Recognition, Sensing, and Trapping of Bicarbonate Anions with a Dicationic meso-Bis(benzimidazolium) Calix[4]pyrrole

Mulugeta, Endale; He, Qing; Sareen, Divya; Hong, Seong-Jin; Oh, Ju Hyun; Lynch, Vincent M.; Sessler, Jonathan L.; Kim, Sung Kuk; Lee, Chang-Hee

doi:10.1016/j.chempr.2017.10.007

Title: Recognition, Sensing, and Trapping of Bicarbonate Anions with a Dicationic meso-Bis(benzimidazolium) Calix[4]pyrrole

Full Record
Other Related Research

Authors:: Mulugeta, Endale; He, Qing; Sareen, Divya; Hong, Seong-Jin; Oh, Ju Hyun; Lynch, Vincent M.; Sessler, Jonathan L.; Kim, Sung Kuk; Lee, Chang-Hee

Publication Date:: 2017-12-01

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1486884

Grant/Contract Number:: FG02-01ER15186

Resource Type:: Published Article

Journal Name:: Chem

Additional Journal Information:: Journal Name: Chem Journal Volume: 3 Journal Issue: 6; Journal ID: ISSN 2451-9294

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Citation Formats


                    Mulugeta, Endale, He, Qing, Sareen, Divya, Hong, Seong-Jin, Oh, Ju Hyun, Lynch, Vincent M., Sessler, Jonathan L., Kim, Sung Kuk, and Lee, Chang-Hee. Recognition, Sensing, and Trapping of Bicarbonate Anions with a Dicationic meso-Bis(benzimidazolium) Calix[4]pyrrole.  United States: N. p., 2017. 
Web.  doi:10.1016/j.chempr.2017.10.007.

Copy to clipboard


                    Mulugeta, Endale, He, Qing, Sareen, Divya, Hong, Seong-Jin, Oh, Ju Hyun, Lynch, Vincent M., Sessler, Jonathan L., Kim, Sung Kuk, & Lee, Chang-Hee. Recognition, Sensing, and Trapping of Bicarbonate Anions with a Dicationic meso-Bis(benzimidazolium) Calix[4]pyrrole.  United States.  https://doi.org/10.1016/j.chempr.2017.10.007

Copy to clipboard


                    Mulugeta, Endale, He, Qing, Sareen, Divya, Hong, Seong-Jin, Oh, Ju Hyun, Lynch, Vincent M., Sessler, Jonathan L., Kim, Sung Kuk, and Lee, Chang-Hee. Fri .  
"Recognition, Sensing, and Trapping of Bicarbonate Anions with a Dicationic meso-Bis(benzimidazolium) Calix[4]pyrrole".  United States.  https://doi.org/10.1016/j.chempr.2017.10.007.

Copy to clipboard


                    
@article{osti_1486884,

  title        = {Recognition, Sensing, and Trapping of Bicarbonate Anions with a Dicationic meso-Bis(benzimidazolium) Calix[4]pyrrole},

  author       = {Mulugeta, Endale and He, Qing and Sareen, Divya and Hong, Seong-Jin and Oh, Ju Hyun and Lynch, Vincent M. and Sessler, Jonathan L. and Kim, Sung Kuk and Lee, Chang-Hee},

  abstractNote = {},

  doi          = {10.1016/j.chempr.2017.10.007},

  journal      = {Chem},

  number       = 6,

  volume       = 3,

  place        = {United States},

  year         = {2017},

  month        = {12}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Publisher's Version of Record
https://doi.org/10.1016/j.chempr.2017.10.007

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 17 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

Recognition, Sensing, and Trapping of Bicarbonate Anions with a Dicationic meso-Bis(benzimidazolium) Calix[4]pyrrole

Journal Article Mulugeta, Endale ; He, Qing ; Sareen, Divya ; ... - Chem

Not provided.
https://doi.org/10.1016/j.chempr.2017.10.007
Capture and displacement-based release of the bicarbonate anion by calix[4]pyrroles with small rigid straps

Journal Article Heo, Nam Jung ; Yang, Ju Ho ; Lynch, Vincent M. ; ... - Chemical Science

Two-phenoxy walled calix[4]pyrroles 1 and 2 strapped with small rigid linkers containing pyridine and benzene, respectively, have been synthesized. ¹H NMR spectroscopic analyses carried out in CDCl₃ revealed that both of receptors 1 and 2 recognize only F^- and HCO₃^- among various test anions with high preference for HCO₃^- (as the tetraethylammonium, TEA⁺ salt) relative to F^- (as the TBA⁺ salt). The bound HCO₃^- anion was completely released out of the receptors upon the addition of F^- (as the tetrabutylammonium, TBA⁺ salt) as a result of significantly enhanced affinities and selectivities of the receptors for F^- once converted to themore »« less
https://doi.org/10.1039/D0SC03445B
Molecular Recognition Under Interfacial Conditions: Calix[4]pyrrole-Based Cross-linkable Micelles for Ion Pair Extraction

Journal Article Chi, Xiaodong ; Peters, Gretchen Marie ; Hammel, Forrest ; ... - Journal of the American Chemical Society

An anthracene-functionalized, long-tailed calix[4]pyrrole 1, containing both an anion-recognition site and cation-recognition functionality, has been synthesized and fully characterized. Upon ion-pair complexation with FeF₂, receptor 1 self-assembles into multi-micelles in aqueous media. This aggregation process is ascribed to a change in polarity from non-polar to amphiphilic induced upon concurrent anion and cation complexation and permits molecular recognition-based control over chemical morphology under interfacial conditions. Photoirradiation of the micelles serves to cross-link the anthracene units thus stabilizing the aggregates. The combination of ion pair recognition, micelle formation, and cross-linking can be used to extract FeF₂ ion pairs from bulk aqueous solutions.more »« less
Cited by 21
https://doi.org/10.1021/jacs.7b04529

Full Text Available
Molecular Recognition Under Interfacial Conditions: Calix[4]pyrrole-Based Cross-linkable Micelles for Ion Pair Extraction

Journal Article Chi, Xiaodong ; Peters, Gretchen Marie ; Hammel, Forrest ; ... - Journal of the American Chemical Society

Not provided.
https://doi.org/10.1021/jacs.7b04529
Phenanthroline-strapped calix[4]pyrroles: anion receptors displaying affinity reversal as a function of solvent polarity

Journal Article Heo, Nam Jung ; Oh, Ju Hyun ; Lee, Jeong Tae ; ... - Organic Chemistry Frontiers (Online)

Calix[4]pyrroles 1 and 2, diametrically strapped with a phenanthroline via ester and amide linkages, respectively, have been synthesized as anion receptors. It was revealed by ¹H NMR spectroscopic analysis that receptors 1 and 2 possessing both hydrogen bonding donors and acceptors were able to bind the bicarbonate anion (as its tetraethylammonium (TEA⁺) or sodium salt) in CDCl₃, as well as in 15% aqueous DMSO with high affinity and selectivity over other anions. The amide-based receptor 2 contains additional potential hydrogen bonding donors relative to its ester-based congener 1. Nevertheless, in CDCl₃ receptor 1 was found to display a higher affinitymore »« less
Cited by 1
https://doi.org/10.1039/c9qo01377f

Full Text Available

Similar Records