Kinetics and Mechanism of Methanol Conversion over Anatase Titania Nanoshapes
Abstract
The kinetics and mechanism of methanol dehydration, redox, and oxidative coupling were explored at 300 °C under dilute oxygen concentration over anatase TiO2 nanoplates and truncated-bipyramidal nanocrystals in order to understand the surface structure effect of TiO2. The two TiO2 nanoshapes displayed both (001) and (101) facets, with a higher fraction of the (001) facet exposed on the nanoplates, while truncated-bipyramidal nanocrystals were dominated by the (101) facet. A kinetic study using in situ titration with ammonia reflects that the active sites for methanol dehydration are acidic and nonequivalent in comparison to redox and oxidative coupling. In situ FTIR spectroscopy reveals that adsorbed methoxy is the dominant surface species for all reactions, while the observed methanol dimer is found to be a spectator species through isotopic methanol exchange, supporting the dissociative mechanism for methanol dehydration via surface methoxy over TiO2 surfaces. Density functional theory calculations show that the formation of dimethyl ether involves the C–H bond dissociation of an adsorbed methoxy, followed by coupling with another surface methoxy on the 5-fold-coordinated Ti cations on the (101) surface, similar to the mechanism reported on the (001) surface. Kinetic isotope effects are observed for dimethyl ether, formaldehyde, and methyl formate in themore »
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Univ. of California, Riverside, CA (United States)
- Georgia Inst. of Technology, Atlanta, GA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; National Science Foundation (NSF)
- OSTI Identifier:
- 1485311
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Catalysis
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 8; Journal ID: ISSN 2155-5435
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; TiO2; surface structure; dehydration; redox; oxidative coupling; dimethyl ether; formaldehyde; methyl formate
Citation Formats
Foo, Guo Shiou, Hu, Guoxiang, Hood, Zachary D., Li, Meijun, Jiang, De-en, and Wu, Zili. Kinetics and Mechanism of Methanol Conversion over Anatase Titania Nanoshapes. United States: N. p., 2017.
Web. doi:10.1021/acscatal.7b01456.
Foo, Guo Shiou, Hu, Guoxiang, Hood, Zachary D., Li, Meijun, Jiang, De-en, & Wu, Zili. Kinetics and Mechanism of Methanol Conversion over Anatase Titania Nanoshapes. United States. https://doi.org/10.1021/acscatal.7b01456
Foo, Guo Shiou, Hu, Guoxiang, Hood, Zachary D., Li, Meijun, Jiang, De-en, and Wu, Zili. Wed .
"Kinetics and Mechanism of Methanol Conversion over Anatase Titania Nanoshapes". United States. https://doi.org/10.1021/acscatal.7b01456. https://www.osti.gov/servlets/purl/1485311.
@article{osti_1485311,
title = {Kinetics and Mechanism of Methanol Conversion over Anatase Titania Nanoshapes},
author = {Foo, Guo Shiou and Hu, Guoxiang and Hood, Zachary D. and Li, Meijun and Jiang, De-en and Wu, Zili},
abstractNote = {The kinetics and mechanism of methanol dehydration, redox, and oxidative coupling were explored at 300 °C under dilute oxygen concentration over anatase TiO2 nanoplates and truncated-bipyramidal nanocrystals in order to understand the surface structure effect of TiO2. The two TiO2 nanoshapes displayed both (001) and (101) facets, with a higher fraction of the (001) facet exposed on the nanoplates, while truncated-bipyramidal nanocrystals were dominated by the (101) facet. A kinetic study using in situ titration with ammonia reflects that the active sites for methanol dehydration are acidic and nonequivalent in comparison to redox and oxidative coupling. In situ FTIR spectroscopy reveals that adsorbed methoxy is the dominant surface species for all reactions, while the observed methanol dimer is found to be a spectator species through isotopic methanol exchange, supporting the dissociative mechanism for methanol dehydration via surface methoxy over TiO2 surfaces. Density functional theory calculations show that the formation of dimethyl ether involves the C–H bond dissociation of an adsorbed methoxy, followed by coupling with another surface methoxy on the 5-fold-coordinated Ti cations on the (101) surface, similar to the mechanism reported on the (001) surface. Kinetic isotope effects are observed for dimethyl ether, formaldehyde, and methyl formate in the presence of deuterated methanol (CD3OH and CD3OD), confirming that the cleavage of the C–H bond is the rate-limiting step for the formation of these products. A comparison between estimated kinetic parameters for methanol dehydration over various TiO2 nanocrystals suggests that (001) has a higher dehydration reactivity in comparison to (101), but the surface density of active sites could be limited by the presence of residual fluorine atoms originating from the synthesis. The (001) surface of TiO2 is also more active than the (101) surface in redox and oxidative coupling of methanol, which is due to the reactive surface oxygen on (001) in comparison to the (101) surface.},
doi = {10.1021/acscatal.7b01456},
journal = {ACS Catalysis},
number = 8,
volume = 7,
place = {United States},
year = {Wed Jul 05 00:00:00 EDT 2017},
month = {Wed Jul 05 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Methanol to Dimethyl Ether over ZSM-22: A Periodic Density Functional Theory Study
journal, February 2013
- Moses, Poul Georg; Nørskov, Jens K.
