Making metals linear super-elastic with ultralow modulus and nearly zero hysteresis

Zhu, Jiaming; Gao, Yipeng; Wang, Dong; Li, Ju; Zhang, Tong-Yi; Wang, Yunzhi

doi:10.1039/C8MH01141A

Title: Making metals linear super-elastic with ultralow modulus and nearly zero hysteresis

Abstract

We demonstrate a novel materials design approach to achieve unprecedented properties by utilizing nanoscale chemo-mechanical coupling. In particular, by using computer simulations we demonstrate how to engineer ultralow modulus (12 GPa), nearly hysteresisfree, and linear super-elastic metals with a giant elastic strain limit (2.7%) by creating appropriate concentration modulations (CMs) at the nanoscale in the parent phase and by pre-straining to regulate the stress-induced martensitic transformation (MT). The nanoscale CMs created via spinodal decomposition produce corresponding phase stability modulations, suppress autocatalysis in nucleation, impose nano-confinements on growth, and hinder long-range ordering of transformation strain during the MT, which changes the otherwise sharp first-order transition into a smeared, macroscopically continuous transition over a large stress range. The pre-straining generates retained martensitic particles that are stable at the test temperature after unloading and act as operational nuclei in subsequent load cycles, eliminating the stress–strain hysteresis and offering an ultralow apparent Young’s modulus. Materials with a high strength and an ultralow apparent Young’s modulus have great potential for application in orthopaedic implants.

Authors:

Zhu, Jiaming ^[1]; Gao, Yipeng ^[2]; Wang, Dong ^[1];

^[3]; Zhang, Tong-Yi ^[4]; Wang, Yunzhi ^[2]

Center of Microstructure Science, Frontier Institute of Science and Technology, Xi’an Jiaotong University, Xi’an 710049, China
Department of Materials Science and Engineering, The Ohio State University, Columbus, USA
Department of Nuclear Science and Engineering and Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, USA
Materials Genome Institute, Shanghai University, Shanghai 200444, China

Publication Date:: Mon Mar 18 00:00:00 EDT 2019

Research Org.:: The Ohio State Univ., Columbus, OH (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); National Natural Science Foundation of China (NSFC)

OSTI Identifier:: 1486894

Alternate Identifier(s):: OSTI ID: 1610547

Grant/Contract Number:: SC0001258; DMR-1410322; DMR-1410636

Resource Type:: Published Article

Journal Name:: Materials Horizons

Additional Journal Information:: Journal Name: Materials Horizons Journal Volume: 6 Journal Issue: 3; Journal ID: ISSN 2051-6347

Publisher:: Royal Society of Chemistry

Country of Publication:: United Kingdom

Language:: English

Subject:: 36 MATERIALS SCIENCE; Chemistry; Materials Science

Citation Formats


                    Zhu, Jiaming, Gao, Yipeng, Wang, Dong, Li, Ju, Zhang, Tong-Yi, and Wang, Yunzhi. Making metals linear super-elastic with ultralow modulus and nearly zero hysteresis.  United Kingdom: N. p., 2019. 
Web.  doi:10.1039/C8MH01141A.

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                    Zhu, Jiaming, Gao, Yipeng, Wang, Dong, Li, Ju, Zhang, Tong-Yi, & Wang, Yunzhi. Making metals linear super-elastic with ultralow modulus and nearly zero hysteresis.  United Kingdom.  https://doi.org/10.1039/C8MH01141A

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                    Zhu, Jiaming, Gao, Yipeng, Wang, Dong, Li, Ju, Zhang, Tong-Yi, and Wang, Yunzhi. Mon .  
"Making metals linear super-elastic with ultralow modulus and nearly zero hysteresis".  United Kingdom.  https://doi.org/10.1039/C8MH01141A.

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@article{osti_1486894,

  title        = {Making metals linear super-elastic with ultralow modulus and nearly zero hysteresis},

  author       = {Zhu, Jiaming and Gao, Yipeng and Wang, Dong and Li, Ju and Zhang, Tong-Yi and Wang, Yunzhi},

