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Title: Guest-Dependent Single-Crystal-to-Single-Crystal Phase Transitions in a Two-Dimensional Uranyl-Based Metal–Organic Framework

Abstract

Here, single-crystal-to-single-crystal phase transitions of a uranyl-based two-dimensional (2D) metal–organic frameworks, NU-1302, illustrated guest-dependent structural isomerism through shifting of neighboring 2D sheets, resulting in the expansion and contraction of one-dimensional channels.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Northwestern Univ., Evanston, IL (United States). International Institute for Nanotechnology and Dept. of Chemistry
Publication Date:
Research Org.:
Univ. of Notre Dame, IN (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1489653
Grant/Contract Number:  
NA0003763
Resource Type:
Accepted Manuscript
Journal Name:
Crystal Growth and Design
Additional Journal Information:
Journal Volume: 19; Journal Issue: 1; Journal ID: ISSN 1528-7483
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY; 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Hanna, Sylvia L., Zhang, Xuan, Otake, Ken-ichi, Drout, Riki J., Li, Peng, Islamoglu, Timur, and Farha, Omar K. Guest-Dependent Single-Crystal-to-Single-Crystal Phase Transitions in a Two-Dimensional Uranyl-Based Metal–Organic Framework. United States: N. p., 2018. Web. doi:10.1021/acs.cgd.8b01689.
Hanna, Sylvia L., Zhang, Xuan, Otake, Ken-ichi, Drout, Riki J., Li, Peng, Islamoglu, Timur, & Farha, Omar K. Guest-Dependent Single-Crystal-to-Single-Crystal Phase Transitions in a Two-Dimensional Uranyl-Based Metal–Organic Framework. United States. https://doi.org/10.1021/acs.cgd.8b01689
Hanna, Sylvia L., Zhang, Xuan, Otake, Ken-ichi, Drout, Riki J., Li, Peng, Islamoglu, Timur, and Farha, Omar K. Thu . "Guest-Dependent Single-Crystal-to-Single-Crystal Phase Transitions in a Two-Dimensional Uranyl-Based Metal–Organic Framework". United States. https://doi.org/10.1021/acs.cgd.8b01689. https://www.osti.gov/servlets/purl/1489653.
@article{osti_1489653,
title = {Guest-Dependent Single-Crystal-to-Single-Crystal Phase Transitions in a Two-Dimensional Uranyl-Based Metal–Organic Framework},
author = {Hanna, Sylvia L. and Zhang, Xuan and Otake, Ken-ichi and Drout, Riki J. and Li, Peng and Islamoglu, Timur and Farha, Omar K.},
abstractNote = {Here, single-crystal-to-single-crystal phase transitions of a uranyl-based two-dimensional (2D) metal–organic frameworks, NU-1302, illustrated guest-dependent structural isomerism through shifting of neighboring 2D sheets, resulting in the expansion and contraction of one-dimensional channels.},
doi = {10.1021/acs.cgd.8b01689},
journal = {Crystal Growth and Design},
number = 1,
volume = 19,
place = {United States},
year = {Thu Dec 20 00:00:00 EST 2018},
month = {Thu Dec 20 00:00:00 EST 2018}
}

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Works referenced in this record:

Introduction to Metal–Organic Frameworks
journal, September 2011

  • Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 673-674
  • DOI: 10.1021/cr300014x

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999

  • Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
  • Nature, Vol. 402, Issue 6759, p. 276-279
  • DOI: 10.1038/46248

Functional Porous Coordination Polymers
journal, April 2004

  • Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro
  • Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2334-2375
  • DOI: 10.1002/anie.200300610

Reticular synthesis and the design of new materials
journal, June 2003

  • Yaghi, Omar M.; O'Keeffe, Michael; Ockwig, Nathan W.
  • Nature, Vol. 423, Issue 6941, p. 705-714
  • DOI: 10.1038/nature01650

Bimetallic Metal–Organic Frameworks for Gas Storage and Separation
journal, March 2017


Metal–organic framework materials as catalysts
journal, January 2009

  • Lee, JeongYong; Farha, Omar K.; Roberts, John
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
  • DOI: 10.1039/b807080f

Metal–Organic Frameworks for Heterogeneous Basic Catalysis
journal, May 2017


Selective Surface and Near-Surface Modification of a Noncatenated, Catalytically Active Metal-Organic Framework Material Based on Mn(salen) Struts
journal, April 2011

  • Shultz, Abraham M.; Farha, Omar K.; Adhikari, Debashis
  • Inorganic Chemistry, Vol. 50, Issue 8
  • DOI: 10.1021/ic101952y

Magnetic ordering in TCNQ-based metal–organic frameworks with host–guest interactions
journal, January 2015

