Templating metastable Pd 2 carboxylate aggregates
Abstract
Evaluation of the potential for metal–metal (M–M) cooperation to enable catalysis requires access to specific polynuclear aggregates that display appropriate geometry and size. In many cases, exerting synthetic control over the aggregation of simple metal salts is a challenge. For example, Pd(II) acetate self assembles as a trimer (i.e. Pd3(OAc)6) both in the solid state and in solution and does not feature close Pd–Pd interactions. Related carboxylate-supported Pd2 aggregates (i.e. Pd2(OAc)4), which would feature close Pd–Pd interactions, are thermodynamically metastable in solution phase and thus largely unavailable. Here we demonstrate ion metathesis within pre-formed metal–organic frameworks (MOFs) to prepare metastable Pd2 tetracarboxylates sites. The newly synthesized materials are characterized by elemental analysis, PXRD, SCXRD, EXAFS, XANES, and gas adsorption analysis. In addition, the critical role of network solvation on the kinetics of ion metathesis was revealed by coupled TGA-MS and ICP-MS experiments. The demonstration of templated ion metathesis to generate specific metastable coordination sites that are inaccessible in solution phase chemistry represents a new opportunity to interrogate the chemistry of specific polynuclear metal aggregates.
- Authors:
-
[1];
[1];
[1]
- Texas A&M University, Department of Chemistry, College Station, USA
- DND-CAT, Northwestern Synchrotron Research Centre at the Advanced Photon Source, Argonne, USA
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Org.:
- USDOE Office of Science (SC); National Science Foundation (NSF); Welch Foundation
- OSTI Identifier:
- 1485518
- Alternate Identifier(s):
- OSTI ID: 1497104
- Grant/Contract Number:
- SC0018977; AC02-06CH11357; CHE-1346572; A-1907
- Resource Type:
- Published Article
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Name: Chemical Science Journal Volume: 10 Journal Issue: 6; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Wang, Chen-Hao, Gao, Wen-Yang, Ma, Qing, and Powers, David C. Templating metastable Pd 2 carboxylate aggregates. United Kingdom: N. p., 2019.
Web. doi:10.1039/C8SC04940H.
Wang, Chen-Hao, Gao, Wen-Yang, Ma, Qing, & Powers, David C. Templating metastable Pd 2 carboxylate aggregates. United Kingdom. https://doi.org/10.1039/C8SC04940H
Wang, Chen-Hao, Gao, Wen-Yang, Ma, Qing, and Powers, David C. Wed .
"Templating metastable Pd 2 carboxylate aggregates". United Kingdom. https://doi.org/10.1039/C8SC04940H.
@article{osti_1485518,
title = {Templating metastable Pd 2 carboxylate aggregates},
author = {Wang, Chen-Hao and Gao, Wen-Yang and Ma, Qing and Powers, David C.},
abstractNote = {Evaluation of the potential for metal–metal (M–M) cooperation to enable catalysis requires access to specific polynuclear aggregates that display appropriate geometry and size. In many cases, exerting synthetic control over the aggregation of simple metal salts is a challenge. For example, Pd(II) acetate self assembles as a trimer (i.e. Pd3(OAc)6) both in the solid state and in solution and does not feature close Pd–Pd interactions. Related carboxylate-supported Pd2 aggregates (i.e. Pd2(OAc)4), which would feature close Pd–Pd interactions, are thermodynamically metastable in solution phase and thus largely unavailable. Here we demonstrate ion metathesis within pre-formed metal–organic frameworks (MOFs) to prepare metastable Pd2 tetracarboxylates sites. The newly synthesized materials are characterized by elemental analysis, PXRD, SCXRD, EXAFS, XANES, and gas adsorption analysis. In addition, the critical role of network solvation on the kinetics of ion metathesis was revealed by coupled TGA-MS and ICP-MS experiments. The demonstration of templated ion metathesis to generate specific metastable coordination sites that are inaccessible in solution phase chemistry represents a new opportunity to interrogate the chemistry of specific polynuclear metal aggregates.},
doi = {10.1039/C8SC04940H},
journal = {Chemical Science},
number = 6,
volume = 10,
place = {United Kingdom},
year = {2019},
month = {2}
}
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Works referenced in this record:
Palladium-Catalyzed Meta -Selective C–H Bond Activation with a Nitrile-Containing Template: Computational Study on Mechanism and Origins of Selectivity
journal, December 2013
- Yang, Yun-Fang; Cheng, Gui-Juan; Liu, Peng
- Journal of the American Chemical Society, Vol. 136, Issue 1
A square-cluster platinum complex with short metal–metal bonds: X-ray crystal structure of the tetragonal form of cyclo -tetrakis[di-μ-acetato-platinum (II)]
journal, June 1978
- Carrondo, M. A. A. F. de C. T.; Skapski, A. C.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 34, Issue 6
Synthesis of palladium(II) 3d-metal(II) paddlewheel acetate-bridged heterodimetallic complexes: Unexpected catalysis by water molecules
journal, April 2009
- Akhmadullina, Nailya S.; Cherkashina, Natalia V.; Kozitsyna, Natalia Yu.
