skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Dichotomy between frustrated local spins and conjugated electrons in a two-dimensional metal–organic framework

Abstract

Dichotomy between local spins and conjugated electrons spawns various exotic physical phenomena. We discover a 2D MOF dichotomy system and propose to characterize the exotic electronic states using STM.

Authors:
ORCiD logo [1];  [2];  [3]; ORCiD logo [4];  [5]
  1. Department of Materials Science and Engineering, University of Utah, Salt Lake City, USA, Department of Electrical and Computer Engineering
  2. Institute for Advanced Study, Tsinghua University, Beijing 100084, China
  3. Institute for Quantum Science and Engineering, and Department of Physics, Southern University of Science and Technology, Shenzhen 518055, China
  4. School of physics, Shandong University, Jinan 250100, China
  5. Department of Materials Science and Engineering, University of Utah, Salt Lake City, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1487170
Grant/Contract Number:  
FG02-04ER46148
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Nanoscale
Additional Journal Information:
Journal Name: Nanoscale Journal Volume: 11 Journal Issue: 3; Journal ID: ISSN 2040-3364
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Jiang, Wei, Liu, Zheng, Mei, Jia-Wei, Cui, Bin, and Liu, Feng. Dichotomy between frustrated local spins and conjugated electrons in a two-dimensional metal–organic framework. United Kingdom: N. p., 2019. Web. doi:10.1039/C8NR08479C.
Jiang, Wei, Liu, Zheng, Mei, Jia-Wei, Cui, Bin, & Liu, Feng. Dichotomy between frustrated local spins and conjugated electrons in a two-dimensional metal–organic framework. United Kingdom. doi:10.1039/C8NR08479C.
Jiang, Wei, Liu, Zheng, Mei, Jia-Wei, Cui, Bin, and Liu, Feng. Thu . "Dichotomy between frustrated local spins and conjugated electrons in a two-dimensional metal–organic framework". United Kingdom. doi:10.1039/C8NR08479C.
@article{osti_1487170,
title = {Dichotomy between frustrated local spins and conjugated electrons in a two-dimensional metal–organic framework},
author = {Jiang, Wei and Liu, Zheng and Mei, Jia-Wei and Cui, Bin and Liu, Feng},
abstractNote = {Dichotomy between local spins and conjugated electrons spawns various exotic physical phenomena. We discover a 2D MOF dichotomy system and propose to characterize the exotic electronic states using STM.},
doi = {10.1039/C8NR08479C},
journal = {Nanoscale},
number = 3,
volume = 11,
place = {United Kingdom},
year = {2019},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8NR08479C

Citation Metrics:
Cited by: 8 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Redox Control and High Conductivity of Nickel Bis(dithiolene) Complex π-Nanosheet: A Potential Organic Two-Dimensional Topological Insulator
journal, October 2014

  • Kambe, Tetsuya; Sakamoto, Ryota; Kusamoto, Tetsuro
  • Journal of the American Chemical Society, Vol. 136, Issue 41
  • DOI: 10.1021/ja507619d

Template-directed supramolecular self-assembly of coordination dumbbells at surfaces
journal, January 2007

  • Lin, Nian; Langner, Alexander; Tait, Steven L.
  • Chemical Communications, Issue 46
  • DOI: 10.1039/b712082f

Tuning interfacial spin filters from metallic to resistive within a single organic semiconductor family
journal, June 2017


Metal–organic framework materials as catalysts
journal, January 2009

  • Lee, JeongYong; Farha, Omar K.; Roberts, John
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
  • DOI: 10.1039/b807080f

Prediction of large gap flat Chern band in a two-dimensional metal-organic framework
journal, January 2018

  • Su, Ninghai; Jiang, Wei; Wang, Zhengfei
  • Applied Physics Letters, Vol. 112, Issue 3
  • DOI: 10.1063/1.5017956

First-principles design of a half-filled flat band of the kagome lattice in two-dimensional metal-organic frameworks
journal, August 2016


High Electrical Conductivity in Ni 3 (2,3,6,7,10,11-hexaiminotriphenylene) 2 , a Semiconducting Metal–Organic Graphene Analogue
journal, April 2014

  • Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A.
  • Journal of the American Chemical Society, Vol. 136, Issue 25
  • DOI: 10.1021/ja502765n

Hydrogen storage in metal–organic frameworks
journal, January 2009

  • Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R.
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314
  • DOI: 10.1039/b802256a

