Realization of Large Electric Polarization and Strong Magnetoelectric Coupling in BiMn3Cr4O12

doi:10.1002/adma.201703435

Title: Realization of Large Electric Polarization and Strong Magnetoelectric Coupling in BiMn₃Cr₄O₁₂

Abstract

Here, magnetoelectric multiferroics have received much attention in the past decade due to their interesting physics and promising multifunctional performance. For practical applications, simultaneous large ferroelectric polarization and strong magnetoelectric coupling are preferred. However, these two properties have not been found to be compatible in the single–phase multiferroic materials discovered as yet. Here, it is shown that superior multiferroic properties exist in the A–site ordered perovskite BiMn₃Cr₄O₁₂ synthesized under high–pressure and high–temperature conditions. The compound experiences a ferroelectric phase transition ascribed to the 6s² lone–pair effects of Bi³⁺ at around 135 K, and a long–range antiferromagnetic order related to the Cr³⁺ spins around 125 K, leading to the presence of a type–I multiferroic phase with huge electric polarization. On further cooling to 48 K, a type–II multiferroic phase induced by the special spin structure composed of both Mn– and Cr–sublattices emerges, accompanied by considerable magnetoelectric coupling. BiMn₃Cr₄O₁₂ thus provides a rare example of joint multiferroicity, where two different types of multiferroic phases develop subsequently so that both large polarization and significant magnetoelectric effect are achieved in a single–phase multiferroic material.

Authors:

Zhou, Long ^[1]; Dai, Jianhong ^[1]; Chai, Yisheng ^[1]; Zhang, Huimin ^[2]; Dong, Shuai ^[2];

^[3];

^[3]; Yin, Yunyu ^[1]; Wang, Xiao ^[1]; Shen, Xudong ^[1]; Liu, Zhehong ^[1]; Saito, Takashi ^[4]; Shimakawa, Yuichi ^[4]; Hojo, Hajime ^[5]; Ikuhara, Yuichi ^[6]; Azuma, Masaki ^[5]; Hu, Zhiwei ^[7]; Sun, Young ^[1]; Jin, Changqing ^[8];

^[8]

Chinese Academy of Sciences (CAS), Beijing (China); Univ. of Chinese Academy of Sciences, Beijing (China)
Southeast Univ., Nanjing (China)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Kyoto Univ., Kyoto (Japan)
Tokyo Institute of Technology, Yokohama (Japan)
Univ. of Tokyo, Tokyo (Japan)
Max Planck Institute for Chemical Physics of Solids, Dresden (Germany)
Chinese Academy of Sciences (CAS), Beijing (China); Univ. of Chinese Academy of Sciences, Beijing (China); Collaborative Innovation Center of Quantum Matter, Beijing (China)

Publication Date:: 2017-10-09

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1485321

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Advanced Materials

Additional Journal Information:: Journal Volume: 29; Journal Issue: 44; Journal ID: ISSN 0935-9648

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; A‐site ordered perovskite; high‐pressure synthesis; magnetoelectric coupling; multiferroic

Citation Formats


                    Zhou, Long, Dai, Jianhong, Chai, Yisheng, Zhang, Huimin, Dong, Shuai, Cao, Huibo, Calder, Stuart A., Yin, Yunyu, Wang, Xiao, Shen, Xudong, Liu, Zhehong, Saito, Takashi, Shimakawa, Yuichi, Hojo, Hajime, Ikuhara, Yuichi, Azuma, Masaki, Hu, Zhiwei, Sun, Young, Jin, Changqing, and Long, Youwen. Realization of Large Electric Polarization and Strong Magnetoelectric Coupling in BiMn3Cr4O12.  United States: N. p., 2017. 
        Web.  doi:10.1002/adma.201703435.

