Frustration and Glasslike Character in RIn1–x MnxO3 (R = Tb, Dy, Gd)

Chen, Peng; Holinsworth, Brian S.; O’Neal, Kenneth R.; Luo, Xuan; Topping, Craig V.; Cheong, Sang W.; Singleton, John; Choi, Eun S.; Musfeldt, Janice L.

doi:10.1021/acs.inorgchem.8b01467

Title: Frustration and Glasslike Character in RIn_1–x Mn_xO₃ (R = Tb, Dy, Gd)

Abstract

Here, we bring together ac susceptibility and dc magnetization to uncover the rich magnetic field-temperature behavior of a series of rare earth indium oxides, RInO₃ (R = Tb, Dy, and Gd). The degree of frustration is much larger than expected, particularly in TbInO₃, and the ground states are glasslike with antiferromagnetic tendencies. The activation energy for spin reorientation is low. Chemical substitution with Mn³⁺ ions to form TbIn_1–xMn_xO₃ (x ≤ 0.01) relieves much of the frustration that characterizes the parent compound and slightly enhances the short-range antiferromagnetic order. The phase diagrams developed from this work reveal the rich competition between spin orders and provide an opportunity to compare the dynamics in the RInO₃ and Mn-substituted systems. Finally, these structure–property relations may be useful for understanding magnetism in other geometrically frustrated multiferroics.

Authors:

^[1]; Holinsworth, Brian S. ^[1];

^[1]; Luo, Xuan ^[2]; Topping, Craig V. ^[3]; Cheong, Sang W. ^[2];

^[4]; Choi, Eun S. ^[5];

^[6]

Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Rutgers Univ., Piscataway, NJ (United States). Rutgers Center for Emergent Materials and Dept. of Physics and Astronomy; Pohang Univ. of Science and Technology (POSTECH) (Korea, Republic of). Lab. for Pohang Emergent Materials and Dept. of Physics
Univ. of Oxford (United Kingdom). Clarendon Lab., Condensed Matter Physics
Univ. of Oxford (United Kingdom). Clarendon Lab., Condensed Matter Physics; Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Florida State Univ., Tallahassee, FL (United States). National High Magnetic Field Lab. (MagLab)
Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry and Dept. of Physics

Publication Date:: 2018-09-28

Research Org.:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1485392

Report Number(s):: LA-UR-18-25203
Journal ID: ISSN 0020-1669

Grant/Contract Number:: 89233218CNA000001

Resource Type:: Accepted Manuscript

Journal Name:: Inorganic Chemistry

Additional Journal Information:: Journal Volume: 57; Journal Issue: 20; Journal ID: ISSN 0020-1669

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; High Magnetic Field Science

Citation Formats


                    Chen, Peng, Holinsworth, Brian S., O’Neal, Kenneth R., Luo, Xuan, Topping, Craig V., Cheong, Sang W., Singleton, John, Choi, Eun S., and Musfeldt, Janice L. Frustration and Glasslike Character in RIn1–x MnxO3 (R = Tb, Dy, Gd).  United States: N. p., 2018. 
Web.  doi:10.1021/acs.inorgchem.8b01467.

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                    Chen, Peng, Holinsworth, Brian S., O’Neal, Kenneth R., Luo, Xuan, Topping, Craig V., Cheong, Sang W., Singleton, John, Choi, Eun S., & Musfeldt, Janice L. Frustration and Glasslike Character in RIn1–x MnxO3 (R = Tb, Dy, Gd).  United States.  https://doi.org/10.1021/acs.inorgchem.8b01467

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                    Chen, Peng, Holinsworth, Brian S., O’Neal, Kenneth R., Luo, Xuan, Topping, Craig V., Cheong, Sang W., Singleton, John, Choi, Eun S., and Musfeldt, Janice L. Fri .  
"Frustration and Glasslike Character in RIn1–x MnxO3 (R = Tb, Dy, Gd)".  United States.  https://doi.org/10.1021/acs.inorgchem.8b01467.  https://www.osti.gov/servlets/purl/1485392.

