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Title: Solid electrolytes and interfaces in all-solid-state sodium batteries: Progress and perspective

Abstract

All-solid-state sodium batteries are promising candidates for the next generation of energy storage with exceptional safety, reliability and stability. The solid electrolytes are key components for enabling all-solid-state sodium batteries with high electrochemical performances. This Review discusses the current developments on inorganic and organic sodium ions solid electrolytes, including β/β’’-alumina, NASICON, sulfides, polymers and others. In particular, the structures, ionic conductivities and fabrications as well as electrochemical/chemical stabilities of solid electrolytes are discussed. Furthermore, the effective approaches for forming intimate interfaces between solid electrolytes and electrodes are also reviewed. And perspectives on future developments in the field of solid electrolytes and possible directions to improve interfacial contacts for future practical applications of all-solid-state sodium batteries are included.

Authors:
 [1]; ORCiD logo [1];  [1]; ORCiD logo [2]; ORCiD logo [1];  [3]
  1. Beijing Univ. of Technology, Beijing (People's Republic of China)
  2. Argonne National Lab. (ANL), Lemont, IL (United States); Stanford Univ., Stanford, CA (United States)
  3. Argonne National Lab. (ANL), Lemont, IL (United States)
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
National Natural Science Foundation of China (NSFC); National Key Research and Development Program of China; USDOE
OSTI Identifier:
1487119
Alternate Identifier(s):
OSTI ID: 1548092
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Nano Energy
Additional Journal Information:
Journal Volume: 52; Journal Issue: C; Journal ID: ISSN 2211-2855
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; all-solid-state batteries; inorganic solid electrolytes; interfaces; organic solid electrolytes; sodium ions

Citation Formats

Hou, Wenru, Guo, Xianwei, Shen, Xuyang, Amine, Khali, Yu, Haijun, and Lu, Jun. Solid electrolytes and interfaces in all-solid-state sodium batteries: Progress and perspective. United States: N. p., 2018. Web. doi:10.1016/j.nanoen.2018.07.036.
Hou, Wenru, Guo, Xianwei, Shen, Xuyang, Amine, Khali, Yu, Haijun, & Lu, Jun. Solid electrolytes and interfaces in all-solid-state sodium batteries: Progress and perspective. United States. https://doi.org/10.1016/j.nanoen.2018.07.036
Hou, Wenru, Guo, Xianwei, Shen, Xuyang, Amine, Khali, Yu, Haijun, and Lu, Jun. Thu . "Solid electrolytes and interfaces in all-solid-state sodium batteries: Progress and perspective". United States. https://doi.org/10.1016/j.nanoen.2018.07.036. https://www.osti.gov/servlets/purl/1487119.
@article{osti_1487119,
title = {Solid electrolytes and interfaces in all-solid-state sodium batteries: Progress and perspective},
author = {Hou, Wenru and Guo, Xianwei and Shen, Xuyang and Amine, Khali and Yu, Haijun and Lu, Jun},
abstractNote = {All-solid-state sodium batteries are promising candidates for the next generation of energy storage with exceptional safety, reliability and stability. The solid electrolytes are key components for enabling all-solid-state sodium batteries with high electrochemical performances. This Review discusses the current developments on inorganic and organic sodium ions solid electrolytes, including β/β’’-alumina, NASICON, sulfides, polymers and others. In particular, the structures, ionic conductivities and fabrications as well as electrochemical/chemical stabilities of solid electrolytes are discussed. Furthermore, the effective approaches for forming intimate interfaces between solid electrolytes and electrodes are also reviewed. And perspectives on future developments in the field of solid electrolytes and possible directions to improve interfacial contacts for future practical applications of all-solid-state sodium batteries are included.},
doi = {10.1016/j.nanoen.2018.07.036},
journal = {Nano Energy},
number = C,
volume = 52,
place = {United States},
year = {Thu Jul 19 00:00:00 EDT 2018},
month = {Thu Jul 19 00:00:00 EDT 2018}
}

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In Situ Generated Fireproof Gel Polymer Electrolyte with Li 6.4 Ga 0.2 La 3 Zr 2 O 12 As Initiator and Ion‐Conductive Filler
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