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Title: Templating metastable Pd 2 carboxylate aggregates


Evaluation of the potential for metal–metal (M–M) cooperation to enable catalysis requires access to specific polynuclear aggregates that display appropriate geometry and size. Here we demonstrate ion metathesis within pre-formed metal–organic frameworks (MOFs) to prepare metastable Pd 2 tetracarboxylates sites.

ORCiD logo [1]; ORCiD logo [1];  [2]; ORCiD logo [1]
  1. Texas A&M University, Department of Chemistry, College Station, USA
  2. DND-CAT, Northwestern Synchrotron Research Centre at the Advanced Photon Source, Argonne, USA
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Sponsoring Org.:
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Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 10 Journal Issue: 6; Journal ID: ISSN 2041-6520
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom

Citation Formats

Wang, Chen-Hao, Gao, Wen-Yang, Ma, Qing, and Powers, David C. Templating metastable Pd 2 carboxylate aggregates. United Kingdom: N. p., 2019. Web.
Wang, Chen-Hao, Gao, Wen-Yang, Ma, Qing, & Powers, David C. Templating metastable Pd 2 carboxylate aggregates. United Kingdom.
Wang, Chen-Hao, Gao, Wen-Yang, Ma, Qing, and Powers, David C. Wed . "Templating metastable Pd 2 carboxylate aggregates". United Kingdom.
title = {Templating metastable Pd 2 carboxylate aggregates},
author = {Wang, Chen-Hao and Gao, Wen-Yang and Ma, Qing and Powers, David C.},
abstractNote = {Evaluation of the potential for metal–metal (M–M) cooperation to enable catalysis requires access to specific polynuclear aggregates that display appropriate geometry and size. Here we demonstrate ion metathesis within pre-formed metal–organic frameworks (MOFs) to prepare metastable Pd 2 tetracarboxylates sites.},
doi = {10.1039/C8SC04940H},
journal = {Chemical Science},
number = 6,
volume = 10,
place = {United Kingdom},
year = {2019},
month = {2}

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Palladium-Catalyzed Meta -Selective C–H Bond Activation with a Nitrile-Containing Template: Computational Study on Mechanism and Origins of Selectivity
journal, December 2013

  • Yang, Yun-Fang; Cheng, Gui-Juan; Liu, Peng
  • Journal of the American Chemical Society, Vol. 136, Issue 1
  • DOI: 10.1021/ja410485g

A square-cluster platinum complex with short metal–metal bonds: X-ray crystal structure of the tetragonal form of cyclo -tetrakis[di-μ-acetato-platinum (II)]
journal, June 1978

  • Carrondo, M. A. A. F. de C. T.; Skapski, A. C.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 34, Issue 6
  • DOI: 10.1107/S0567740878006846

Synthesis of palladium(II) 3d-metal(II) paddlewheel acetate-bridged heterodimetallic complexes: Unexpected catalysis by water molecules
journal, April 2009

  • Akhmadullina, Nailya S.; Cherkashina, Natalia V.; Kozitsyna, Natalia Yu.
  • Inorganica Chimica Acta, Vol. 362, Issue 6
  • DOI: 10.1016/j.ica.2008.09.042

Water-Splitting Chemistry of Photosystem II
journal, November 2006

  • McEvoy, James P.; Brudvig, Gary W.
  • Chemical Reviews, Vol. 106, Issue 11
  • DOI: 10.1021/cr0204294

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage
journal, January 2014

  • Hoffman, Brian M.; Lukoyanov, Dmitriy; Yang, Zhi-Yong
  • Chemical Reviews, Vol. 114, Issue 8
  • DOI: 10.1021/cr400641x

Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd–Pd Bond Cleavage
journal, July 2012

  • Powers, David C.; Lee, Eunsung; Ariafard, Alireza
  • Journal of the American Chemical Society, Vol. 134, Issue 29
  • DOI: 10.1021/ja304401u

Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions
journal, May 2009

  • Marenich, Aleksandr V.; Cramer, Christopher J.; Truhlar, Donald G.
  • The Journal of Physical Chemistry B, Vol. 113, Issue 18, p. 6378-6396
  • DOI: 10.1021/jp810292n

Catalytic Methane Monofunctionalization by an Electrogenerated High-Valent Pd Intermediate
journal, October 2017

Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals
journal, January 1985

  • Hay, P. Jeffrey; Wadt, Willard R.
  • The Journal of Chemical Physics, Vol. 82, Issue 1, p. 299-310
  • DOI: 10.1063/1.448975

Multimetallic complexes: synthesis and applications
journal, January 2017

  • Berry, John F.; Thomas, Christine M.
  • Dalton Transactions, Vol. 46, Issue 17
  • DOI: 10.1039/C7DT90057K

Selective Dimerization of Ethylene to 1-Butene with a Porous Catalyst
journal, February 2016

A Chemical Route to Activation of Open Metal Sites in the Copper-Based Metal–Organic Framework Materials HKUST-1 and Cu-MOF-2
journal, July 2015

  • Kim, Hong Ki; Yun, Won Seok; Kim, Min-Bum
  • Journal of the American Chemical Society, Vol. 137, Issue 31
  • DOI: 10.1021/jacs.5b06637

Vanadium–iron complexes featuring metal–metal multiple bonds
journal, January 2013

  • Kuppuswamy, Subramaniam; Powers, Tamara M.; Krogman, Jeremy P.
  • Chemical Science, Vol. 4, Issue 9
  • DOI: 10.1039/c3sc51337h

Revised Basis Sets for the LANL Effective Core Potentials
journal, June 2008

  • Roy, Lindsay E.; Hay, P. Jeffrey; Martin, Richard L.
  • Journal of Chemical Theory and Computation, Vol. 4, Issue 7
  • DOI: 10.1021/ct8000409

Energy‐adjusted a b i n i t i o pseudopotentials for the first row transition elements
journal, January 1987

  • Dolg, M.; Wedig, U.; Stoll, H.
  • The Journal of Chemical Physics, Vol. 86, Issue 2
  • DOI: 10.1063/1.452288

A new mixing of Hartree–Fock and local density‐functional theories
journal, January 1993

  • Becke, Axel D.
  • The Journal of Chemical Physics, Vol. 98, Issue 2
  • DOI: 10.1063/1.464304

Beyond post-synthesis modification: evolution of metal–organic frameworks via building block replacement
journal, January 2014

  • Deria, Pravas; Mondloch, Joseph E.; Karagiaridi, Olga
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00067F

Mono- and Dimetalation of a Tridentate Bisimidazole-Phosphine Ligand
journal, August 2014

  • Flowers, Sarah E.; Cossairt, Brandi M.
  • Organometallics, Vol. 33, Issue 17
  • DOI: 10.1021/om500592u

Structural and Functional Aspects of Metal Sites in Biology
journal, January 1996

  • Holm, Richard H.; Kennepohl, Pierre; Solomon, Edward I.
  • Chemical Reviews, Vol. 96, Issue 7
  • DOI: 10.1021/cr9500390

The average Pd oxidation state in Pd/SiO2 quantified by L3-edge XANES analysis and its effects on catalytic activity for CO oxidation
journal, January 2012

  • Shimizu, Ken-ichi; Kamiya, Yuichi; Osaki, Kaoru
  • Catalysis Science & Technology, Vol. 2, Issue 4
  • DOI: 10.1039/c2cy00422d

N−N Bond Forming Reductive Elimination via a Mixed-Valent Nickel(II)-Nickel(III) Intermediate
journal, May 2016

  • Diccianni, Justin B.; Hu, Chunhua; Diao, Tianning
  • Angewandte Chemie International Edition, Vol. 55, Issue 26
  • DOI: 10.1002/anie.201602566

Bimetallic Redox Synergy in Oxidative Palladium Catalysis
journal, October 2011

  • Powers, David C.; Ritter, Tobias
  • Accounts of Chemical Research, Vol. 45, Issue 6
  • DOI: 10.1021/ar2001974

