DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Ultrafast Shock-Induced Reactions in Pentaerythritol Tetranitrate Thin Films

Authors:
 [1];  [2];  [1];  [2];  [1];  [1];  [2];  [3]
  1. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
  2. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
  3. Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Sandia National Lab. (SNL-CA), Livermore, CA (United States); Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1485824
Alternate Identifier(s):
OSTI ID: 1497278
Report Number(s):
SAND-2018-11358J; LLNL-JRNL-747961
Journal ID: ISSN 1089-5639; 669458
Grant/Contract Number:  
AC04-94AL85000; AC52-07NA27344
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory
Additional Journal Information:
Journal Volume: 122; Journal Issue: 41; Journal ID: ISSN 1089-5639
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Park, Samuel D., Armstrong, Michael R., Kohl, Ian Thomas, Zaug, Joseph M., Knepper, Robert, Tappan, Alexander S., Bastea, Sorin, and Kay, Jeffrey J. Ultrafast Shock-Induced Reactions in Pentaerythritol Tetranitrate Thin Films. United States: N. p., 2018. Web. doi:10.1021/acs.jpca.8b05387.
Park, Samuel D., Armstrong, Michael R., Kohl, Ian Thomas, Zaug, Joseph M., Knepper, Robert, Tappan, Alexander S., Bastea, Sorin, & Kay, Jeffrey J. Ultrafast Shock-Induced Reactions in Pentaerythritol Tetranitrate Thin Films. United States. https://doi.org/10.1021/acs.jpca.8b05387
Park, Samuel D., Armstrong, Michael R., Kohl, Ian Thomas, Zaug, Joseph M., Knepper, Robert, Tappan, Alexander S., Bastea, Sorin, and Kay, Jeffrey J. Mon . "Ultrafast Shock-Induced Reactions in Pentaerythritol Tetranitrate Thin Films". United States. https://doi.org/10.1021/acs.jpca.8b05387. https://www.osti.gov/servlets/purl/1485824.
@article{osti_1485824,
title = {Ultrafast Shock-Induced Reactions in Pentaerythritol Tetranitrate Thin Films},
author = {Park, Samuel D. and Armstrong, Michael R. and Kohl, Ian Thomas and Zaug, Joseph M. and Knepper, Robert and Tappan, Alexander S. and Bastea, Sorin and Kay, Jeffrey J.},
abstractNote = {},
doi = {10.1021/acs.jpca.8b05387},
journal = {Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory},
number = 41,
volume = 122,
place = {United States},
year = {Mon Oct 01 00:00:00 EDT 2018},
month = {Mon Oct 01 00:00:00 EDT 2018}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 7 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Phenomenological model of shock initiation in heterogeneous explosives
journal, January 1980

  • Lee, E. L.; Tarver, C. M.
  • Physics of Fluids, Vol. 23, Issue 12
  • DOI: 10.1063/1.862940

Critical Conditions for Impact- and Shock-Induced Hot Spots in Solid Explosives
journal, January 1996

  • Tarver, Craig M.; Chidester, Steven K.; Nichols, Albert L.
  • The Journal of Physical Chemistry, Vol. 100, Issue 14
  • DOI: 10.1021/jp953123s

Physicochemical Parameters of Nitramines Influencing Shock Sensitivity
journal, October 2004

  • van?der?Heijden, Antoine?E. ?D. ?M.; Bouma, Richard?H. ?B.; van?der?Steen, Albert?C.
  • Propellants, Explosives, Pyrotechnics, Vol. 29, Issue 5
  • DOI: 10.1002/prep.200400058

Starvation Kinetics
journal, February 1978


A microscopic theory of compressive wave‐induced reactions in solid explosives
journal, January 1982

  • Coffey, C. S.; Toton, E. T.
  • The Journal of Chemical Physics, Vol. 76, Issue 2
  • DOI: 10.1063/1.443065

