Novel manganese-promoted inverse CeO2/CuO catalyst: In situ characterization and activity for the water-gas shift reaction

Cámara, A. López; Corberán, V. Cortés; Martínez-Arias, A.; Barrio, L.; Si, R.; Hanson, J. C.; Rodriguez, Jose A.

doi:10.1016/j.cattod.2019.01.014

Title: Novel manganese-promoted inverse CeO₂/CuO catalyst: In situ characterization and activity for the water-gas shift reaction

Journal Article · 04 January 2019 · Catalysis Today

DOI: https://doi.org/10.1016/j.cattod.2019.01.014 · OSTI ID:1489744

Cámara, A. López ^[1];

^[1]; Martínez-Arias, A. ^[1]; Barrio, L. ^[2]; Si, R. ^[2];

^[2];

^[2]

Instituto de Catalisis y Petroleoquimica, CSIC, Madrid (Spain)
Brookhaven National Lab. (BNL), Upton, NY (United States)

In this study, the behavior of a novel manganese-promoted inverse CeO₂/CuO catalyst under water-gas shift (WGS) reaction conditions is studied. CeO₂/CuO and CeO₂/Mn-CuO catalysts are characterized by X-ray diffraction (XRD), Raman and X-ray photoelectron spectroscopy (XPS). Structure/activity relationships and redox characteristics are established on the basis of such results along with those of in situ XRD and X-ray absorption fine structure (XAFS) experiments performed either under WGS or CO-temperature programmed reduction (TPR) conditions. The manganese coprecipitated together with the copper during the preparation of the samples and the Mn-CuO phase strongly affected the size and chemical properties of the catalytically-active ceria nanoparticles. A manganese-induced enhancement on the WGS activity was observed. As a result, differences in the characteristics of the supported ceria particles are proposed as most relevant to explain the observed Mn-promoting effect.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: Ministerio de Economía, Industria y Competitividad; USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012704

OSTI ID:: 1489744

Report Number(s):: BNL--210847-2019-JAAM

Journal Information:: Catalysis Today, Journal Name: Catalysis Today Vol. 339; ISSN 0920-5861

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Novel manganese-promoted inverse CeO2/CuO catalyst: In situ characterization and activity for the water-gas shift reaction

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Title: Novel manganese-promoted inverse CeO₂/CuO catalyst: In situ characterization and activity for the water-gas shift reaction