Role of Oxygen Vacancy Defects in the Electrocatalytic Activity of Substoichiometric Molybdenum Oxide

Kashfi-Sadabad, Raana; Yazdani, Sajad; Huan, Tran Doan; Cai, Zhao; Pettes, Michael Thompson

doi:10.1021/acs.jpcc.8b03536

Title: Role of Oxygen Vacancy Defects in the Electrocatalytic Activity of Substoichiometric Molybdenum Oxide

Authors:

Kashfi-Sadabad, Raana ^[1];

^[2];

^[3]; Cai, Zhao ^[4];

^[5]

Univ. of Connecticut, Storrs, CT (United States). Inst. of Materials Science
Univ. of Connecticut, Storrs, CT (United States). Dept. of Mechanical Engineering
Univ. of Connecticut, Storrs, CT (United States). Inst. of Materials Science; Ton Duc Thang Univ., Ho Chi Minh City (Vietnam). Advanced Functional Materials for Energy and Environmental Applications Research Group and Faculty of Applied Sciences
Yale Univ., New Haven, CT (United States). Dept. of Chemistry
Univ. of Connecticut, Storrs, CT (United States). Inst. of Materials Science and Dept. of Mechanical Engineering; Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Center for Integrated Nanotechnologies (CINT)

Publication Date:: Mon Jul 23 00:00:00 EDT 2018

Research Org.:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; USDOE National Nuclear Security Administration (NNSA); National Science Foundation (NSF); General Electric Co. (GE), Boston, MA (United States)

OSTI Identifier:: 1466269

Alternate Identifier(s):: OSTI ID: 1485394

Report Number(s):: LA-UR-18-27143
Journal ID: ISSN 1932-7447; LA-UR-18-27143

Grant/Contract Number:: AC52-06NA25396; CAREER-1553987; PD17-0137; TG-DMR170031

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Physical Chemistry. C

Additional Journal Information:: Journal Volume: 122; Journal Issue: 32; Journal ID: ISSN 1932-7447

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Kashfi-Sadabad, Raana, Yazdani, Sajad, Huan, Tran Doan, Cai, Zhao, and Pettes, Michael Thompson. Role of Oxygen Vacancy Defects in the Electrocatalytic Activity of Substoichiometric Molybdenum Oxide.  United States: N. p., 2018. 
Web.  doi:10.1021/acs.jpcc.8b03536.

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                    Kashfi-Sadabad, Raana, Yazdani, Sajad, Huan, Tran Doan, Cai, Zhao, & Pettes, Michael Thompson. Role of Oxygen Vacancy Defects in the Electrocatalytic Activity of Substoichiometric Molybdenum Oxide.  United States.  https://doi.org/10.1021/acs.jpcc.8b03536

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                    Kashfi-Sadabad, Raana, Yazdani, Sajad, Huan, Tran Doan, Cai, Zhao, and Pettes, Michael Thompson. Mon .  
"Role of Oxygen Vacancy Defects in the Electrocatalytic Activity of Substoichiometric Molybdenum Oxide".  United States.  https://doi.org/10.1021/acs.jpcc.8b03536.  https://www.osti.gov/servlets/purl/1466269.

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@article{osti_1466269,

  title        = {Role of Oxygen Vacancy Defects in the Electrocatalytic Activity of Substoichiometric Molybdenum Oxide},

  author       = {Kashfi-Sadabad, Raana and Yazdani, Sajad and Huan, Tran Doan and Cai, Zhao and Pettes, Michael Thompson},

  abstractNote = {},

  doi          = {10.1021/acs.jpcc.8b03536},

  journal      = {Journal of Physical Chemistry. C},

  number       = 32,

  volume       = 122,

  place        = {United States},

  year         = {Mon Jul 23 00:00:00 EDT 2018},

  month        = {Mon Jul 23 00:00:00 EDT 2018}

}

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https://doi.org/10.1021/acs.jpcc.8b03536

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Vacancy-coordinated hydrogen evolution reaction on MoO _3−x anchored atomically dispersed MoRu pairs
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Title: Role of Oxygen Vacancy Defects in the Electrocatalytic Activity of Substoichiometric Molybdenum Oxide