- ACS Catalysis, Vol. 3, Issue 4
Reaction Mechanism of Methanol to Formaldehyde over Fe- and FeO-Modified Graphene
journal, January 2015
- Thivasasith, Anawat; Sirijaraensre, Jakkapan; Khongpracha, Pipat
- ChemPhysChem, Vol. 16, Issue 5
Selective oxidation of methanol to form dimethoxymethane and methyl formate over a monolayer V2O5/TiO2 catalyst
journal, March 2014
- Kaichev, V. V.; Popova, G. Ya.; Chesalov, Yu. A.
- Journal of Catalysis, Vol. 311
Catalysis Chemistry of Dimethyl Ether Synthesis
journal, August 2014
- Sun, Jian; Yang, Guohui; Yoneyama, Yoshiharu
- ACS Catalysis, Vol. 4, Issue 10
The potential of di-methyl ether (DME) as an alternative fuel for compression-ignition engines: A review
journal, June 2008
- Arcoumanis, Constantine; Bae, Choongsik; Crookes, Roy
- Fuel, Vol. 87, Issue 7
An Oft-Studied Reaction That May Never Have Been: Direct Catalytic Conversion of Methanol or Dimethyl Ether to Hydrocarbons on the Solid Acids HZSM-5 or HSAPO-34
journal, April 2002
- Song, Weiguo; Marcus, David M.; Fu, Hui
- Journal of the American Chemical Society, Vol. 124, Issue 15
Implications of Cofeeding Acetaldehyde on Ethene Selectivity in Methanol-to-Hydrocarbons Conversion on MFI and Its Mechanistic Interpretation
journal, March 2016
- Khare, Rachit; Arora, Sukaran S.; Bhan, Aditya
- ACS Catalysis, Vol. 6, Issue 4
Mechanism of the Catalytic Conversion of Methanol to Hydrocarbons
journal, December 2012
- Ilias, Samia; Bhan, Aditya
- ACS Catalysis, Vol. 3, Issue 1, p. 18-31
Hydrogen Transfer Pathways during Zeolite Catalyzed Methanol Conversion to Hydrocarbons
journal, November 2016
- Müller, Sebastian; Liu, Yue; Kirchberger, Felix M.