  • Zhang, Xuan; Saber, Mohamed R.; Prosvirin, Andrey P.
  • Inorganic Chemistry Frontiers, Vol. 2, Issue 10
  • DOI: 10.1039/C5QI00128E

Solid-State Molecular Nanomagnet Inclusion into a Magnetic Metal-Organic Framework: Interplay of the Magnetic Properties
journal, November 2015

  • Mon, Marta; Pascual-Álvarez, Alejandro; Grancha, Thais
  • Chemistry - A European Journal, Vol. 22, Issue 2
  • DOI: 10.1002/chem.201504176

Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011

  • Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
  • Chemical Reviews, Vol. 112, Issue 2, p. 724-781
  • DOI: 10.1021/cr2003272

Made-to-order metal-organic frameworks for trace carbon dioxide removal and air capture
journal, June 2014

  • Shekhah, Osama; Belmabkhout, Youssef; Chen, Zhijie
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5228

Water-stable metal-organic frameworks for aqueous removal of heavy metals and radionuclides: A review
journal, October 2018


Postsynthetic Methods for the Functionalization of Metal–Organic Frameworks
journal, September 2011

  • Cohen, Seth M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 970-1000
  • DOI: 10.1021/cr200179u

Postsynthetic Tuning of Metal–Organic Frameworks for Targeted Applications
journal, February 2017


Controlling flexibility of metal–organic frameworks
journal, October 2017

  • Zhang, Jie-Peng; Zhou, Hao-Long; Zhou, Dong-Dong
  • National Science Review, Vol. 5, Issue 6
  • DOI: 10.1093/nsr/nwx127

Shape-Memory Nanopores Induced in Coordination Frameworks by Crystal Downsizing
journal, January 2013


A Flexible Metal–Organic Framework with 4-Connected Zr 6 Nodes
journal, August 2018

  • Zhang, Yuanyuan; Zhang, Xuan; Lyu, Jiafei
  • Journal of the American Chemical Society, Vol. 140, Issue 36
  • DOI: 10.1021/jacs.8b06789

Exceptional Framework Flexibility and Sorption Behavior of a Multifunctional Porous Cuprous Triazolate Framework
journal, May 2008

  • Zhang, Jie-Peng; Chen, Xiao-Ming
  • Journal of the American Chemical Society, Vol. 130, Issue 18, p. 6010-6017
  • DOI: 10.1021/ja800550a

A Mesh-Adjustable Molecular Sieve for General Use in Gas Separation
journal, March 2007

  • Ma, Shengqian; Sun, Daofeng; Wang, Xi-Sen
  • Angewandte Chemie International Edition, Vol. 46, Issue 14
  • DOI: 10.1002/anie.200604353

Methane storage in flexible metal–organic frameworks with intrinsic thermal management
journal, October 2015

  • Mason, Jarad A.; Oktawiec, Julia; Taylor, Mercedes K.
  • Nature, Vol. 527, Issue 7578
  • DOI: 10.1038/nature15732

Electrically Induced Breathing of the MIL-53(Cr) Metal–Organic Framework
journal, April 2017


Crystal-to-Crystal Sliding of 2D Coordination Layers Triggered by Guest Exchange
journal, September 2002


A Redox-Active Two-Dimensional Coordination Polymer:  Preparation of Silver and Gold Nanoparticles and Crystal Dynamics on Guest Removal
journal, April 2006

  • Suh, Myunghyun Paik; Moon, Hoi Ri; Lee, Eun Young
  • Journal of the American Chemical Society, Vol. 128, Issue 14
  • DOI: 10.1021/ja056963l

Single-crystal X-ray diffraction studies on structural transformations of porous coordination polymers
journal, January 2014

  • Zhang, Jie-Peng; Liao, Pei-Qin; Zhou, Hao-Long
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00129J

Layer-sliding-driven crystal size and photoluminescence change in a novel SCC-MOF
journal, January 2018

  • Du, Xiang-Sha; Yan, Bing-Jie; Wang, Jia-Yin
  • Chemical Communications, Vol. 54, Issue 42
  • DOI: 10.1039/C8CC01559G

Flexible Mixed-Spin Kagomé Coordination Polymers with Reversible Magnetism Triggered by Dehydration and Rehydration
journal, January 2011

  • Zhang, Wei-Xiong; Xue, Wei; Chen, Xiao-Ming
  • Inorganic Chemistry, Vol. 50, Issue 1
  • DOI: 10.1021/ic101948q

U6+ Minerals and Inorganic Compounds: Insights into an Expanded Structural Hierarchy of Crystal Structures
journal, December 2005


