skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Enhancing the activity of oxygen-evolution and chlorine-evolution electrocatalysts by atomic layer deposition of TiO 2

Abstract

Atomic layer deposition of TiO 2 may be used to tune the catalytic activity of three metal oxide catalysts for two reactions.

Authors:
ORCiD logo [1];  [2];  [1];  [3];  [4]; ORCiD logo [5];  [1]
  1. The Linde Center for Global Environmental Science, Caltech, Pasadena, USA, The Resnick Sustainability Institute, Caltech, Pasadena
  2. Division of Engineering and Applied Science, Caltech, Pasadena, USA
  3. The Linde Center for Global Environmental Science, Caltech, Pasadena, USA
  4. The Resnick Sustainability Institute, Caltech, Pasadena, USA, Division of Chemistry and Chemical Engineering, Caltech, Pasadena
  5. Division of Chemistry and Chemical Engineering, Caltech, Pasadena, USA
Publication Date:
Research Org.:
California Institute of Technology (CalTech), Pasadena, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC); Bill and Melinda Gates Foundation
OSTI Identifier:
1486898
Alternate Identifier(s):
OSTI ID: 1610783
Grant/Contract Number:  
SC0004993; OPP1111246; OPP1149755
Resource Type:
Published Article
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Name: Energy & Environmental Science Journal Volume: 12 Journal Issue: 1; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Country of Publication:
United Kingdom
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology

Citation Formats

Finke, Cody E., Omelchenko, Stefan T., Jasper, Justin T., Lichterman, Michael F., Read, Carlos G., Lewis, Nathan S., and Hoffmann, Michael R. Enhancing the activity of oxygen-evolution and chlorine-evolution electrocatalysts by atomic layer deposition of TiO 2. United Kingdom: N. p., 2019. Web. doi:10.1039/C8EE02351D.
Finke, Cody E., Omelchenko, Stefan T., Jasper, Justin T., Lichterman, Michael F., Read, Carlos G., Lewis, Nathan S., & Hoffmann, Michael R. Enhancing the activity of oxygen-evolution and chlorine-evolution electrocatalysts by atomic layer deposition of TiO 2. United Kingdom. doi:10.1039/C8EE02351D.
Finke, Cody E., Omelchenko, Stefan T., Jasper, Justin T., Lichterman, Michael F., Read, Carlos G., Lewis, Nathan S., and Hoffmann, Michael R. Wed . "Enhancing the activity of oxygen-evolution and chlorine-evolution electrocatalysts by atomic layer deposition of TiO 2". United Kingdom. doi:10.1039/C8EE02351D.
@article{osti_1486898,
title = {Enhancing the activity of oxygen-evolution and chlorine-evolution electrocatalysts by atomic layer deposition of TiO 2},
author = {Finke, Cody E. and Omelchenko, Stefan T. and Jasper, Justin T. and Lichterman, Michael F. and Read, Carlos G. and Lewis, Nathan S. and Hoffmann, Michael R.},
abstractNote = {Atomic layer deposition of TiO 2 may be used to tune the catalytic activity of three metal oxide catalysts for two reactions.},
doi = {10.1039/C8EE02351D},
journal = {Energy & Environmental Science},
number = 1,
volume = 12,
place = {United Kingdom},
year = {2019},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8EE02351D

Citation Metrics:
Cited by: 10 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices
journal, March 2015

  • McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M.
  • Journal of the American Chemical Society, Vol. 137, Issue 13
  • DOI: 10.1021/ja510442p

Tailoring the Activity for Oxygen Evolution Electrocatalysis on Rutile TiO2(110) by Transition-Metal Substitution
journal, August 2011

  • García-Mota, Mónica; Vojvodic, Aleksandra; Metiu, Horia
  • ChemCatChem, Vol. 3, Issue 10
  • DOI: 10.1002/cctc.201100160

Potentials of zero total and zero free charge of platinum group metals
journal, May 1975


Activating and optimizing MoS2 basal planes for hydrogen evolution through the formation of strained sulphur vacancies
journal, November 2015

  • Li, Hong; Tsai, Charlie; Koh, Ai Leen
  • Nature Materials, Vol. 15, Issue 1
  • DOI: 10.1038/nmat4465

The Role of TiO 2 Doping on RuO 2 -Coated Electrodes for the Water Oxidation Reaction
journal, February 2013

  • Näslund, Lars-Åke; Sánchez-Sánchez, Carlos M.; Ingason, Árni S.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 12
  • DOI: 10.1021/jp308941g

Controlling Selectivity in the Chlorine Evolution Reaction over RuO 2 -Based Catalysts
journal, August 2014

  • Exner, Kai S.; Anton, Josef; Jacob, Timo
  • Angewandte Chemie International Edition, Vol. 53, Issue 41
  • DOI: 10.1002/anie.201406112

Environmental Applications of Semiconductor Photocatalysis
journal, January 1995

  • Hoffmann, Michael R.; Martin, Scot T.; Choi, Wonyong.
  • Chemical Reviews, Vol. 95, Issue 1
  • DOI: 10.1021/cr00033a004

Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction
journal, February 2009