- Journal of the American Chemical Society, Vol. 138, Issue 49
Conversion of Methanol to Olefins over H-ZSM-5 Zeolite: Reaction Pathway Is Related to the Framework Aluminum Siting
journal, September 2016
- Liang, Tingyu; Chen, Jialing; Qin, Zhangfeng
- ACS Catalysis, Vol. 6, Issue 11
Effect of the Operating Conditions in the Transformation of DME to olefins over a HZSM-5 Zeolite Catalyst
journal, June 2016
- Pérez-Uriarte, Paula; Ateka, Ainara; Gamero, Mónica
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 23
Preparation and Properties of Coated Nitrogen Fertilizer with Slow Release and Water Retention
journal, December 2006
- Liang, Rui; Liu, Mingzhu
- Industrial & Engineering Chemistry Research, Vol. 45, Issue 25
Methyl Formate Formation from Methanol Oxidation Using Supported Gold–Palladium Nanoparticles
journal, December 2014
- Whiting, Gareth T.; Kondrat, Simon A.; Hammond, Ceri
- ACS Catalysis, Vol. 5, Issue 2
Methanol dehydration to dimethylether over Al2O3 catalysts
journal, February 2014
- Akarmazyan, Siranush S.; Panagiotopoulou, Paraskevi; Kambolis, Anastasios
- Applied Catalysis B: Environmental, Vol. 145
Titanium-doped alumina for catalytic dehydration of methanol to dimethyl ether at relatively low temperatures
journal, July 2011
- Khaleel, Abbas
- Fuel, Vol. 90, Issue 7
Kinetic, Spectroscopic, and Theoretical Assessment of Associative and Dissociative Methanol Dehydration Routes in Zeolites
journal, September 2014
- Jones, Andrew J.; Iglesia, Enrique
- Angewandte Chemie International Edition, Vol. 53, Issue 45
Catalytic consequences of acid strength in the conversion of methanol to dimethyl ether
journal, February 2011
- Carr, Robert T.; Neurock, Matthew; Iglesia, Enrique
- Journal of Catalysis, Vol. 278, Issue 1
Synthesis of dimethyl ether (DME) from methanol over solid-acid catalysts
journal, February 1997
- Xu, Mingting; Lunsford, Jack H.; Goodman, D. Wayne
- Applied Catalysis A: General, Vol. 149, Issue 2
Surface and Bulk Aspects of Mixed Oxide Catalytic Nanoparticles: Oxidation and Dehydration of CH 3 OH by Polyoxometallates
journal, October 2009
- Nakka, Lingaiah; Molinari, Julie E.; Wachs, Israel E.
- Journal of the American Chemical Society, Vol. 131, Issue 42
Microcalorimetric and FT-IR spectroscopic study of the adsorption of methanol on TiO2 (anatase)
journal, November 1985
- Rossi, Pier Francesco; Busca, Guido
- Colloids and Surfaces, Vol. 16, Issue 2
Titanium Dioxide Nanomaterials: Synthesis, Properties, Modifications, and Applications
journal, July 2007
- Chen, Xiaobo; Mao, Samuel S.
- Chemical Reviews, Vol. 107, Issue 7
The surface science of titanium dioxide
journal, January 2003
- Diebold, Ulrike
- Surface Science Reports, Vol. 48, Issue 5-8
Structure of Clean and Adsorbate-Covered Single-Crystal Rutile TiO 2 Surfaces
journal, December 2012
- Pang, Chi Lun; Lindsay, Robert; Thornton, Geoff
- Chemical Reviews, Vol. 113, Issue 6
Stress-Driven Reconstruction of an Oxide Surface: The Anatase Surface
journal, December 2001
- Lazzeri, Michele; Selloni, Annabella
- Physical Review Letters, Vol. 87, Issue 26
Surface structure of anatase Reconstruction, atomic steps, and domains
journal, May 2001
- Liang, Yong; Gan, Shupan; Chambers, Scott A.
- Physical Review B, Vol. 63, Issue 23
Structure and stability of the anatase TiO2 (101) and (001) surfaces
journal, July 2000
- Hengerer, R.; Bolliger, B.; Erbudak, M.
- Surface Science, Vol. 460, Issue 1-3
Prediction of TiO 2 Nanoparticle Phase and Shape Transitions Controlled by Surface Chemistry
journal, July 2005
- Barnard, A. S.; Curtiss, L. A.
- Nano Letters, Vol. 5, Issue 7
Anatase TiO2 single crystals with a large percentage of reactive facets
journal, May 2008
- Yang, Hua Gui; Sun, Cheng Hua; Qiao, Shi Zhang
- Nature, Vol. 453, Issue 7195
Shape-dependence of the thermal and photochemical reactions of methanol on nanocrystalline anatase TiO2
journal, December 2016
- Bennett, David A.; Cargnello, Matteo; Diroll, Benjamin T.
