Multi-modal, ultrasensitive, wide-range humidity sensing with Ti3C2 film

Muckley, Eric S.; Naguib, Michael; Ivanov, Ilia N.

doi:10.1039/c8nr05170d

Title: Multi-modal, ultrasensitive, wide-range humidity sensing with Ti₃C₂ film

Journal Article · 08 November 2018 · Nanoscale

DOI: https://doi.org/10.1039/c8nr05170d · OSTI ID:1486937

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Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Gravimetric, direct-current electrical, and electrical impedance sensing modes were used to measure response of high surface area 2D Ti₃C₂ MXene film to water vapor pressures spanning 3 orders of magnitude (20 mTorr–20 Torr). The Ti₃C₂ film exhibited reproducible reversible response in 0.1%–95% relative humidity (RH) range with a detection limit of <20 mTorr H₂O partial pressure (<0.1% RH). DC electrical current-based sensing with 3 mV operating voltage and 0.8 pW power consumption was demonstrated. The highest normalized sensitivity was shown for gravimetric sensing modalities which scale with the overtone number, reaching highest sensitivity of about 12 Hz/% RH at the 9th crystal overtone (45 MHz oscillation).

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1486937

Journal Information:: Nanoscale, Journal Name: Nanoscale Journal Issue: 46 Vol. 10; ISSN NANOHL; ISSN 2040-3364

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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