DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Solid electrolytes and interfaces in all-solid-state sodium batteries: Progress and perspective

Abstract

All-solid-state sodium batteries are promising candidates for the next generation of energy storage with exceptional safety, reliability and stability. The solid electrolytes are key components for enabling all-solid-state sodium batteries with high electrochemical performances. This Review discusses the current developments on inorganic and organic sodium ions solid electrolytes, including β/β’’-alumina, NASICON, sulfides, polymers and others. In particular, the structures, ionic conductivities and fabrications as well as electrochemical/chemical stabilities of solid electrolytes are discussed. Furthermore, the effective approaches for forming intimate interfaces between solid electrolytes and electrodes are also reviewed. And perspectives on future developments in the field of solid electrolytes and possible directions to improve interfacial contacts for future practical applications of all-solid-state sodium batteries are included.

Authors:
 [1]; ORCiD logo [1];  [1]; ORCiD logo [2]; ORCiD logo [1];  [3]
  1. Beijing Univ. of Technology, Beijing (People's Republic of China)
  2. Argonne National Lab. (ANL), Lemont, IL (United States); Stanford Univ., Stanford, CA (United States)
  3. Argonne National Lab. (ANL), Lemont, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
National Natural Science Foundation of China (NSFC); National Key Research and Development Program of China; USDOE
OSTI Identifier:
1487119
Alternate Identifier(s):
OSTI ID: 1548092
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Nano Energy
Additional Journal Information:
Journal Volume: 52; Journal Issue: C; Journal ID: ISSN 2211-2855
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; all-solid-state batteries; inorganic solid electrolytes; interfaces; organic solid electrolytes; sodium ions

Citation Formats

Hou, Wenru, Guo, Xianwei, Shen, Xuyang, Amine, Khali, Yu, Haijun, and Lu, Jun. Solid electrolytes and interfaces in all-solid-state sodium batteries: Progress and perspective. United States: N. p., 2018. Web. doi:10.1016/j.nanoen.2018.07.036.
Hou, Wenru, Guo, Xianwei, Shen, Xuyang, Amine, Khali, Yu, Haijun, & Lu, Jun. Solid electrolytes and interfaces in all-solid-state sodium batteries: Progress and perspective. United States. https://doi.org/10.1016/j.nanoen.2018.07.036
Hou, Wenru, Guo, Xianwei, Shen, Xuyang, Amine, Khali, Yu, Haijun, and Lu, Jun. Thu . "Solid electrolytes and interfaces in all-solid-state sodium batteries: Progress and perspective". United States. https://doi.org/10.1016/j.nanoen.2018.07.036. https://www.osti.gov/servlets/purl/1487119.
@article{osti_1487119,
title = {Solid electrolytes and interfaces in all-solid-state sodium batteries: Progress and perspective},
author = {Hou, Wenru and Guo, Xianwei and Shen, Xuyang and Amine, Khali and Yu, Haijun and Lu, Jun},
abstractNote = {All-solid-state sodium batteries are promising candidates for the next generation of energy storage with exceptional safety, reliability and stability. The solid electrolytes are key components for enabling all-solid-state sodium batteries with high electrochemical performances. This Review discusses the current developments on inorganic and organic sodium ions solid electrolytes, including β/β’’-alumina, NASICON, sulfides, polymers and others. In particular, the structures, ionic conductivities and fabrications as well as electrochemical/chemical stabilities of solid electrolytes are discussed. Furthermore, the effective approaches for forming intimate interfaces between solid electrolytes and electrodes are also reviewed. And perspectives on future developments in the field of solid electrolytes and possible directions to improve interfacial contacts for future practical applications of all-solid-state sodium batteries are included.},
doi = {10.1016/j.nanoen.2018.07.036},
journal = {Nano Energy},
number = C,
volume = 52,
place = {United States},
year = {2018},
month = {7}
}

Journal Article:

Citation Metrics:
Cited by: 18 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Li–O2 and Li–S batteries with high energy storage
journal, January 2012

  • Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J.
  • Nature Materials, Vol. 11, Issue 1, p. 19-29
  • DOI: 10.1038/nmat3191

Electrochemical Energy Storage for Green Grid
journal, May 2011

  • Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W.
  • Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613
  • DOI: 10.1021/cr100290v

Towards greener and more sustainable batteries for electrical energy storage
journal, November 2014