Citation Formats

Electrochemistry and the Future of the Automobile journal, June 2010

Review of Pt-Based Bimetallic Catalysis: From Model Surfaces to Supported Catalysts journal, August 2012

Electroreduction of Dioxygen for Fuel-Cell Applications: Materials and Challenges journal, April 2010

Core–shell MoO3–MoS2 Nanowires for Hydrogen Evolution A Functional Design for Electrocatalytic Materials journal, October 2011

Ordered Mesoporous Metallic MoO 2 Materials with Highly Reversible Lithium Storage Capacity journal, December 2009

Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3−x journal, December 2016

High performance bifunctional electrocatalytic activity of a reduced graphene oxide–molybdenum oxide hybrid catalyst journal, January 2016

Mesoporous Metal–Nitrogen-Doped Carbon Electrocatalysts for Highly Efficient Oxygen Reduction Reaction journal, October 2013

Graphene nanosheet: synthesis, molecular engineering, thin film, hybrids, and energy and analytical applications journal, January 2011

Polyelectrolyte-Assisted Oxygen Vacancies: A New Route to Defect Engineering in Molybdenum Oxide journal, May 2018

Carbon Nanotube−Inorganic Hybrids journal, March 2010

Polyelectrolyte-Functionalized Graphene as Metal-Free Electrocatalysts for Oxygen Reduction journal, July 2011

MCM-48-like Large Mesoporous Silicas with Tailored Pore Structure: Facile Synthesis Domain in a Ternary Triblock Copolymer−Butanol−Water System journal, May 2005

Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores journal, January 1998

Synthesis of Self-Supported Ordered Mesoporous Cobalt and Chromium Nitrides journal, August 2008

Formation Mechanism of Porous Single-Crystal Cr 2 O 3 and Co 3 O 4 Templated by Mesoporous Silica journal, June 2006

Mn3O4−Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries journal, October 2010

Preparation of Graphitic Oxide journal, March 1958

Asymmetric Supercapacitors Based on Graphene/MnO 2 Nanospheres and Graphene/MoO 3 Nanosheets with High Energy Density journal, August 2013

Fabrication of Graphene-Encapsulated Oxide Nanoparticles: Towards High-Performance Anode Materials for Lithium Storage journal, September 2010

Tailored graphene-encapsulated mesoporous Co3O4 composite microspheres for high-performance lithium ion batteries journal, January 2012

Raman spectroscopy of molybdenum oxides journal, February 2002

Binder-free α-MoO3 nanobelt electrode for lithium-ion batteries utilizing van der Waals forces for film formation and connection with current collector journal, January 2013

Structure of Graphitic Oxide journal, November 1962

Synthesis and Solid-State NMR Structural Characterization of 13C-Labeled Graphite Oxide journal, September 2008

Hydrazine and Thermal Reduction of Graphene Oxide: Reaction Mechanisms, Product Structures, and Reaction Design journal, December 2009

Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide journal, June 2007

Characterisation of reduced graphene oxide: Effects of reduction variables on electrical conductivity journal, March 2015

Raman Spectrum of Graphite journal, August 1970

Facile Synthesis of Graphene Nanosheets via Fe Reduction of Exfoliated Graphite Oxide journal, December 2010

Polyelectrolyte Functionalized Carbon Nanotubes as Efficient Metal-free Electrocatalysts for Oxygen Reduction journal, April 2011

A Raman and XPS investigation of supported molybdenum oxide thin films. 1. Calcination and reduction studies journal, October 1993

Crystal chemistry of metal dioxides with rutile-related structures journal, April 1969

Review of gas diffusion cathodes for alkaline fuel cells journal, February 2009

Vacancy-coordinated hydrogen evolution reaction on MoO 3−x anchored atomically dispersed MoRu pairs journal, January 2019

Oxygen Vacancy‐Engineered PEGylated MoO 3 −x Nanoparticles with Superior Sulfite Oxidase Mimetic Activity for Vitamin B1 Detection journal, October 2019

Ellipsometric Investigations of Electronic Polarizability and Thermo-optic Coefficients of ZxMoO3 (Z = H+, Li+) Bronzes journal, August 2019

