Rational Design of Statically and Dynamically Stable Lithium-Sulfur Batteries with High Sulfur Loading and Low Electrolyte/Sulfur Ratio

Chung, Sheng -Heng; Manthiram, Arumugam

doi:10.1002/adma.201705951

Title: Rational Design of Statically and Dynamically Stable Lithium-Sulfur Batteries with High Sulfur Loading and Low Electrolyte/Sulfur Ratio

Journal Article · 22 December 2017 · Advanced Materials

DOI: https://doi.org/10.1002/adma.201705951 · OSTI ID:1488238

Chung, Sheng -Heng ^[1];

^[1]

Univ. of Texas at Austin, Austin, TX (United States)

Abstract The primary challenge with lithium–sulfur battery research is the design of sulfur cathodes that exhibit high electrochemical efficiency and stability while keeping the sulfur content and loading high and the electrolyte/sulfur ratio low. With a systematic investigation, a novel graphene/cotton‐carbon cathode is presented here that enables sulfur loading and content as high as 46 mg cm ⁻² and 70 wt% with an electrolyte/sulfur ratio of as low as only 5. The graphene/cotton‐carbon cathodes deliver peak capacities of 926 and 765 mA h g ⁻¹ , respectively, at C/10 and C/5 rates, which translate into high areal, gravimetric, and volumetric capacities of, respectively, 43 and 35 mA h cm ⁻² , 648 and 536 mA h g ⁻¹ , and 1067 and 881 mA h cm ⁻³ with a stable cyclability. They also exhibit superior cell‐storage capability with 95% capacity‐retention, a low self‐discharge constant of just 0.0012 per day, and stable poststorage cyclability after storing over a long period of six months. This work demonstrates a viable approach to develop lithium–sulfur batteries with practical energy densities exceeding that of lithium‐ion batteries.

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Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0007218; DE‐EE0007218

OSTI ID:: 1488238

Alternate ID(s):: OSTI ID: 1414806

Journal Information:: Advanced Materials, Vol. 30, Issue 6; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 151 works

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low self‐discharge

Title: Rational Design of Statically and Dynamically Stable Lithium-Sulfur Batteries with High Sulfur Loading and Low Electrolyte/Sulfur Ratio

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