An ultrafast rechargeable aluminium-ion battery
journal, April 2015

  • Lin, Meng-Chang; Gong, Ming; Lu, Bingan
  • Nature, Vol. 520, Issue 7547
  • DOI: 10.1038/nature14340

An Ultrastable Anode for Long-Life Room-Temperature Sodium-Ion Batteries
journal, June 2014

  • Yu, Haijun; Ren, Yang; Xiao, Dongdong
  • Angewandte Chemie International Edition, Vol. 53, Issue 34
  • DOI: 10.1002/anie.201404549

A High-Current, Stable Nonaqueous Organic Redox Flow Battery
journal, September 2016


Quasi–solid state rechargeable Na-CO 2 batteries with reduced graphene oxide Na anodes
journal, February 2017


Burning lithium in CS2 for high-performing compact Li2S–graphene nanocapsules for Li–S batteries
journal, June 2017


3D Nanoporous Nitrogen-Doped Graphene with Encapsulated RuO 2 Nanoparticles for Li-O 2 Batteries
journal, September 2015


Promise and reality of post-lithium-ion batteries with high energy densities
journal, March 2016


Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

High-energy ‘composite’ layered manganese-rich cathode materials via controlling Li2MnO3 phase activation for lithium-ion batteries
journal, January 2012

  • Yu, Haijun; Kim, Hyunjeong; Wang, Yarong
  • Physical Chemistry Chemical Physics, Vol. 14, Issue 18
  • DOI: 10.1039/c2cp40745k

The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013

  • Goodenough, John B.; Park, Kyu-Sung
  • Journal of the American Chemical Society, Vol. 135, Issue 4
  • DOI: 10.1021/ja3091438

Nanostructured high-energy cathode materials for advanced lithium batteries
journal, October 2012

  • Sun, Yang-Kook; Chen, Zonghai; Noh, Hyung-Joo
  • Nature Materials, Vol. 11, Issue 11
  • DOI: 10.1038/nmat3435

Recent advances in all-solid-state rechargeable lithium batteries
journal, March 2017


A Safe High-Performance All-Solid-State Lithium–Vanadium Battery with a Freestanding V 2 O 5 Nanowire Composite Paper Cathode
journal, December 2016

  • Zhang, Yue; Lai, Jingyuan; Gong, Yudong
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 50
  • DOI: 10.1021/acsami.6b10358

A durable and safe solid-state lithium battery with a hybrid electrolyte membrane
journal, March 2018


Amorphous modified silyl-terminated 3D polymer electrolyte for high-performance lithium metal battery
journal, November 2017


A rechargeable room-temperature sodium superoxide (NaO2) battery
journal, December 2012

  • Hartmann, Pascal; Bender, Conrad L.; Vračar, Miloš
  • Nature Materials, Vol. 12, Issue 3, p. 228-232
  • DOI: 10.1038/nmat3486

Research Development on Sodium-Ion Batteries
journal, October 2014

  • Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
  • Chemical Reviews, Vol. 114, Issue 23
  • DOI: 10.1021/cr500192f

Recent Advances and Prospects of Cathode Materials for Sodium-Ion Batteries
journal, August 2015


Live-Cell Bioorthogonal Chemical Imaging: Stimulated Raman Scattering Microscopy of Vibrational Probes
journal, August 2016


Transition metal oxides for sodium-ion batteries
journal, October 2016


A stable room-temperature sodium–sulfur battery
journal, June 2016

  • Wei, Shuya; Xu, Shaomao; Agrawral, Akanksha
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms11722

Sodium-ion batteries: present and future
journal, January 2017

  • Hwang, Jang-Yeon; Myung, Seung-Taek; Sun, Yang-Kook
  • Chemical Society Reviews, Vol. 46, Issue 12
  • DOI: 10.1039/C6CS00776G

Na+ ion conductors of glass–ceramics in the system Na1+xAlxGe2−xP3O12(0.3≤x≤1.0)
journal, June 2009


Electrolyte design strategies and research progress for room-temperature sodium-ion batteries
journal, January 2017

  • Che, Haiying; Chen, Suli; Xie, Yingying
  • Energy & Environmental Science, Vol. 10, Issue 5
  • DOI: 10.1039/C7EE00524E

Progress in the Development of Sodium-Ion Solid Electrolytes
journal, September 2017


Recent Progress of the Solid-State Electrolytes for High-Energy Metal-Based Batteries
journal, January 2018


Efficient Storing Energy Harvested by Triboelectric Nanogenerators Using a Safe and Durable All-Solid-State Sodium-Ion Battery
journal, April 2017