  abstractNote = {We demonstrate a novel materials design approach to achieve unprecedented properties by utilizing nanoscale chemo-mechanical coupling. In particular, by using computer simulations we demonstrate how to engineer ultralow modulus (12 GPa), nearly hysteresisfree, and linear super-elastic metals with a giant elastic strain limit (2.7%) by creating appropriate concentration modulations (CMs) at the nanoscale in the parent phase and by pre-straining to regulate the stress-induced martensitic transformation (MT). The nanoscale CMs created via spinodal decomposition produce corresponding phase stability modulations, suppress autocatalysis in nucleation, impose nano-confinements on growth, and hinder long-range ordering of transformation strain during the MT, which changes the otherwise sharp first-order transition into a smeared, macroscopically continuous transition over a large stress range. The pre-straining generates retained martensitic particles that are stable at the test temperature after unloading and act as operational nuclei in subsequent load cycles, eliminating the stress–strain hysteresis and offering an ultralow apparent Young’s modulus. Materials with a high strength and an ultralow apparent Young’s modulus have great potential for application in orthopaedic implants.},

  doi          = {10.1039/C8MH01141A},

  journal      = {Materials Horizons},

  number       = 3,

  volume       = 6,

  place        = {United Kingdom},

  year         = {Mon Mar 18 00:00:00 EDT 2019},

  month        = {Mon Mar 18 00:00:00 EDT 2019}

}

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Works referenced in this record:

The Mechanics and Physics of Defect Nucleation
journal, February 2007

Li, Ju
MRS Bulletin, Vol. 32, Issue 2
DOI: 10.1557/mrs2007.48

Effect of thermo-mechanical treatment on mechanical properties and shape memory behavior of Ti–(26–28)at.% Nb alloys
journal, November 2006

Kim, H. Y.; Kim, J. I.; Inamura, T.
Materials Science and Engineering: A, Vol. 438-440
DOI: 10.1016/j.msea.2006.02.136

Effect of aging on martensitic transformation in γ-MnCu alloy
journal, June 2000

Tsuchiya, K.; Sato, H.; Edo, S.
Materials Science and Engineering: A, Vol. 285, Issue 1-2
DOI: 10.1016/S0921-5093(00)00691-2

Ferrous Polycrystalline Shape-Memory Alloy Showing Huge Superelasticity
journal, March 2010

Tanaka, Y.; Himuro, Y.; Kainuma, R.
Science, Vol. 327, Issue 5972
DOI: 10.1126/science.1183169

Design and mechanical properties of new β type titanium alloys for implant materials
journal, March 1998

Kuroda, Daisuke; Niinomi, Mitsuo; Morinaga, Masahiko
Materials Science and Engineering: A, Vol. 243, Issue 1-2
DOI: 10.1016/S0921-5093(97)00808-3

Titanium alloys in total joint replacement—a materials science perspective
journal, September 1998

Long, Marc; Rack, H. J.
Biomaterials, Vol. 19, Issue 18
DOI: 10.1016/S0142-9612(97)00146-4

Load-biased shape-memory and superelastic properties of a precipitation strengthened high-temperature Ni50.3Ti29.7Hf20 alloy
journal, April 2011

Bigelow, G. S.; Garg, A.; Padula II, S. A.
Scripta Materialia, Vol. 64, Issue 8
DOI: 10.1016/j.scriptamat.2010.12.028

A Transforming Metal Nanocomposite with Large Elastic Strain, Low Modulus, and High Strength
journal, March 2013

Hao, Shijie; Cui, Lishan; Jiang, Daqiang
Science, Vol. 339, Issue 6124, p. 1191-1194
DOI: 10.1126/science.1228602

Crystallographic analysis and phase field simulation of transformation plasticity in a multifunctional β-Ti alloy
journal, February 2017

Zhu, Jiaming; Wu, Honghui; Wang, Dong
International Journal of Plasticity, Vol. 89
DOI: 10.1016/j.ijplas.2016.11.006

A universal symmetry criterion for the design of high performance ferroic materials
journal, April 2017

Gao, Yipeng; Dregia, Suliman A.; Wang, Yunzhi
Acta Materialia, Vol. 127
DOI: 10.1016/j.actamat.2017.01.037

Taming martensitic transformation via concentration modulation at nanoscale
journal, May 2017

Zhu, Jiaming; Gao, Yipeng; Wang, Dong
Acta Materialia, Vol. 130
DOI: 10.1016/j.actamat.2017.03.042

Martensitic transformation, shape memory effect and superelasticity of Ti–Nb binary alloys
journal, May 2006

Kim, H. Y.; Ikehara, Y.; Kim, J. I.
Acta Materialia, Vol. 54, Issue 9
DOI: 10.1016/j.actamat.2006.01.019

Aerospace applications of shape memory alloys
journal, April 2007

Hartl, D. J.; Lagoudas, D. C.
Proceedings of the Institution of Mechanical Engineers, Part G: Journal of Aerospace Engineering, Vol. 221, Issue 4
DOI: 10.1243/09544100JAERO211

