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Title: A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2

Abstract

Methanol is a major fuel and chemical feedstock currently produced from syngas, a CO/CO2/H2 mixture. Herein we identify formate binding strength as a key parameter limiting the activity and stability of known catalysts for methanol synthesis in the presence of CO2. We present a molybdenum phosphide catalyst for CO and CO2 reduction to methanol, which through a weaker interaction with formate, can improve the activity and stability of methanol synthesis catalysts in a wide range of CO/CO2/H2 feeds.

Authors:
ORCiD logo [1]; ORCiD logo [1];  [1];  [1];  [1];  [1];  [1]; ORCiD logo [1];  [1]; ORCiD logo [1];  [1];  [1]; ORCiD logo [1]
  1. SUNCAT Center for Interface Science and Catalysis, Stanford University, Stanford CA 94305 USA; SLAC National Accelerator Laboratory, Menlo Park CA 94025 USA
Publication Date:
Research Org.:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1490879
Alternate Identifier(s):
OSTI ID: 1478126; OSTI ID: 1490722
Grant/Contract Number:  
AC02-76SF00515
Resource Type:
Accepted Manuscript
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Name: Angewandte Chemie (International Edition); Journal Volume: 57; Journal Issue: 46; Journal ID: ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
10 SYNTHETIC FUELS; CO hydrogenation; CO2 hydrogenation; formate; methanol synthesis; molybdenum phosphide

Citation Formats

Duyar, Melis S., Tsai, Charlie, Snider, Jonathan L., Singh, Joseph A., Gallo, Alessandro, Yoo, Jong Suk, Medford, Andrew J., Abild-Pedersen, Frank, Studt, Felix, Kibsgaard, Jakob, Bent, Stacey F., Nørskov, Jens K., and Jaramillo, Thomas F. A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2. United States: N. p., 2018. Web. doi:10.1002/anie.201806583.
Duyar, Melis S., Tsai, Charlie, Snider, Jonathan L., Singh, Joseph A., Gallo, Alessandro, Yoo, Jong Suk, Medford, Andrew J., Abild-Pedersen, Frank, Studt, Felix, Kibsgaard, Jakob, Bent, Stacey F., Nørskov, Jens K., & Jaramillo, Thomas F. A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2. United States. doi:10.1002/anie.201806583.
Duyar, Melis S., Tsai, Charlie, Snider, Jonathan L., Singh, Joseph A., Gallo, Alessandro, Yoo, Jong Suk, Medford, Andrew J., Abild-Pedersen, Frank, Studt, Felix, Kibsgaard, Jakob, Bent, Stacey F., Nørskov, Jens K., and Jaramillo, Thomas F. Thu . "A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2". United States. doi:10.1002/anie.201806583. https://www.osti.gov/servlets/purl/1490879.
@article{osti_1490879,
title = {A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2},
author = {Duyar, Melis S. and Tsai, Charlie and Snider, Jonathan L. and Singh, Joseph A. and Gallo, Alessandro and Yoo, Jong Suk and Medford, Andrew J. and Abild-Pedersen, Frank and Studt, Felix and Kibsgaard, Jakob and Bent, Stacey F. and Nørskov, Jens K. and Jaramillo, Thomas F.},
abstractNote = {Methanol is a major fuel and chemical feedstock currently produced from syngas, a CO/CO2/H2 mixture. Herein we identify formate binding strength as a key parameter limiting the activity and stability of known catalysts for methanol synthesis in the presence of CO2. We present a molybdenum phosphide catalyst for CO and CO2 reduction to methanol, which through a weaker interaction with formate, can improve the activity and stability of methanol synthesis catalysts in a wide range of CO/CO2/H2 feeds.},
doi = {10.1002/anie.201806583},
journal = {Angewandte Chemie (International Edition)},
number = 46,
volume = 57,
place = {United States},
year = {2018},
month = {10}
}

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Works referenced in this record:

Novel catalysts for advanced hydroprocessing: transition metal phosphides
journal, May 2003


The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts
journal, April 2012