What makes a material printable? A viscoelastic model for extrusion-based 3D printing of polymers
Abstract
This paper presents a practical model for evaluating polymer feedstock materials as candidates for 3D printing across a variety of extrusion-based platforms. In order for a material to be successfully utilized for 3D printing operations, a series of fundamental conditions must be met. First, pressure-driven extrusion must occur through a given diameter nozzle at a specified flow rate. Second, the extruded material must form and sustain the desired shape. Third, the extruded structure must be able to bridge a specified gap and serve as a mechanically sound foundation for successive deposits. Finally, the deposited structure must be dimensionally stable during the transition to the final state (i.e. fully cured at room temperature). This article presents a framework for extrusion-based printing and a simple viscoelastic model for each of these conditions based on the rheological and thermo-physical properties of the candidate material and the processing parameters of the extrusion-based deposition platform. The model is demonstrated to be a useful tool for the evaluation of example test cases including: high temperature thermoplastics (polyphenylsulfone), fiber reinforced thermoplastics (acrylonitrile butadiene styrene), low-viscosity thermosets (epoxy resins), and thermoplastics with a high coefficient of thermal expansion (polypropylene).
- Authors:
-
- Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Manufacturing Demonstration Facility
- Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Manufacturing Demonstration Facility; Purdue Univ., West Lafayette, IN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1488709
- Alternate Identifier(s):
- OSTI ID: 1637097
- Grant/Contract Number:
- AC05-00OR22725; AC05-00OR22725 with UT-Battelle
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Manufacturing Processes
- Additional Journal Information:
- Journal Volume: 35; Journal Issue: C; Journal ID: ISSN 1526-6125
- Publisher:
- Society of Manufacturing Engineers; Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 3D printing; Extrusion; Fused filament fabrication (FFF); Thermoplastic polymers; Viscoelastic model
Citation Formats
Duty, Chad E., Ajinjeru, Christine, Kishore, Vidya, Compton, Brett G., Hmeidat, Nadim, Chen, Xun, Liu, Peng, Hassen, Ahmed A., Lindahl, John M., and Kunc, Vlastimil. What makes a material printable? A viscoelastic model for extrusion-based 3D printing of polymers. United States: N. p., 2018.
Web. doi:10.1016/j.jmapro.2018.08.008.
Duty, Chad E., Ajinjeru, Christine, Kishore, Vidya, Compton, Brett G., Hmeidat, Nadim, Chen, Xun, Liu, Peng, Hassen, Ahmed A., Lindahl, John M., & Kunc, Vlastimil. What makes a material printable? A viscoelastic model for extrusion-based 3D printing of polymers. United States. https://doi.org/10.1016/j.jmapro.2018.08.008
Duty, Chad E., Ajinjeru, Christine, Kishore, Vidya, Compton, Brett G., Hmeidat, Nadim, Chen, Xun, Liu, Peng, Hassen, Ahmed A., Lindahl, John M., and Kunc, Vlastimil. Thu .
"What makes a material printable? A viscoelastic model for extrusion-based 3D printing of polymers". United States. https://doi.org/10.1016/j.jmapro.2018.08.008. https://www.osti.gov/servlets/purl/1488709.