Alkali metal crystalline polymer electrolytes
journal, July 2009

  • Zhang, Chuhong; Gamble, Stephen; Ainsworth, David
  • Nature Materials, Vol. 8, Issue 7
  • DOI: 10.1038/nmat2474

Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries
journal, January 2012

  • Hayashi, Akitoshi; Noi, Kousuke; Sakuda, Atsushi
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms1843

Na 3 SbS 4 : A Solution Processable Sodium Superionic Conductor for All-Solid-State Sodium-Ion Batteries
journal, July 2016

  • Banerjee, Abhik; Park, Kern Ho; Heo, Jongwook W.
  • Angewandte Chemie International Edition, Vol. 55, Issue 33
  • DOI: 10.1002/anie.201604158

Scandium-Substituted Na 3 Zr 2 (SiO 4 ) 2 (PO 4 ) Prepared by a Solution-Assisted Solid-State Reaction Method as Sodium-Ion Conductors
journal, June 2016


Design and synthesis of the superionic conductor Na10SnP2S12
journal, March 2016

  • Richards, William D.; Tsujimura, Tomoyuki; Miara, Lincoln J.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms11009

A Self-Forming Composite Electrolyte for Solid-State Sodium Battery with Ultralong Cycle Life
journal, October 2016

  • Zhang, Zhizhen; Zhang, Qinghua; Shi, Jinan
  • Advanced Energy Materials, Vol. 7, Issue 4
  • DOI: 10.1002/aenm.201601196

A Na+ Superionic Conductor for Room-Temperature Sodium Batteries
journal, August 2016

  • Song, Shufeng; Duong, Hai M.; Korsunsky, Alexander M.
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep32330

A stable 3 V all-solid-state sodium–ion battery based on a closo -borate electrolyte
journal, January 2017

  • Duchêne, L.; Kühnel, R. -S.; Stilp, E.
  • Energy & Environmental Science, Vol. 10, Issue 12
  • DOI: 10.1039/C7EE02420G

Fabrication and performances of all solid-state symmetric sodium battery based on NASICON-related compounds
journal, July 2013


�-Al2O3 synthesis from m-Al2O3
journal, May 1980

  • Takahashi, T.; Kuwabara, K.
  • Journal of Applied Electrochemistry, Vol. 10, Issue 3
  • DOI: 10.1007/BF00617203

Advanced materials for sodium-beta alumina batteries: Status, challenges and perspectives
journal, May 2010


High temperature sodium batteries: status, challenges and future trends
journal, January 2013

  • Hueso, Karina B.; Armand, Michel; Rojo, Teófilo
  • Energy & Environmental Science, Vol. 6, Issue 3
  • DOI: 10.1039/c3ee24086j

Fast Na+-ion transport in skeleton structures
journal, February 1976


Crystal structures and crystal chemistry in the system Na1+xZr2SixP3−xO12
journal, February 1976


Liquid-phase sintering of highly Na + ion conducting Na 3 Zr 2 Si 2 PO 12 ceramics using Na 3 BO 3 additive
journal, October 2017

  • Noi, Kousuke; Suzuki, Kenji; Tanibata, Naoto
  • Journal of the American Ceramic Society, Vol. 101, Issue 3
  • DOI: 10.1111/jace.15288

Fast Na-Ion Conduction in a Chalcogenide Glass–Ceramic in the Ternary System Na 2 Se–Ga 2 Se 3 –GeSe 2
journal, September 2014

  • Kim, Seong K.; Mao, Alvin; Sen, Sabyasachi
  • Chemistry of Materials, Vol. 26, Issue 19
  • DOI: 10.1021/cm502542p

Computational and Experimental Investigations of Na-Ion Conduction in Cubic Na 3 PSe 4
journal, December 2015


Na 3 PSe 4 : A Novel Chalcogenide Solid Electrolyte with High Ionic Conductivity
journal, October 2015


Role of Na + Interstitials and Dopants in Enhancing the Na + Conductivity of the Cubic Na 3 PS 4 Superionic Conductor
journal, December 2015


An Air-Stable Na 3 SbS 4 Superionic Conductor Prepared by a Rapid and Economic Synthetic Procedure
journal, June 2016

  • Wang, Hui; Chen, Yan; Hood, Zachary D.
  • Angewandte Chemie International Edition, Vol. 55, Issue 30
  • DOI: 10.1002/anie.201601546