Shocked molecular solids: Vibrational up pumping, defect hot spot formation, and the onset of chemistry
journal, March 1990

  • Dlott, Dana D.; Fayer, Michael D.
  • The Journal of Chemical Physics, Vol. 92, Issue 6
  • DOI: 10.1063/1.457838

Physical kinetics
journal, June 1988

  • Walker, Franklin E.
  • Journal of Applied Physics, Vol. 63, Issue 11
  • DOI: 10.1063/1.341152

Reactive Molecular Dynamics of Hypervelocity Collisions of PETN Molecules
journal, November 2009

  • Landerville, A. C.; Oleynik, I. I.; White, C. T.
  • The Journal of Physical Chemistry A, Vol. 113, Issue 44
  • DOI: 10.1021/jp905969y

New Developments in the Physical Chemistry of Shock Compression
journal, May 2011


Shock Induced Reaction Observed via Ultrafast Infrared Absorption in Poly(vinyl nitrate) Films
journal, October 2004

  • McGrane, S. D.; Moore, D. S.; Funk, D. J.
  • The Journal of Physical Chemistry A, Vol. 108, Issue 43
  • DOI: 10.1021/jp048464x

Ultrafast Shock Initiation of Exothermic Chemistry in Hydrogen Peroxide
journal, October 2013

  • Armstrong, Michael R.; Zaug, Joseph M.; Goldman, Nir
  • The Journal of Physical Chemistry A, Vol. 117, Issue 49
  • DOI: 10.1021/jp407595u

Ultrafast Chemical Reactions in Shocked Nitromethane Probed with Dynamic Ellipsometry and Transient Absorption Spectroscopy
journal, March 2014

  • Brown, Kathryn E.; McGrane, Shawn D.; Bolme, Cynthia A.
  • The Journal of Physical Chemistry A, Vol. 118, Issue 14
  • DOI: 10.1021/jp4125793

Ultrafast shock-induced chemistry in carbon disulfide probed with dynamic ellipsometry and transient absorption spectroscopy
journal, February 2015

  • Brown, Kathryn E.; Bolme, Cynthia A.; McGrane, Shawn D.
  • Journal of Applied Physics, Vol. 117, Issue 8
  • DOI: 10.1063/1.4913488

Phase transitions under shock-wave loading
journal, July 1977


Chemical Reactions in Energetic Materials
journal, October 1992


Theoretical Studies of the Hydrostatic Compression of RDX, HMX, HNIW, and PETN Crystals
journal, August 1999

  • Sorescu, Dan C.; Rice, Betsy M.; Thompson, Donald L.
  • The Journal of Physical Chemistry B, Vol. 103, Issue 32
  • DOI: 10.1021/jp991202o

Atomistic Simulation of Orientation Dependence in Shock-Induced Initiation of Pentaerythritol Tetranitrate
journal, January 2013

  • Shan, Tzu-Ray; Wixom, Ryan R.; Mattsson, Ann E.
  • The Journal of Physical Chemistry B, Vol. 117, Issue 3
  • DOI: 10.1021/jp310473h

Detonation waves in pentaerythritol tetranitrate
journal, June 1997

  • Tarver, Craig M.; Breithaupt, R. Don; Kury, John W.
  • Journal of Applied Physics, Vol. 81, Issue 11, p. 7193-7202
  • DOI: 10.1063/1.365318

Carbon clustering in detonations
journal, September 1987

  • Shaw, M. S.; Johnson, J. D.
  • Journal of Applied Physics, Vol. 62, Issue 5
  • DOI: 10.1063/1.339554

Dynamic elastic‐plastic properties of single‐crystal pentaerythritol tetranitrate
journal, March 1976

  • Halleck, P. M.; Wackerle, Jerry
  • Journal of Applied Physics, Vol. 47, Issue 3
  • DOI: 10.1063/1.322689

Shock response of pentaerythritol tetranitrate single crystals
journal, October 1991