A Spectroscopic Study of the Homogeneous Catalytic Conversion of Ethylene to Vinyl Acetate by Palladium Acetate
journal, January 1999

  • Kragten, David D.; van Santen, Rutger A.; Crawford, Michael K.
  • Inorganic Chemistry, Vol. 38, Issue 2
  • DOI: 10.1021/ic980399g

Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density
journal, January 1988

Activation and Catalytic Dehydrogenation of Methane on Small Pd x + and Pd x O + Clusters
journal, May 2013

  • Lang, Sandra M.; Frank, Anja; Bernhardt, Thorsten M.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 19
  • DOI: 10.1021/jp312852r

Stabilization of Metal−Organic Frameworks with High Surface Areas by the Incorporation of Mesocavities with Microwindows
journal, July 2009

  • Zhao, Dan; Yuan, Daqiang; Sun, Daofeng
  • Journal of the American Chemical Society, Vol. 131, Issue 26
  • DOI: 10.1021/ja901109t

Harnessing Structural Dynamics in a 2D Manganese–Benzoquinoid Framework To Dramatically Accelerate Metal Transport in Diffusion-Limited Metal Exchange Reactions
journal, July 2018

  • Liu, Lujia; Li, Liang; DeGayner, Jordan A.
  • Journal of the American Chemical Society, Vol. 140, Issue 36
  • DOI: 10.1021/jacs.8b06774

Mechanism of the Palladium-Catalyzed Arene C–H Acetoxylation: A Comparison of Catalysts and Ligand Effects
journal, February 2015

  • Cook, Amanda K.; Sanford, Melanie S.
  • Journal of the American Chemical Society, Vol. 137, Issue 8
  • DOI: 10.1021/jacs.5b00238

Ti 3+ -, V 2+/3+ -, Cr 2+/3+ -, Mn 2+ -, and Fe 2+ -Substituted MOF-5 and Redox Reactivity in Cr- and Fe-MOF-5
journal, August 2013

  • Brozek, Carl K.; Dincă, Mircea
  • Journal of the American Chemical Society, Vol. 135, Issue 34
  • DOI: 10.1021/ja4064475

Structure of Complexes Formed by Dissolution of Palladium Diacetate in Methanol and Chloroform. In Situ NMR Study
journal, October 2011

  • Nosova, Valentina M.; Ustynyuk, Yuri A.; Bruk, Lev G.
  • Inorganic Chemistry, Vol. 50, Issue 19
  • DOI: 10.1021/ic200617e

Metathesis in Single Crystal: Complete and Reversible Exchange of Metal Ions Constituting the Frameworks of Metal−Organic Frameworks
journal, March 2009

  • Das, Sunirban; Kim, Hyunuk; Kim, Kimoon
  • Journal of the American Chemical Society, Vol. 131, Issue 11
  • DOI: 10.1021/ja808995d

Factors Controlling Stability and Reactivity of Dimeric Pd(II) Complexes in C–H Functionalization Catalysis
journal, January 2016

Metal–metal multiple bonding in C3-symmetric bimetallic complexes of the first row transition metals
journal, January 2014

  • Krogman, Jeremy P.; Thomas, Christine M.
  • Chemical Communications, Vol. 50, Issue 40
  • DOI: 10.1039/c3cc47537a

Post-synthetic modification of isomorphic coordination layers: exchange dynamics of metal ions in a single crystal to single crystal fashion
journal, January 2012

  • Mukherjee, Gargi; Biradha, Kumar
  • Chemical Communications, Vol. 48, Issue 36
  • DOI: 10.1039/c2cc30983a

Large H2 storage capacity of a new polyhedron-based metal–organic framework with high thermal and hygroscopic stability
journal, January 2009

  • Hong, Seunghee; Oh, Minhak; Park, Mira
  • Chemical Communications, Issue 36
  • DOI: 10.1039/b909250a