- Surface Science, Vol. 654
Methanol Adsorption and Reactivity on Clean and Hydroxylated Anatase(101) Surfaces
journal, December 2004
- Tilocca, Antonio; Selloni, Annabella
- The Journal of Physical Chemistry B, Vol. 108, Issue 50
Methanol Conversion into Dimethyl Ether on the Anatase TiO 2 (001) Surface
journal, November 2015
- Xiong, Feng; Yu, Yan-Yan; Wu, Zongfang
- Angewandte Chemie International Edition, Vol. 55, Issue 2
Methanol oxidation on MoO3/TiO2 catalysts
journal, March 1993
- Brückman, K.; Grzybowska, B.; Che, M.
- Applied Catalysis A: General, Vol. 96, Issue 2
Methanol oxidation on Au/TiO2 catalysts
journal, June 2007
- Nuhu, Abdullahi; Soares, Jorge; Gonzalez-Herrera, Monica
- Topics in Catalysis, Vol. 44, Issue 1-2
Engineering the TiO 2 -Graphene Interface to Enhance Photocatalytic H 2 Production
journal, December 2013
- Liu, Lichen; Liu, Zhe; Liu, Annai
- ChemSusChem, Vol. 7, Issue 2
Promoting effect of fluorine on titania-supported cobalt–molybdenum hydrodesulfurization catalysts
journal, January 2007
- Wang, Danhong; Li, Wei; Zhang, Minghui
- Applied Catalysis A: General, Vol. 317, Issue 1
Adsorption of Gases in Multimolecular Layers
journal, February 1938
- Brunauer, Stephen; Emmett, P. H.; Teller, Edward
- Journal of the American Chemical Society, Vol. 60, Issue 2, p. 309-319
Direct measurements of water adsorption enthalpy on hafnia and zirconia
journal, October 2005
- Ushakov, Sergey V.; Navrotsky, Alexandra
- Applied Physics Letters, Vol. 87, Issue 16
Energy Landscape of Water and Ethanol on Silica Surfaces
journal, June 2015
- Wu, Di; Guo, Xiaofeng; Sun, Hui
- The Journal of Physical Chemistry C, Vol. 119, Issue 27
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
journal, April 2010
- Grimme, Stefan; Antony, Jens; Ehrlich, Stephan
- The Journal of Chemical Physics, Vol. 132, Issue 15
A climbing image nudged elastic band method for finding saddle points and minimum energy paths
journal, December 2000
- Henkelman, Graeme; Uberuaga, Blas P.; Jónsson, Hannes
- The Journal of Chemical Physics, Vol. 113, Issue 22, p. 9901-9904
Synthesis of chiral TiO2 nanofibre with electron transition-based optical activity
journal, January 2012
- Liu, Shaohua; Han, Lu; Duan, Yingying
- Nature Communications, Vol. 3, Issue 1
Anatase TiO2 Crystals with Exposed High-Index Facets
journal, March 2011
- Jiang, Hai Bo; Cuan, Qian; Wen, Ci Zhang
- Angewandte Chemie International Edition, Vol. 50, Issue 16
Quantitative Analysis of the Morphology of {101} and {001} Faceted Anatase TiO 2 Nanocrystals and Its Implication on Photocatalytic Activity
journal, June 2017
- Liu, Jue; Olds, Daniel; Peng, Rui
- Chemistry of Materials, Vol. 29, Issue 13
Visible Light Responsive Nitrogen Doped Anatase TiO 2 Sheets with Dominant {001} Facets Derived from TiN
journal, September 2009
- Liu, Gang; Yang, Hua Gui; Wang, Xuewen
- Journal of the American Chemical Society, Vol. 131, Issue 36
Nonaqueous Synthesis of TiO 2 Nanocrystals Using TiF 4 to Engineer Morphology, Oxygen Vacancy Concentration, and Photocatalytic Activity
journal, April 2012
- Gordon, Thomas R.; Cargnello, Matteo; Paik, Taejong
- Journal of the American Chemical Society, Vol. 134, Issue 15
Enhanced Photoactivity of Oxygen-Deficient Anatase TiO 2 Sheets with Dominant {001} Facets
journal, December 2009
- Liu, Gang; Yang, Hua Gui; Wang, Xuewen
- The Journal of Physical Chemistry C, Vol. 113, Issue 52
Infrared studies of the surface acidity of oxides and zeolites using adsorbed probe molecules
journal, February 1996
- Lercher, Johannes A.; Gründling, Christian; Eder-Mirth, Gabriele
- Catalysis Today, Vol. 27, Issue 3-4
Comprehensive IR study on acid/base properties of metal oxides
journal, August 2012
- Tamura, Masazumi; Shimizu, Ken-ichi; Satsuma, Atsushi
- Applied Catalysis A: General, Vol. 433-434
Microcalorimetric, FTIR, and DFT Studies of the Adsorption of Methanol, Ethanol, and 2,2,2-Trifluoroethanol on Silica
journal, April 1998
- Natal-Santiago, M. A.; Dumesic, J. A.