- Inorganica Chimica Acta, Vol. 362, Issue 6
Water-Splitting Chemistry of Photosystem II
journal, November 2006
- McEvoy, James P.; Brudvig, Gary W.
- Chemical Reviews, Vol. 106, Issue 11
Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage
journal, January 2014
- Hoffman, Brian M.; Lukoyanov, Dmitriy; Yang, Zhi-Yong
- Chemical Reviews, Vol. 114, Issue 8
Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd–Pd Bond Cleavage
journal, July 2012
- Powers, David C.; Lee, Eunsung; Ariafard, Alireza
- Journal of the American Chemical Society, Vol. 134, Issue 29
Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions
journal, May 2009
- Marenich, Aleksandr V.; Cramer, Christopher J.; Truhlar, Donald G.
- The Journal of Physical Chemistry B, Vol. 113, Issue 18, p. 6378-6396
Catalytic Methane Monofunctionalization by an Electrogenerated High-Valent Pd Intermediate
journal, October 2017
- O’Reilly, Matthew E.; Kim, R. Soyoung; Oh, Seokjoon
- ACS Central Science, Vol. 3, Issue 11
Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals
journal, January 1985
- Hay, P. Jeffrey; Wadt, Willard R.
- The Journal of Chemical Physics, Vol. 82, Issue 1, p. 299-310
Multimetallic complexes: synthesis and applications
journal, January 2017
- Berry, John F.; Thomas, Christine M.
- Dalton Transactions, Vol. 46, Issue 17
Selective Dimerization of Ethylene to 1-Butene with a Porous Catalyst
journal, February 2016
- Metzger, Eric D.; Brozek, Carl K.; Comito, Robert J.
- ACS Central Science, Vol. 2, Issue 3
A Chemical Route to Activation of Open Metal Sites in the Copper-Based Metal–Organic Framework Materials HKUST-1 and Cu-MOF-2
journal, July 2015
- Kim, Hong Ki; Yun, Won Seok; Kim, Min-Bum
- Journal of the American Chemical Society, Vol. 137, Issue 31
Vanadium–iron complexes featuring metal–metal multiple bonds
journal, January 2013
- Kuppuswamy, Subramaniam; Powers, Tamara M.; Krogman, Jeremy P.
- Chemical Science, Vol. 4, Issue 9
Revised Basis Sets for the LANL Effective Core Potentials
journal, June 2008
- Roy, Lindsay E.; Hay, P. Jeffrey; Martin, Richard L.
- Journal of Chemical Theory and Computation, Vol. 4, Issue 7
Energy‐adjusted a b i n i t i o pseudopotentials for the first row transition elements
journal, January 1987
- Dolg, M.; Wedig, U.; Stoll, H.
- The Journal of Chemical Physics, Vol. 86, Issue 2
A new mixing of Hartree–Fock and local density‐functional theories
journal, January 1993
- Becke, Axel D.
- The Journal of Chemical Physics, Vol. 98, Issue 2
The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals
journal, July 2007
- Zhao, Yan; Truhlar, Donald G.
- Theoretical Chemistry Accounts, Vol. 120, Issue 1-3
Diverse bimetallic mechanisms emerging from transition metal Lewis acid/base pairs: development of co-catalysis with metal carbenes and metal carbonyl anions
journal, January 2018
- Mankad, Neal P.