  • Dick, J. J.; Mulford, R. N.; Spencer, W. J.
  • Journal of Applied Physics, Vol. 70, Issue 7
  • DOI: 10.1063/1.349253

Shock Wave Induced Decomposition Chemistry of Pentaerythritol Tetranitrate Single Crystals:  Time-Resolved Emission Spectroscopy
journal, January 2002

  • Dreger, Zbigniew A.; Gruzdkov, Yuri A.; Gupta, Yogendra M.
  • The Journal of Physical Chemistry B, Vol. 106, Issue 2
  • DOI: 10.1021/jp011682v

Effect of crystal orientation on shock initiation sensitivity of pentaerythritol tetranitrate explosive
journal, May 1984

  • Dick, J. J.
  • Applied Physics Letters, Vol. 44, Issue 9
  • DOI: 10.1063/1.94951

Ultrafast observation of shocked states in a precompressed material
journal, July 2010

  • Armstrong, Michael R.; Crowhurst, Jonathan C.; Bastea, Sorin
  • Journal of Applied Physics, Vol. 108, Issue 2
  • DOI: 10.1063/1.3460801

Chirped pulse reflectivity and frequency domain interferometry in laser driven shock experiments
journal, September 1999


Controlling the microstructure of vapor-deposited pentaerythritol tetranitrate films
journal, June 2011

  • Knepper, Robert; Tappan, Alexander S.; Wixom, Ryan R.
  • Journal of Materials Research, Vol. 26, Issue 13
  • DOI: 10.1557/jmr.2011.177

Spectrally modified chirped pulse generation of sustained shock waves
journal, May 2002

  • McGrane, S. D.; Moore, D. S.; Funk, D. J.
  • Applied Physics Letters, Vol. 80, Issue 21
  • DOI: 10.1063/1.1481986

Anomalous shock initiation of detonation in pentaerythritol tetranitrate crystals
journal, January 1997

  • Dick, J. J.
  • Journal of Applied Physics, Vol. 81, Issue 2
  • DOI: 10.1063/1.364201

High Pressure–High Temperature Polymorphism and Decomposition of Pentaerythritol Tetranitrate (PETN)
journal, June 2013

  • Dreger, Zbigniew A.; Gupta, Yogendra M.
  • The Journal of Physical Chemistry A, Vol. 117, Issue 25
  • DOI: 10.1021/jp404283a

An excitonic mechanism of detonation initiation in explosives
journal, February 2000

  • Kuklja, Maija M.; Stefanovich, Eugene V.; Kunz, A. Barry
  • The Journal of Chemical Physics, Vol. 112, Issue 7
  • DOI: 10.1063/1.480922

First-principles investigation of anisotropic constitutive relationships in pentaerythritol tetranitrate
journal, March 2008


Catalytic behaviour of dense hot water
journal, March 2009

  • Wu, Christine J.; Fried, Laurence E.; Yang, Lin H.
  • Nature Chemistry, Vol. 1, Issue 1
  • DOI: 10.1038/nchem.130

Effect of microstructure on the detonation behavior of vapor-deposited pentaerythritol tetranitrate (PETN) films
conference, January 2018

  • Knepper, Robert; Forrest, Eric C.; Marquez, Michael P.
  • SHOCK COMPRESSION OF CONDENSED MATTER - 2017: Proceedings of the Conference of the American Physical Society Topical Group on Shock Compression of Condensed Matter, AIP Conference Proceedings
  • DOI: 10.1063/1.5044978

Dynamic Transition in the Structure of an Energetic Crystal during Chemical Reactions at Shock Front Prior to Detonation
journal, October 2007


Works referencing / citing this record:

A benchtop shock physics laboratory: Ultrafast laser driven shock spectroscopy and interferometry methods
journal, June 2019

  • Powell, M. S.; Bowlan, P. R.; Son, S. F.
  • Review of Scientific Instruments, Vol. 90, Issue 6
  • DOI: 10.1063/1.5092244