- Journal of Catalysis, Vol. 175, Issue 2
Hydrogen Bond Breaking and Reformation in Alcohol Oligomers Following Vibrational Relaxation of a Non-Hydrogen-Bond Donating Hydroxyl Stretch
journal, October 2002
- Gaffney, K. J.; Piletic, I. R.; Fayer, M. D.
- The Journal of Physical Chemistry A, Vol. 106, Issue 41
Quantification of Active Sites for the Determination of Methanol Oxidation Turn-over Frequencies Using Methanol Chemisorption and in Situ Infrared Techniques. 1. Supported Metal Oxide Catalysts
journal, October 2001
- Burcham, Loyd J.; Briand, Laura E.; Wachs, Israel E.
- Langmuir, Vol. 17, Issue 20
Mechanism of selective methanol oxidation over vanadium oxide-titanium oxide catalysts: a FT-IR and flow reactor study
journal, September 1987
- Busca, Guido.; Elmi, Ahmed S.; Forzatti, Pio.
- The Journal of Physical Chemistry, Vol. 91, Issue 20
(Non)formation of Methanol by Direct Hydrogenation of Formate on Copper Catalysts
journal, July 2010
- Yang, Yong; Mims, C. A.; Disselkamp, R. S.
- The Journal of Physical Chemistry C, Vol. 114, Issue 40
Structure and Vibrational Spectrum of Formate and Acetate Adsorbed from Aqueous Solution onto the TiO 2 Rutile (110) Surface
journal, April 2004
- Rotzinger, François P.; Kesselman-Truttmann, Janet M.; Hug, Stephan J.
- The Journal of Physical Chemistry B, Vol. 108, Issue 16
Acid strength and solvation in catalysis by MFI zeolites and effects of the identity, concentration and location of framework heteroatoms
journal, April 2014
- Jones, Andrew J.; Carr, Robert T.; Zones, Stacey I.
- Journal of Catalysis, Vol. 312
Dehydration of Methanol to Dimethyl Ether over Heteropoly Acid Catalysts: The Relationship between Reaction Rate and Catalyst Acid Strength
journal, November 2015
- Alharbi, Walaa; Kozhevnikova, Elena F.; Kozhevnikov, Ivan V.
- ACS Catalysis, Vol. 5, Issue 12
Bonding Geometry and Reactivity of Methoxy and Ethoxy Groups Adsorbed on Powdered TiO 2
journal, September 2000
- Wu, Wen-Chun; Chuang, Chih-Chung; Lin, Jong-Liang
- The Journal of Physical Chemistry B, Vol. 104, Issue 36
Experimental Investigation of the Interaction of Water and Methanol with Anatase−TiO 2 (101)
journal, March 2003
- Herman, G. S.; Dohnálek, Z.; Ruzycki, N.
- The Journal of Physical Chemistry B, Vol. 107, Issue 12
CO 2 Capture by TiO 2 Anatase Surfaces: A Combined DFT and FTIR Study
journal, October 2014
- Mino, Lorenzo; Spoto, Giuseppe; Ferrari, Anna Maria
- The Journal of Physical Chemistry C, Vol. 118, Issue 43
Low-temperature CO2 adsorption on metal oxides: spectroscopic characterization of some weakly adsorbed species
journal, September 1991
- Ramis, G.; Busca, G.; Lorenzelli, V.