Oxidation-promoted Interfacial Synthesis of Redox-active Bis(diimino)nickel Nanosheet
journal, February 2018

  • Phua, Eunice J. H.; Wu, Kuo-Hui; Wada, Keisuke
  • Chemistry Letters, Vol. 47, Issue 2
  • DOI: 10.1246/cl.170928

CMR manganites: physics, thin films and devices
journal, April 2003


Introduction to Metal–Organic Frameworks
journal, September 2011

  • Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 673-674
  • DOI: 10.1021/cr300014x

Hexaaminobenzene as a building block for a Family of 2D Coordination Polymers
journal, December 2016

  • Lahiri, Nabajit; Lotfizadeh, Neda; Tsuchikawa, Ryuichi
  • Journal of the American Chemical Society, Vol. 139, Issue 1
  • DOI: 10.1021/jacs.6b09889

Stability of the Spontaneous Quantum Hall State in the Triangular Kondo-Lattice Model
journal, December 2010


Insulator-metal transition and giant magnetoresistance in La 1 x Sr x MnO 3
journal, May 1995


Resistance Minimum in Dilute Magnetic Alloys
journal, July 1964

  • Kondo, J.
  • Progress of Theoretical Physics, Vol. 32, Issue 1, p. 37-49
  • DOI: 10.1143/PTP.32.37

Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009

  • Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504
  • DOI: 10.1039/b802426j

Beyond post-synthesis modification: evolution of metal–organic frameworks via building block replacement
journal, January 2014

  • Deria, Pravas; Mondloch, Joseph E.; Karagiaridi, Olga
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00067F

Spin-polarized scanning tunnelling microscopy
journal, March 2003


Current-Induced Magnetization Switching with a Spin-Polarized Scanning Tunneling Microscope
journal, September 2007


Iron pnictides as a new setting for quantum criticality
journal, March 2009

  • Dai, J.; Si, Q.; Zhu, J. -X.
  • Proceedings of the National Academy of Sciences, Vol. 106, Issue 11
  • DOI: 10.1073/pnas.0900886106

Li doped kagome spin liquid compounds
journal, January 2018

  • Jiang, Wei; Huang, Huaqing; Mei, Jia-Wei
  • Physical Chemistry Chemical Physics, Vol. 20, Issue 33
  • DOI: 10.1039/C8CP03219J

Assembling Isostructural Metal-Organic Coordination Architectures on Cu(100), Ag(100) and Ag(111) Substrates
journal, December 2008


π-Conjugated Nickel Bis(dithiolene) Complex Nanosheet
journal, February 2013

  • Kambe, Tetsuya; Sakamoto, Ryota; Hoshiko, Ken
  • Journal of the American Chemical Society, Vol. 135, Issue 7
  • DOI: 10.1021/ja312380b

Prediction of two-dimensional nodal-line semimetals in a carbon nitride covalent network
journal, January 2018

  • Chen, Haiyuan; Zhang, Shunhong; Jiang, Wei
  • Journal of Materials Chemistry A, Vol. 6, Issue 24
  • DOI: 10.1039/C8TA02555J

Intrinsic quantum anomalous hall effect in a two-dimensional anilato-based lattice
journal, January 2018

  • Ni, Xiaojuan; Jiang, Wei; Huang, Huaqing
  • Nanoscale, Vol. 10, Issue 25
  • DOI: 10.1039/C8NR02651C

Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
journal, September 2011

  • O’Keeffe, Michael; Yaghi, Omar M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 675-702
  • DOI: 10.1021/cr200205j

Electronic Structure of Bis( o -iminobenzosemiquinonato)metal Complexes (Cu, Ni, Pd). The Art of Establishing Physical Oxidation States in Transition-Metal Complexes Containing Radical Ligands
journal, March 2001

  • Chaudhuri, Phalguni; Verani, Claudio Nazari; Bill, Eckhard
  • Journal of the American Chemical Society, Vol. 123, Issue 10
  • DOI: 10.1021/ja003831d

High-throughput computational screening of metal–organic frameworks
journal, January 2014

  • Colón, Yamil J.; Snurr, Randall Q.
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00070F

Giant magnetoresistance of manganese oxides with a layered perovskite structure
journal, March 1996

  • Moritomo, Y.; Asamitsu, A.; Kuwahara, H.
  • Nature, Vol. 380, Issue 6570
  • DOI: 10.1038/380141a0

