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Title: Competition between Exceptionally Long‐Range Alkyl Sidechain Ordering and Backbone Ordering in Semiconducting Polymers and Its Impact on Electronic and Optoelectronic Properties

Abstract

Abstract Intra‐ and intermolecular ordering greatly impacts the electronic and optoelectronic properties of semiconducting polymers. The interrelationship between ordering of alkyl sidechains and conjugated backbones has yet to be fully detailed, despite much prior effort. Here, the discovery of a highly ordered alkyl sidechain phase in six representative semiconducting polymers, determined from distinct spectroscopic and diffraction signatures, is reported. The sidechain ordering exhibits unusually large coherence lengths (≥70 nm), induces torsional/twisting backbone disorder, and results in a vertically multilayered nanostructure with ordered sidechain layers alternating with disordered backbone layers. Calorimetry and in situ variable temperature scattering measurements in a model system poly{4‐(5‐(4,8‐bis(3‐butylnonyl)‐6‐methylbenzo[1,2‐b:4,5‐b′]dithiophen‐2‐yl)thiophen‐2‐yl)‐2‐(2‐butyloctyl)‐5,6‐difluoro‐7‐(5‐methylthiophen‐2‐yl)‐2H‐benzo[d][1,2,3]triazole} (PBnDT‐FTAZ) clearly delineate this competition of ordering that prevents simultaneous long‐range order of both moieties. The long‐range sidechain ordering can be exploited as a transient state to fabricate PBnDT‐FTAZ films with an atypical edge‐on texture and 2.5× improved field‐effect transistor mobility. The observed influence of ordering between the moieties implies that improved molecular design can produce synergistic rather than destructive ordering effects. Given the large sidechain coherence lengths observed, such synergistic ordering should greatly improve the coherence length of backbone ordering and thereby improve electronic and optoelectronic properties such as charge transport and exciton diffusion lengths.

Authors:
 [1];  [1];  [2];  [1];  [1];  [3];  [3];  [4];  [3];  [3];  [2]; ORCiD logo [1]
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  1. Department of Physics and Organic and Carbon Electronics Lab (ORaCEL) North Carolina State University Raleigh NC 27695 USA
  2. Materials Science and Engineering Division National Institute of Standards and Technology 100 Bureau Drive Gaithersburg MD 20899 USA
  3. Department of Chemistry University of North Carolina at Chapel Hill Chapel Hill NC 27599‐3290 USA
  4. Department of Mechanical and Aerospace Engineering and ORaCEL North Carolina State University Raleigh NC 27695 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1485503
Grant/Contract Number:  
DE‐AC02‐05CH11231
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Name: Advanced Functional Materials Journal Volume: 29 Journal Issue: 5; Journal ID: ISSN 1616-301X
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Carpenter, Joshua H., Ghasemi, Masoud, Gann, Eliot, Angunawela, Indunil, Stuard, Samuel J., Rech, Jeromy James, Ritchie, Earl, O'Connor, Brendan T., Atkin, Joanna, You, Wei, DeLongchamp, Dean M., and Ade, Harald. Competition between Exceptionally Long‐Range Alkyl Sidechain Ordering and Backbone Ordering in Semiconducting Polymers and Its Impact on Electronic and Optoelectronic Properties. Germany: N. p., 2018. Web. doi:10.1002/adfm.201806977.
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Carpenter, Joshua H., Ghasemi, Masoud, Gann, Eliot, Angunawela, Indunil, Stuard, Samuel J., Rech, Jeromy James, Ritchie, Earl, O'Connor, Brendan T., Atkin, Joanna, You, Wei, DeLongchamp, Dean M., & Ade, Harald. Competition between Exceptionally Long‐Range Alkyl Sidechain Ordering and Backbone Ordering in Semiconducting Polymers and Its Impact on Electronic and Optoelectronic Properties. Germany. https://doi.org/10.1002/adfm.201806977
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Carpenter, Joshua H., Ghasemi, Masoud, Gann, Eliot, Angunawela, Indunil, Stuard, Samuel J., Rech, Jeromy James, Ritchie, Earl, O'Connor, Brendan T., Atkin, Joanna, You, Wei, DeLongchamp, Dean M., and Ade, Harald. Wed . "Competition between Exceptionally Long‐Range Alkyl Sidechain Ordering and Backbone Ordering in Semiconducting Polymers and Its Impact on Electronic and Optoelectronic Properties". Germany. https://doi.org/10.1002/adfm.201806977.
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@article{osti_1485503,
title = {Competition between Exceptionally Long‐Range Alkyl Sidechain Ordering and Backbone Ordering in Semiconducting Polymers and Its Impact on Electronic and Optoelectronic Properties},
author = {Carpenter, Joshua H. and Ghasemi, Masoud and Gann, Eliot and Angunawela, Indunil and Stuard, Samuel J. and Rech, Jeromy James and Ritchie, Earl and O'Connor, Brendan T. and Atkin, Joanna and You, Wei and DeLongchamp, Dean M. and Ade, Harald},
abstractNote = {Abstract Intra‐ and intermolecular ordering greatly impacts the electronic and optoelectronic properties of semiconducting polymers. The interrelationship between ordering of alkyl sidechains and conjugated backbones has yet to be fully detailed, despite much prior effort. Here, the discovery of a highly ordered alkyl sidechain phase in six representative semiconducting polymers, determined from distinct spectroscopic and diffraction signatures, is reported. The sidechain ordering exhibits unusually large coherence lengths (≥70 nm), induces torsional/twisting backbone disorder, and results in a vertically multilayered nanostructure with ordered sidechain layers alternating with disordered backbone layers. Calorimetry and in situ variable temperature scattering measurements in a model system poly{4‐(5‐(4,8‐bis(3‐butylnonyl)‐6‐methylbenzo[1,2‐b:4,5‐b′]dithiophen‐2‐yl)thiophen‐2‐yl)‐2‐(2‐butyloctyl)‐5,6‐difluoro‐7‐(5‐methylthiophen‐2‐yl)‐2H‐benzo[d][1,2,3]triazole} (PBnDT‐FTAZ) clearly delineate this competition of ordering that prevents simultaneous long‐range order of both moieties. The long‐range sidechain ordering can be exploited as a transient state to fabricate PBnDT‐FTAZ films with an atypical edge‐on texture and 2.5× improved field‐effect transistor mobility. The observed influence of ordering between the moieties implies that improved molecular design can produce synergistic rather than destructive ordering effects. Given the large sidechain coherence lengths observed, such synergistic ordering should greatly improve the coherence length of backbone ordering and thereby improve electronic and optoelectronic properties such as charge transport and exciton diffusion lengths.},
doi = {10.1002/adfm.201806977},
journal = {Advanced Functional Materials},
number = 5,
volume = 29,
place = {Germany},
year = {2018},
month = {12}
}
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https://doi.org/10.1002/adfm.201806977
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