- Materials Chemistry and Physics, Vol. 29, Issue 1-4
Lewis acid and base sites at the surface of microcrystalline TiO2 anatase: relationships between surface morphology and chemical behaviour
journal, August 2000
- Martra, Gianmario
- Applied Catalysis A: General, Vol. 200, Issue 1-2
Reactions of methanol on TiO2(001) single crystal surfaces
journal, December 1989
- Kim, K. S.; Barteau, M. A.
- Surface Science, Vol. 223, Issue 1-2
Reactivity of Anatase TiO 2 Nanoparticles: The Role of the Minority (001) Surface
journal, October 2005
- Gong, Xue-Qing; Selloni, Annabella
- The Journal of Physical Chemistry B, Vol. 109, Issue 42
Chemistry of and on TiO2-anatase surfaces by DFT calculations: a partial review
journal, December 2006
- Vittadini, Andrea; Casarin, Maurizio; Selloni, Annabella
- Theoretical Chemistry Accounts, Vol. 117, Issue 5-6
Steps on anatase TiO2(101)
journal, July 2006
- Gong, Xue-Qing; Selloni, Annabella; Batzill, Matthias
- Nature Materials, Vol. 5, Issue 8
Monolayer V2O5/TiO2 and MoO3/TiO2 catalysts prepared by different methods
journal, January 1991
- Machej, Tadeusz; Haber, Jerzy; M. Turek, Andrzej
- Applied Catalysis, Vol. 70, Issue 1
Electrostatic potential calculations on crystalline TiO2: The surface reducibility of rutile and anatase
journal, November 1983
- Ivoning, J.; van Santen*, R. A.
- Chemical Physics Letters, Vol. 101, Issue 6
Particle size effects on the reducibility of titanium dioxide and its relation to the water–gas shift activity of Pt/TiO2 catalysts
journal, June 2006
- Panagiotopoulou, P.; Christodoulakis, A.; Kondarides, D. I.
- Journal of Catalysis, Vol. 240, Issue 2
Surface chemistry of titania (anatase) and titania-supported catalysts
journal, January 1996
- Hadjiivanov, Konstantin I.; Klissurski, Dimitar G.
- Chemical Society Reviews, Vol. 25, Issue 1
Structures and Properties of Zirconia-Supported Ruthenium Oxide Catalysts for the Selective Oxidation of Methanol to Methyl Formate
journal, November 2006
- Li, Weizhen; Liu, Haichao; Iglesia, Enrique
- The Journal of Physical Chemistry B, Vol. 110, Issue 46
Methanol Selective Oxidation to Methyl Formate over ReOx/CeO2 Catalysts
journal, October 2007
- Liu, Junlong; Zhan, Ensheng; Cai, Weijie
- Catalysis Letters, Vol. 120, Issue 3-4
Adsorption and decomposition of aliphatic alcohols on titania
journal, May 1988
- Kim, K. S.; Barteau, M. A.; Farneth, W. E.
- Langmuir, Vol. 4, Issue 3
Reactivity of Supported Vanadium Oxide Catalysts: The Partial Oxidation of Methanol
journal, April 1994
- Deo, G.; Wachs, I. E.
- Journal of Catalysis, Vol. 146, Issue 2
Kinetics of hydrogen activation on ceria–zirconia
journal, September 2015
- Schimming, Sarah M.; Foo, Guo Shiou; LaMont, Onaje D.
- Journal of Catalysis, Vol. 329
Heterogeneous Ceria Catalyst with Water-Tolerant Lewis Acidic Sites for One-Pot Synthesis of 1,3-Diols via Prins Condensation and Hydrolysis Reactions
journal, January 2013
- Wang, Yehong; Wang, Feng; Song, Qi
- Journal of the American Chemical Society, Vol. 135, Issue 4
Works referencing / citing this record:
Ethanol as a Binder to Fabricate a Highly‐Efficient Capsule‐Structured CuO−ZnO−Al 2 O 3 @HZSM‐5 Catalyst for Direct Production of Dimethyl Ether from Syngas
journal, December 2019
- Guo, Yongle; Zhao, Zhongkui
- ChemCatChem, Vol. 12, Issue 4