbed to Pt Atoms, Oxidized Pt Clusters, and Metallic Pt Clusters on TiO 2
journal, September 2017
- DeRita, Leo; Dai, Sheng; Lopez-Zepeda, Kimberly
- Journal of the American Chemical Society, Vol. 139, Issue 40
An atomic-scale view of single-site Pt catalysis for low-temperature CO oxidation
journal, March 2018
- Therrien, Andrew J.; Hensley, Alyssa J. R.; Marcinkowski, Matthew D.
- Nature Catalysis, Vol. 1, Issue 3
Effects of interionic interactions in 1,3-dialkylimidazolium ionic liquids on the electronic structure of metal sites in solid catalysts with ionic liquid layer (SCILL)
journal, April 2016
- Babucci, Melike; Uzun, Alper
- Journal of Molecular Liquids, Vol. 216
Evidence for antisite disorder in YBa2Cu3O7
journal, June 1989
- Lytle, F. W.; Larson, E. M.; Greegor, R. B.
- Physica B: Condensed Matter, Vol. 158, Issue 1-3
Bridging homogeneous and heterogeneous catalysis by heterogeneous single-metal-site catalysts
journal, June 2018
- Cui, Xinjiang; Li, Wu; Ryabchuk, Pavel
- Nature Catalysis, Vol. 1, Issue 6
Solid Catalyst with Ionic Liquid Layer (SCILL) – A New Concept to Improve Selectivity Illustrated by Hydrogenation of Cyclooctadiene
journal, August 2007
- Kernchen, U.; Etzold, B.; Korth, W.
- Chemical Engineering & Technology, Vol. 30, Issue 8
Interaction trends between single metal atoms and oxide supports identified with density functional theory and statistical learning
journal, July 2018
- O’Connor, Nolan J.; Jonayat, A. S. M.; Janik, Michael J.
- Nature Catalysis, Vol. 1, Issue 7
Effects of Cu–Ni Bimetallic Catalyst Composition and Support on Activity, Selectivity, and Stability for Furfural Conversion to 2-Methyfuran
journal, December 2017
- Seemala, Bhogeswararao; Cai, Charles M.; Kumar, Rajeev
- ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 2
Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations
journal, March 2012
- Kyriakou, Georgios; Boucher, Matthew B.; Jewell, April D.
- Science, Vol. 335, Issue 6073
Tuning the Catalytic Activity and Selectivity of Pd Nanoparticles Using Ligand-Modified Supports and Surfaces
journal, September 2017
- da Silva, Fernanda Parra; Fiorio, Jhonatan Luiz; Rossi, Liane Marcia
- ACS Omega, Vol. 2, Issue 9
A new method for parameterization of phase shift and backscattering amplitude
journal, March 1995
- Vaarkamp, Marius; Linders, Johannes C.; Koningsberger, Diek C.
- Physica B: Condensed Matter, Vol. 208-209
Isoelectric points and points of zero charge of metal (hydr)oxides: 50years after Parks' review
journal, December 2016
- Kosmulski, Marek
- Advances in Colloid and Interface Science, Vol. 238
Supported Molecular Iridium Catalysts: Resolving Effects of Metal Nuclearity and Supports as Ligands
journal, October 2011
- Lu, Jing; Serna, Pedro; Aydin, Ceren
- Journal of the American Chemical Society, Vol. 133, Issue 40
Interactions Between the Room-Temperature Ionic Liquid [C 2 C 1 Im][OTf] and Pd(111), Well-Ordered Al 2 O 3 , and Supported Pd Model Catalysts from IR Spectroscopy
journal, January 2014
- Schernich, Stefan; Kostyshyn, Dmytro; Wagner, Valentin
- The Journal of Physical Chemistry C, Vol. 118, Issue 6
Interactions of [BMIM][BF 4 ] with Metal Oxides and Their Consequences on Stability Limits
journal, September 2016
- Babucci, Melike; Balci, Volkan; Akçay, Aslı
- The Journal of Physical Chemistry C, Vol. 120, Issue 36
A New Type of Strong Metal–Support Interaction and the Production of H 2 through the Transformation of Water on Pt/CeO 2 (111) and Pt/CeO x /TiO 2 (110) Catalysts
journal, May 2012
- Bruix, Albert; Rodriguez, José A.; Ramírez, Pedro J.
