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Title: Templating metastable Pd 2 carboxylate aggregates

Evaluation of the potential for metal–metal (M–M) cooperation to enable catalysis requires access to specific polynuclear aggregates that display appropriate geometry and size. Here we demonstrate ion metathesis within pre-formed metal–organic frameworks (MOFs) to prepare metastable Pd 2 tetracarboxylates sites.
Authors:
ORCiD logo [1] ; ORCiD logo [1] ;  [2] ; ORCiD logo [1]
  1. Texas A&M University, Department of Chemistry, College Station, USA
  2. DND-CAT, Northwestern Synchrotron Research Centre at the Advanced Photon Source, Argonne, USA
Publication Date:
Grant/Contract Number:
SC0018977
Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1485518

Wang, Chen-Hao, Gao, Wen-Yang, Ma, Qing, and Powers, David C. Templating metastable Pd 2 carboxylate aggregates. United Kingdom: N. p., Web. doi:10.1039/C8SC04940H.
Wang, Chen-Hao, Gao, Wen-Yang, Ma, Qing, & Powers, David C. Templating metastable Pd 2 carboxylate aggregates. United Kingdom. doi:10.1039/C8SC04940H.
Wang, Chen-Hao, Gao, Wen-Yang, Ma, Qing, and Powers, David C. 2019. "Templating metastable Pd 2 carboxylate aggregates". United Kingdom. doi:10.1039/C8SC04940H.
@article{osti_1485518,
title = {Templating metastable Pd 2 carboxylate aggregates},
author = {Wang, Chen-Hao and Gao, Wen-Yang and Ma, Qing and Powers, David C.},
abstractNote = {Evaluation of the potential for metal–metal (M–M) cooperation to enable catalysis requires access to specific polynuclear aggregates that display appropriate geometry and size. Here we demonstrate ion metathesis within pre-formed metal–organic frameworks (MOFs) to prepare metastable Pd 2 tetracarboxylates sites.},
doi = {10.1039/C8SC04940H},
journal = {Chemical Science},
number = ,
volume = ,
place = {United Kingdom},
year = {2019},
month = {1}
}

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