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@article{osti_1485392,

  title        = {Frustration and Glasslike Character in RIn1–x MnxO3 (R = Tb, Dy, Gd)},

  author       = {Chen, Peng and Holinsworth, Brian S. and O’Neal, Kenneth R. and Luo, Xuan and Topping, Craig V. and Cheong, Sang W. and Singleton, John and Choi, Eun S. and Musfeldt, Janice L.},

  abstractNote = {Here, we bring together ac susceptibility and dc magnetization to uncover the rich magnetic field-temperature behavior of a series of rare earth indium oxides, RInO3 (R = Tb, Dy, and Gd). The degree of frustration is much larger than expected, particularly in TbInO3, and the ground states are glasslike with antiferromagnetic tendencies. The activation energy for spin reorientation is low. Chemical substitution with Mn3+ ions to form TbIn1–xMnxO3 (x ≤ 0.01) relieves much of the frustration that characterizes the parent compound and slightly enhances the short-range antiferromagnetic order. The phase diagrams developed from this work reveal the rich competition between spin orders and provide an opportunity to compare the dynamics in the RInO3 and Mn-substituted systems. Finally, these structure–property relations may be useful for understanding magnetism in other geometrically frustrated multiferroics.},

  doi          = {10.1021/acs.inorgchem.8b01467},

  journal      = {Inorganic Chemistry},

  number       = 20,

  volume       = 57,

  place        = {United States},

  year         = {2018},

  month        = {9}

}

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Figures / Tables:

Figure 1: (a) Hexagonal TbInO₃ lattice with space group symmetry P6₃cm. These polar oxides are highly frustrated because of the triangular lattice of rare earth centers. As shown by the shaded InO₅ and TbO₇ polyhedra, the In³⁺ ions are located on 5-fold coordinated trigonal-bipyramidal sites, whereas the rare earth ionsmore »

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Works referencing / citing this record:

Field-induced glassy state in disordered cluster antiferromagnets
journal, October 2019

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Similar Records

Title: Frustration and Glasslike Character in RIn1–x MnxO3 (R = Tb, Dy, Gd)

Abstract

Citation Formats

Figures / Tables:

Spin liquids in frustrated magnets journal, March 2010

Strongly Geometrically Frustrated Magnets journal, August 1994

Colloquium : Artificial spin ice: Designing and imaging magnetic frustration journal, October 2013

The physics of manganites: Structure and transport journal, August 2001

Magnetic pyrochlore oxides journal, January 2010

Hydration-induced spin-glass state in a frustrated Na-Mn-O triangular lattice journal, May 2016

Magnetoelastic Coupling and Symmetry Breaking in the Frustrated Antiferromagnet α − NaMnO 2 journal, December 2007

Frustration-induced nanometre-scale inhomogeneity in a triangular antiferromagnet journal, January 2014

Colloquium : Herbertsmithite and the search for the quantum spin liquid journal, December 2016

High-Pressure Synthesis of Perovskite Type RInO 3 (R=Eu, Gd, and Dy) journal, September 1973

The origin of ferroelectricity in magnetoelectric YMnO3 journal, February 2004

Experimentally determining the exchange parameters of quasi-two-dimensional Heisenberg magnets journal, August 2008

Electronic State Structure and Optical Properties of Tb(oda) 3 3 - Complexes in Trigonal Na 3 [Tb(oda) 3 ]·2NaClO 4 ·6H 2 O Crystals † journal, March 1998

Barlowite: A Spin- 1 / 2 Antiferromagnet with a Geometrically Perfect Kagome Motif journal, November 2014

Spin-orbit coupling control of anisotropy, ground state and frustration in 5d2 Sr2MgOsO6 journal, August 2016

Glassiness and canted antiferromagnetism in three geometrically frustrated triangular quantum Heisenberg antiferromagnets with additional Dzyaloshinskii-Moriya interaction journal, February 2000

