Dynamic Ferrimagnetic Order in a Highly Distorted Double Perovskite Y2CoRuO6

Deng, Zheng; Retuerto, Maria; Liu, Sizhan; Croft, Mark; Stephens, Peter W.; Calder, Stuart; Li, Wenmin; Chen, Bijuan; Jin, Changqing; Hu, Zhiwei; Li, Man-Rong; Lin, Hong-Ji; Chan, Ting-Shan; Chen, Chien-Te; Kim, Sun Woo; Greenblatt, Martha

doi:10.1021/acs.chemmater.8b02728

Title: Dynamic Ferrimagnetic Order in a Highly Distorted Double Perovskite Y₂CoRuO₆

Journal Article · 24 September 2018 · Chemistry of Materials

DOI: https://doi.org/10.1021/acs.chemmater.8b02728 · OSTI ID:1486928

Deng, Zheng ^[1]; Retuerto, Maria ^[2]; Liu, Sizhan ^[3]; Croft, Mark ^[4];

^[5]; Calder, Stuart ^[6]; Li, Wenmin ^[7]; Chen, Bijuan ^[7]; Jin, Changqing ^[7]; Hu, Zhiwei ^[8];

^[1]; Lin, Hong-Ji ^[9]; Chan, Ting-Shan ^[9]; Chen, Chien-Te ^[9]; Kim, Sun Woo ^[10];

^[4]

Rutgers Univ., Piscataway, NJ (United States); Chinese Academy of Sciences (CAS), Beijing (China)
Consejo Superior de Investigaciones Cientificas (CSIC), Madrid (Spain). Instituto de Catálisis y Petroleoquímica
New Jersey Inst. of Technology, Newark, NJ (United States)
Rutgers Univ., Piscataway, NJ (United States)
State Univ. of New York (SUNY), Stony Brook, NY (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Chinese Academy of Sciences (CAS), Beijing (China)
Max Planck Society, Dresden (Germany). Max Planck Inst. for Chemical Physics of Solids
National Synchrotron Radiation Research Center, Hsinchu (Taiwan)
Rutgers Univ., Piscataway, NJ (United States); Chosun Univ., Qwangji (South Korea)

Y₂CoRuO₆ was synthesized as a B-site ordered double perovskite with distorted monoclinic P2₁/n symmetry and an average tilting of the CoO₆ and RuO₆ octahedra of $$\bar{ψ}$$= 19.7°. DC magnetization measurements show a ferrimagnetic transition at around 82 K. Although long-range ferrimagntic order is supported by neutron diffraction studies, aging phenomena in time-dependent isothermal magnetization, frequency dependence of AC susceptibility, and a smeared peak in the specific heat together reveal spin glass-like dynamics. The magnetic subtleties resemble chaotic behavior as previously observed in some ferro- or ferrimagnetic materials that exhibit spin glass-like dynamics. It is argued that the magnetic dynamics in Y₂CoRuO₆ mainly stem from competition between antiferromagnetic Co↑-O-(Ru)-O-Co↓/Ru↑-O-(Co)-O-Ru↓ and antiferromagnetic Co↑-O-Ru↓ interactions, besides a degree of Co:Ru antisite disorder. Herein, the B-site ordered Y₂CoRuO₆ offers a model to explore the intriguing dynamics in correlated 3d–4d transition metal double perovskites.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1486928

Journal Information:: Chemistry of Materials, Vol. 30, Issue 20; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 15 works

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