Copy to clipboard


                    Zhou, Long, Dai, Jianhong, Chai, Yisheng, Zhang, Huimin, Dong, Shuai, Cao, Huibo, Calder, Stuart A., Yin, Yunyu, Wang, Xiao, Shen, Xudong, Liu, Zhehong, Saito, Takashi, Shimakawa, Yuichi, Hojo, Hajime, Ikuhara, Yuichi, Azuma, Masaki, Hu, Zhiwei, Sun, Young, Jin, Changqing, & Long, Youwen. Realization of Large Electric Polarization and Strong Magnetoelectric Coupling in BiMn3Cr4O12.  United States.  doi:https://doi.org/10.1002/adma.201703435

Copy to clipboard


                    Zhou, Long, Dai, Jianhong, Chai, Yisheng, Zhang, Huimin, Dong, Shuai, Cao, Huibo, Calder, Stuart A., Yin, Yunyu, Wang, Xiao, Shen, Xudong, Liu, Zhehong, Saito, Takashi, Shimakawa, Yuichi, Hojo, Hajime, Ikuhara, Yuichi, Azuma, Masaki, Hu, Zhiwei, Sun, Young, Jin, Changqing, and Long, Youwen. Mon .  
        "Realization of Large Electric Polarization and Strong Magnetoelectric Coupling in BiMn3Cr4O12".  United States.  doi:https://doi.org/10.1002/adma.201703435.  https://www.osti.gov/servlets/purl/1485321.

Copy to clipboard


                    
@article{osti_1485321,

  title        = {Realization of Large Electric Polarization and Strong Magnetoelectric Coupling in BiMn3Cr4O12},

  author       = {Zhou, Long and Dai, Jianhong and Chai, Yisheng and Zhang, Huimin and Dong, Shuai and Cao, Huibo and Calder, Stuart A. and Yin, Yunyu and Wang, Xiao and Shen, Xudong and Liu, Zhehong and Saito, Takashi and Shimakawa, Yuichi and Hojo, Hajime and Ikuhara, Yuichi and Azuma, Masaki and Hu, Zhiwei and Sun, Young and Jin, Changqing and Long, Youwen},

  abstractNote = {Here, magnetoelectric multiferroics have received much attention in the past decade due to their interesting physics and promising multifunctional performance. For practical applications, simultaneous large ferroelectric polarization and strong magnetoelectric coupling are preferred. However, these two properties have not been found to be compatible in the single–phase multiferroic materials discovered as yet. Here, it is shown that superior multiferroic properties exist in the A–site ordered perovskite BiMn3Cr4O12 synthesized under high–pressure and high–temperature conditions. The compound experiences a ferroelectric phase transition ascribed to the 6s2 lone–pair effects of Bi3+ at around 135 K, and a long–range antiferromagnetic order related to the Cr3+ spins around 125 K, leading to the presence of a type–I multiferroic phase with huge electric polarization. On further cooling to 48 K, a type–II multiferroic phase induced by the special spin structure composed of both Mn– and Cr–sublattices emerges, accompanied by considerable magnetoelectric coupling. BiMn3Cr4O12 thus provides a rare example of joint multiferroicity, where two different types of multiferroic phases develop subsequently so that both large polarization and significant magnetoelectric effect are achieved in a single–phase multiferroic material.},

  doi          = {10.1002/adma.201703435},

  journal      = {Advanced Materials},

  number       = 44,

  volume       = 29,

  place        = {United States},

  year         = {2017},

  month        = {10}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

DOI: https://doi.org/10.1002/adma.201703435

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 17 works

Citation information provided by
Web of Science

Figures / Tables:

Figure 1: Crystal structural characterization of BiMn₃Cr₄O₁₂. a, The synchrotron x-ray diffraction pattern and the refinement results. The observed (red circles), calculated (blue line), and difference (cyan line) were shown. The ticks indicate the allowed Bragg reflections in Im-3 symmetry. b, Schematic illustration for the crystal structure of BMCO. Themore »

All figures and tables (10 total)

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

MATERIALS SCIENCE: The Renaissance of Magnetoelectric Multiferroics
journal, July 2005

Spaldin, N. A.
Science, Vol. 309, Issue 5733
DOI: 10.1126/science.1113357

Features of the magnetoelectric properties of BiFeO3 in high magnetic fields
journal, June 2001

Popov, Yu. F.; Kadomtseva, A. M.; Krotov, S. S.
Low Temperature Physics, Vol. 27, Issue 6
DOI: 10.1063/1.1382990

Ferroelectricity from iron valence ordering in the charge-frustrated system LuFe2O4
journal, August 2005

Ikeda, Naoshi; Ohsumi, Hiroyuki; Ohwada, Kenji
Nature, Vol. 436, Issue 7054
DOI: 10.1038/nature04039

