Frustration and Glasslike Character in RIn1–x MnxO3 (R = Tb, Dy, Gd)
Abstract
Here, we bring together ac susceptibility and dc magnetization to uncover the rich magnetic field-temperature behavior of a series of rare earth indium oxides, RInO3 (R = Tb, Dy, and Gd). The degree of frustration is much larger than expected, particularly in TbInO3, and the ground states are glasslike with antiferromagnetic tendencies. The activation energy for spin reorientation is low. Chemical substitution with Mn3+ ions to form TbIn1–xMnxO3 (x ≤ 0.01) relieves much of the frustration that characterizes the parent compound and slightly enhances the short-range antiferromagnetic order. The phase diagrams developed from this work reveal the rich competition between spin orders and provide an opportunity to compare the dynamics in the RInO3 and Mn-substituted systems. Finally, these structure–property relations may be useful for understanding magnetism in other geometrically frustrated multiferroics.
- Authors:
-
- Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
- Rutgers Univ., Piscataway, NJ (United States). Rutgers Center for Emergent Materials and Dept. of Physics and Astronomy; Pohang Univ. of Science and Technology (POSTECH) (Korea, Republic of). Lab. for Pohang Emergent Materials and Dept. of Physics
- Univ. of Oxford (United Kingdom). Clarendon Lab., Condensed Matter Physics
- Univ. of Oxford (United Kingdom). Clarendon Lab., Condensed Matter Physics; Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Florida State Univ., Tallahassee, FL (United States). National High Magnetic Field Lab. (MagLab)
- Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry and Dept. of Physics
- Publication Date:
- Research Org.:
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1485392
- Report Number(s):
- LA-UR-18-25203
Journal ID: ISSN 0020-1669
- Grant/Contract Number:
- 89233218CNA000001
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Inorganic Chemistry
- Additional Journal Information:
- Journal Volume: 57; Journal Issue: 20; Journal ID: ISSN 0020-1669
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; High Magnetic Field Science
Citation Formats
Chen, Peng, Holinsworth, Brian S., O’Neal, Kenneth R., Luo, Xuan, Topping, Craig V., Cheong, Sang W., Singleton, John, Choi, Eun S., and Musfeldt, Janice L. Frustration and Glasslike Character in RIn1–x MnxO3 (R = Tb, Dy, Gd). United States: N. p., 2018.
Web. doi:10.1021/acs.inorgchem.8b01467.
Chen, Peng, Holinsworth, Brian S., O’Neal, Kenneth R., Luo, Xuan, Topping, Craig V., Cheong, Sang W., Singleton, John, Choi, Eun S., & Musfeldt, Janice L. Frustration and Glasslike Character in RIn1–x MnxO3 (R = Tb, Dy, Gd). United States. https://doi.org/10.1021/acs.inorgchem.8b01467
Chen, Peng, Holinsworth, Brian S., O’Neal, Kenneth R., Luo, Xuan, Topping, Craig V., Cheong, Sang W., Singleton, John, Choi, Eun S., and Musfeldt, Janice L. Fri .
"Frustration and Glasslike Character in RIn1–x MnxO3 (R = Tb, Dy, Gd)". United States. https://doi.org/10.1021/acs.inorgchem.8b01467. https://www.osti.gov/servlets/purl/1485392.
@article{osti_1485392,
title = {Frustration and Glasslike Character in RIn1–x MnxO3 (R = Tb, Dy, Gd)},
author = {Chen, Peng and Holinsworth, Brian S. and O’Neal, Kenneth R. and Luo, Xuan and Topping, Craig V. and Cheong, Sang W. and Singleton, John and Choi, Eun S. and Musfeldt, Janice L.},
abstractNote = {Here, we bring together ac susceptibility and dc magnetization to uncover the rich magnetic field-temperature behavior of a series of rare earth indium oxides, RInO3 (R = Tb, Dy, and Gd). The degree of frustration is much larger than expected, particularly in TbInO3, and the ground states are glasslike with antiferromagnetic tendencies. The activation energy for spin reorientation is low. Chemical substitution with Mn3+ ions to form TbIn1–xMnxO3 (x ≤ 0.01) relieves much of the frustration that characterizes the parent compound and slightly enhances the short-range antiferromagnetic order. The phase diagrams developed from this work reveal the rich competition between spin orders and provide an opportunity to compare the dynamics in the RInO3 and Mn-substituted systems. Finally, these structure–property relations may be useful for understanding magnetism in other geometrically frustrated multiferroics.},
doi = {10.1021/acs.inorgchem.8b01467},
journal = {Inorganic Chemistry},
number = 20,
volume = 57,
place = {United States},
year = {2018},
month = {9}
}
Web of Science
Figures / Tables:

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Works referencing / citing this record:
Field-induced glassy state in disordered cluster antiferromagnets
journal, October 2019
- Schmidt, M.; Romitti, M. V.; Magalhaes, S. G.
- Journal of Physics: Condensed Matter, Vol. 32, Issue 3
Figures / Tables found in this record: