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Title: High-Rate Performance and Ultralong Cycle Life Enabled by Hybrid Organic-Inorganic Vanadyl Ethylene Glycolate for Lithium-Ion Batteries

Abstract

Transition metal oxides (TMOs) possess high theoretical capacity and serve as promising anode candidates for lithium-ion batteries. However, the intrinsic low conductivity handicaps the application of TMOs. Molecular modification by coupling TMOs structure with Li-ion conductive polymer ligands can facilitate the kinetics of electrochemical lithiation/delithiation process. Herein, a proof-of-concept investigation on the Li-ion storage capability by vanadyl ethylene glycolate (VEG) is achieved with the improvement of Li-ion diffusion kinetics by modifiying the vanadium oxide with organic ligands. In conclusion, VEG demonstrates unprecedented advantage for fast rate capability, stable cycleability, and high capacity at both room temperarture (25 °C) and elevated temperature (60 °C).

Authors:
 [1];  [2];  [1];  [1];  [1];  [3]; ORCiD logo [2]
  1. Chinese Academy of Sciences (CAS), Beijing (China)
  2. Argonne National Lab. (ANL), Lemont, IL (United States)
  3. Chinese Academy of Sciences (CAS), Beijing (China); Univ. of Chinese Academy of Sciences, Beijing (China)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1489780
Alternate Identifier(s):
OSTI ID: 1479538
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 8; Journal Issue: 33; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; hybrid electrodes; lithium-ion batteries; rate performance; vanadyl ethylene glycolate

Citation Formats

Wang, Xinran, Bi, Xuanxuan, Zheng, Shili, Wang, Shaona, Zhang, Yi, Du, Hao, and Lu, Jun. High-Rate Performance and Ultralong Cycle Life Enabled by Hybrid Organic-Inorganic Vanadyl Ethylene Glycolate for Lithium-Ion Batteries. United States: N. p., 2018. Web. doi:10.1002/aenm.201801978.
Wang, Xinran, Bi, Xuanxuan, Zheng, Shili, Wang, Shaona, Zhang, Yi, Du, Hao, & Lu, Jun. High-Rate Performance and Ultralong Cycle Life Enabled by Hybrid Organic-Inorganic Vanadyl Ethylene Glycolate for Lithium-Ion Batteries. United States. doi:10.1002/aenm.201801978.
Wang, Xinran, Bi, Xuanxuan, Zheng, Shili, Wang, Shaona, Zhang, Yi, Du, Hao, and Lu, Jun. Mon . "High-Rate Performance and Ultralong Cycle Life Enabled by Hybrid Organic-Inorganic Vanadyl Ethylene Glycolate for Lithium-Ion Batteries". United States. doi:10.1002/aenm.201801978. https://www.osti.gov/servlets/purl/1489780.
@article{osti_1489780,
title = {High-Rate Performance and Ultralong Cycle Life Enabled by Hybrid Organic-Inorganic Vanadyl Ethylene Glycolate for Lithium-Ion Batteries},
author = {Wang, Xinran and Bi, Xuanxuan and Zheng, Shili and Wang, Shaona and Zhang, Yi and Du, Hao and Lu, Jun},
abstractNote = {Transition metal oxides (TMOs) possess high theoretical capacity and serve as promising anode candidates for lithium-ion batteries. However, the intrinsic low conductivity handicaps the application of TMOs. Molecular modification by coupling TMOs structure with Li-ion conductive polymer ligands can facilitate the kinetics of electrochemical lithiation/delithiation process. Herein, a proof-of-concept investigation on the Li-ion storage capability by vanadyl ethylene glycolate (VEG) is achieved with the improvement of Li-ion diffusion kinetics by modifiying the vanadium oxide with organic ligands. In conclusion, VEG demonstrates unprecedented advantage for fast rate capability, stable cycleability, and high capacity at both room temperarture (25 °C) and elevated temperature (60 °C).},
doi = {10.1002/aenm.201801978},
journal = {Advanced Energy Materials},
number = 33,
volume = 8,
place = {United States},
year = {2018},
month = {10}
}

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Figures / Tables:

Figure 1 Figure 1: Scheme of vanadyl ethylene glycolate synthesis with enhanced bulk phase Li-ion conductivity: (a) one–pot solvothermal process from vanadium oxide (or vanadate) and ethylene glycol; (b) the molecular structure of vanadyl ethylene glycolate; and (c) the scheme of enhanced bulk phase Li-ion transfer through the ethylene glycol ligands, themore » overall chain flexibility and molecular thermal segmental mobility.« less

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