New Na-Ion Solid Electrolytes Na 4− x Sn 1− x Sb x S 4 (0.02 ≤ x ≤ 0.33) for All-Solid-State Na-Ion Batteries
journal, January 2018

  • Heo, Jongwook W.; Banerjee, Abhik; Park, Kern Ho
  • Advanced Energy Materials, Vol. 8, Issue 11
  • DOI: 10.1002/aenm.201702716

Vacancy-Controlled Na + Superion Conduction in Na 11 Sn 2 PS 12
journal, January 2018

  • Duchardt, Marc; Ruschewitz, Uwe; Adams, Stefan
  • Angewandte Chemie, Vol. 130, Issue 5
  • DOI: 10.1002/ange.201712769

Na 11 Sn 2 PS 12 : a new solid state sodium superionic conductor
journal, January 2018

  • Zhang, Z.; Ramos, E.; Lalère, F.
  • Energy & Environmental Science, Vol. 11, Issue 1
  • DOI: 10.1039/C7EE03083E

Conductivity studies of new polymer electrolytes based on the poly(ethylene glycol)/sodium iodide system
journal, January 1993


Fluorine-free electrolytes for all-solid sodium-ion batteries based on percyano-substituted organic salts
journal, January 2017

  • Bitner-Michalska, Anna; Nolis, Gene M.; Żukowska, Grażyna
  • Scientific Reports, Vol. 7, Issue 1
  • DOI: 10.1038/srep40036

A new Na[(FSO 2 )(n-C 4 F 9 SO 2 )N]-based polymer electrolyte for solid-state sodium batteries
journal, January 2017

  • Ma, Qiang; Liu, Juanjuan; Qi, Xingguo
  • Journal of Materials Chemistry A, Vol. 5, Issue 17
  • DOI: 10.1039/C7TA01820G

Solid-state polymer nanocomposite electrolyte of TiO2/PEO/NaClO4 for sodium ion batteries
journal, March 2015


Structural manipulation approaches towards enhanced sodium ionic conductivity in Na-rich antiperovskites
journal, October 2015


A Plastic-Crystal Electrolyte Interphase for All-Solid-State Sodium Batteries
journal, April 2017

  • Gao, Hongcai; Xue, Leigang; Xin, Sen
  • Angewandte Chemie International Edition, Vol. 56, Issue 20
  • DOI: 10.1002/anie.201702003

Fast sodium ionic conduction in Na 2 B 10 H 10 -Na 2 B 12 H 12 pseudo-binary complex hydride and application to a bulk-type all-solid-state battery
journal, March 2017

  • Yoshida, Koji; Sato, Toyoto; Unemoto, Atsushi
  • Applied Physics Letters, Vol. 110, Issue 10
  • DOI: 10.1063/1.4977885

A highly stable sodium solid-state electrolyte based on a dodeca/deca-borate equimolar mixture
journal, January 2017

  • Duchêne, L.; Kühnel, R. -S.; Rentsch, D.
  • Chemical Communications, Vol. 53, Issue 30
  • DOI: 10.1039/C7CC00794A

Composition, ion-ion correlations and conductivity of beta″-alumina
journal, October 1981


Ionic conductivity of sodium beta″-alumina☆
journal, November 1981


Solid-State Sodium Batteries
journal, February 2018

  • Zhao, Chenglong; Liu, Lilu; Qi, Xingguo
  • Advanced Energy Materials, Vol. 8, Issue 17
  • DOI: 10.1002/aenm.201703012

Lithium battery chemistries enabled by solid-state electrolytes
journal, February 2017


Study of transport and electrochemical cell characteristics of PVP:NaClO3 polymer electrolyte system
journal, October 2001


Composite polymer electrolyte based on (PEO)6:NaPO3 dispersed with BaTiO3
journal, January 2008

  • Bhide, Amrtha; Hariharan, Krishnaswamy
  • Polymer International, Vol. 57, Issue 3
  • DOI: 10.1002/pi.2379

Increasing ionic conductivity of polymer–sodium salt complex by addition of a non-ionic plastic crystal
journal, June 2010

  • Patel, Monalisa; Chandrappa, Kodihalli G.; Bhattacharyya, Aninda J.
  • Solid State Ionics, Vol. 181, Issue 17-18
  • DOI: 10.1016/j.ssi.2010.04.013

Cation only conduction in new polymer–SiO2 nanohybrids: Na+ electrolytes
journal, January 2013