Magnetic control of ferroelectric polarization
journal, November 2003

Kimura, T.; Goto, T.; Shintani, H.
Nature, Vol. 426, Issue 6962
DOI: 10.1038/nature02018

Role of t _2g electrons in Mn-Tb coupling of multiferroic TbMnO ₃
journal, August 2014

Guo, Y. Y.; Wang, Y. L.; Liu, J. -M.
Journal of Applied Physics, Vol. 116, Issue 6
DOI: 10.1063/1.4893018

Observation of Magnetoelectric Multiferroicity in a Cubic Perovskite System: ${LaMn}_{3} {Cr}_{4} O_{12}$
journal, August 2015

Wang, Xiao; Chai, Yisheng; Zhou, Long
Physical Review Letters, Vol. 115, Issue 8
DOI: 10.1103/PhysRevLett.115.087601

Multiferroic properties of CaMn $_{7}$ O $_{12}$
journal, November 2011

Zhang, Guoquan; Dong, Shuai; Yan, Zhibo
Physical Review B, Vol. 84, Issue 17
DOI: 10.1103/PhysRevB.84.174413

Phonons and related crystal properties from density-functional perturbation theory
journal, July 2001

Baroni, Stefano; de Gironcoli, Stefano; Dal Corso, Andrea
Reviews of Modern Physics, Vol. 73, Issue 2
DOI: 10.1103/RevModPhys.73.515

Switching kinetics of lead zirconate titanate submicron thin‐film memories
journal, July 1988

Scott, J. F.; Kammerdiner, L.; Parris, M.
Journal of Applied Physics, Vol. 64, Issue 2
DOI: 10.1063/1.341925

Multiferroics of spin origin
journal, July 2014

Tokura, Yoshinori; Seki, Shinichiro; Nagaosa, Naoto
Reports on Progress in Physics, Vol. 77, Issue 7
DOI: 10.1088/0034-4885/77/7/076501

Multi-ferroic magnetoelectrics
journal, January 1994

Schmid, Hans
Ferroelectrics, Vol. 162, Issue 1
DOI: 10.1080/00150199408245120

Pyroelectric properties and domain structure of modified lead ferroniobate-based ceramics
journal, August 2000

Zakharov, Yu. N.; Raevski, I. P.; Eknadiosians, E. I.
Ferroelectrics, Vol. 247, Issue 1
DOI: 10.1080/00150190008214939

X-ray study of and structural approach to the incommensurate perovskite Pb2CoWO6
journal, February 1995

Bonin, M.; Paciorek, W.; Schenk, K. J.
Acta Crystallographica Section B Structural Science, Vol. 51, Issue 1
DOI: 10.1107/S0108768194011109

Multiferroic materials and magnetoelectric physics: symmetry, entanglement, excitation, and topology
journal, November 2015

Dong, Shuai; Liu, Jun-Ming; Cheong, Sang-Wook
Advances in Physics, Vol. 64, Issue 5-6
DOI: 10.1080/00018732.2015.1114338

The origin of ferroelectricity in magnetoelectric YMnO3
journal, February 2004

Van Aken, Bas B.; Palstra, Thomas T. M.; Filippetti, Alessio
Nature Materials, Vol. 3, Issue 3
DOI: 10.1038/nmat1080

Anisotropic symmetric exchange as a new mechanism for multiferroicity
journal, May 2016

Feng, J. S.; Xiang, H. J.
Physical Review B, Vol. 93, Issue 17
DOI: 10.1103/PhysRevB.93.174416

Ferroelectricity Induced by Acentric Spin-Density Waves in ${YMn}_{2} O_{5}$
journal, March 2006

Chapon, L. C.; Radaelli, P. G.; Blake, G. R.
Physical Review Letters, Vol. 96, Issue 9
DOI: 10.1103/PhysRevLett.96.097601

Multiferroics with Spiral Spin Orders
journal, December 2009

Tokura, Yoshinori; Seki, Shinichiro
Advanced Materials, Vol. 22, Issue 14
DOI: 10.1002/adma.200901961

Classifying multiferroics: Mechanisms and effects
journal, March 2009

Khomskii, Daniel
Physics, Vol. 2
DOI: 10.1103/Physics.2.20

Various Valence States of Square-Coordinated Mn in A-Site-Ordered Perovskites
journal, November 2009

