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Title: Shape-Controlled CO 2 Electrochemical Reduction on Nanosized Pd Hydride Cubes and Octahedra

 [1];  [2];  [1]; ORCiD logo [2]
  1. Center for Catalytic Science and Technology, Department of Chemical Engineering, University of Delaware, Newark DE 10716 USA
  2. Department of Chemical Engineering, Columbia University, New York NY 10027 USA
Publication Date:
Sponsoring Org.:
OSTI Identifier:
Grant/Contract Number:  
FG02-13ER16381; SC0009476
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Name: Advanced Energy Materials Journal Volume: 9 Journal Issue: 9; Journal ID: ISSN 1614-6832
Wiley Blackwell (John Wiley & Sons)
Country of Publication:

Citation Formats

Zhu, Wenlei, Kattel, Shyam, Jiao, Feng, and Chen, Jingguang G. Shape-Controlled CO 2 Electrochemical Reduction on Nanosized Pd Hydride Cubes and Octahedra. Germany: N. p., 2019. Web. doi:10.1002/aenm.201802840.
Zhu, Wenlei, Kattel, Shyam, Jiao, Feng, & Chen, Jingguang G. Shape-Controlled CO 2 Electrochemical Reduction on Nanosized Pd Hydride Cubes and Octahedra. Germany. doi:10.1002/aenm.201802840.
Zhu, Wenlei, Kattel, Shyam, Jiao, Feng, and Chen, Jingguang G. Wed . "Shape-Controlled CO 2 Electrochemical Reduction on Nanosized Pd Hydride Cubes and Octahedra". Germany. doi:10.1002/aenm.201802840.
title = {Shape-Controlled CO 2 Electrochemical Reduction on Nanosized Pd Hydride Cubes and Octahedra},
author = {Zhu, Wenlei and Kattel, Shyam and Jiao, Feng and Chen, Jingguang G.},
abstractNote = {},
doi = {10.1002/aenm.201802840},
journal = {Advanced Energy Materials},
number = 9,
volume = 9,
place = {Germany},
year = {2019},
month = {1}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/aenm.201802840

Citation Metrics:
Cited by: 14 works
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Works referenced in this record:

CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films
journal, April 2012

  • Li, Christina W.; Kanan, Matthew W.
  • Journal of the American Chemical Society, Vol. 134, Issue 17, p. 7231-7234
  • DOI: 10.1021/ja3010978

Electrochemical conversion of CO2 to useful chemicals: current status, remaining challenges, and future opportunities
journal, May 2013

  • Jhong, Huei-Ru “Molly”; Ma, Sichao; Kenis, Paul JA
  • Current Opinion in Chemical Engineering, Vol. 2, Issue 2
  • DOI: 10.1016/j.coche.2013.03.005

Rational Design of Efficient Palladium Catalysts for Electroreduction of Carbon Dioxide to Formate
journal, November 2016

Size-dependent lattice structure of palladium studied by x-ray absorption spectroscopy
journal, March 2007

High-rate electroreduction of carbon monoxide to multi-carbon products
journal, August 2018

Projector augmented-wave method
journal, December 1994

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996

Electrochemical CO2 Reduction on Metal Electrodes
book, January 2008

Switchable CO2 electroreduction via engineering active phases of Pd nanoparticles
journal, April 2017

Special points for Brillouin-zone integrations
journal, June 1976

  • Monkhorst, Hendrik J.; Pack, James D.
  • Physical Review B, Vol. 13, Issue 12, p. 5188-5192
  • DOI: 10.1103/PhysRevB.13.5188

Temperature- and Pressure-Dependent Hydrogen Concentration in Supported PdH x Nanoparticles by Pd K-Edge X-ray Absorption Spectroscopy
journal, May 2014

  • Bugaev, Aram L.; Guda, Alexander A.; Lomachenko, Kirill A.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 19
  • DOI: 10.1021/jp500734p

Ab initio molecular dynamics for open-shell transition metals
journal, November 1993

A selective and efficient electrocatalyst for carbon dioxide reduction
journal, January 2014

  • Lu, Qi; Rosen, Jonathan; Zhou, Yang
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4242

Boosting Formate Production in Electrocatalytic CO 2 Reduction over Wide Potential Window on Pd Surfaces
journal, February 2018