  • Villaluenga, Irune; Bogle, Xavier; Greenbaum, Steve
  • Journal of Materials Chemistry A, Vol. 1, Issue 29
  • DOI: 10.1039/c3ta11290j

Characterization of NaX (X: TFSI, FSI) – PEO based solid polymer electrolytes for sodium batteries
journal, September 2015


Ionic conductivity and battery characteristic studies of a new PAN-based Na+ ion conducting gel polymer electrolyte system
journal, August 2015

  • Krishna Jyothi, N.; Vijaya Kumar, K.; Sunita Sundari, G.
  • Indian Journal of Physics, Vol. 90, Issue 3
  • DOI: 10.1007/s12648-015-0758-9

Recent advances in solid polymer electrolytes for lithium batteries
journal, August 2017


Preparation of sodium ion conducting Na3PS4–NaI glasses by a mechanochemical technique
journal, February 2015


Structural and Na-ion conduction characteristics of Na 3 PS x Se 4−x
journal, January 2016

  • Bo, Shou-Hang; Wang, Yan; Ceder, Gerbrand
  • Journal of Materials Chemistry A, Vol. 4, Issue 23
  • DOI: 10.1039/C6TA03027K

Air-stable, high-conduction solid electrolytes of arsenic-substituted Li 4 SnS 4
journal, January 2014

  • Sahu, Gayatri; Lin, Zhan; Li, Juchuan
  • Energy Environ. Sci., Vol. 7, Issue 3
  • DOI: 10.1039/C3EE43357A

Structural change of Li2S–P2S5 sulfide solid electrolytes in the atmosphere
journal, February 2011

  • Muramatsu, Hiromasa; Hayashi, Akitoshi; Ohtomo, Takamasa
  • Solid State Ionics, Vol. 182, Issue 1
  • DOI: 10.1016/j.ssi.2010.10.013

Improvement of chemical stability of Li3PS4 glass electrolytes by adding MxOy (M = Fe, Zn, and Bi) nanoparticles
journal, January 2013

  • Hayashi, Akitoshi; Muramatsu, Hiromasa; Ohtomo, Takamasa
  • Journal of Materials Chemistry A, Vol. 1, Issue 21
  • DOI: 10.1039/c3ta10247e

C-axis oriented β″-alumina ceramics with anisotropic ionic conductivity prepared by spark plasma sintering
journal, December 2014


Preparation and characterization of TiO2 doped and MgO stabilized Na–β″-Al2O3 electrolyte via a citrate sol–gel method
journal, June 2013


The mechanical and electrical properties of Nb 2 O 5 doped Na- β" -Al 2 O 3 solid electrolyte
journal, April 2016

  • Xu, Dong; Jiang, Hongyi; Li, Yong
  • The European Physical Journal Applied Physics, Vol. 74, Issue 1
  • DOI: 10.1051/epjap/2016150466

Analysis of properties of partially stabilized zirconia-doped Na + -beta-alumina prepared by calcining-cum-sintering process
journal, December 2017


Synthesis and characterization of titanium doped sodium beta″-alumina
journal, May 2011


Relation of Properties to Microstructure in beta"-Alumina Ceramic
journal, November 1974


Fracture Properties of Polycrystalline Lithia-Stabilized β “- Alumina
journal, January 1977


Solution combustion synthesis of magnesium compensated sodium-β-aluminas
journal, October 2000


The relative stability of spray-frozen/freeze-dried β″-Al2O3 powders
journal, October 1980


Synthesis of beta-alumina powders by microwave heating from solution-derived precipitates
journal, January 2005


Mechanochemical synthesis of Na-β/β″-Al2O3
journal, April 2010

  • Lin, Jiu; Wen, Zhaoyin; Wang, Xiuyan
  • Journal of Solid State Electrochemistry, Vol. 14, Issue 10
  • DOI: 10.1007/s10008-010-1053-5

A wide-ranging review on Nasicon type materials
journal, February 2011

  • Anantharamulu, N.; Koteswara Rao, K.; Rambabu, G.
  • Journal of Materials Science, Vol. 46, Issue 9
  • DOI: 10.1007/s10853-011-5302-5

Electrical conductivity of Na2O–Nb2O5–P2O5 glass and fabrication of glass–ceramic composites with NASICON type Na3Zr2Si2PO12
journal, January 2015


A Single-Phase, All-Solid-State Sodium Battery Using Na 3− x V 2− x Zr x (PO 4 ) 3 as the Cathode, Anode, and Electrolyte
journal, December 2016