Stress-Induced Cubic-to-Hexagonal Phase Transformation in Perovskite Nanothin Films
journal, July 2017

Cao, Shi-Gu; Li, Yunsong; Wu, Hong-Hui
Nano Letters, Vol. 17, Issue 8
DOI: 10.1021/acs.nanolett.7b02570

Ti based biomaterials, the ultimate choice for orthopaedic implants – A review
journal, May 2009

Geetha, M.; Singh, A. K.; Asokamani, R.
Progress in Materials Science, Vol. 54, Issue 3
DOI: 10.1016/j.pmatsci.2008.06.004

Phase Transformations of Nanocrystalline Martensitic Materials
journal, November 2009

Waitz, T.; Tsuchiya, K.; Antretter, T.
MRS Bulletin, Vol. 34, Issue 11
DOI: 10.1557/mrs2009.231

Structural analysis of a new precipitate phase in high-temperature TiNiPt shape memory alloys
journal, August 2010

Kovarik, L.; Yang, F.; Garg, A.
Acta Materialia, Vol. 58, Issue 14
DOI: 10.1016/j.actamat.2010.04.039

A review of shape memory alloy research, applications and opportunities
journal, April 2014

Mohd Jani, Jaronie; Leary, Martin; Subic, Aleksandar
Materials & Design (1980-2015), Vol. 56
DOI: 10.1016/j.matdes.2013.11.084

Beta TiNbSn Alloys with Low Young’s Modulus and High Strength
journal, January 2005

Matsumoto, Hiroaki; Watanabe, Sadao; Hanada, Shuji
MATERIALS TRANSACTIONS, Vol. 46, Issue 5
DOI: 10.2320/matertrans.46.1070

Pseudo-first-order phase transition for ultrahigh positive/negative electrocaloric effects in perovskite ferroelectrics
journal, September 2015

Wu, Hong-Hui; Zhu, Jiaming; Zhang, Tong-Yi
Nano Energy, Vol. 16
DOI: 10.1016/j.nanoen.2015.06.030

Composition dependent crystallography of α ″-martensite in Ti–Nb-based β-titanium alloy
journal, August 2007

Inamura, T.; Kim, J. I.; Kim, H. Y.
Philosophical Magazine, Vol. 87, Issue 23
DOI: 10.1080/14786430601003874

Zur Theorie der Elastizit�tsgrenze und der Festigkeit kristallinischer K�rper
journal, July 1926

Frenkel, J.
Zeitschrift f�r Physik, Vol. 37, Issue 7-8
DOI: 10.1007/BF01397292

Ferroelastic Materials
journal, August 2012

Salje, Ekhard K. H.
Annual Review of Materials Research, Vol. 42, Issue 1
DOI: 10.1146/annurev-matsci-070511-155022

Improvements in spinodal alloys from past to present
journal, December 2012

Findik, Fehim
Materials & Design, Vol. 42
DOI: 10.1016/j.matdes.2012.05.039

Giant Nonhysteretic Responses of Two-Phase Nanostructured Alloys
journal, March 2011

Rao, Wei-Feng; Wuttig, Manfred; Khachaturyan, Armen G.
Physical Review Letters, Vol. 106, Issue 10
DOI: 10.1103/PhysRevLett.106.105703

Free Energy of a Nonuniform System. I. Interfacial Free Energy
journal, February 1958

Cahn, John W.; Hilliard, John E.
The Journal of Chemical Physics, Vol. 28, Issue 2
DOI: 10.1063/1.1744102

Stress-induced nanoscale phase transition in superelastic NiTi by in situ X-ray diffraction
journal, May 2015

Ahadi, Aslan; Sun, Qingping
Acta Materialia, Vol. 90
DOI: 10.1016/j.actamat.2015.02.024

Real-space phase field investigation of evolving magnetic domains and twin structures in a ferromagnetic shape memory alloy
journal, November 2016

Wu, H. H.; Pramanick, A.; Ke, Y. B.
Journal of Applied Physics, Vol. 120, Issue 18
DOI: 10.1063/1.4967531

Kinetics of strain-induced morphological transformation in cubic alloys with a miscibility gap
journal, January 1993

Wang, Y.; Chen, L. -Q.; Khachaturyan, A. G.
Acta Metallurgica et Materialia, Vol. 41, Issue 1
DOI: 10.1016/0956-7151(93)90359-Z

Modeling Abnormal Strain States in Ferroelastic Systems: The Role of Point Defects
journal, November 2010

