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Title: Predicting High-Temperature Decomposition of Lithiated Graphite: Part II. Passivation Layer Evolution and the Role of Surface Area

Journal Article · · Journal of the Electrochemical Society

Not Available

Sponsoring Organization:
USDOE Office of Electricity (OE)
OSTI ID:
1487160
Alternate ID(s):
OSTI ID: 1492378; OSTI ID: 1492379
Journal Information:
Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 16 Vol. 165; ISSN 0013-4651
Publisher:
The Electrochemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (52)

Studies of Li and Mn-Rich Li x [MnNiCo]O 2 Electrodes: Electrochemical Performance, Structure, and the Effect of the Aluminum Fluoride Coating journal January 2013
Thermal abuse performance of high-power 18650 Li-ion cells journal April 2004
Lithium Ion Battery Safety journal January 2012
A Mathematical Model for the Lithium-Ion Negative Electrode Solid Electrolyte Interphase journal January 2004
Recent studies of the lithium-liquid electrolyte interface Electrochemical, morphological and spectral studies of a few important systems journal March 1995
Thermal Model of Cylindrical and Prismatic Lithium-Ion Cells journal January 2001
A Comparison Between the High Temperature Electrode /Electrolyte Reactions of Li[sub x]CoO[sub 2] and Li[sub x]Mn[sub 2]O[sub 4] journal January 2001
Assessment of Surface Heterogeneity: a Route to Correlate and Quantify the 1st Cycle Irreversible Capacity Caused by SEI Formation to the Various Surfaces of Graphite Anodes for Lithium Ion Cells journal January 2015
Effects of solvents and salts on the thermal stability of LiC6 journal October 2004
The Reaction of Charged Cathodes with Nonaqueous Solvents and Electrolytes: I. Li[sub 0.5]CoO[sub 2] journal January 2001
Solubility of Lithium Salts Formed on the Lithium-Ion Battery Negative Electrode Surface in Organic Solvents journal January 2009
The formation and stability of the solid electrolyte interface on the graphite anode journal December 2014
Comparison of the Thermal Stability of Lithiated Graphite in LiBOB EC/DEC and in LiPF[sub 6] EC/DEC journal January 2003
An Investigation of the Effect of Graphite Degradation on Irreversible Capacity in Lithium-ion Cells journal January 2008
Revealing SEI Morphology: In-Depth Analysis of a Modeling Approach journal January 2017
Predicting High-Temperature Decomposition of Lithiated Graphite: Part I. Review of Phenomena and a Comprehensive Model journal January 2018
Connecting the irreversible capacity loss in Li-ion batteries with the electronic insulating properties of solid electrolyte interphase (SEI) components journal March 2016
Comparison of the Reactivity of Various Carbon Electrode Materials with Electrolyte at Elevated Temperature journal January 1999
Challenges in the development of advanced Li-ion batteries: a review journal January 2011
Effect of ionic composition on thermal properties of energetic ionic liquids journal May 2018
An Autocatalytic Mechanism for the Reaction of Li[sub x]CoO[sub 2] in Electrolyte at Elevated Temperature journal January 2000
Influence of graphite surface modifications on the ratio of basal plane to “non-basal plane” surface area and on the anode performance in lithium ion batteries journal February 2012
Differential Scanning Calorimetry Study of the Reactivity of Carbon Anodes in Plastic Li-Ion Batteries journal January 1998
Modeling detailed chemistry and transport for solid-electrolyte-interface (SEI) films in Li–ion batteries journal December 2011
Effects of particle size on the thermal stability of lithiated graphite anode journal April 2009
Thermal stability of LiPF6/EC+DEC electrolyte with charged electrodes for lithium ion batteries journal October 2005
Review—SEI: Past, Present and Future journal January 2017
High-voltage positive electrode materials for lithium-ion batteries journal January 2017
Solvent Diffusion Model for Aging of Lithium-Ion Battery Cells journal January 2004
Simulation of Abuse Behavior of Lithium-Ion Batteries journal January 2012
Edge/basal/defect ratios in graphite and their influence on the thermal stability of lithium ion batteries journal June 2016
Accelerating Rate Calorimetry Study on the Thermal Stability of Lithium Intercalated Graphite in Electrolyte. I. Experimental journal June 1999
Computational Exploration of the Li-Electrode|Electrolyte Interface in the Presence of a Nanometer Thick Solid-Electrolyte Interphase Layer journal September 2016
A three-dimensional thermal abuse model for lithium-ion cells journal July 2007
Test of Reaction Kinetics Using Both Differential Scanning and Accelerating Rate Calorimetries As Applied to the Reaction of Li x CoO 2 in Non-aqueous Electrolyte journal May 2001
The Study of Electrolyte Solutions Based on Ethylene and Diethyl Carbonates for Rechargeable Li Batteries journal January 1995
Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes journal January 1997
Electronic Structure Modeling of Electrochemical Reactions at Electrode/Electrolyte Interfaces in Lithium Ion Batteries journal December 2012
Spatial Heterogeneities and Onset of Passivation Breakdown at Lithium Anode Interfaces journal September 2017
Influence of Graphite Characteristics on the Electrochemical Intercalation of Bis(trifluoromethanesulfonyl) imide Anions into a Graphite-Based Cathode journal January 2013
A Critical Review of Thermal Issues in Lithium-Ion Batteries journal January 2011
Using Atomic Layer Deposition to Hinder Solvent Decomposition in Lithium Ion Batteries: First-Principles Modeling and Experimental Studies journal September 2011
Determination of the absolute and relative extents of basal plane surface area and “non-basal plane surface” area of graphites and their impact on anode performance in lithium ion batteries journal July 2001
Electrochemical Intercalation of Bis(Trifluoromethanesulfonyl) Imide Anion into Various Graphites for Dual-Ion Cells journal April 2013
The Correlation Between the Surface Chemistry and the Performance of Li-Carbon Intercalation Anodes for Rechargeable ‘Rocking-Chair’ Type Batteries journal January 1994
Electrolytes and Interphases in Li-Ion Batteries and Beyond journal October 2014
Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteries journal August 2000
A General Discussion of Li Ion Battery Safety journal January 2012
The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model journal January 1979
Accelerating Rate Calorimetry Study on the Thermal Stability of Lithium Intercalated Graphite in Electrolyte. II. Modeling the Results and Predicting Differential Scanning Calorimeter Curves journal June 1999
On the Thermal Behavior of Lithium Intercalated Graphites journal January 2011
Comparison of the Reactions Between Li[sub 7/3]Ti[sub 5/3]O[sub 4] or LiC[sub 6] and Nonaqueous Solvents or Electrolytes Using Accelerating Rate Calorimetry journal January 2004