  • Inoishi, Atsushi; Omuta, Takuya; Kobayashi, Eiji
  • Advanced Materials Interfaces, Vol. 4, Issue 5
  • DOI: 10.1002/admi.201600942

Nominal vs. actual stoichiometries in Al-doped NASICONs: A study of the Na1.4Al0.4M1.6(PO4)3 (M=Ge, Sn, Ti, Hf, Zr) family
journal, May 2005

  • Maldonado-Manso, Pilar; Aranda, Miguel A. G.; Bruque, Sebastián
  • Solid State Ionics, Vol. 176, Issue 17-18
  • DOI: 10.1016/j.ssi.2005.04.009

Impedance measurements for some nasicon analogues
journal, March 1988


Spark Plasma Sintering (SPS) of NASICON Ceramics
journal, February 2004


Formation and structure of Na2S+P2S5 amorphous materials prepared by melt-quenching and mechanical milling
journal, January 2012


Glass formation and ionic conduction in the M2SGeS2 (M = Li, Na, Ag) systems
journal, August 1981


Vacancy-Contained Tetragonal Na 3 SbS 4 Superionic Conductor
journal, April 2016


Room-Temperature All-solid-state Rechargeable Sodium-ion Batteries with a Cl-doped Na3PS4 Superionic Conductor
journal, September 2016

  • Chu, Iek-Heng; Kompella, Christopher S.; Nguyen, Han
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep33733

Diffusion Mechanism of the Sodium-Ion Solid Electrolyte Na 3 PS 4 and Potential Improvements of Halogen Doping
journal, April 2016


Na 3+x M x P 1−x S 4 (M = Ge 4+ , Ti 4+ , Sn 4+ ) enables high rate all-solid-state Na-ion batteries Na 2+2δ Fe 2−δ (SO 4 ) 3 |Na 3+x M x P 1−x S 4 |Na 2 Ti 3 O 7
journal, January 2017

  • Rao, Rayavarapu Prasada; Chen, Haomin; Wong, Lee Loong
  • Journal of Materials Chemistry A, Vol. 5, Issue 7
  • DOI: 10.1039/C6TA09809F

Preparation and characterization of highly sodium ion conducting Na 3 PS 4 –Na 4 SiS 4 solid electrolytes
journal, January 2014

  • Tanibata, Naoto; Noi, Kousuke; Hayashi, Akitoshi
  • RSC Adv., Vol. 4, Issue 33
  • DOI: 10.1039/C4RA00996G

The Measurement of a Complete Set of Transport Properties for a Concentrated Solid Polymer Electrolyte Solution
journal, January 1995

  • Ma, Yanping
  • Journal of The Electrochemical Society, Vol. 142, Issue 6
  • DOI: 10.1149/1.2044206

Microscopic investigation of ionic conductivity in alkali metal salts-poly(ethylene oxide) adducts
journal, September 1983


Preparation and characterization of (PVP + NaClO4) electrolytes for battery applications
journal, April 2006


Investigations on electrical properties of (PVA:NaF) polymer electrolytes for electrochemical cell applications
journal, January 2009


A comparative study of lithium and sodium salts in PAN-based ion conducting polymer electrolytes
journal, January 2010


Polycarbonates as alternative electrolyte host materials for solid-state sodium batteries
journal, April 2017


Synthesis and morphological change in poly(ethylene oxide)–sodium chlorate based polymer electrolyte complex with polyaniline
journal, November 2011


Experimental investigations on a sodium-ion-conducting polymer electrolyte based on poly(ethylene oxide) complexed with NaPF6
journal, October 1995


FT-IR studies on interactions of AlCl3 with PEO–NaSCN polymer electrolytes
journal, April 2006


Vibrational spectroscopy and ionic conductivity of polyethylene oxide–NaClO4–CuO nanocomposite
journal, December 2011

  • Dey, Arup; Das, Kajari; Karan, S.
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 83, Issue 1
  • DOI: 10.1016/j.saa.2011.08.050

Size effect of cubic ZrO 2 nanoparticles on ionic conductivity of polyethylene oxide-based composite
journal, August 2011

  • Dey, Arup; Ghoshal, Tandra; Karan, S.
  • Journal of Applied Physics, Vol. 110, Issue 4
  • DOI: 10.1063/1.3622671

A ceramic/polymer composite solid electrolyte for sodium batteries
journal, January 2016

