skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: The Impact of Initial SEI Formation Conditions on Strain‐Induced Capacity Losses in Silicon Electrodes

Authors:
 [1];  [1]; ORCiD logo [1]
  1. School of EngineeringBrown University Providence RI 02912 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1485707
Grant/Contract Number:  
DE‐EE0007787
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Name: Advanced Energy Materials; Journal ID: ISSN 1614-6832
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Zhang, Wei, Cai, Truong H., and Sheldon, Brian W. The Impact of Initial SEI Formation Conditions on Strain‐Induced Capacity Losses in Silicon Electrodes. Germany: N. p., 2018. Web. doi:10.1002/aenm.201803066.
Zhang, Wei, Cai, Truong H., & Sheldon, Brian W. The Impact of Initial SEI Formation Conditions on Strain‐Induced Capacity Losses in Silicon Electrodes. Germany. doi:10.1002/aenm.201803066.
Zhang, Wei, Cai, Truong H., and Sheldon, Brian W. Thu . "The Impact of Initial SEI Formation Conditions on Strain‐Induced Capacity Losses in Silicon Electrodes". Germany. doi:10.1002/aenm.201803066.
@article{osti_1485707,
title = {The Impact of Initial SEI Formation Conditions on Strain‐Induced Capacity Losses in Silicon Electrodes},
author = {Zhang, Wei and Cai, Truong H. and Sheldon, Brian W.},
abstractNote = {},
doi = {10.1002/aenm.201803066},
journal = {Advanced Energy Materials},
number = ,
volume = ,
place = {Germany},
year = {2018},
month = {12}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/aenm.201803066

Citation Metrics:
Cited by: 2 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Highly elastic binders integrating polyrotaxanes for silicon microparticle anodes in lithium ion batteries
journal, July 2017


Revealing SEI Morphology: In-Depth Analysis of a Modeling Approach
journal, January 2017

  • Single, Fabian; Horstmann, Birger; Latz, Arnulf
  • Journal of The Electrochemical Society, Vol. 164, Issue 11
  • DOI: 10.1149/2.0121711jes

The Mechanism of SEI Formation on a Single Crystal Si(100) Electrode
journal, January 2015

  • Vogl, Ulrike S.; Lux, Simon F.; Crumlin, Ethan J.
  • Journal of The Electrochemical Society, Vol. 162, Issue 4
  • DOI: 10.1149/2.0391504jes

A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries
journal, September 2010


Silicon-based anodes for lithium-ion batteries: Effectiveness of materials synthesis and electrode preparation
journal, September 2016


Chemistry, Impedance, and Morphology Evolution in Solid Electrolyte Interphase Films during Formation in Lithium Ion Batteries
journal, December 2013

  • Lu, Peng; Li, Chen; Schneider, Eric W.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 2
  • DOI: 10.1021/jp4111019

Ageing mechanisms in lithium-ion batteries
journal, September 2005


Role of the LiPF 6 Salt for the Long-Term Stability of Silicon Electrodes in Li-Ion Batteries – A Photoelectron Spectroscopy Study
journal, January 2013

  • Philippe, Bertrand; Dedryvère, Rémi; Gorgoi, Mihaela
  • Chemistry of Materials, Vol. 25, Issue 3
  • DOI: 10.1021/cm303399v

Thickness effects on the lithiation of amorphous silicon thin films
journal, February 2011


Self-healing SEI enables full-cell cycling of a silicon-majority anode with a coulombic efficiency exceeding 99.9%
journal, January 2017

  • Jin, Yang; Li, Sa; Kushima, Akihiro
  • Energy & Environmental Science, Vol. 10, Issue 2
  • DOI: 10.1039/C6EE02685K

An In Situ X-Ray Diffraction Study of the Reaction of Li with Crystalline Si
journal, January 2007

  • Li, Jing; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 154, Issue 3
  • DOI: 10.1149/1.2409862

Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells
journal, January 2007


In Situ Study of Silicon Electrode Lithiation with X-ray Reflectivity
journal, November 2016


Strain-Induced Lithium Losses in the Solid Electrolyte Interphase on Silicon Electrodes
journal, August 2017

  • Kumar, Ravi; Lu, Peng; Xiao, Xingcheng
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 34
  • DOI: 10.1021/acsami.7b06647

Modeling the delamination of amorphous-silicon thin film anode for lithium-ion battery
journal, January 2014


Silicon Solid Electrolyte Interphase (SEI) of Lithium Ion Battery Characterized by Microscopy and Spectroscopy
journal, June 2013

  • Nie, Mengyun; Abraham, Daniel P.; Chen, Yanjing
  • The Journal of Physical Chemistry C, Vol. 117, Issue 26
  • DOI: 10.1021/jp404155y

In Situ TEM of Two-Phase Lithiation of Amorphous Silicon Nanospheres
journal, January 2013

  • McDowell, Matthew T.; Lee, Seok Woo; Harris, Justin T.
  • Nano Letters, Vol. 13, Issue 2
  • DOI: 10.1021/nl3044508

Reaction of Li with Alloy Thin Films Studied by In Situ AFM
journal, January 2003

  • Beaulieu, L. Y.; Hatchard, T. D.; Bonakdarpour, A.
  • Journal of The Electrochemical Society, Vol. 150, Issue 11
  • DOI: 10.1149/1.1613668

Failure mechanisms of single-crystal silicon electrodes in lithium-ion batteries
journal, June 2016