- Chemical Communications, Vol. 54, Issue 11
Beyond post-synthesis modification: evolution of metal–organic frameworks via building block replacement
journal, January 2014
- Deria, Pravas; Mondloch, Joseph E.; Karagiaridi, Olga
- Chem. Soc. Rev., Vol. 43, Issue 16
Mechanism of Pd-Catalyzed Ar–Ar Bond Formation Involving Ligand-Directed C–H Arylation and Diaryliodonium Oxidants: Computational Studies of Orthopalladation at Binuclear Pd(II) Centers, Oxidation To Form Binuclear Palladium(III) Species, and Ar···Ar Reductive Coupling
journal, January 2013
- Canty, Allan J.; Ariafard, Alireza; Sanford, Melanie S.
- Organometallics, Vol. 32, Issue 2
Mono- and Dimetalation of a Tridentate Bisimidazole-Phosphine Ligand
journal, August 2014
- Flowers, Sarah E.; Cossairt, Brandi M.
- Organometallics, Vol. 33, Issue 17
Structural and Functional Aspects of Metal Sites in Biology
journal, January 1996
- Holm, Richard H.; Kennepohl, Pierre; Solomon, Edward I.
- Chemical Reviews, Vol. 96, Issue 7
The average Pd oxidation state in Pd/SiO2 quantified by L3-edge XANES analysis and its effects on catalytic activity for CO oxidation
journal, January 2012
- Shimizu, Ken-ichi; Kamiya, Yuichi; Osaki, Kaoru
- Catalysis Science & Technology, Vol. 2, Issue 4
N−N Bond Forming Reductive Elimination via a Mixed-Valent Nickel(II)-Nickel(III) Intermediate
journal, May 2016
- Diccianni, Justin B.; Hu, Chunhua; Diao, Tianning
- Angewandte Chemie International Edition, Vol. 55, Issue 26
Bimetallic Redox Synergy in Oxidative Palladium Catalysis
journal, October 2011
- Powers, David C.; Ritter, Tobias
- Accounts of Chemical Research, Vol. 45, Issue 6
A Spectroscopic Study of the Homogeneous Catalytic Conversion of Ethylene to Vinyl Acetate by Palladium Acetate
journal, January 1999
- Kragten, David D.; van Santen, Rutger A.; Crawford, Michael K.
- Inorganic Chemistry, Vol. 38, Issue 2
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density
journal, January 1988
- Lee, Chengteh; Yang, Weitao; Parr, Robert G.
- Physical Review B, Vol. 37, Issue 2
Activation and Catalytic Dehydrogenation of Methane on Small Pd x + and Pd x O + Clusters
journal, May 2013
- Lang, Sandra M.; Frank, Anja; Bernhardt, Thorsten M.
- The Journal of Physical Chemistry C, Vol. 117, Issue 19
Stabilization of Metal−Organic Frameworks with High Surface Areas by the Incorporation of Mesocavities with Microwindows
journal, July 2009
- Zhao, Dan; Yuan, Daqiang; Sun, Daofeng
- Journal of the American Chemical Society, Vol. 131, Issue 26
Harnessing Structural Dynamics in a 2D Manganese–Benzoquinoid Framework To Dramatically Accelerate Metal Transport in Diffusion-Limited Metal Exchange Reactions
journal, July 2018
- Liu, Lujia; Li, Liang; DeGayner, Jordan A.
- Journal of the American Chemical Society, Vol. 140, Issue 36
Mechanism of the Palladium-Catalyzed Arene C–H Acetoxylation: A Comparison of Catalysts and Ligand Effects
journal, February 2015
- Cook, Amanda K.; Sanford, Melanie S.
- Journal of the American Chemical Society, Vol. 137, Issue 8
Ti 3+ -, V 2+/3+ -, Cr 2+/3+ -, Mn 2+ -, and Fe 2+ -Substituted MOF-5 and Redox Reactivity in Cr- and Fe-MOF-5
journal, August 2013
- Brozek, Carl K.; Dincă, Mircea
- Journal of the American Chemical Society, Vol. 135, Issue 34
Structure of Complexes Formed by Dissolution of Palladium Diacetate in Methanol and Chloroform. In Situ NMR Study
journal, October 2011
- Nosova, Valentina M.; Ustynyuk, Yuri A.; Bruk, Lev G.