  • Zhang, Zhizhen; Zhang, Qiangqiang; Ren, Cheng
  • Journal of Materials Chemistry A, Vol. 4, Issue 41
  • DOI: 10.1039/C6TA07590H

A hybrid solid electrolyte for flexible solid-state sodium batteries
journal, January 2015

  • Kim, Jae-Kwang; Lim, Young Jun; Kim, Hyojin
  • Energy & Environmental Science, Vol. 8, Issue 12
  • DOI: 10.1039/C5EE01941A

Structural, electrical and optical properties of pure and NaLaF4 doped PEO polymer electrolyte films
journal, April 2007


Synthesis and ion conduction mechanism on hot-pressed sodium ion conducting nano composite polymer electrolytes
journal, May 2016


A hybrid polymer/oxide/ionic-liquid solid electrolyte for Na-metal batteries
journal, January 2017

  • Song, Shufeng; Kotobuki, Masashi; Zheng, Feng
  • Journal of Materials Chemistry A, Vol. 5, Issue 14
  • DOI: 10.1039/C6TA11165C

Characterization of poly(vinyl alcohol)/sodium bromide polymer electrolytes for electrochemical cell applications
journal, January 2008

  • Bhargav, P. Balaji; Mohan, V. M.; Sharma, A. K.
  • Journal of Applied Polymer Science, Vol. 108, Issue 1
  • DOI: 10.1002/app.27566

Cellulose-based novel hybrid polymer electrolytes for green and efficient Na-ion batteries
journal, August 2015


A Self-Binding, Melt-Castable, Crystalline Organic Electrolyte for Sodium Ion Conduction
journal, November 2016

  • Chinnam, Parameswara Rao; Fall, Birane; Dikin, Dmitriy A.
  • Angewandte Chemie International Edition, Vol. 55, Issue 49
  • DOI: 10.1002/anie.201606363

An All-solid-state and All-organic Sodium-ion Battery based on Redox-active Polymers and Plastic Crystal Electrolyte
journal, October 2015


Phosphonium plastic crystal salt alloyed with a sodium salt as a solid-state electrolyte for sodium devices: phase behaviour and electrochemical performance
journal, January 2017

  • Makhlooghiazad, Faezeh; Howlett, Patrick C.; Wang, Xiaoen
  • Journal of Materials Chemistry A, Vol. 5, Issue 12
  • DOI: 10.1039/C6TA10340E

Exceptional Superionic Conductivity in Disordered Sodium Decahydro- closo -decaborate
journal, October 2014

  • Udovic, Terrence J.; Matsuo, Motoaki; Tang, Wan Si
  • Advanced Materials, Vol. 26, Issue 45
  • DOI: 10.1002/adma.201403157

Sodium ionic conduction in complex hydrides with [BH 4 ] and [NH 2 ] anions
journal, May 2012

  • Matsuo, Motoaki; Kuromoto, Shingo; Sato, Toyoto
  • Applied Physics Letters, Vol. 100, Issue 20
  • DOI: 10.1063/1.4716021

Experimental and Computational Evaluation of a Sodium-Rich Anti-Perovskite for Solid State Electrolytes
journal, January 2016

  • Nguyen, Han; Hy, Sunny; Wu, Erik
  • Journal of The Electrochemical Society, Vol. 163, Issue 10
  • DOI: 10.1149/2.0091610jes

Complex high-temperature phase transitions in Li2B12H12 and Na2B12H12
journal, April 2014


Halogenated Sodium- closo -Dodecaboranes as Solid-State Ion Conductors
journal, April 2017


Nuclear Magnetic Resonance Study of Atomic Motion in A 2 B 12 H 12 (A = Na, K, Rb, Cs): Anion Reorientations and Na + Mobility
journal, November 2013

  • Skripov, Alexander V.; Babanova, Olga A.; Soloninin, Alexei V.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 49
  • DOI: 10.1021/jp4106585

Sodium superionic conduction in Na 2 B 12 H 12
journal, January 2014

  • Udovic, Terrence J.; Matsuo, Motoaki; Unemoto, Atsushi
  • Chem. Commun., Vol. 50, Issue 28
  • DOI: 10.1039/C3CC49805K

Physicochemical properties of NaxCoO2 as a cathode for solid state sodium battery
journal, June 2011


Toothpaste-like Electrode: A Novel Approach to Optimize the Interface for Solid-State Sodium-Ion Batteries with Ultralong Cycle Life
journal, November 2016