Electrochemistry and the Future of the Automobile
journal, June 2010

Review of Pt-Based Bimetallic Catalysis: From Model Surfaces to Supported Catalysts
journal, August 2012

Electroreduction of Dioxygen for Fuel-Cell Applications: Materials and Challenges
journal, April 2010

Core–shell MoO₃–MoS₂ Nanowires for Hydrogen Evolution A Functional Design for Electrocatalytic Materials
journal, October 2011

Ordered Mesoporous Metallic MoO ₂ Materials with Highly Reversible Lithium Storage Capacity
journal, December 2009

Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3−x
journal, December 2016

High performance bifunctional electrocatalytic activity of a reduced graphene oxide–molybdenum oxide hybrid catalyst
journal, January 2016

Mesoporous Metal–Nitrogen-Doped Carbon Electrocatalysts for Highly Efficient Oxygen Reduction Reaction
journal, October 2013

Graphene nanosheet: synthesis, molecular engineering, thin film, hybrids, and energy and analytical applications
journal, January 2011

Polyelectrolyte-Assisted Oxygen Vacancies: A New Route to Defect Engineering in Molybdenum Oxide
journal, May 2018

Carbon Nanotube−Inorganic Hybrids
journal, March 2010

Polyelectrolyte-Functionalized Graphene as Metal-Free Electrocatalysts for Oxygen Reduction
journal, July 2011

MCM-48-like Large Mesoporous Silicas with Tailored Pore Structure: Facile Synthesis Domain in a Ternary Triblock Copolymer−Butanol−Water System
journal, May 2005

Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores
journal, January 1998

Synthesis of Self-Supported Ordered Mesoporous Cobalt and Chromium Nitrides
journal, August 2008

Formation Mechanism of Porous Single-Crystal Cr ₂ O ₃ and Co ₃ O ₄ Templated by Mesoporous Silica
journal, June 2006

Mn₃O₄−Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries
journal, October 2010

Preparation of Graphitic Oxide
journal, March 1958

Asymmetric Supercapacitors Based on Graphene/MnO ₂ Nanospheres and Graphene/MoO ₃ Nanosheets with High Energy Density
journal, August 2013

Fabrication of Graphene-Encapsulated Oxide Nanoparticles: Towards High-Performance Anode Materials for Lithium Storage
journal, September 2010

Tailored graphene-encapsulated mesoporous Co3O4 composite microspheres for high-performance lithium ion batteries
journal, January 2012

Raman spectroscopy of molybdenum oxides
journal, February 2002

Binder-free α-MoO3 nanobelt electrode for lithium-ion batteries utilizing van der Waals forces for film formation and connection with current collector
journal, January 2013

Structure of Graphitic Oxide
journal, November 1962

Synthesis and Solid-State NMR Structural Characterization of 13C-Labeled Graphite Oxide
journal, September 2008

Hydrazine and Thermal Reduction of Graphene Oxide: Reaction Mechanisms, Product Structures, and Reaction Design
journal, December 2009

Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide
journal, June 2007

Characterisation of reduced graphene oxide: Effects of reduction variables on electrical conductivity
journal, March 2015

Raman Spectrum of Graphite
journal, August 1970

Facile Synthesis of Graphene Nanosheets via Fe Reduction of Exfoliated Graphite Oxide
journal, December 2010

Polyelectrolyte Functionalized Carbon Nanotubes as Efficient Metal-free Electrocatalysts for Oxygen Reduction
journal, April 2011

A Raman and XPS investigation of supported molybdenum oxide thin films. 1. Calcination and reduction studies
journal, October 1993

Crystal chemistry of metal dioxides with rutile-related structures
journal, April 1969

Review of gas diffusion cathodes for alkaline fuel cells
journal, February 2009

Vacancy-coordinated hydrogen evolution reaction on MoO _3−x anchored atomically dispersed MoRu pairs
journal, January 2019

Oxygen Vacancy‐Engineered PEGylated MoO ₃ _−x Nanoparticles with Superior Sulfite Oxidase Mimetic Activity for Vitamin B1 Detection
journal, October 2019

Ellipsometric Investigations of Electronic Polarizability and Thermo-optic Coefficients of ZxMoO3 (Z = H+, Li+) Bronzes
journal, August 2019