Design and Synthesis of a Water-Stable Anionic Uranium-Based Metal-Organic Framework (MOF) with Ultra Large Pores
journal, July 2016

  • Li, Peng; Vermeulen, Nicolaas A.; Gong, Xirui
  • Angewandte Chemie International Edition, Vol. 55, Issue 35
  • DOI: 10.1002/anie.201605547

Bottom-up construction of a superstructure in a porous uranium-organic crystal
journal, April 2017

  • Li, Peng; Vermeulen, Nicolaas A.; Malliakas, Christos D.
  • Science, Vol. 356, Issue 6338
  • DOI: 10.1126/science.aam7851

Restricted Speciation and Supramolecular Assembly in the 5f Block
journal, July 2018

  • Carter, Korey P.; Surbella, Robert G.; Kalaj, Mark
  • Chemistry - A European Journal, Vol. 24, Issue 49
  • DOI: 10.1002/chem.201801044

Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species
journal, January 2017

  • Thuéry, Pierre; Harrowfield, Jack
  • Dalton Transactions, Vol. 46, Issue 40
  • DOI: 10.1039/C7DT03105J

The crystal chemistry of uranium carboxylates
journal, May 2014

  • Loiseau, Thierry; Mihalcea, Ionut; Henry, Natacha
  • Coordination Chemistry Reviews, Vol. 266-267
  • DOI: 10.1016/j.ccr.2013.08.038

Extended Structures and Physicochemical Properties of Uranyl–Organic Compounds
journal, July 2011

  • Wang, Kai-Xue; Chen, Jie-Sheng
  • Accounts of Chemical Research, Vol. 44, Issue 7
  • DOI: 10.1021/ar200042t

Mixed Formate-Dicarboxylate Coordination Polymers with Tetravalent Uranium: Occurrence of Tetranuclear {U 4 O 4 } and Hexanuclear {U 6 O 4 (OH) 4 } Motifs
journal, June 2013

  • Falaise, Clément; Volkringer, Christophe; Loiseau, Thierry
  • Crystal Growth & Design, Vol. 13, Issue 7
  • DOI: 10.1021/cg400643g

Use of Zwitterionic Ligands in Uranyl Hybrid Materials: Explorations on the Structural Features that Control Water Ordering and Mobility
journal, October 2017

  • Payne, Maurice K.; Laird, Rebecca C.; Schnell, Margaret A.
  • Crystal Growth & Design, Vol. 17, Issue 12
  • DOI: 10.1021/acs.cgd.7b01183

Network Dimensionality of Selected Uranyl(VI) Coordination Polymers and Octopus-like Uranium(IV) Clusters
journal, September 2017

  • Zehnder, Ralph A.; Boncella, James M.; Cross, Justin N.
  • Crystal Growth & Design, Vol. 17, Issue 10
  • DOI: 10.1021/acs.cgd.7b01165

Multifaceted Modularity: A Key for Stepwise Building of Hierarchical Complexity in Actinide Metal–Organic Frameworks
journal, November 2017

  • Dolgopolova, Ekaterina A.; Ejegbavwo, Otega A.; Martin, Corey R.
  • Journal of the American Chemical Society, Vol. 139, Issue 46
  • DOI: 10.1021/jacs.7b09496

An Anionic Uranium-Based Metal–Organic Framework with Ultralarge Nanocages for Selective Dye Adsorption
journal, January 2018


Preparation, Structures, and Photocatalytic Properties of Three New Uranyl−Organic Assembly Compounds
journal, June 2008

  • Liao, Zuo-Lei; Li, Guo-Dong; Bi, Ming-Hui
  • Inorganic Chemistry, Vol. 47, Issue 11
  • DOI: 10.1021/ic800109y

The influence of pressure on the structure of a 2D uranium(VI) carboxyphosphonoate compound
journal, October 2014

  • Spencer, Elinor C.; Ross, Nancy L.; Surbella, Robert G.
  • Journal of Solid State Chemistry, Vol. 218
  • DOI: 10.1016/j.jssc.2014.05.026

Impacts of oxo interactions within actinyl metal organic materials: highlight on thermal expansion behaviour
journal, January 2018

  • Payne, Maurice K.; Pyrch, Mikaela M.; Jubinsky, Matthew
  • Chemical Communications, Vol. 54, Issue 77
  • DOI: 10.1039/C8CC05240A

Supercritical Processing as a Route to High Internal Surface Areas and Permanent Microporosity in Metal−Organic Framework Materials
journal, January 2009

  • Nelson, Andrew P.; Farha, Omar K.; Mulfort, Karen L.
  • Journal of the American Chemical Society, Vol. 131, Issue 2, p. 458-460
  • DOI: 10.1021/ja808853q

SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8
  • DOI: 10.1107/S2053273314026370

Crystal structure refinement with SHELXL
journal, January 2015

  • Sheldrick, George M.
  • Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8
  • DOI: 10.1107/S2053229614024218

単結晶構造解析ソフトウェア(Yadokari‐XG 2009)の公開
journal, January 2009

  • Kabuto, Chizuko; Akine, Shigehisa; Nemoto, Takashi
  • Nihon Kessho Gakkaishi, Vol. 51, Issue 3
  • DOI: 10.5940/jcrsj.51.218

OLEX2 : a complete structure solution, refinement and analysis program
journal, January 2009

  • Dolomanov, Oleg V.; Bourhis, Luc J.; Gildea, Richard J.
  • Journal of Applied Crystallography, Vol. 42, Issue 2
  • DOI: 10.1107/S0021889808042726

Structure validation in chemical crystallography
journal, January 2009

  • Spek, Anthony L.
  • Acta Crystallographica Section D Biological Crystallography, Vol. 65, Issue 2, p. 148-155
  • DOI: 10.1107/S090744490804362X

A supermolecular building approach for the design and construction of metal–organic frameworks
journal, January 2014

  • Guillerm, Vincent; Kim, Dongwook; Eubank, Jarrod F.
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00135D

Molecular docking sites designed for the generation of highly crystalline covalent organic frameworks
journal, February 2016

  • Ascherl, Laura; Sick, Torben; Margraf, Johannes T.
  • Nature Chemistry, Vol. 8, Issue 4
  • DOI: 10.1038/nchem.2444

Flexibility in metal-organic framework materials: Impact on sorption properties
journal, August 2005

  • Fletcher, Ashleigh J.; Thomas, K. Mark; Rosseinsky, Matthew J.
  • Journal of Solid State Chemistry, Vol. 178, Issue 8
  • DOI: 10.1016/j.jssc.2005.05.019

On the breathing effect of a metal–organic framework upon CO2 adsorption: Monte Carlo compared to microcalorimetry experiments
journal, January 2007

  • Ramsahye, Naseem A.; Maurin, Guillaume; Bourrelly, Sandrine
  • Chemical Communications, Issue 31
  • DOI: 10.1039/b702986a

Opening the Gate: Framework Flexibility in ZIF-8 Explored by Experiments and Simulations
journal, June 2011

  • Fairen-Jimenez, D.; Moggach, S. A.; Wharmby, M. T.
  • Journal of the American Chemical Society, Vol. 133, Issue 23
  • DOI: 10.1021/ja202154j

Control over Flexibility of Entangled Porous Coordination Frameworks by Molecular and Mesoscopic Chemistries
journal, June 2013

  • Furukawa, Shuhei; Sakata, Yoko; Kitagawa, Susumu
  • Chemistry Letters, Vol. 42, Issue 6
  • DOI: 10.1246/cl.130357

Self-Accelerating CO Sorption in a Soft Nanoporous Crystal
journal, December 2013


Solvent- and Pressure-Induced Phase Changes in Two 3D Copper Glutarate-Based Metal–Organic Frameworks via Glutarate (+ gauche ⇄ − gauche ) Conformational Isomerism
journal, April 2017

  • Bezuidenhout, Charl X.; Smith, Vincent J.; Esterhuysen, Catharine
  • Journal of the American Chemical Society, Vol. 139, Issue 16
  • DOI: 10.1021/jacs.7b01764

Works referencing / citing this record:

Mechanical properties of metal–organic frameworks
journal, January 2019

  • Redfern, Louis R.; Farha, Omar K.
  • Chemical Science, Vol. 10, Issue 46
  • DOI: 10.1039/c9sc04249k

Two New Coordination Polymers with UO 2 2+ Units and Fluorinated Aromatic Carboxylate Linkers
journal, January 2020

  • Christoffels, Ronja; Ruschewitz, Uwe
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 646, Issue 3
  • DOI: 10.1002/zaac.201900302

H-Bonded and metal( ii )–organic architectures assembled from an unexplored aromatic tricarboxylic acid: structural variety and functional properties
journal, January 2020

  • Gu, Jin-Zhong; Wan, Shi-Mao; Kirillova, Marina V.
  • Dalton Transactions, Vol. 49, Issue 21
  • DOI: 10.1039/d0dt01261k

Zero-, mono- and diperiodic uranyl ion complexes with the diphenate dianion: influences of transition metal ion coordination and differential U VI chelation
journal, January 2020

  • Thuéry, Pierre; Atoini, Youssef; Harrowfield, Jack
  • Dalton Transactions, Vol. 49, Issue 3
  • DOI: 10.1039/c9dt04126e