Competing interactions and spin-glass-like features in the UCu 2 Ge 2 system journal, September 1992

Ac susceptibility studies of ferrimagnetic FeCr2S4 single crystals journal, November 2001

Isosbestic Points in the Spectral Function of Correlated Electrons journal, February 2007

Optical phase diagram of perovskite colossal magnetoresistance manganites near half doping journal, February 2008

Spin-glass behavior with short-range antiferromagnetic order in Nd2AgIn3 journal, December 2001

Spin Glass Behavior in URh 2 Ge 2 journal, January 1997

How ‘spin ice’ freezes journal, September 2001

Measurement of complex susceptibility on a metallic spin glass with broad relaxation spectrum journal, November 1981

Exploiting single-ion anisotropy in the design of f-element single-molecule magnets journal, January 2011

Strong spin-lattice coupling in CrSiTe 3 journal, April 2015

Field-induced glassy state in disordered cluster antiferromagnets journal, October 2019

Title: Frustration and Glasslike Character in RIn_1–x Mn_xO₃ (R = Tb, Dy, Gd)

Spin liquids in frustrated magnets
journal, March 2010

Strongly Geometrically Frustrated Magnets
journal, August 1994

Colloquium : Artificial spin ice: Designing and imaging magnetic frustration
journal, October 2013

The physics of manganites: Structure and transport
journal, August 2001

Magnetic pyrochlore oxides
journal, January 2010

Hydration-induced spin-glass state in a frustrated Na-Mn-O triangular lattice
journal, May 2016

Magnetoelastic Coupling and Symmetry Breaking in the Frustrated Antiferromagnet $α − {NaMnO}_{2}$
journal, December 2007

Frustration-induced nanometre-scale inhomogeneity in a triangular antiferromagnet
journal, January 2014

Colloquium : Herbertsmithite and the search for the quantum spin liquid
journal, December 2016

High-Pressure Synthesis of Perovskite Type RInO ₃ (R=Eu, Gd, and Dy)
journal, September 1973

The origin of ferroelectricity in magnetoelectric YMnO3
journal, February 2004

Experimentally determining the exchange parameters of quasi-two-dimensional Heisenberg magnets
journal, August 2008

Electronic State Structure and Optical Properties of Tb(oda) ₃ ³ ^- Complexes in Trigonal Na ₃ [Tb(oda) ₃ ]·2NaClO ₄ ·6H ₂ O Crystals ^†
journal, March 1998

Barlowite: A Spin- $1 / 2$ Antiferromagnet with a Geometrically Perfect Kagome Motif
journal, November 2014

Spin-orbit coupling control of anisotropy, ground state and frustration in 5d2 Sr2MgOsO6
journal, August 2016

Glassiness and canted antiferromagnetism in three geometrically frustrated triangular quantum Heisenberg antiferromagnets with additional Dzyaloshinskii-Moriya interaction
journal, February 2000

Competing interactions and spin-glass-like features in the ${UCu}_{2}$ ${Ge}_{2}$ system
journal, September 1992

Ac susceptibility studies of ferrimagnetic FeCr2S4 single crystals
journal, November 2001

Isosbestic Points in the Spectral Function of Correlated Electrons
journal, February 2007

Optical phase diagram of perovskite colossal magnetoresistance manganites near half doping
journal, February 2008

Spin-glass behavior with short-range antiferromagnetic order in Nd2AgIn3
journal, December 2001

Spin Glass Behavior in ${URh}_{2} {Ge}_{2}$
journal, January 1997

How ‘spin ice’ freezes
journal, September 2001

Measurement of complex susceptibility on a metallic spin glass with broad relaxation spectrum
journal, November 1981

Exploiting single-ion anisotropy in the design of f-element single-molecule magnets
journal, January 2011

Strong spin-lattice coupling in CrSiTe ₃
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