- Inorganic Chemistry, Vol. 50, Issue 19
Metathesis in Single Crystal: Complete and Reversible Exchange of Metal Ions Constituting the Frameworks of Metal−Organic Frameworks
journal, March 2009
- Das, Sunirban; Kim, Hyunuk; Kim, Kimoon
- Journal of the American Chemical Society, Vol. 131, Issue 11
Factors Controlling Stability and Reactivity of Dimeric Pd(II) Complexes in C–H Functionalization Catalysis
journal, January 2016
- Haines, Brandon E.; Berry, John F.; Yu, Jin-Quan
- ACS Catalysis, Vol. 6, Issue 2
Metal–metal multiple bonding in C3-symmetric bimetallic complexes of the first row transition metals
journal, January 2014
- Krogman, Jeremy P.; Thomas, Christine M.
- Chemical Communications, Vol. 50, Issue 40
Post-synthetic modification of isomorphic coordination layers: exchange dynamics of metal ions in a single crystal to single crystal fashion
journal, January 2012
- Mukherjee, Gargi; Biradha, Kumar
- Chemical Communications, Vol. 48, Issue 36
Large H2 storage capacity of a new polyhedron-based metal–organic framework with high thermal and hygroscopic stability
journal, January 2009
- Hong, Seunghee; Oh, Minhak; Park, Mira
- Chemical Communications, Issue 36
Multiple Metal-Metal Bonds in Iron-Chromium Complexes
journal, March 2013
- Rudd, P. Alex; Liu, Shengsi; Planas, Nora
- Angewandte Chemie International Edition, Vol. 52, Issue 16
Reactions of carbon monoxide with free palladium oxide clusters: strongly size dependent competition between adsorption and combustion
journal, January 2012
- Lang, Sandra M.; Schnabel, Thomas; Bernhardt, Thorsten M.
- Physical Chemistry Chemical Physics, Vol. 14, Issue 26
Density functional study on the activation of methane over Pd2, PdO, and Pd2O clusters
journal, January 1997
- Broclawik, Ewa; Yamauchi, Ryo; Endou, Akira
- International Journal of Quantum Chemistry, Vol. 61, Issue 4
The crystal structures of nickel acetate, Ni(CH 3 COO) 2 .4H 2 O, and cobalt acetate, Co(CH 3 COO) 2 .4H 2 O
journal, July 1953
- van Niekerk, J. N.; Schoening, F. R. L.
- Acta Crystallographica, Vol. 6, Issue 7
IR study of CS2 adsorption on metal oxides: relation with their surface oxygen basicity and mobility
journal, November 2000
- Sahibed-Dine, A.; Aboulayt, A.; Bensitel, M.
- Journal of Molecular Catalysis A: Chemical, Vol. 162, Issue 1-2
Palladium Acetate Revisited: Unusual Ring-Current Effects, One-Electron Reduction, and Metal–Metal Bonding
journal, June 2018
- Pakula, Ryan J.; Srebro-Hooper, Monika; Fry, Charles G.
- Inorganic Chemistry, Vol. 57, Issue 14
Electronic Structures of Pd II Dimers
journal, February 2010
- Bercaw, John E.; Durrell, Alec C.; Gray, Harry B.
- Inorganic Chemistry, Vol. 49, Issue 4
Structure/Function Relationships of [NiFe]- and [FeFe]-Hydrogenases
journal, October 2007
- Fontecilla-Camps, Juan C.; Volbeda, Anne; Cavazza, Christine
- Chemical Reviews, Vol. 107, Issue 10
Direct Characterization of a Reactive Lattice-Confined Ru 2 Nitride by Photocrystallography
journal, February 2017
- Das, Anuvab; Reibenspies, Joseph H.; Chen, Yu-Sheng
- Journal of the American Chemical Society, Vol. 139, Issue 8
Preparation, Crystal Structures, and Properties of the Acetate-Bridged Platinum(III) Compounds [{(H2O)Pt(.mu.-CH3CO2)2}2]A2 (A- = ClO4-, CF3SO3-)
journal, October 1995
- Appleton, Trevor G.; Byriel, Karl A.; Garrett, Jodie M.