@article{osti_1488709,
title = {What makes a material printable? A viscoelastic model for extrusion-based 3D printing of polymers},
author = {Duty, Chad E. and Ajinjeru, Christine and Kishore, Vidya and Compton, Brett G. and Hmeidat, Nadim and Chen, Xun and Liu, Peng and Hassen, Ahmed A. and Lindahl, John M. and Kunc, Vlastimil},
abstractNote = {This paper presents a practical model for evaluating polymer feedstock materials as candidates for 3D printing across a variety of extrusion-based platforms. In order for a material to be successfully utilized for 3D printing operations, a series of fundamental conditions must be met. First, pressure-driven extrusion must occur through a given diameter nozzle at a specified flow rate. Second, the extruded material must form and sustain the desired shape. Third, the extruded structure must be able to bridge a specified gap and serve as a mechanically sound foundation for successive deposits. Finally, the deposited structure must be dimensionally stable during the transition to the final state (i.e. fully cured at room temperature). This article presents a framework for extrusion-based printing and a simple viscoelastic model for each of these conditions based on the rheological and thermo-physical properties of the candidate material and the processing parameters of the extrusion-based deposition platform. The model is demonstrated to be a useful tool for the evaluation of example test cases including: high temperature thermoplastics (polyphenylsulfone), fiber reinforced thermoplastics (acrylonitrile butadiene styrene), low-viscosity thermosets (epoxy resins), and thermoplastics with a high coefficient of thermal expansion (polypropylene).},
doi = {10.1016/j.jmapro.2018.08.008},
journal = {Journal of Manufacturing Processes},
number = C,
volume = 35,
place = {United States},
year = {Thu Sep 13 00:00:00 EDT 2018},
month = {Thu Sep 13 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
The importance of carbon fiber to polymer additive manufacturing
journal, September 2014
- Love, Lonnie J.; Kunc, Vlastamil; Rios, Orlando
- Journal of Materials Research, Vol. 29, Issue 17
Structure and mechanical behavior of Big Area Additive Manufacturing (BAAM) materials
journal, January 2017
- Duty, Chad E.; Kunc, Vlastimil; Compton, Brett
- Rapid Prototyping Journal, Vol. 23, Issue 1
Highly oriented carbon fiber–polymer composites via additive manufacturing
journal, December 2014
- Tekinalp, Halil L.; Kunc, Vlastimil; Velez-Garcia, Gregorio M.
- Composites Science and Technology, Vol. 105
High-strength epoxy nanocomposites for 3D printing
journal, May 2018
- Hmeidat, Nadim S.; Kemp, James W.; Compton, Brett G.
- Composites Science and Technology, Vol. 160
Electrical and Mechanical Properties of 3D-Printed Graphene-Reinforced Epoxy
journal, December 2017
- Compton, Brett G.; Hmeidat, Nadim S.; Pack, Robert C.
- JOM, Vol. 70, Issue 3
3D printing via ambient reactive extrusion
journal, June 2018
- Rios, Orlando; Carter, William; Post, Brian
- Materials Today Communications, Vol. 15
Extrusion Freeform Fabrication of Chopped-Fibre Reinforced Composites
journal, December 1997
- Calvert, Paul; Lin, Tung Liang; Martin, Hogan
- High Performance Polymers, Vol. 9, Issue 4
3D-Printing of Lightweight Cellular Composites
journal, June 2014
- Compton, Brett G.; Lewis, Jennifer A.
- Advanced Materials, Vol. 26, Issue 34, p. 5930-5935
Three-Dimensional Printing of Elastomeric, Cellular Architectures with Negative Stiffness
journal, May 2014
- Duoss, Eric B.; Weisgraber, Todd H.; Hearon, Keith
- Advanced Functional Materials, Vol. 24, Issue 31
Deposition of ordered two-phase materials using microfluidic print nozzles with acoustic focusing
journal, September 2016
- Collino, Rachel R.; Ray, Tyler R.; Fleming, Rachel C.
- Extreme Mechanics Letters, Vol. 8
Microfluidic Printheads for Multimaterial 3D Printing of Viscoelastic Inks
journal, April 2015
- Hardin, James O.; Ober, Thomas J.; Valentine, Alexander D.
- Advanced Materials, Vol. 27, Issue 21
Photocurable Liquid Core-Fugitive Shell Printing of Optical Waveguides
journal, October 2011
- Lorang, David J.; Tanaka, Douglas; Spadaccini, Christopher M.
- Advanced Materials, Vol. 23, Issue 43
Active mixing of complex fluids at the microscale
journal, September 2015
- Ober, Thomas J.; Foresti, Daniele; Lewis, Jennifer A.