  • Shi, Feifei; Song, Zhichao; Ross, Philip N.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms11886

Silicon oxycarbide glass-graphene composite paper electrode for long-cycle lithium-ion batteries
journal, March 2016

  • David, Lamuel; Bhandavat, Romil; Barrera, Uriel
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10998

Alumina-Coated Patterned Amorphous Silicon as the Anode for a Lithium-Ion Battery with High Coulombic Efficiency
journal, September 2011


Challenges in the development of advanced Li-ion batteries: a review
journal, January 2011

  • Etacheri, Vinodkumar; Marom, Rotem; Elazari, Ran
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01598b

In Situ and Quantitative Characterization of Solid Electrolyte Interphases
journal, February 2014

  • Cresce, Arthur v.; Russell, Selena M.; Baker, David R.
  • Nano Letters, Vol. 14, Issue 3
  • DOI: 10.1021/nl404471v

Theory of SEI Formation in Rechargeable Batteries: Capacity Fade, Accelerated Aging and Lifetime Prediction
journal, December 2012

  • Pinson, Matthew B.; Bazant, Martin Z.
  • Journal of The Electrochemical Society, Vol. 160, Issue 2
  • DOI: 10.1149/2.044302jes

In Situ and Operando Investigations of Failure Mechanisms of the Solid Electrolyte Interphase on Silicon Electrodes
journal, September 2016


Voltage Dependent Solid Electrolyte Interphase Formation in Silicon Electrodes: Monitoring the Formation of Organic Decomposition Products
journal, December 2015


In Situ Atomic Force Microscopy Study of Initial Solid Electrolyte Interphase Formation on Silicon Electrodes for Li-Ion Batteries
journal, April 2014

  • Tokranov, Anton; Sheldon, Brian W.; Li, Chunzeng
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 9
  • DOI: 10.1021/am500363t

Highly Reversible Lithium Storage in Nanostructured Silicon
journal, January 2003

  • Graetz, J.; Ahn, C. C.; Yazami, R.
  • Electrochemical and Solid-State Letters, Vol. 6, Issue 9
  • DOI: 10.1149/1.1596917

The emerging era of supramolecular polymeric binders in silicon anodes
journal, January 2018

  • Kwon, Tae-woo; Choi, Jang Wook; Coskun, Ali
  • Chemical Society Reviews, Vol. 47, Issue 6
  • DOI: 10.1039/C7CS00858A

Interfacial Properties of the a-Si∕Cu:Active–Inactive Thin-Film Anode System for Lithium-Ion Batteries
journal, January 2006

  • Maranchi, J. P.; Hepp, A. F.; Evans, A. G.
  • Journal of The Electrochemical Society, Vol. 153, Issue 6
  • DOI: 10.1149/1.2184753

Dual-Functionalized Double Carbon Shells Coated Silicon Nanoparticles for High Performance Lithium-Ion Batteries
journal, March 2017

  • Chen, Shuangqiang; Shen, Laifa; van Aken, Peter A.
  • Advanced Materials, Vol. 29, Issue 21
  • DOI: 10.1002/adma.201605650

Direct Visualization of the Solid Electrolyte Interphase and Its Effects on Silicon Electrochemical Performance
journal, August 2016

  • Sina, Mahsa; Alvarado, Judith; Shobukawa, Hitoshi
  • Advanced Materials Interfaces, Vol. 3, Issue 20
  • DOI: 10.1002/admi.201600438

Modified Stoney Equation for Patterned Thin Film Electrodes on Substrates in the Presence of Interfacial Sliding
journal, April 2012

  • Haftbaradaran, Hamed; Soni, Sumit K.; Sheldon, Brian W.
  • Journal of Applied Mechanics, Vol. 79, Issue 3
  • DOI: 10.1115/1.4005900

Elastic softening of amorphous and crystalline Li–Si Phases with increasing Li concentration: A first-principles study
journal, October 2010


Laser Porosificated Silicon Anodes for Lithium Ion Batteries
journal, September 2017

  • Sämann, Christian; Kelesiadou, Katerina; Hosseinioun, Seyedeh Sheida
  • Advanced Energy Materials, Vol. 8, Issue 1
  • DOI: 10.1002/aenm.201701705

The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013

  • Goodenough, John B.; Park, Kyu-Sung
  • Journal of the American Chemical Society, Vol. 135, Issue 4
  • DOI: 10.1021/ja3091438

The mechanism of HF formation in LiPF6 based organic carbonate electrolytes
journal, January 2012


Stable cycling of double-walled silicon nanotube battery anodes through solid–electrolyte interphase control
journal, March 2012

  • Wu, Hui; Chan, Gerentt; Choi, Jang Wook
  • Nature Nanotechnology, Vol. 7, Issue 5
  • DOI: 10.1038/nnano.2012.35

A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes
journal, May 2012

  • Liu, Nian; Wu, Hui; McDowell, Matthew T.
  • Nano Letters, Vol. 12, Issue 6
  • DOI: 10.1021/nl3014814

Review—SEI: Past, Present and Future
journal, January 2017

  • Peled, E.; Menkin, S.
  • Journal of The Electrochemical Society, Vol. 164, Issue 7
  • DOI: 10.1149/2.1441707jes

Nanostructured silicon for high capacity lithium battery anodes
journal, January 2011

  • Szczech, Jeannine R.; Jin, Song
  • Energy Environ. Sci., Vol. 4, Issue 1
  • DOI: 10.1039/C0EE00281J