Wang, Dong; Wang, Yunzhi; Zhang, Zhen
Physical Review Letters, Vol. 105, Issue 20
DOI: 10.1103/PhysRevLett.105.205702

The Ti−V (Titanium-Vanadium) system
journal, June 1981

Murray, Joanne L.
Bulletin of Alloy Phase Diagrams, Vol. 2, Issue 1
DOI: 10.1007/BF02873703

Elastic deformation behaviour of Ti–24Nb–4Zr–7.9Sn for biomedical applications
journal, March 2007

Hao, Y. L.; Li, S. J.; Sun, S. Y.
Acta Biomaterialia, Vol. 3, Issue 2
DOI: 10.1016/j.actbio.2006.11.002

Numerical Simulation of Intercalation-Induced Stress in Li-Ion Battery Electrode Particles
journal, January 2007

Zhang, Xiangchun; Shyy, Wei; Marie Sastry, Ann
Journal of The Electrochemical Society, Vol. 154, Issue 10
DOI: 10.1149/1.2759840

Heterogeneities and strain glass behavior: Role of nanoscale precipitates in low-temperature-aged Ti $_{48.7}$ Ni $_{51.3}$ alloys
journal, March 2013

Ji, Yuanchao; Ding, Xiangdong; Lookman, Turab
Physical Review B, Vol. 87, Issue 10
DOI: 10.1103/PhysRevB.87.104110

Recent titanium R&D for biomedical applications in japan
journal, June 1999

Niinomi, Mitsuo
JOM, Vol. 51, Issue 6
DOI: 10.1007/s11837-999-0091-x

Superelasticity and Tunable Thermal Expansion across a Wide Temperature Range
journal, August 2016

Hao, Y. L.; Wang, H. L.; Li, T.
Journal of Materials Science & Technology, Vol. 32, Issue 8
DOI: 10.1016/j.jmst.2016.06.017

Multifunctional Alloys Obtained via a Dislocation-Free Plastic Deformation Mechanism
journal, April 2003

Saito, T.
Science, Vol. 300, Issue 5618
DOI: 10.1126/science.1081957

Physical metallurgy of Ti–Ni-based shape memory alloys
journal, July 2005

Otsuka, K.; Ren, X.
Progress in Materials Science, Vol. 50, Issue 5
DOI: 10.1016/j.pmatsci.2004.10.001

Ideal Pure Shear Strength of Aluminum and Copper
journal, October 2002

Ogata, S.
Science, Vol. 298, Issue 5594
DOI: 10.1126/science.1076652

Ferroelectric polarization reversal via successive ferroelastic transitions
journal, October 2014

Xu, Ruijuan; Liu, Shi; Grinberg, Ilya
Nature Materials, Vol. 14, Issue 1
DOI: 10.1038/nmat4119

Experiment and theoretical prediction of martensitic transformation crystallography in a Ni–Mn–Ga ferromagnetic shape memory alloy
journal, August 2007

Cong, D. Y.; Zhang, Y. D.; Wang, Y. D.
Acta Materialia, Vol. 55, Issue 14
DOI: 10.1016/j.actamat.2007.04.045

Compositionally graded metals: A new frontier of additive manufacturing
journal, August 2014

Hofmann, Douglas C.; Kolodziejska, Joanna; Roberts, Scott
Journal of Materials Research, Vol. 29, Issue 17
DOI: 10.1557/jmr.2014.208

Martensitic phase transformations in nanocrystalline NiTi studied by TEM
journal, January 2004

Waitz, T.; Kazykhanov, V.; Karnthaler, H. P.
Acta Materialia, Vol. 52, Issue 1
DOI: 10.1016/j.actamat.2003.08.036

The stable and metastable Ti-Nb phase diagrams
journal, October 1988

Moffat, D. L.; Kattner, U. R.
Metallurgical Transactions A, Vol. 19, Issue 10
DOI: 10.1007/BF02645466

Novel ultra-high straining process for bulk materials—development of the accumulative roll-bonding (ARB) process
journal, January 1999

Saito, Y.; Utsunomiya, H.; Tsuji, N.
Acta Materialia, Vol. 47, Issue 2
DOI: 10.1016/S1359-6454(98)00365-6

On the mechanism of superelasticity in Gum metal
journal, February 2009

Talling, R. J.; Dashwood, R. J.; Jackson, M.
Acta Materialia, Vol. 57, Issue 4
DOI: 10.1016/j.actamat.2008.11.013

Strain glass and ferroic glass - Unusual properties from glassy nano-domains: Strain glass and ferroic glass
journal, September 2014

Ren, Xiaobing
physica status solidi (b), Vol. 251, Issue 10
DOI: 10.1002/pssb.201451351