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 40
Liquefier Dynamics in Fused Deposition
journal, May 2004
- Bellini, Anna; Gu¨c¸eri, Selc¸uk; Bertoldi, Maurizio
- Journal of Manufacturing Science and Engineering, Vol. 126, Issue 2
A review of melt extrusion additive manufacturing processes: I. Process design and modeling
journal, April 2014
- N. Turner, Brian; Strong, Robert; A. Gold, Scott
- Rapid Prototyping Journal, Vol. 20, Issue 3
Melt flow behaviour of poly-ε-caprolactone in fused deposition modelling
journal, July 2007
- Ramanath, H. S.; Chua, C. K.; Leong, K. F.
- Journal of Materials Science: Materials in Medicine, Vol. 19, Issue 7
Modeling of Bond Formation Between Polymer Filaments in the Fused Deposition Modeling Process
journal, January 2004
- Bellehumeur, Céline; Li, Longmei; Sun, Qian
- Journal of Manufacturing Processes, Vol. 6, Issue 2
Effect of processing conditions on the bonding quality of FDM polymer filaments
journal, March 2008
- Sun, Q.; Rizvi, G. M.; Bellehumeur, C. T.
- Rapid Prototyping Journal, Vol. 14, Issue 2
Evaluation and prediction of the tensile properties of continuous fiber-reinforced 3D printed structures
journal, October 2016
- Melenka, Garrett W.; Cheung, Benjamin K. O.; Schofield, Jonathon S.
- Composite Structures, Vol. 153
Feedstock material property – process relationships in fused deposition of ceramics (FDC)
journal, December 2000
- Venkataraman, N.; Rangarajan, S.; Matthewson, M. J.
- Rapid Prototyping Journal, Vol. 6, Issue 4
Predicting molding forces in SMC compression molding
journal, December 1990
- Castro, J. M.; Tomlinson, G.
- Polymer Engineering and Science, Vol. 30, Issue 24
A model research for prototype warp deformation in the FDM process
journal, April 2006
- Wang, Tian-Ming; Xi, Jun-Tong; Jin, Ye
- The International Journal of Advanced Manufacturing Technology, Vol. 33, Issue 11-12
Works referencing / citing this record:
The influence of dynamic rheological properties on carbon fiber-reinforced polyetherimide for large-scale extrusion-based additive manufacturing
journal, August 2018
- Ajinjeru, Christine; Kishore, Vidya; Lindahl, John
- The International Journal of Advanced Manufacturing Technology, Vol. 99, Issue 1-4
Semi‐Crystalline Polymer Blends for Material Extrusion Additive Manufacturing Printability: A Case Study with Poly(ethylene terephthalate) and Polypropylene
journal, February 2019
- Chatham, Camden A.; Zawaski, Callie E.; Bobbitt, Daniel C.
- Macromolecular Materials and Engineering, Vol. 304, Issue 5
Material extrusion‐based additive manufacturing of polypropylene: A review on how to improve dimensional inaccuracy and warpage
journal, October 2019
- Spoerk, Martin; Holzer, Clemens; Gonzalez‐Gutierrez, Joamin
- Journal of Applied Polymer Science, Vol. 137, Issue 12
Rheological survey of carbon fiber-reinforced high-temperature thermoplastics for big area additive manufacturing tooling applications
journal, September 2019
- Ajinjeru, Christine; Kishore, Vidya; Chen, Xun
- Journal of Thermoplastic Composite Materials
Nondegradative additive manufacturing of medical grade copolyesters of high molecular weight and with varied elastic response
journal, October 2019
- Ahlinder, Astrid; Fuoco, Tiziana; Morales‐López, Álvaro
- Journal of Applied Polymer Science, Vol. 137, Issue 15
Dimensional Accuracy and Mechanical Properties of Chopped Carbon Reinforced Polymers Produced by Material Extrusion Additive Manufacturing
journal, November 2019
- Yasa, Evren; Ersoy, Kıvılcım
- Materials, Vol. 12, Issue 23