- Inorganic Chemistry, Vol. 34, Issue 22
Ab Initio Calculation of Vibrational Absorption and Circular Dichroism Spectra Using Density Functional Force Fields
journal, November 1994
- Stephens, P. J.; Devlin, F. J.; Chabalowski, C. F.
- The Journal of Physical Chemistry, Vol. 98, Issue 45, p. 11623-11627
A Density Functional Study of the Acetoxylation of Ethylene to Vinyl Acetate Catalyzed by Palladium Acetate
journal, April 1999
- Kragten, David D.; van Santen, Rutger A.; Neurock, Matthew
- The Journal of Physical Chemistry A, Vol. 103, Issue 15
Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation
journal, June 2009
- Powers, David C.; Ritter, Tobias
- Nature Chemistry, Vol. 1, Issue 4
Simultaneous introduction of various palladium active sites into MOF via one-pot synthesis: Pd@[Cu 3−x Pd x (BTC) 2 ] n
journal, January 2016
- Zhang, Wenhua; Chen, Zhihao; Al-Naji, Majd
- Dalton Transactions, Vol. 45, Issue 38
A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n
journal, February 1999
- Chui, Stephen S.-Y.; Lo, Samuel M.-F.; Charmant, Jonathan P. H.
- Science, Vol. 283, Issue 5405, p. 1148-1150
Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogues
journal, July 2015
- Brozek, Carl K.; Michaelis, Vladimir K.; Ong, Ta-Chung
- ACS Central Science, Vol. 1, Issue 5
Probing Substrate Diffusion in Interstitial MOF Chemistry with Kinetic Isotope Effects
journal, March 2018
- Wang, Chen-Hao; Das, Anuvab; Gao, Wen-Yang
- Angewandte Chemie International Edition, Vol. 57, Issue 14
Two crystalline modifications of Pd2(μ-ac)2(acac)2
journal, June 2011
- Khranenko, S. P.; Shusharina, E. A.; Gromilov, S. A.
- Journal of Structural Chemistry, Vol. 52, Issue 3
Postsynthetic Ligand and Cation Exchange in Robust Metal–Organic Frameworks
journal, October 2012
- Kim, Min; Cahill, John F.; Fei, Honghan
- Journal of the American Chemical Society, Vol. 134, Issue 43
Mechanism of C−H Bond Activation/C−C Bond Formation Reaction between Diazo Compound and Alkane Catalyzed by Dirhodium Tetracarboxylate
journal, June 2002
- Nakamura, Eiichi; Yoshikai, Naohiko; Yamanaka, Masahiro
- Journal of the American Chemical Society, Vol. 124, Issue 24
A set of f-polarization functions for pseudo-potential basis sets of the transition metals ScCu, YAg and LaAu
journal, June 1993
- Ehlers, A. W.; Böhme, M.; Dapprich, S.
- Chemical Physics Letters, Vol. 208, Issue 1-2
A three-dimensional study of the crystal structure of nickel acetate tetrahydrate
journal, March 1971
- Downie, T. C.; Harrison, W.; Raper, E. S.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 27, Issue 3
Self‐Consistent Molecular‐Orbital Methods. IX. An Extended Gaussian‐Type Basis for Molecular‐Orbital Studies of Organic Molecules
journal, January 1971
- Ditchfield, R.; Hehre, W. J.; Pople, J. A.
- The Journal of Chemical Physics, Vol. 54, Issue 2
Self‐consistent molecular orbital methods. XX. A basis set for correlated wave functions
journal, January 1980
- Krishnan, R.; Binkley, J. S.; Seeger, R.
- The Journal of Chemical Physics, Vol. 72, Issue 1
Synthetic and Mechanistic Studies of Pd-Catalyzed C−H Arylation with Diaryliodonium Salts: Evidence for a Bimetallic High Oxidation State Pd Intermediate
journal, August 2009
- Deprez, Nicholas R.; Sanford, Melanie S.
- Journal of the American Chemical Society, Vol. 131, Issue 31
Bimetallic Palladium Catalysis: Direct Observation of Pd(III)−Pd(III) Intermediates
journal, December 2009
- Powers, David C.; Geibel, Matthias A. L.; Klein, Johannes E. M. N.
- Journal of the American Chemical Society, Vol. 131, Issue 47
Interaction of Palladium(II) Acetate with Sodium and Lithium Acetate in Acetic Acid
journal, April 1974
- Pandey, Raj N.; Henry, Patrick M.
