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Title: Dynamic Ferrimagnetic Order in a Highly Distorted Double Perovskite Y2CoRuO6

Abstract

Y2CoRuO6 was synthesized as a B-site ordered double perovskite with distorted monoclinic P21/n symmetry and an average tilting of the CoO6 and RuO6 octahedra of $$\bar{ψ}$$= 19.7°. DC magnetization measurements show a ferrimagnetic transition at around 82 K. Although long-range ferrimagntic order is supported by neutron diffraction studies, aging phenomena in time-dependent isothermal magnetization, frequency dependence of AC susceptibility, and a smeared peak in the specific heat together reveal spin glass-like dynamics. The magnetic subtleties resemble chaotic behavior as previously observed in some ferro- or ferrimagnetic materials that exhibit spin glass-like dynamics. It is argued that the magnetic dynamics in Y2CoRuO6 mainly stem from competition between antiferromagnetic Co↑-O-(Ru)-O-Co↓/Ru↑-O-(Co)-O-Ru↓ and antiferromagnetic Co↑-O-Ru↓ interactions, besides a degree of Co:Ru antisite disorder. Herein, the B-site ordered Y2CoRuO6 offers a model to explore the intriguing dynamics in correlated 3d–4d transition metal double perovskites.

Authors:
 [1];  [2];  [3];  [4]; ORCiD logo [5];  [6];  [7];  [7];  [7];  [8]; ORCiD logo [1];  [9];  [9];  [9];  [10]; ORCiD logo [4]
  1. Rutgers Univ., Piscataway, NJ (United States); Chinese Academy of Sciences (CAS), Beijing (China)
  2. Consejo Superior de Investigaciones Cientificas (CSIC), Madrid (Spain). Instituto de Catálisis y Petroleoquímica
  3. New Jersey Inst. of Technology, Newark, NJ (United States)
  4. Rutgers Univ., Piscataway, NJ (United States)
  5. State Univ. of New York (SUNY), Stony Brook, NY (United States)
  6. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  7. Chinese Academy of Sciences (CAS), Beijing (China)
  8. Max Planck Society, Dresden (Germany). Max Planck Inst. for Chemical Physics of Solids
  9. National Synchrotron Radiation Research Center, Hsinchu (Taiwan)
  10. Rutgers Univ., Piscataway, NJ (United States); Chosun Univ., Qwangji (South Korea)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1486928
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Chemistry of Materials
Additional Journal Information:
Journal Volume: 30; Journal Issue: 20; Journal ID: ISSN 0897-4756
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Deng, Zheng, Retuerto, Maria, Liu, Sizhan, Croft, Mark, Stephens, Peter W., Calder, Stuart, Li, Wenmin, Chen, Bijuan, Jin, Changqing, Hu, Zhiwei, Li, Man-Rong, Lin, Hong-Ji, Chan, Ting-Shan, Chen, Chien-Te, Kim, Sun Woo, and Greenblatt, Martha. Dynamic Ferrimagnetic Order in a Highly Distorted Double Perovskite Y2CoRuO6. United States: N. p., 2018. Web. https://doi.org/10.1021/acs.chemmater.8b02728.
Deng, Zheng, Retuerto, Maria, Liu, Sizhan, Croft, Mark, Stephens, Peter W., Calder, Stuart, Li, Wenmin, Chen, Bijuan, Jin, Changqing, Hu, Zhiwei, Li, Man-Rong, Lin, Hong-Ji, Chan, Ting-Shan, Chen, Chien-Te, Kim, Sun Woo, & Greenblatt, Martha. Dynamic Ferrimagnetic Order in a Highly Distorted Double Perovskite Y2CoRuO6. United States. https://doi.org/10.1021/acs.chemmater.8b02728
Deng, Zheng, Retuerto, Maria, Liu, Sizhan, Croft, Mark, Stephens, Peter W., Calder, Stuart, Li, Wenmin, Chen, Bijuan, Jin, Changqing, Hu, Zhiwei, Li, Man-Rong, Lin, Hong-Ji, Chan, Ting-Shan, Chen, Chien-Te, Kim, Sun Woo, and Greenblatt, Martha. Mon . "Dynamic Ferrimagnetic Order in a Highly Distorted Double Perovskite Y2CoRuO6". United States. https://doi.org/10.1021/acs.chemmater.8b02728. https://www.osti.gov/servlets/purl/1486928.
@article{osti_1486928,
title = {Dynamic Ferrimagnetic Order in a Highly Distorted Double Perovskite Y2CoRuO6},
author = {Deng, Zheng and Retuerto, Maria and Liu, Sizhan and Croft, Mark and Stephens, Peter W. and Calder, Stuart and Li, Wenmin and Chen, Bijuan and Jin, Changqing and Hu, Zhiwei and Li, Man-Rong and Lin, Hong-Ji and Chan, Ting-Shan and Chen, Chien-Te and Kim, Sun Woo and Greenblatt, Martha},
abstractNote = {Y2CoRuO6 was synthesized as a B-site ordered double perovskite with distorted monoclinic P21/n symmetry and an average tilting of the CoO6 and RuO6 octahedra of $\bar{ψ}$= 19.7°. DC magnetization measurements show a ferrimagnetic transition at around 82 K. Although long-range ferrimagntic order is supported by neutron diffraction studies, aging phenomena in time-dependent isothermal magnetization, frequency dependence of AC susceptibility, and a smeared peak in the specific heat together reveal spin glass-like dynamics. The magnetic subtleties resemble chaotic behavior as previously observed in some ferro- or ferrimagnetic materials that exhibit spin glass-like dynamics. It is argued that the magnetic dynamics in Y2CoRuO6 mainly stem from competition between antiferromagnetic Co↑-O-(Ru)-O-Co↓/Ru↑-O-(Co)-O-Ru↓ and antiferromagnetic Co↑-O-Ru↓ interactions, besides a degree of Co:Ru antisite disorder. Herein, the B-site ordered Y2CoRuO6 offers a model to explore the intriguing dynamics in correlated 3d–4d transition metal double perovskites.},
doi = {10.1021/acs.chemmater.8b02728},
journal = {Chemistry of Materials},
number = 20,
volume = 30,
place = {United States},
year = {2018},
month = {9}
}

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Figures / Tables:

Figure 1 Figure 1: (a) Rietveld refined SPXD profiles of Y2CoRuO6 at room-temperature. (b) The crystal structure of Y2CoRuO6.

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