Electrocatalysis: understanding the success of DSA®
journal, May 2000


Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
journal, March 2011

  • Man, Isabela C.; Su, Hai‐Yan; Calle‐Vallejo, Federico
  • ChemCatChem, Vol. 3, Issue 7
  • DOI: 10.1002/cctc.201000397

From the Sabatier principle to a predictive theory of transition-metal heterogeneous catalysis
journal, August 2015


Promoting water photooxidation on transparent WO3 thin films using an alumina overlayer
journal, January 2013

  • Kim, Wooyul; Tachikawa, Takashi; Monllor-Satoca, Damián
  • Energy & Environmental Science, Vol. 6, Issue 12
  • DOI: 10.1039/c3ee42151a

Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis
journal, December 2016


Multilayer Heterojunction Anodes for Saline Wastewater Treatment: Design Strategies and Reactive Species Generation Mechanisms
journal, July 2016

  • Yang, Yang; Shin, Jieun; Jasper, Justin T.
  • Environmental Science & Technology, Vol. 50, Issue 16
  • DOI: 10.1021/acs.est.6b00688

Electrochemical treatment of human waste coupled with molecular hydrogen production
journal, January 2014

  • Cho, Kangwoo; Kwon, Daejung; Hoffmann, Michael R.
  • RSC Adv., Vol. 4, Issue 9
  • DOI: 10.1039/C3RA46699J

An Interpretation of Bond Lengths and a Classification of Bonds
journal, December 1951


Work function, electronegativity, and electrochemical behaviour of metals
journal, September 1972


On the faradaic selectivity and the role of surface inhomogeneity during the chlorine evolution reaction on ternary Ti–Ru–Ir mixed metal oxide electrocatalysts
journal, January 2014

  • Zeradjanin, Aleksandar R.; Menzel, Nadine; Schuhmann, Wolfgang
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 27
  • DOI: 10.1039/C4CP00896K

Oxygen evolution reaction on IrO2-based DSA® type electrodes: kinetics analysis of Tafel lines and EIS
journal, July 2004


A comparative technoeconomic analysis of renewable hydrogen production using solar energy
journal, January 2016

  • Shaner, Matthew R.; Atwater, Harry A.; Lewis, Nathan S.
  • Energy & Environmental Science, Vol. 9, Issue 7
  • DOI: 10.1039/C5EE02573G

Work function, electronegativity, and electrochemical behaviour of metals
journal, December 1971


Characterization of dsa-type oxygen evolving electrodes. Choice of base metal
journal, March 1991


Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
journal, October 2013

  • McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 135, Issue 45
  • DOI: 10.1021/ja407115p

XPS study of thin films of titanium oxysulfides
journal, August 1991


Electrochemical chlorine evolution at rutile oxide (110) surfaces
journal, January 2010

  • Hansen, Heine A.; Man, Isabela C.; Studt, Felix
  • Phys. Chem. Chem. Phys., Vol. 12, Issue 1
  • DOI: 10.1039/B917459A

Correlation among electronegativity, cation polarizability, optical basicity and single bond strength of simple oxides
journal, December 2012


Synthesis and Stabilization of Blue-Black TiO 2 Nanotube Arrays for Electrochemical Oxidant Generation and Wastewater Treatment
journal, October 2016

  • Yang, Yang; Hoffmann, Michael R.
  • Environmental Science & Technology, Vol. 50, Issue 21
  • DOI: 10.1021/acs.est.6b03540

A highly active and stable IrO x /SrIrO 3 catalyst for the oxygen evolution reaction
journal, September 2016


Tuning the surface metal work function by deposition of ultrathin oxide films: Density functional calculations
journal, January 2006


Corundum Structure Oxides Studied by XPS
journal, July 1983


Synthesis of Monodispere Au@Co 3 O 4 Core-Shell Nanocrystals and Their Enhanced Catalytic Activity for Oxygen Evolution Reaction
journal, March 2014

  • Zhuang, Zhongbin; Sheng, Wenchao; Yan, Yushan
  • Advanced Materials, Vol. 26, Issue 23
  • DOI: 10.1002/adma.201400336

Electrocatalysis in the anodic evolution of oxygen and chlorine
journal, November 1984


Combining theory and experiment in electrocatalysis: Insights into materials design
journal, January 2017


Hydrogen or batteries for grid storage? A net energy analysis
journal, January 2015

  • Pellow, Matthew A.; Emmott, Christopher J. M.; Barnhart, Charles J.
  • Energy & Environmental Science, Vol. 8, Issue 7
  • DOI: 10.1039/C4EE04041D

Stable Ti/IrO x −Sb 2 O 5 −SnO 2 Anode for O 2 Evolution with Low Ir Content
journal, May 2001

  • Chen, Xueming; Chen, Guohua; Yue, Po Lock
  • The Journal of Physical Chemistry B, Vol. 105, Issue 20
  • DOI: 10.1021/jp010038d

Electronegativities in inorganic chemistry: (II)
journal, January 1954

  • Sanderson, R. T.
  • Journal of Chemical Education, Vol. 31, Issue 1
  • DOI: 10.1021/ed031p2