- Canadian Journal of Chemistry, Vol. 52, Issue 8
667. Carboxylates of palladium, platinum, and rhodium, and their adducts
journal, January 1965
- Stephenson, T. A.; Morehouse, S. M.; Powell, A. R.
- Journal of the Chemical Society (Resumed)
Non-trivial behavior of palladium(ii) acetate
journal, January 2005
- Bakhmutov, Vladimir I.; Berry, John F.; Cotton, F. Albert
- Dalton Transactions, Issue 11
Stepwise Synthesis of Metal–Organic Frameworks
journal, February 2017
- Bosch, Mathieu; Yuan, Shuai; Rutledge, William
- Accounts of Chemical Research, Vol. 50, Issue 4
Density‐functional thermochemistry. III. The role of exact exchange
journal, April 1993
- Becke, Axel D.
- The Journal of Chemical Physics, Vol. 98, Issue 7, p. 5648-5652
Speciation of Pd(OAc) 2 in ligandless Suzuki–Miyaura reactions
journal, January 2012
- Adrio, Luis A.; Nguyen, Bao N.; Guilera, Gemma
- Catal. Sci. Technol., Vol. 2, Issue 2
Palladium(II) Containing γ-Keggin Silicodecatungstate That Efficiently Catalyzes Hydration of Nitriles
journal, March 2012
- Hirano, Tomohisa; Uehara, Kazuhiro; Kamata, Keigo
- Journal of the American Chemical Society, Vol. 134, Issue 14
The influence of polarization functions on molecular orbital hydrogenation energies
journal, January 1973
- Hariharan, P. C.; Pople, J. A.
- Theoretica Chimica Acta, Vol. 28, Issue 3
Bimetallic catalysis for C–C and C–X coupling reactions
journal, January 2017
- Pye, Dominic R.; Mankad, Neal P.
- Chemical Science, Vol. 8, Issue 3
On the Mechanism of Palladium-Catalyzed Aromatic C−H Oxidation
journal, October 2010
- Powers, David C.; Xiao, Daphne Y.; Geibel, Matthias A. L.
- Journal of the American Chemical Society, Vol. 132, Issue 41
Searching for Precursors to Metal−Metal Bonded Dipalladium Species: A Study of Pd 2 4+ Complexes
journal, August 2005
- Berry, John F.; Cotton, F. Albert; Ibragimov, Sergey A.
- Inorganic Chemistry, Vol. 44, Issue 17
Identification of the "Active Sites" of a Surface-Catalyzed Reaction
journal, September 1996
- Zambelli, T.; Wintterlin, J.; Trost, J.
- Science, Vol. 273, Issue 5282
Metal–Metal Bonds in Catalysis
journal, December 2016
- Powers, Ian G.; Uyeda, Christopher
- ACS Catalysis, Vol. 7, Issue 2
Rational Construction of Porous Polymeric Cadmium Ferrocene-1,1′-disulfonates for Transition Metal Ion Exchange and Sorption
journal, December 2007
- Mi, Liwei; Hou, Hongwei; Song, Zhiyong
- Crystal Growth & Design, Vol. 7, Issue 12
Reactivity of Hydride Bridges in High-Spin [3M–3(μ-H)] Clusters (M = Fe II , Co II )
journal, August 2015
- Lee, Yousoon; Anderton, Kevin J.; Sloane, Forrest T.
- Journal of the American Chemical Society, Vol. 137, Issue 33
Structurally Diverse Diazafluorene-Ligated Palladium(II) Complexes and Their Implications for Aerobic Oxidation Reactions
journal, March 2016
- White, Paul B.; Jaworski, Jonathan N.; Fry, Charles G.
- Journal of the American Chemical Society, Vol. 138, Issue 14
Can Palladium Acetate Lose Its “Saltiness”? Catalytic Activities of the Impurities in Palladium Acetate
journal, October 2015
- Carole, William A.; Bradley, Jonathan; Sarwar, Misbah
- Organic Letters, Vol. 17, Issue 21
Transmetalation: routes to metal exchange within metal–organic frameworks
journal, January 2013
- Lalonde, Marianne; Bury, Wojciech; Karagiaridi, Olga
- Journal of Materials Chemistry A, Vol. 1, Issue 18
Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru)
journal, January 2012
- Wade, Casey R.; Dincă, Mircea
- Dalton Transactions, Vol. 41, Issue 26
Energy-adjustedab initio pseudopotentials for the second and third row transition elements
journal, January 1990
- Andrae, D.; H�u�ermann, U.; Dolg, M.