Long, Youwen; Saito, Takashi; Mizumaki, Masaichiro
Journal of the American Chemical Society, Vol. 131, Issue 44
DOI: 10.1021/ja906668c

Recent Progress in Multiferroic Magnetoelectric Composites: from Bulk to Thin Films
journal, February 2011

Ma, Jing; Hu, Jiamian; Li, Zheng
Advanced Materials, Vol. 23, Issue 9
DOI: 10.1002/adma.201003636

The absence of ferroelectricity and the origin of depolarization currents in YFe _0.8 Mn _0.2 O ₃
journal, April 2017

Cho, Kwanghee; Hur, Soomin; Park, Soonyong
Applied Physics Letters, Vol. 110, Issue 16
DOI: 10.1063/1.4981806

Independent ferroelectric contributions and rare-earth-induced polarization reversal in multiferroic TbMn $_{2}$ O $_{5}$
journal, March 2012

Leo, N.; Meier, D.; Pisarev, R. V.
Physical Review B, Vol. 85, Issue 9
DOI: 10.1103/PhysRevB.85.094408

Intrinsic ferroelectric polarization of orthorhombic manganites with $E$ -type spin order
journal, May 2012

Chai, Y. S.; Oh, Y. S.; Wang, L. J.
Physical Review B, Vol. 85, Issue 18
DOI: 10.1103/PhysRevB.85.184406

Structural Anomalies and Multiferroic Behavior in Magnetically Frustrated ${T b M n}_{2} O_{5}$
journal, October 2004

Chapon, L. C.; Blake, G. R.; Gutmann, M. J.
Physical Review Letters, Vol. 93, Issue 17
DOI: 10.1103/PhysRevLett.93.177402

Multiferroics progress and prospects in thin films
journal, January 2007

Ramesh, R.; Spaldin, Nicola A.
Nature Materials, Vol. 6, Issue 1, p. 21-29
DOI: 10.1038/nmat1805

Multiferroics: a magnetic twist for ferroelectricity
journal, January 2007

Cheong, Sang-Wook; Mostovoy, Maxim
Nature Materials, Vol. 6, Issue 1
DOI: 10.1038/nmat1804

Ferroelectricity in the Magnetic $E$ -Phase of Orthorhombic Perovskites
journal, November 2006

Sergienko, Ivan A.; Şen, Cengiz; Dagotto, Elbio
Physical Review Letters, Vol. 97, Issue 22
DOI: 10.1103/PhysRevLett.97.227204

Macroscopic polarization in crystalline dielectrics: the geometric phase approach
journal, July 1994

Resta, Raffaele
Reviews of Modern Physics, Vol. 66, Issue 3
DOI: 10.1103/RevModPhys.66.899

Multiferroic and magnetoelectric materials
journal, August 2006

Eerenstein, W.; Mathur, N. D.; Scott, J. F.
Nature, Vol. 442, Issue 7104
DOI: 10.1038/nature05023

Epitaxial BiFeO₃ Multiferroic Thin Film Heterostructures
journal, March 2003

Wang, J.; Neaton, J. B.; Zheng, H.
Science, Vol. 299, Issue 5613, p. 1719-1722
DOI: 10.1126/science.1080615

Dielectric hysteresis in single crystal BiFeO3
journal, July 1970

Teague, James R.; Gerson, Robert; James, W. J.
Solid State Communications, Vol. 8, Issue 13
DOI: 10.1016/0038-1098(70)90262-0

Electric polarization reversal and memory in a multiferroic material induced by magnetic fields
journal, May 2004

Hur, N.; Park, S.; Sharma, P. A.
Nature, Vol. 429, Issue 6990
DOI: 10.1038/nature02572

Giant Improper Ferroelectricity in the Ferroaxial Magnet ${CaMn}_{7} O_{12}$
journal, February 2012

Johnson, R. D.; Chapon, L. C.; Khalyavin, D. D.
Physical Review Letters, Vol. 108, Issue 6
DOI: 10.1103/PhysRevLett.108.067201

Works referencing / citing this record:

Single-phase multiferroics: new materials, phenomena, and physics
journal, July 2019

Lu, Chengliang; Wu, Menghao; Lin, Lin
National Science Review, Vol. 6, Issue 4
DOI: 10.1093/nsr/nwz091

Neutron Instruments for Research in Coordination Chemistry: Neutron Instruments for Research in Coordination Chemistry
journal, January 2019

Xue, Zi-Ling; Ramirez-Cuesta, Anibal J.; Brown, Craig M.
European Journal of Inorganic Chemistry, Vol. 2019, Issue 8
DOI: 10.1002/ejic.201801076

Magnetodielectric Coupling Response in La-Modified M-Type Strontium Hexaferrite
journal, June 2018

Feng, Yuan; Tan, Guolong
physica status solidi (a), Vol. 215, Issue 14
DOI: 10.1002/pssa.201800295

Large linear magnetoelectric effect and field-induced ferromagnetism and ferroelectricity in DyCrO4
journal, September 2019

Shen, Xudong; Zhou, Long; Chai, Yisheng
NPG Asia Materials, Vol. 11, Issue 1
DOI: 10.1038/s41427-019-0151-9

Low leakage current resistive memory based on Bi _1.10 (Fe _0.95 Mn _0.05 ) O ₃ films
journal, July 2018

Li, Zhen; Yang, Zhengchun; Wu, Jiagang
Semiconductor Science and Technology, Vol. 33, Issue 9
DOI: 10.1088/1361-6641/aad340

Low temperature magnetocaloric properties of RE _2/3 Cu ₃ Ti ₄ O ₁₂ (RE = La, Ho and Dy) systems
journal, February 2019

Vinod, K.; Satya, A. T.; Ravindran, N. Radhikesh
Materials Research Express, Vol. 6, Issue 5
DOI: 10.1088/2053-1591/ab0229

Characterization of magnetic symmetry and electric polarization of $YC r_{0.5} F e_{0.5} O_{3}$
journal, January 2020

Yang, J. Y.; Shen, X. D.; Pomjakushin, V.
Physical Review B, Vol. 101, Issue 1
DOI: 10.1103/physrevb.101.014415

Group-theoretical analysis of 1:3 A -site-ordered perovskite formation
journal, February 2019

Talanov, Mikhail V.
Acta Crystallographica Section A Foundations and Advances, Vol. 75, Issue 2
DOI: 10.1107/s2053273318018338

Ferroelectricity driven by soft phonon and spin order in multiferroic BiMn ₃ Cr ₄ O ₁₂
journal, April 2019

Dai, Jian‐Qing; Zhang, Chang‐Chang
Journal of the American Ceramic Society, Vol. 102, Issue 10
DOI: 10.1111/jace.16482

Figures / Tables found in this record:

Extended Data Table 1 (p. 23)

Extended Data Figure 1 (p. 24)

Extended Data Figure 2 (p. 25)

Extended Data Figure 3 (p. 26)

Extended Data Figure 4 (p. 27)

Extended Data Figure 5 (p. 28)

Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

Similar Records in DOE PAGES and OSTI.GOV collections:

Crystal structure of the monoclinic and cubic polymorphs of BiMn{sub 7}O{sub 12}

Journal Article Okamoto, H ; Imamura, N ; Karppinen, M ; ... - Journal of Solid State Chemistry

The complex perovskite BiMn{sub 7}O{sub 12} occurs with two polymorphic structures, cubic and monoclinic. Currently their crystal structures are investigated with high-resolution synchrotron powder X-ray diffraction at room temperature. Rietveld analysis reveals unusual behavior for, respectively, the oxygen and bismuth atoms in the monoclinic and cubic phases. Bond valence calculations indicate that all the Mn atoms in both the phases are in trivalent state. Possible roles of the 6s{sup 2} lone-pair electrons of Bi{sup 3+} in BiMn{sub 7}O{sub 12} are discussed in comparison with the LaMn{sub 7}O{sub 12} phase that is isomorphic to monoclinic BiMn{sub 7}O{sub 12}. Multiple roles ofmore »« less
DOI: https://doi.org/10.1016/j.jssc.2009.10.013
Giant magnetoelectric effects achieved by tuning spin cone symmetry in Y-type hexaferrites

Journal Article Zhai, Kun ; Wu, Yan ; Shen, Shipeng ; ... - Nature Communications

Multiferroics materials, which exhibit coupled magnetic and ferroelectric properties, have attracted tremendous research interest because of their potential in constructing next-generation multifunctional devices. The application of single-phase multiferroics is currently limited by their usually small magnetoelectric effects. Here, we report the realization of giant magnetoelectric effects in a Y-type hexaferrite Ba_0.4Sr_1.6Mg₂Fe₁₂O₂₂ single crystal, which exhibits record-breaking direct and converse magnetoelectric coefficients and a large electric-field-reversed magnetization. We have uncovered the origin of the giant magnetoelectric effects by a systematic study in the Ba_2-x Sr _x Mg₂Fe₁₂O₂₂ family with magnetization, ferroelectricity and neutron diffraction measurements. With the transverse spin cone symmetrymore »« less
Cited by 24
DOI: https://doi.org/10.1038/s41467-017-00637-x

Full Text Available
Time-Resolved Spectroscopy of Insulator-Metal Transitions: Exploring Low-Energy Dynamics in Strongly Correlated Systems (Final Report)

Technical Report Luepke, Gunter

Transition metal oxides (TMOs) have attracted much attention in recent years. The strong coupling between charge, spin, and orbital degrees of freedom creates novel functional properties. The research at the interplay between ferromagnetism, ferroelectricity and conductivity provides a promising way to the development of future spintronic devices. The interface characterization of multifunctional oxide heterostructures is crucial to understand deeply the magnetic response, spin injection and spin transport. In year one, we characterized optically the magnetic property with the method of magnetization-induced second-harmonic generation (MSHG), which is a sensitive technique to selectively probe the interface where the spatial inversion symmetry ismore »« less
DOI: https://doi.org/10.2172/1638826

Full Text Available
Experimental observation of magnetoelectricity in spin ice Dy ₂ Ti ₂ O ₇

Journal Article Lin, L. ; Xie, Y. L. ; Wen, J-J ; ... - New Journal of Physics

The intrinsic noncollinear spin patterns in rare-earth pyrochlore are physically interesting, due to their many emergent properties (e.g., spin-ice and monopole-type excitation). Recent works have suggested that the magnetic monopole excitation of spin-ice systems is magnetoelectric active, but this fact has rarely been confirmed via experiment. In this work, we performed a systematic experimental investigation on the magnetoelectricity of Dy₂Ti₂O₇ by probing the ferroelectricity, spin dynamics, and dielectric behaviors. Two ferroelectric transitions at T_c1 = 25 K and T_c2 =13 K were observed. Remarkable magnetoelectric coupling was identified below the lower transition temperature, with significant suppression of the electric polarizationmore »« less
Cited by 2
DOI: https://doi.org/10.1088/1367-2630/17/12/123018
Magnetoelectric coupling of multiferroic chromium doped barium titanate thin film probed by magneto-impedance spectroscopy

Journal Article Shah, Jyoti ; Kotnala, Ravinder K., E-mail: rkkotnala@nplindia.org, E-mail: rkkotnala@gmail.com - Applied Physics Letters

Thin film of BaTiO{sub 3} doped with 0.1 at. % Cr (Cr:BTO) has been prepared by pulsed laser deposition technique. Film was deposited on Pt/SrTiO{sub 3} substrate at 500 °C in 50 mTorr Oxygen gas pressure using KrF (298 nm) laser. Polycrystalline growth of single phase Cr:BTO thin film has been confirmed by grazing angle X-ray diffraction. Cr:BTO film exhibited remnant polarization 6.4 μC/cm{sup 2} and 0.79 MV/cm coercivity. Magnetization measurement of Cr:BTO film showed magnetic moment 12 emu/cc. Formation of weakly magnetic domains has been captured by magnetic force microscopy. Theoretical impedance equation fitted to experimental data in Cole-Cole plot for thin film inmore »« less
DOI: https://doi.org/10.1063/1.4870263

Similar Records

Title: Realization of Large Electric Polarization and Strong Magnetoelectric Coupling in BiMn3Cr4O12

Abstract

Citation Formats

Figures / Tables:

MATERIALS SCIENCE: The Renaissance of Magnetoelectric Multiferroics journal, July 2005

Features of the magnetoelectric properties of BiFeO3 in high magnetic fields journal, June 2001

Ferroelectricity from iron valence ordering in the charge-frustrated system LuFe2O4 journal, August 2005

Magnetic control of ferroelectric polarization journal, November 2003

Role of t 2g electrons in Mn-Tb coupling of multiferroic TbMnO 3 journal, August 2014

Observation of Magnetoelectric Multiferroicity in a Cubic Perovskite System: LaMn 3 Cr 4 O 12 journal, August 2015

Multiferroic properties of CaMn 7 O 12 journal, November 2011

Phonons and related crystal properties from density-functional perturbation theory journal, July 2001

Switching kinetics of lead zirconate titanate submicron thin‐film memories journal, July 1988

Multiferroics of spin origin journal, July 2014

Multi-ferroic magnetoelectrics journal, January 1994

Pyroelectric properties and domain structure of modified lead ferroniobate-based ceramics journal, August 2000

X-ray study of and structural approach to the incommensurate perovskite Pb2CoWO6 journal, February 1995

Multiferroic materials and magnetoelectric physics: symmetry, entanglement, excitation, and topology journal, November 2015

The origin of ferroelectricity in magnetoelectric YMnO3 journal, February 2004

Anisotropic symmetric exchange as a new mechanism for multiferroicity journal, May 2016

Ferroelectricity Induced by Acentric Spin-Density Waves in YMn 2 O 5 journal, March 2006

Multiferroics with Spiral Spin Orders journal, December 2009

Classifying multiferroics: Mechanisms and effects journal, March 2009

Various Valence States of Square-Coordinated Mn in A-Site-Ordered Perovskites journal, November 2009

Recent Progress in Multiferroic Magnetoelectric Composites: from Bulk to Thin Films journal, February 2011

The absence of ferroelectricity and the origin of depolarization currents in YFe 0.8 Mn 0.2 O 3 journal, April 2017

Independent ferroelectric contributions and rare-earth-induced polarization reversal in multiferroic TbMn 2 O 5 journal, March 2012

Intrinsic ferroelectric polarization of orthorhombic manganites with E -type spin order journal, May 2012

Structural Anomalies and Multiferroic Behavior in Magnetically Frustrated T b M n 2 O 5 journal, October 2004

Multiferroics progress and prospects in thin films journal, January 2007

Multiferroics: a magnetic twist for ferroelectricity journal, January 2007

Ferroelectricity in the Magnetic E -Phase of Orthorhombic Perovskites journal, November 2006

Macroscopic polarization in crystalline dielectrics: the geometric phase approach journal, July 1994

Multiferroic and magnetoelectric materials journal, August 2006

Epitaxial BiFeO3 Multiferroic Thin Film Heterostructures journal, March 2003

Dielectric hysteresis in single crystal BiFeO3 journal, July 1970

Electric polarization reversal and memory in a multiferroic material induced by magnetic fields journal, May 2004

Giant Improper Ferroelectricity in the Ferroaxial Magnet CaMn 7 O 12 journal, February 2012

Single-phase multiferroics: new materials, phenomena, and physics journal, July 2019

Neutron Instruments for Research in Coordination Chemistry: Neutron Instruments for Research in Coordination Chemistry journal, January 2019

Magnetodielectric Coupling Response in La-Modified M-Type Strontium Hexaferrite journal, June 2018

Large linear magnetoelectric effect and field-induced ferromagnetism and ferroelectricity in DyCrO4 journal, September 2019

Low leakage current resistive memory based on Bi 1.10 (Fe 0.95 Mn 0.05 ) O 3 films journal, July 2018

Low temperature magnetocaloric properties of RE 2/3 Cu 3 Ti 4 O 12 (RE = La, Ho and Dy) systems journal, February 2019

Characterization of magnetic symmetry and electric polarization of YC r 0.5 F e 0.5 O 3 journal, January 2020

Group-theoretical analysis of 1:3 A -site-ordered perovskite formation journal, February 2019

Ferroelectricity driven by soft phonon and spin order in multiferroic BiMn 3 Cr 4 O 12 journal, April 2019

Title: Realization of Large Electric Polarization and Strong Magnetoelectric Coupling in BiMn₃Cr₄O₁₂

MATERIALS SCIENCE: The Renaissance of Magnetoelectric Multiferroics
journal, July 2005

Features of the magnetoelectric properties of BiFeO3 in high magnetic fields
journal, June 2001

Ferroelectricity from iron valence ordering in the charge-frustrated system LuFe2O4
journal, August 2005

Magnetic control of ferroelectric polarization
journal, November 2003

Role of t _2g electrons in Mn-Tb coupling of multiferroic TbMnO ₃
journal, August 2014

Observation of Magnetoelectric Multiferroicity in a Cubic Perovskite System: ${LaMn}_{3} {Cr}_{4} O_{12}$
journal, August 2015

Multiferroic properties of CaMn $_{7}$ O $_{12}$
journal, November 2011

Phonons and related crystal properties from density-functional perturbation theory
journal, July 2001

Switching kinetics of lead zirconate titanate submicron thin‐film memories
journal, July 1988

Multiferroics of spin origin
journal, July 2014

Multi-ferroic magnetoelectrics
journal, January 1994

Pyroelectric properties and domain structure of modified lead ferroniobate-based ceramics
journal, August 2000

X-ray study of and structural approach to the incommensurate perovskite Pb2CoWO6
journal, February 1995

Multiferroic materials and magnetoelectric physics: symmetry, entanglement, excitation, and topology
journal, November 2015

The origin of ferroelectricity in magnetoelectric YMnO3
journal, February 2004

Anisotropic symmetric exchange as a new mechanism for multiferroicity
journal, May 2016

Ferroelectricity Induced by Acentric Spin-Density Waves in ${YMn}_{2} O_{5}$
journal, March 2006

Multiferroics with Spiral Spin Orders
journal, December 2009

Classifying multiferroics: Mechanisms and effects
journal, March 2009

Various Valence States of Square-Coordinated Mn in A-Site-Ordered Perovskites
journal, November 2009

Recent Progress in Multiferroic Magnetoelectric Composites: from Bulk to Thin Films
journal, February 2011

The absence of ferroelectricity and the origin of depolarization currents in YFe _0.8 Mn _0.2 O ₃
journal, April 2017

Independent ferroelectric contributions and rare-earth-induced polarization reversal in multiferroic TbMn $_{2}$ O $_{5}$
journal, March 2012

Intrinsic ferroelectric polarization of orthorhombic manganites with $E$ -type spin order
journal, May 2012

Structural Anomalies and Multiferroic Behavior in Magnetically Frustrated ${T b M n}_{2} O_{5}$
journal, October 2004

Multiferroics progress and prospects in thin films
journal, January 2007

Multiferroics: a magnetic twist for ferroelectricity
journal, January 2007

Ferroelectricity in the Magnetic $E$ -Phase of Orthorhombic Perovskites
journal, November 2006

Macroscopic polarization in crystalline dielectrics: the geometric phase approach
journal, July 1994

Multiferroic and magnetoelectric materials
journal, August 2006

Epitaxial BiFeO₃ Multiferroic Thin Film Heterostructures
journal, March 2003

Dielectric hysteresis in single crystal BiFeO3
journal, July 1970

Electric polarization reversal and memory in a multiferroic material induced by magnetic fields
journal, May 2004

Giant Improper Ferroelectricity in the Ferroaxial Magnet ${CaMn}_{7} O_{12}$
journal, February 2012

Single-phase multiferroics: new materials, phenomena, and physics
journal, July 2019

Neutron Instruments for Research in Coordination Chemistry: Neutron Instruments for Research in Coordination Chemistry
journal, January 2019

Magnetodielectric Coupling Response in La-Modified M-Type Strontium Hexaferrite
journal, June 2018

Large linear magnetoelectric effect and field-induced ferromagnetism and ferroelectricity in DyCrO4
journal, September 2019

Low leakage current resistive memory based on Bi _1.10 (Fe _0.95 Mn _0.05 ) O ₃ films
journal, July 2018

Low temperature magnetocaloric properties of RE _2/3 Cu ₃ Ti ₄ O ₁₂ (RE = La, Ho and Dy) systems
journal, February 2019

Characterization of magnetic symmetry and electric polarization of $YC r_{0.5} F e_{0.5} O_{3}$
journal, January 2020

Group-theoretical analysis of 1:3 A -site-ordered perovskite formation
journal, February 2019

Ferroelectricity driven by soft phonon and spin order in multiferroic BiMn ₃ Cr ₄ O ₁₂
journal, April 2019