Multiple Metal-Metal Bonds in Iron-Chromium Complexes
journal, March 2013

  • Rudd, P. Alex; Liu, Shengsi; Planas, Nora
  • Angewandte Chemie International Edition, Vol. 52, Issue 16
  • DOI: 10.1002/anie.201208686

Reactions of carbon monoxide with free palladium oxide clusters: strongly size dependent competition between adsorption and combustion
journal, January 2012

  • Lang, Sandra M.; Schnabel, Thomas; Bernhardt, Thorsten M.
  • Physical Chemistry Chemical Physics, Vol. 14, Issue 26
  • DOI: 10.1039/c2cp23976k

Density functional study on the activation of methane over Pd2, PdO, and Pd2O clusters
journal, January 1997

The crystal structures of nickel acetate, Ni(CH 3 COO) 2 .4H 2 O, and cobalt acetate, Co(CH 3 COO) 2 .4H 2 O
journal, July 1953

IR study of CS2 adsorption on metal oxides: relation with their surface oxygen basicity and mobility
journal, November 2000

  • Sahibed-Dine, A.; Aboulayt, A.; Bensitel, M.
  • Journal of Molecular Catalysis A: Chemical, Vol. 162, Issue 1-2
  • DOI: 10.1016/S1381-1169(00)00326-5

Palladium Acetate Revisited: Unusual Ring-Current Effects, One-Electron Reduction, and Metal–Metal Bonding
journal, June 2018

Electronic Structures of Pd II Dimers
journal, February 2010

  • Bercaw, John E.; Durrell, Alec C.; Gray, Harry B.
  • Inorganic Chemistry, Vol. 49, Issue 4
  • DOI: 10.1021/ic902189g

Structure/Function Relationships of [NiFe]- and [FeFe]-Hydrogenases
journal, October 2007

  • Fontecilla-Camps, Juan C.; Volbeda, Anne; Cavazza, Christine
  • Chemical Reviews, Vol. 107, Issue 10
  • DOI: 10.1021/cr050195z

Direct Characterization of a Reactive Lattice-Confined Ru 2 Nitride by Photocrystallography
journal, February 2017

  • Das, Anuvab; Reibenspies, Joseph H.; Chen, Yu-Sheng
  • Journal of the American Chemical Society, Vol. 139, Issue 8
  • DOI: 10.1021/jacs.6b13357

Preparation, Crystal Structures, and Properties of the Acetate-Bridged Platinum(III) Compounds [{(H2O)Pt(.mu.-CH3CO2)2}2]A2 (A- = ClO4-, CF3SO3-)
journal, October 1995

  • Appleton, Trevor G.; Byriel, Karl A.; Garrett, Jodie M.
  • Inorganic Chemistry, Vol. 34, Issue 22
  • DOI: 10.1021/ic00126a039

Ab Initio Calculation of Vibrational Absorption and Circular Dichroism Spectra Using Density Functional Force Fields
journal, November 1994

  • Stephens, P. J.; Devlin, F. J.; Chabalowski, C. F.
  • The Journal of Physical Chemistry, Vol. 98, Issue 45, p. 11623-11627
  • DOI: 10.1021/j100096a001

A Density Functional Study of the Acetoxylation of Ethylene to Vinyl Acetate Catalyzed by Palladium Acetate
journal, April 1999

  • Kragten, David D.; van Santen, Rutger A.; Neurock, Matthew
  • The Journal of Physical Chemistry A, Vol. 103, Issue 15
  • DOI: 10.1021/jp982956q

Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation
journal, June 2009

  • Powers, David C.; Ritter, Tobias
  • Nature Chemistry, Vol. 1, Issue 4
  • DOI: 10.1038/nchem.246

Simultaneous introduction of various palladium active sites into MOF via one-pot synthesis: Pd@[Cu 3−x Pd x (BTC) 2 ] n
journal, January 2016

  • Zhang, Wenhua; Chen, Zhihao; Al-Naji, Majd
  • Dalton Transactions, Vol. 45, Issue 38
  • DOI: 10.1039/C6DT02893D

A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n
journal, February 1999

Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogues
journal, July 2015

Probing Substrate Diffusion in Interstitial MOF Chemistry with Kinetic Isotope Effects
journal, March 2018

  • Wang, Chen-Hao; Das, Anuvab; Gao, Wen-Yang
  • Angewandte Chemie International Edition, Vol. 57, Issue 14
  • DOI: 10.1002/anie.201713244

Two crystalline modifications of Pd2(μ-ac)2(acac)2
journal, June 2011

  • Khranenko, S. P.; Shusharina, E. A.; Gromilov, S. A.
  • Journal of Structural Chemistry, Vol. 52, Issue 3
  • DOI: 10.1134/S0022476611030140

Postsynthetic Ligand and Cation Exchange in Robust Metal–Organic Frameworks
journal, October 2012

  • Kim, Min; Cahill, John F.; Fei, Honghan
  • Journal of the American Chemical Society, Vol. 134, Issue 43
  • DOI: 10.1021/ja3079219

Mechanism of C−H Bond Activation/C−C Bond Formation Reaction between Diazo Compound and Alkane Catalyzed by Dirhodium Tetracarboxylate
journal, June 2002

  • Nakamura, Eiichi; Yoshikai, Naohiko; Yamanaka, Masahiro
  • Journal of the American Chemical Society, Vol. 124, Issue 24
  • DOI: 10.1021/ja017823o

A set of f-polarization functions for pseudo-potential basis sets of the transition metals ScCu, YAg and LaAu
journal, June 1993

A three-dimensional study of the crystal structure of nickel acetate tetrahydrate
journal, March 1971

  • Downie, T. C.; Harrison, W.; Raper, E. S.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 27, Issue 3
  • DOI: 10.1107/S0567740871002802

Self‐Consistent Molecular‐Orbital Methods. IX. An Extended Gaussian‐Type Basis for Molecular‐Orbital Studies of Organic Molecules
journal, January 1971

  • Ditchfield, R.; Hehre, W. J.; Pople, J. A.
  • The Journal of Chemical Physics, Vol. 54, Issue 2
  • DOI: 10.1063/1.1674902

Self‐consistent molecular orbital methods. XX. A basis set for correlated wave functions
journal, January 1980

  • Krishnan, R.; Binkley, J. S.; Seeger, R.
  • The Journal of Chemical Physics, Vol. 72, Issue 1
  • DOI: 10.1063/1.438955

Synthetic and Mechanistic Studies of Pd-Catalyzed C−H Arylation with Diaryliodonium Salts: Evidence for a Bimetallic High Oxidation State Pd Intermediate
journal, August 2009

  • Deprez, Nicholas R.; Sanford, Melanie S.
  • Journal of the American Chemical Society, Vol. 131, Issue 31
  • DOI: 10.1021/ja904116k

Bimetallic Palladium Catalysis: Direct Observation of Pd(III)−Pd(III) Intermediates
journal, December 2009

  • Powers, David C.; Geibel, Matthias A. L.; Klein, Johannes E. M. N.
  • Journal of the American Chemical Society, Vol. 131, Issue 47
  • DOI: 10.1021/ja906935c

Interaction of Palladium(II) Acetate with Sodium and Lithium Acetate in Acetic Acid
journal, April 1974

  • Pandey, Raj N.; Henry, Patrick M.
  • Canadian Journal of Chemistry, Vol. 52, Issue 8
  • DOI: 10.1139/v74-193

667. Carboxylates of palladium, platinum, and rhodium, and their adducts
journal, January 1965

  • Stephenson, T. A.; Morehouse, S. M.; Powell, A. R.
  • Journal of the Chemical Society (Resumed)
  • DOI: 10.1039/jr9650003632

Non-trivial behavior of palladium(ii) acetate
journal, January 2005

  • Bakhmutov, Vladimir I.; Berry, John F.; Cotton, F. Albert
  • Dalton Transactions, Issue 11
  • DOI: 10.1039/b502122g

Stepwise Synthesis of Metal–Organic Frameworks
journal, February 2017

Density‐functional thermochemistry. III. The role of exact exchange
journal, April 1993

  • Becke, Axel D.
  • The Journal of Chemical Physics, Vol. 98, Issue 7, p. 5648-5652
  • DOI: 10.1063/1.464913

Speciation of Pd(OAc) 2 in ligandless Suzuki–Miyaura reactions
journal, January 2012

  • Adrio, Luis A.; Nguyen, Bao N.; Guilera, Gemma
  • Catal. Sci. Technol., Vol. 2, Issue 2
  • DOI: 10.1039/C1CY00241D

Palladium(II) Containing γ-Keggin Silicodecatungstate That Efficiently Catalyzes Hydration of Nitriles
journal, March 2012

  • Hirano, Tomohisa; Uehara, Kazuhiro; Kamata, Keigo
  • Journal of the American Chemical Society, Vol. 134, Issue 14
  • DOI: 10.1021/ja3006012

The influence of polarization functions on molecular orbital hydrogenation energies
journal, January 1973

  • Hariharan, P. C.; Pople, J. A.
  • Theoretica Chimica Acta, Vol. 28, Issue 3
  • DOI: 10.1007/BF00533485

Bimetallic catalysis for C–C and C–X coupling reactions
journal, January 2017

  • Pye, Dominic R.; Mankad, Neal P.
  • Chemical Science, Vol. 8, Issue 3
  • DOI: 10.1039/C6SC05556G

On the Mechanism of Palladium-Catalyzed Aromatic C−H Oxidation
journal, October 2010

  • Powers, David C.; Xiao, Daphne Y.; Geibel, Matthias A. L.
  • Journal of the American Chemical Society, Vol. 132, Issue 41
  • DOI: 10.1021/ja1054274

Searching for Precursors to Metal−Metal Bonded Dipalladium Species:  A Study of Pd 2 4+ Complexes
journal, August 2005

  • Berry, John F.; Cotton, F. Albert; Ibragimov, Sergey A.
  • Inorganic Chemistry, Vol. 44, Issue 17
  • DOI: 10.1021/ic050876c

Identification of the "Active Sites" of a Surface-Catalyzed Reaction
journal, September 1996

Metal–Metal Bonds in Catalysis
journal, December 2016

Rational Construction of Porous Polymeric Cadmium Ferrocene-1,1′-disulfonates for Transition Metal Ion Exchange and Sorption
journal, December 2007

  • Mi, Liwei; Hou, Hongwei; Song, Zhiyong
  • Crystal Growth & Design, Vol. 7, Issue 12
  • DOI: 10.1021/cg070468e

Reactivity of Hydride Bridges in High-Spin [3M–3(μ-H)] Clusters (M = Fe II , Co II )
journal, August 2015

  • Lee, Yousoon; Anderton, Kevin J.; Sloane, Forrest T.
  • Journal of the American Chemical Society, Vol. 137, Issue 33
  • DOI: 10.1021/jacs.5b05204

Structurally Diverse Diazafluorene-Ligated Palladium(II) Complexes and Their Implications for Aerobic Oxidation Reactions
journal, March 2016

  • White, Paul B.; Jaworski, Jonathan N.; Fry, Charles G.
  • Journal of the American Chemical Society, Vol. 138, Issue 14
  • DOI: 10.1021/jacs.6b01188

Can Palladium Acetate Lose Its “Saltiness”? Catalytic Activities of the Impurities in Palladium Acetate
journal, October 2015

Transmetalation: routes to metal exchange within metal–organic frameworks
journal, January 2013

  • Lalonde, Marianne; Bury, Wojciech; Karagiaridi, Olga
  • Journal of Materials Chemistry A, Vol. 1, Issue 18
  • DOI: 10.1039/c3ta10784a

Energy-adjustedab initio pseudopotentials for the second and third row transition elements
journal, January 1990