Tracing the coupled atomic shear and shuffle for a cubic to a hexagonal crystal transition
journal, May 2017

Wang, H. L.; Hao, Y. L.; He, S. Y.
Scripta Materialia, Vol. 133
DOI: 10.1016/j.scriptamat.2017.02.024

Titanium-Based Biomaterials for Preventing Stress Shielding between Implant Devices and Bone
journal, January 2011

Niinomi, M.; Nakai, M.
International Journal of Biomaterials, Vol. 2011
DOI: 10.1155/2011/836587

Influence of Ni on martensitic phase transformations in NiTi shape memory alloys
journal, May 2010

Frenzel, J.; George, E. P.; Dlouhy, A.
Acta Materialia, Vol. 58, Issue 9
DOI: 10.1016/j.actamat.2010.02.019

Design and fabrication of a metastable β-type titanium alloy with ultralow elastic modulus and high strength
journal, October 2015

Guo, Shun; Meng, Qingkun; Zhao, Xinqing
Scientific Reports, Vol. 5, Issue 1
DOI: 10.1038/srep14688

The size of a dislocation
journal, January 1940

Peierls, R.
Proceedings of the Physical Society, Vol. 52, Issue 1
DOI: 10.1088/0959-5309/52/1/305

An origin of functional fatigue of shape memory alloys
journal, March 2017

Gao, Y.; Casalena, L.; Bowers, M. L.
Acta Materialia, Vol. 126
DOI: 10.1016/j.actamat.2017.01.001

Direct observation of hierarchical nucleation of martensite and size-dependent superelasticity in shape memory alloys
journal, January 2014

Liu, Lifeng; Ding, Xiangdong; Li, Ju
Nanoscale, Vol. 6, Issue 4
DOI: 10.1039/c3nr05258c

Magnetron sputtering: a review of recent developments and applications
journal, March 2000

Kelly, P. J.; Arnell, R. D.
Vacuum, Vol. 56, Issue 3
DOI: 10.1016/S0042-207X(99)00189-X

Ultralow-fatigue shape memory alloy films
journal, May 2015

Chluba, C.; Ge, W.; Lima de Miranda, R.
Science, Vol. 348, Issue 6238
DOI: 10.1126/science.1261164

Elastic properties of Ti–24Nb–4Zr–8Sn single crystals with bcc crystal structure
journal, May 2011

Zhang, Y. W.; Li, S. J.; Obbard, E. G.
Acta Materialia, Vol. 59, Issue 8
DOI: 10.1016/j.actamat.2011.01.048

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Similar Records

Title: Making metals linear super-elastic with ultralow modulus and nearly zero hysteresis

Abstract

Citation Formats

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Effect of thermo-mechanical treatment on mechanical properties and shape memory behavior of Ti–(26–28)at.% Nb alloys journal, November 2006

Effect of aging on martensitic transformation in γ-MnCu alloy journal, June 2000

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A universal symmetry criterion for the design of high performance ferroic materials journal, April 2017

Taming martensitic transformation via concentration modulation at nanoscale journal, May 2017

Martensitic transformation, shape memory effect and superelasticity of Ti–Nb binary alloys journal, May 2006

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Stress-Induced Cubic-to-Hexagonal Phase Transformation in Perovskite Nanothin Films journal, July 2017

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Zur Theorie der Elastizit�tsgrenze und der Festigkeit kristallinischer K�rper journal, July 1926

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Giant Nonhysteretic Responses of Two-Phase Nanostructured Alloys journal, March 2011

Free Energy of a Nonuniform System. I. Interfacial Free Energy journal, February 1958

Stress-induced nanoscale phase transition in superelastic NiTi by in situ X-ray diffraction journal, May 2015

Real-space phase field investigation of evolving magnetic domains and twin structures in a ferromagnetic shape memory alloy journal, November 2016

Kinetics of strain-induced morphological transformation in cubic alloys with a miscibility gap journal, January 1993

Modeling Abnormal Strain States in Ferroelastic Systems: The Role of Point Defects journal, November 2010

The Ti−V (Titanium-Vanadium) system journal, June 1981

Elastic deformation behaviour of Ti–24Nb–4Zr–7.9Sn for biomedical applications journal, March 2007

Numerical Simulation of Intercalation-Induced Stress in Li-Ion Battery Electrode Particles journal, January 2007

Heterogeneities and strain glass behavior: Role of nanoscale precipitates in low-temperature-aged Ti 48.7 Ni 51.3 alloys journal, March 2013

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