  • Liu, Lilu; Qi, Xingguo; Ma, Qiang
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 48
  • DOI: 10.1021/acsami.6b11773

An all-solid state NASICON sodium battery operating at 200 °C
journal, February 2014


A room temperature solid-state rechargeable sodium ion cell based on a ceramic Na-β″-Al2O3 electrolyte and NaTi2(PO4)3 cathode
journal, August 2016


All-solid-state sodium batteries using amorphous TiS3 electrode with high capacity
journal, February 2015


High-Performance All-Inorganic Solid-State Sodium–Sulfur Battery
journal, April 2017


High sodium ion conductivity of glass–ceramic electrolytes with cubic Na3PS4
journal, July 2014


Main Challenges for High Performance NAS Battery: Materials and Interfaces
journal, May 2012

  • Wen, Zhaoyin; Hu, Yingying; Wu, Xiangwei
  • Advanced Functional Materials, Vol. 23, Issue 8
  • DOI: 10.1002/adfm.201200473

Rechargeable Sodium All-Solid-State Battery
journal, January 2017


Improvement of Rate Performance for All-Solid-State Na 15 Sn 4 /Amorphous TiS 3 Cells Using 94Na 3 PS 4 ·6Na 4 SiS 4 Glass-Ceramic Electrolytes
journal, January 2015

  • Tanibata, Naoto; Hayashi, Akitoshi; Tatsumisago, Masahiro
  • Journal of The Electrochemical Society, Vol. 162, Issue 6
  • DOI: 10.1149/2.0011506jes

Ultrathin Surface Coating Enables the Stable Sodium Metal Anode
journal, September 2016

  • Luo, Wei; Lin, Chuan-Fu; Zhao, Oliver
  • Advanced Energy Materials, Vol. 7, Issue 2
  • DOI: 10.1002/aenm.201601526

Inorganic–Organic Coating via Molecular Layer Deposition Enables Long Life Sodium Metal Anode
journal, August 2017


Works referencing / citing this record:

Progress and Perspective of Ceramic/Polymer Composite Solid Electrolytes for Lithium Batteries
journal, January 2020


Conductive carbon nanofiber interpenetrated graphene architecture for ultra-stable sodium ion battery
journal, September 2019


Highly Tough, Li‐Metal Compatible Organic–Inorganic Double‐Network Solvate Ionogel
journal, April 2019


Anisotropically Electrochemical–Mechanical Evolution in Solid‐State Batteries and Interfacial Tailored Strategy
journal, November 2019


A review on battery management system from the modeling efforts to its multiapplication and integration
journal, April 2019

  • Shen, Ming; Gao, Qing
  • International Journal of Energy Research, Vol. 43, Issue 10
  • DOI: 10.1002/er.4433

Solid-state synthesis of NASICON (Na3Zr2Si2PO12) using nanoparticle precursors for optimisation of ionic conductivity
journal, November 2019

  • Jalalian-Khakshour, A.; Phillips, C. O.; Jackson, L.
  • Journal of Materials Science, Vol. 55, Issue 6
  • DOI: 10.1007/s10853-019-04162-8

Dissolution–Crystallization Transition within a Polymer Hydrogel for a Processable Ultratough Electrolyte
journal, June 2019


In Situ Generated Fireproof Gel Polymer Electrolyte with Li 6.4 Ga 0.2 La 3 Zr 2 O 12 As Initiator and Ion‐Conductive Filler
journal, May 2019


Anisotropically Electrochemical–Mechanical Evolution in Solid‐State Batteries and Interfacial Tailored Strategy
journal, November 2019

  • Sun, Nan; Liu, Qingsong; Cao, Yi
  • Angewandte Chemie International Edition, Vol. 58, Issue 51
  • DOI: 10.1002/anie.201910993

High cathode utilization efficiency through interface engineering in all-solid-state lithium-metal batteries
journal, January 2019

  • Guo, Xianwei; Hao, Liangwei; Yang, Yubo
  • Journal of Materials Chemistry A, Vol. 7, Issue 45
  • DOI: 10.1039/c9ta09935b

New KRb 2 Sb 4 BO 13 and Rb 3 Sb 4 BO 13 compounds prepared by Rb + /K + ion exchange from the K 3 Sb 4 BO 13 ion conductor
journal, January 2019

  • Doux, Jean-Marie; Stephant, Nicolas; La Salle, Annie Le Gal
  • CrystEngComm, Vol. 21, Issue 4
  • DOI: 10.1039/c8ce01712c