Flat Chern Band in a Two-Dimensional Organometallic Framework
journal, March 2013


A Theory for a Self-Trapped Antiferromagnetic Polaron at T =0 K
journal, September 1972

  • Umehara, Masakatu; Kasuya, Tadao
  • Journal of the Physical Society of Japan, Vol. 33, Issue 3
  • DOI: 10.1143/JPSJ.33.602

Possible highT c superconductivity in the Ba?La?Cu?O system
journal, June 1986

  • Bednorz, J. G.; M�ller, K. A.
  • Zeitschrift f�r Physik B Condensed Matter, Vol. 64, Issue 2
  • DOI: 10.1007/BF01303701

Localized Magnetic States in Metals
journal, October 1961


Phase diagram of the Kondo lattice model on the kagome lattice
journal, January 2016


Tailoring molecular layers at metal surfaces
journal, January 2010


Luttinger-volume violating Fermi liquid in the pseudogap phase of the cuprate superconductors
journal, April 2012


Cu 3 (hexaiminotriphenylene) 2 : An Electrically Conductive 2D Metal-Organic Framework for Chemiresistive Sensing
journal, February 2015

  • Campbell, Michael G.; Sheberla, Dennis; Liu, Sophie F.
  • Angewandte Chemie International Edition, Vol. 54, Issue 14
  • DOI: 10.1002/anie.201411854

Giant Magnetoresistance and Related Properties of Rare-Earth Manganates and Other Oxide Systems
journal, January 1996

  • Rao, C. N. R.; Cheetham, A. K.; Mahesh, R.
  • Chemistry of Materials, Vol. 8, Issue 10
  • DOI: 10.1021/cm960201v

4 f -Virtual-Bound-State Formation in Ce Al 3 at Low Temperatures
journal, December 1975


Weak magnetism and non-Fermi liquids near heavy-fermion critical points
journal, January 2004


Polaron coherence condensation as the mechanism for colossal magnetoresistance in layered manganites
journal, December 2007


Two-Dimensional Band Structure in Honeycomb Metal–Organic Frameworks
journal, August 2018


Hidden Multiple-Spin Interactions as an Origin of Spin Scalar Chiral Order in Frustrated Kondo Lattice Models
journal, February 2012


Doping a Mott insulator: Physics of high-temperature superconductivity
journal, January 2006

  • Lee, Patrick A.; Nagaosa, Naoto; Wen, Xiao-Gang
  • Reviews of Modern Physics, Vol. 78, Issue 1
  • DOI: 10.1103/RevModPhys.78.17

Cation exchange at the secondary building units of metal–organic frameworks
journal, January 2014


Prediction of a Two-Dimensional Organic Topological Insulator
journal, May 2013

  • Wang, Z. F.; Su, Ninghai; Liu, Feng
  • Nano Letters, Vol. 13, Issue 6, p. 2842-2845
  • DOI: 10.1021/nl401147u

Signature of Metallic Behavior in the Metal–Organic Frameworks M 3 (hexaiminobenzene) 2 (M = Ni, Cu)
journal, September 2017

  • Dou, Jin-Hu; Sun, Lei; Ge, Yicong
  • Journal of the American Chemical Society, Vol. 139, Issue 39
  • DOI: 10.1021/jacs.7b07234

EuTe. I. Magnetic Behavior of Insulating and Conducting Single Crystals
journal, April 1972


Stability condition for the paramagnetic polaron in a magnetic semiconductor
journal, October 1970


Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites
journal, September 2011

  • Stock, Norbert; Biswas, Shyam
  • Chemical Reviews, Vol. 112, Issue 2
  • DOI: 10.1021/cr200304e

Bis(aminothiolato)nickel nanosheet as a redox switch for conductivity and an electrocatalyst for the hydrogen evolution reaction
journal, January 2017

  • Sun, Xinsen; Wu, Kuo-Hui; Sakamoto, Ryota
  • Chemical Science, Vol. 8, Issue 12
  • DOI: 10.1039/C7SC02688A

Flat Bands and Wigner Crystallization in the Honeycomb Optical Lattice
journal, August 2007


Theoretical Evidence for the Singlet Diradical Character of Square Planar Nickel Complexes Containing Two o -Semiquinonato Type Ligands
journal, August 2002

  • Bachler, Vinzenz; Olbrich, Gottfried; Neese, Frank
  • Inorganic Chemistry, Vol. 41, Issue 16
  • DOI: 10.1021/ic0113101