- Theoretica Chimica Acta, Vol. 77, Issue 2
Oxidative Group Transfer to a Triiron Complex to Form a Nucleophilic μ 3 -Nitride, [Fe 3 (μ 3 -N)] −
journal, March 2011
- Powers, Tamara M.; Fout, Alison R.; Zheng, Shao-Liang
- Journal of the American Chemical Society, Vol. 133, Issue 10
Reduced and Superreduced Diplatinum Complexes
journal, April 2016
- Darnton, Tania V.; Hunter, Bryan M.; Hill, Michael G.
- Journal of the American Chemical Society, Vol. 138, Issue 17
High-Enthalpy Hydrogen Adsorption in Cation-Exchanged Variants of the Microporous Metal−Organic Framework Mn 3 [(Mn 4 Cl) 3 (BTT) 8 (CH 3 OH) 10 ] 2
journal, September 2007
- Dincǎ, Mircea; Long, Jeffrey R.
- Journal of the American Chemical Society, Vol. 129, Issue 36
Transmetalations in two metal–organic frameworks with different framework flexibilities: Kinetics and core–shell heterostructure
journal, January 2012
- Song, Xiaokai; Jeong, Seok; Kim, Dongwook
- CrystEngComm, Vol. 14, Issue 18
Cation exchange at the secondary building units of metal–organic frameworks
journal, January 2014
- Brozek, C. K.; Dincă, M.
- Chem. Soc. Rev., Vol. 43, Issue 16
Structure extending and cation exchange of Cd(ii) and Co(ii) materials compounds inducing fluorescence signal mutation
journal, January 2010
- Huang, Shengli; Li, Xiaoxia; Shi, Xianju
- Journal of Materials Chemistry, Vol. 20, Issue 27
Heterogeneous Catalysis
journal, February 2015
- Schlögl, Robert
- Angewandte Chemie International Edition, Vol. 54, Issue 11
[Pd(CH 3 COO) 2 ] n from X-ray powder diffraction data
journal, August 2004
- Kirik, Sergei D.; Mulagaleev, Ruslan F.; Blokhin, Alexander I.
- Acta Crystallographica Section C Crystal Structure Communications, Vol. 60, Issue 9
The Postsynthetic Renaissance in Porous Solids
journal, February 2017
- Cohen, Seth M.
- Journal of the American Chemical Society, Vol. 139, Issue 8
Synthesis and C−C Coupling Reactivity of a Dinuclear Ni I −Ni I Complex Supported by a Terphenyl Diphosphine
journal, May 2010
- Velian, Alexandra; Lin, Sibo; Miller, Alexander J. M.
- Journal of the American Chemical Society, Vol. 132, Issue 18
Multiple chromium(II)-chromium(II) and rhodium(II)-rhodium(II) bonds
journal, May 1970
- Cotton, F. Albert.; DeBoer, B. G.; Laprade, Marie D.
- Journal of the American Chemical Society, Vol. 92, Issue 9
The crystal structure of trimeric palladium(II) acetate
journal, January 1970
- Skapski, A. C.; Smart, M. L.
- Journal of the Chemical Society D: Chemical Communications, Issue 11
Mechanistic Details of Pd(II)-Catalyzed C–H Iodination with Molecular I 2 : Oxidative Addition vs Electrophilic Cleavage
journal, July 2015
- Haines, Brandon E.; Xu, Huiying; Verma, Pritha
- Journal of the American Chemical Society, Vol. 137, Issue 28
1,3,5,7-Tetrakis(tetrazol-5-yl)-adamantane: the smallest tetrahedral tetrazole-functionalized ligand and its complexes formed by reaction with anhydrous M( ii )Cl 2 (M = Mn, Cu, Zn, Cd)
journal, January 2014
- Boldog, Ishtvan; Domasevitch, Konstantin V.; Sanchiz, Joaquín
- Dalton Trans., Vol. 43, Issue 33