  • Andrae, D.; H�u�ermann, U.; Dolg, M.
  • Theoretica Chimica Acta, Vol. 77, Issue 2
  • DOI: 10.1007/BF01114537

Oxidative Group Transfer to a Triiron Complex to Form a Nucleophilic μ 3 -Nitride, [Fe 33 -N)]
journal, March 2011

  • Powers, Tamara M.; Fout, Alison R.; Zheng, Shao-Liang
  • Journal of the American Chemical Society, Vol. 133, Issue 10
  • DOI: 10.1021/ja2003445

Reduced and Superreduced Diplatinum Complexes
journal, April 2016

  • Darnton, Tania V.; Hunter, Bryan M.; Hill, Michael G.
  • Journal of the American Chemical Society, Vol. 138, Issue 17
  • DOI: 10.1021/jacs.6b02559

High-Enthalpy Hydrogen Adsorption in Cation-Exchanged Variants of the Microporous Metal−Organic Framework Mn 3 [(Mn 4 Cl) 3 (BTT) 8 (CH 3 OH) 10 ] 2
journal, September 2007

  • Dincǎ, Mircea; Long, Jeffrey R.
  • Journal of the American Chemical Society, Vol. 129, Issue 36
  • DOI: 10.1021/ja072871f

Transmetalations in two metal–organic frameworks with different framework flexibilities: Kinetics and core–shell heterostructure
journal, January 2012

  • Song, Xiaokai; Jeong, Seok; Kim, Dongwook
  • CrystEngComm, Vol. 14, Issue 18
  • DOI: 10.1039/c2ce26115d

Cation exchange at the secondary building units of metal–organic frameworks
journal, January 2014

Structure extending and cation exchange of Cd(ii) and Co(ii) materials compounds inducing fluorescence signal mutation
journal, January 2010

  • Huang, Shengli; Li, Xiaoxia; Shi, Xianju
  • Journal of Materials Chemistry, Vol. 20, Issue 27
  • DOI: 10.1039/c0jm00605j

Heterogeneous Catalysis
journal, February 2015

[Pd(CH 3 COO) 2 ] n from X-ray powder diffraction data
journal, August 2004

  • Kirik, Sergei D.; Mulagaleev, Ruslan F.; Blokhin, Alexander I.
  • Acta Crystallographica Section C Crystal Structure Communications, Vol. 60, Issue 9
  • DOI: 10.1107/S0108270104016129

The Postsynthetic Renaissance in Porous Solids
journal, February 2017

  • Cohen, Seth M.
  • Journal of the American Chemical Society, Vol. 139, Issue 8
  • DOI: 10.1021/jacs.6b11259

Synthesis and C−C Coupling Reactivity of a Dinuclear Ni I −Ni I Complex Supported by a Terphenyl Diphosphine
journal, May 2010

  • Velian, Alexandra; Lin, Sibo; Miller, Alexander J. M.
  • Journal of the American Chemical Society, Vol. 132, Issue 18
  • DOI: 10.1021/ja101699a

Multiple chromium(II)-chromium(II) and rhodium(II)-rhodium(II) bonds
journal, May 1970

  • Cotton, F. Albert.; DeBoer, B. G.; Laprade, Marie D.
  • Journal of the American Chemical Society, Vol. 92, Issue 9
  • DOI: 10.1021/ja00712a060

The crystal structure of trimeric palladium(II) acetate
journal, January 1970

  • Skapski, A. C.; Smart, M. L.
  • Journal of the Chemical Society D: Chemical Communications, Issue 11
  • DOI: 10.1039/c2970000658b

Mechanistic Details of Pd(II)-Catalyzed C–H Iodination with Molecular I 2 : Oxidative Addition vs Electrophilic Cleavage
journal, July 2015

  • Haines, Brandon E.; Xu, Huiying; Verma, Pritha
  • Journal of the American Chemical Society, Vol. 137, Issue 28
  • DOI: 10.1021/jacs.5b03410