  • Jiang, Bei; Zhang, Xia-Guang; Jiang, Kun
  • Journal of the American Chemical Society, Vol. 140, Issue 8
  • DOI: 10.1021/jacs.7b12506

Forests, carbon and global climate
journal, June 2002

  • Malhi, Yadvinder; Meir, Patrick; Brown, Sandra
  • Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 360, Issue 1797
  • DOI: 10.1098/rsta.2002.1020

Inhomogeneous Electron Gas
journal, November 1964

Electrochemical reduction of CO 2 to synthesis gas with controlled CO/H 2 ratios
journal, January 2017

  • Sheng, Wenchao; Kattel, Shyam; Yao, Siyu
  • Energy & Environmental Science, Vol. 10, Issue 5
  • DOI: 10.1039/C7EE00071E

CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
journal, May 2018

Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO 2 to CO
journal, October 2013

  • Zhu, Wenlei; Michalsky, Ronald; Metin, Önder
  • Journal of the American Chemical Society, Vol. 135, Issue 45
  • DOI: 10.1021/ja409445p

Understanding of Strain Effects in the Electrochemical Reduction of CO 2 : Using Pd Nanostructures as an Ideal Platform
journal, February 2017

  • Huang, Hongwen; Jia, Huanhuan; Liu, Zhao
  • Angewandte Chemie International Edition, Vol. 56, Issue 13
  • DOI: 10.1002/anie.201612617

Accurate and simple analytic representation of the electron-gas correlation energy
journal, June 1992

Facet design promotes electroreduction of carbon dioxide to carbon monoxide on palladium nanocrystals
journal, February 2019

Palladium nanocrystals enclosed by {100} and {111} facets in controlled proportions and their catalytic activities for formic acid oxidation
journal, January 2012

  • Jin, Mingshang; Zhang, Hui; Xie, Zhaoxiong
  • Energy Environ. Sci., Vol. 5, Issue 4
  • DOI: 10.1039/C2EE02866B

journal, November 1985

  • Hori, Yoshio; Kikuchi, Katsuhei; Suzuki, Shin
  • Chemistry Letters, Vol. 14, Issue 11
  • DOI: 10.1246/cl.1985.1695

Surface and Subsurface Hydrogen:  Adsorption Properties on Transition Metals and Near-Surface Alloys
journal, March 2005

  • Greeley, Jeff; Mavrikakis, Manos
  • The Journal of Physical Chemistry B, Vol. 109, Issue 8
  • DOI: 10.1021/jp046540q

Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
journal, November 2004

  • Nørskov, J. K.; Rossmeisl, J.; Logadottir, A.
  • The Journal of Physical Chemistry B, Vol. 108, Issue 46
  • DOI: 10.1021/jp047349j

Technical photosynthesis involving CO2 electrolysis and fermentation
journal, January 2018

Pd-Containing Nanostructures for Electrochemical CO 2 Reduction Reaction
journal, January 2018

Synthesis of Pd nanocrystals enclosed by {100} facets and with sizes <10 nm for application in CO oxidation
journal, October 2010

Size-Dependent Electrocatalytic Reduction of CO 2 over Pd Nanoparticles
journal, March 2015

  • Gao, Dunfeng; Zhou, Hu; Wang, Jing
  • Journal of the American Chemical Society, Vol. 137, Issue 13
  • DOI: 10.1021/jacs.5b00046

Systematic Structure in the K -Edge Photoabsorption Spectra of the 4 d Transition Metals: Theory
journal, March 1978

Band-structure approach to the x-ray spectra of metals
journal, April 1984

Bifunctional alloys for the electroreduction of CO 2 and CO
journal, January 2016

  • Hansen, H. A.; Shi, C.; Lausche, A. C.
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 13
  • DOI: 10.1039/C5CP07717F

Steering post-C–C coupling selectivity enables high efficiency electroreduction of carbon dioxide to multi-carbon alcohols
journal, June 2018

Self-Consistent Equations Including Exchange and Correlation Effects
journal, November 1965

Ongoing climate change following a complete cessation of carbon dioxide emissions
journal, January 2011

  • Gillett, Nathan P.; Arora, Vivek K.; Zickfeld, Kirsten
  • Nature Geoscience, Vol. 4, Issue 2
  • DOI: 10.1038/ngeo1047