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Title: Understanding ZIF-8 Performance upon Gas Adsorption by Means of Inelastic Neutron Scattering

Abstract

We present that despite the vast number of publication dealing with ZIF-8, the performance of this zeolitic MOF upon adsorption is still a matter of debate. The understanding of its adsorption properties its of great importance to define its potential in aplications such as gas separation, sensing and catalytic processes. Using inelastic neutron scattering (INS) upon exposure to different probe molecules we get further insight about the adsortion performance at cryogenic temperatures, including the possible swinging of the imidazolate linkers.

Authors:
 [1];  [1]; ORCiD logo [2];  [2]; ORCiD logo [2];  [1];  [1]; ORCiD logo [1]
  1. Universidad de Alicante, San Vicente del Raspeig (Spain)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1488727
Alternate Identifier(s):
OSTI ID: 1401315
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Chemistry Select
Additional Journal Information:
Journal Volume: 2; Journal Issue: 9; Journal ID: ISSN 2365-6549
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; breathing; flexibility; Inelastic Neutron Scattering; swinging; ZIF-8

Citation Formats

Casco, Mirian E., Fernández-Catalá, Javier, Cheng, Yongqiang, Daemen, Luke L., Ramirez-Cuesta, Anibal J., Cuadrado-Collados, Carlos, Silvestre-Albero, Joaquin, and Ramos-Fernandez, Enrique V. Understanding ZIF-8 Performance upon Gas Adsorption by Means of Inelastic Neutron Scattering. United States: N. p., 2017. Web. doi:10.1002/slct.201700250.
Casco, Mirian E., Fernández-Catalá, Javier, Cheng, Yongqiang, Daemen, Luke L., Ramirez-Cuesta, Anibal J., Cuadrado-Collados, Carlos, Silvestre-Albero, Joaquin, & Ramos-Fernandez, Enrique V. Understanding ZIF-8 Performance upon Gas Adsorption by Means of Inelastic Neutron Scattering. United States. doi:10.1002/slct.201700250.
Casco, Mirian E., Fernández-Catalá, Javier, Cheng, Yongqiang, Daemen, Luke L., Ramirez-Cuesta, Anibal J., Cuadrado-Collados, Carlos, Silvestre-Albero, Joaquin, and Ramos-Fernandez, Enrique V. Thu . "Understanding ZIF-8 Performance upon Gas Adsorption by Means of Inelastic Neutron Scattering". United States. doi:10.1002/slct.201700250. https://www.osti.gov/servlets/purl/1488727.
@article{osti_1488727,
title = {Understanding ZIF-8 Performance upon Gas Adsorption by Means of Inelastic Neutron Scattering},
author = {Casco, Mirian E. and Fernández-Catalá, Javier and Cheng, Yongqiang and Daemen, Luke L. and Ramirez-Cuesta, Anibal J. and Cuadrado-Collados, Carlos and Silvestre-Albero, Joaquin and Ramos-Fernandez, Enrique V.},
abstractNote = {We present that despite the vast number of publication dealing with ZIF-8, the performance of this zeolitic MOF upon adsorption is still a matter of debate. The understanding of its adsorption properties its of great importance to define its potential in aplications such as gas separation, sensing and catalytic processes. Using inelastic neutron scattering (INS) upon exposure to different probe molecules we get further insight about the adsortion performance at cryogenic temperatures, including the possible swinging of the imidazolate linkers.},
doi = {10.1002/slct.201700250},
journal = {Chemistry Select},
number = 9,
volume = 2,
place = {United States},
year = {2017},
month = {3}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 4 works
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Figures / Tables:

Figure 1. Figure 1.: Adsorption isotherms of different gases at 77K in ZIF-8.

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