- Journal of the American Chemical Society, Vol. 134, Issue 21
Tuning Zr 6 Metal–Organic Framework (MOF) Nodes as Catalyst Supports: Site Densities and Electron-Donor Properties Influence Molecular Iridium Complexes as Ethylene Conversion Catalysts
journal, December 2015
- Yang, Dong; Odoh, Samuel O.; Borycz, Joshua
- ACS Catalysis, Vol. 6, Issue 1
Well-Defined Noble Metal Single Sites in Zeolites as an Alternative to Catalysis by Insoluble Metal Salts
journal, September 2015
- Rubio-Marqués, Paula; Rivero-Crespo, Miguel A.; Leyva-Pérez, Antonio
- Journal of the American Chemical Society, Vol. 137, Issue 36
Single-Atom Pd 1 /Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene
journal, August 2015
- Yan, Huan; Cheng, Hao; Yi, Hong
- Journal of the American Chemical Society, Vol. 137, Issue 33
Interfacial electronic effects control the reaction selectivity of platinum catalysts
journal, January 2016
- Chen, Guangxu; Xu, Chaofa; Huang, Xiaoqing
- Nature Materials, Vol. 15, Issue 5
Transmission and fluorescence X-ray absorption spectroscopy cell/flow reactor for powder samples under vacuum or in reactive atmospheres
journal, July 2016
- Hoffman, A. S.; Debefve, L. M.; Bendjeriou-Sedjerari, A.
- Review of Scientific Instruments, Vol. 87, Issue 7
Surface Science and Model Catalysis with Ionic Liquid-Modified Materials
journal, April 2011
- Steinrück, H. -P.; Libuda, J.; Wasserscheid, P.
- Advanced Materials, Vol. 23, Issue 22-23
Multiple-scattering calculations of x-ray-absorption spectra
journal, July 1995
- Zabinsky, S. I.; Rehr, J. J.; Ankudinov, A.
- Physical Review B, Vol. 52, Issue 4
Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles
journal, April 2018
- Liu, Lichen; Corma, Avelino
- Chemical Reviews, Vol. 118, Issue 10
Remarkable Performance of Ir 1 /FeO x Single-Atom Catalyst in Water Gas Shift Reaction
journal, October 2013
- Lin, Jian; Wang, Aiqin; Qiao, Botao
- Journal of the American Chemical Society, Vol. 135, Issue 41
Dynamic Structural Changes in a Molecular Zeolite-Supported Iridium Catalyst for Ethene Hydrogenation
journal, November 2009
- Uzun, Alper; Gates, Bruce C.
- Journal of the American Chemical Society, Vol. 131, Issue 43
An exceptional selectivity for partial hydrogenation on a supported nickel catalyst coated with [BMIM][BF 4 ]
journal, June 2017
- Jalal, Ahsan; Uzun, Alper
- Journal of Catalysis, Vol. 350
Pt/Cu single-atom alloys as coke-resistant catalysts for efficient C–H activation
journal, January 2018
- Marcinkowski, Matthew D.; Darby, Matthew T.; Liu, Jilei
- Nature Chemistry, Vol. 10, Issue 3
The Multifaceted Reactivity of Single-Atom Heterogeneous Catalysts
journal, October 2018
- Mitchell, Sharon; Vorobyeva, Evgeniya; Pérez-Ramírez, Javier
- Angewandte Chemie International Edition, Vol. 57, Issue 47
Mild oxidation of methane to methanol or acetic acid on supported isolated rhodium catalysts
journal, November 2017
- Shan, Junjun; Li, Mengwei; Allard, Lawrence F.
- Nature, Vol. 551, Issue 7682
A site-isolated mononuclear iridium complex catalyst supported on MgO: Characterization by spectroscopy and aberration-corrected scanning transmission electron microscopy
journal, February 2010
- Uzun, Alper; Ortalan, Volkan; Browning, Nigel D.
- Journal of Catalysis, Vol. 269, Issue 2
Works referencing / citing this record:
In situ formation of mononuclear complexes by reaction-induced atomic dispersion of supported noble metal nanoparticles
journal, November 2019
- Feng, Siquan; Song, Xiangen; Liu, Yang
- Nature Communications, Vol. 10, Issue 1
Tailoring the ORR and HER electrocatalytic performances of gold nanoparticles through metal–ligand interfaces
journal, January 2019
- Alba-Molina, David; Puente Santiago, Alain R.; Giner-Casares, Juan J.
- Journal of Materials Chemistry A, Vol. 7, Issue 35
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