A novel P3-type Na2/3Mg1/3Mn2/3O2 as high capacity sodium-ion cathode using reversible oxygen redox
Abstract
A novel P3-type Na2/3Mg1/3Mn2/3O2cathode delivers a reversible capacity over 200 mA h g-1mainly using lattice oxygen redox.
- Authors:
-
[1];
[2];
[1];
[1];
[2];
[1];
[1];
[1]
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1485260
- Alternate Identifier(s):
- OSTI ID: 1485332; OSTI ID: 1502593
- Report Number(s):
- BNL-209657-2018-JAAM
Journal ID: ISSN 2050-7488; JMCAET
- Grant/Contract Number:
- SC0012704; KC040602; AC05-00OR22725; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 4; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Song, Bohang, Hu, Enyuan, Liu, Jue, Zhang, Yiman, Yang, Xiao -Qing, Nanda, Jagjit, Huq, Ashfia, and Page, Katharine. A novel P3-type Na2/3Mg1/3Mn2/3O2 as high capacity sodium-ion cathode using reversible oxygen redox. United States: N. p., 2018.
Web. doi:10.1039/C8TA09422E.
Song, Bohang, Hu, Enyuan, Liu, Jue, Zhang, Yiman, Yang, Xiao -Qing, Nanda, Jagjit, Huq, Ashfia, & Page, Katharine. A novel P3-type Na2/3Mg1/3Mn2/3O2 as high capacity sodium-ion cathode using reversible oxygen redox. United States. https://doi.org/10.1039/C8TA09422E
Song, Bohang, Hu, Enyuan, Liu, Jue, Zhang, Yiman, Yang, Xiao -Qing, Nanda, Jagjit, Huq, Ashfia, and Page, Katharine. Mon .
"A novel P3-type Na2/3Mg1/3Mn2/3O2 as high capacity sodium-ion cathode using reversible oxygen redox". United States. https://doi.org/10.1039/C8TA09422E. https://www.osti.gov/servlets/purl/1485260.
@article{osti_1485260,
title = {A novel P3-type Na2/3Mg1/3Mn2/3O2 as high capacity sodium-ion cathode using reversible oxygen redox},
author = {Song, Bohang and Hu, Enyuan and Liu, Jue and Zhang, Yiman and Yang, Xiao -Qing and Nanda, Jagjit and Huq, Ashfia and Page, Katharine},
abstractNote = {A novel P3-type Na2/3Mg1/3Mn2/3O2cathode delivers a reversible capacity over 200 mA h g-1mainly using lattice oxygen redox.},
doi = {10.1039/C8TA09422E},
journal = {Journal of Materials Chemistry. A},
number = 4,
volume = 7,
place = {United States},
year = {2018},
month = {12}
}
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Works referenced in this record:
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005
- Ravel, B.; Newville, M.
- Journal of Synchrotron Radiation, Vol. 12, Issue 4
Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] for Lithium-Ion Batteries
journal, January 2001
- Lu, Zhonghua; MacNeil, D. D.; Dahn, J. R.
- Electrochemical and Solid-State Letters, Vol. 4, Issue 11
Electrochemical extraction of lithium from LiMn2O4
journal, February 1984
- Thackeray, M. M.; Johnson, P. J.; de Picciotto, L. A.
- Materials Research Bulletin, Vol. 19, Issue 2
Challenges for Rechargeable Li Batteries
journal, February 2010
- Goodenough, John B.; Kim, Youngsik
- Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries
journal, September 2007
- Ellis, B. L.; Makahnouk, W. R. M.; Makimura, Y.
- Nature Materials, Vol. 6, Issue 10
Polyanionic (Phosphates, Silicates, Sulfates) Frameworks as Electrode Materials for Rechargeable Li (or Na) Batteries
journal, June 2013
- Masquelier, Christian; Croguennec, Laurence
- Chemical Reviews, Vol. 113, Issue 8
Rapid-acquisition pair distribution function (RA-PDF) analysis
journal, November 2003
- Chupas, Peter J.; Qiu, Xiangyun; Hanson, Jonathan C.
- Journal of Applied Crystallography, Vol. 36, Issue 6, p. 1342-1347
Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen
journal, March 2016
- Luo, Kun; Roberts, Matthew R.; Hao, Rong
- Nature Chemistry, Vol. 8, Issue 7
Review—Li-Rich Layered Oxide Cathodes for Next-Generation Li-Ion Batteries: Chances and Challenges
journal, January 2015
- Rozier, Patrick; Tarascon, Jean Marie
- Journal of The Electrochemical Society, Vol. 162, Issue 14
Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release
journal, July 2018
- Hu, Enyuan; Yu, Xiqian; Lin, Ruoqian
- Nature Energy, Vol. 3, Issue 8
A new electrode material for rechargeable sodium batteries: P2-type Na 2/3 [Mg 0.28 Mn 0.72 ]O 2 with anomalously high reversible capacity
journal, January 2014
- Yabuuchi, Naoaki; Hara, Ryo; Kubota, Kei
- J. Mater. Chem. A, Vol. 2, Issue 40
Lithium manganese oxyfluoride as a new cathode material exhibiting oxygen redox
journal, January 2018
- House, Robert A.; Jin, Liyu; Maitra, Urmimala
- Energy & Environmental Science, Vol. 11, Issue 4
The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials
journal, May 2016
- Seo, Dong-Hwa; Lee, Jinhyuk; Urban, Alexander
- Nature Chemistry, Vol. 8, Issue 7
Quantification of Honeycomb Number-Type Stacking Faults: Application to Na 3 Ni 2 BiO 6 Cathodes for Na-Ion Batteries
journal, August 2016
- Liu, Jue; Yin, Liang; Wu, Lijun
- Inorganic Chemistry, Vol. 55, Issue 17
Fast synthesis and refinement of the atomic pair distribution function
journal, May 2015
- Coelho, A. A.; Chater, P. A.; Kern, A.
- Journal of Applied Crystallography, Vol. 48, Issue 3
The Nanoscale Ordered MAterials Diffractometer NOMAD at the Spallation Neutron Source SNS
journal, September 2012
- Neuefeind, Jörg; Feygenson, Mikhail; Carruth, John
- Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 287
Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion intercalation materials
journal, January 2011
- Ong, Shyue Ping; Chevrier, Vincent L.; Hautier, Geoffroy
- Energy & Environmental Science, Vol. 4, Issue 9
High voltage structural evolution and enhanced Na-ion diffusion in P2-Na 2/3 Ni 1/3−x Mg x Mn 2/3 O 2 (0 ≤ x ≤ 0.2) cathodes from diffraction, electrochemical and ab initio studies
journal, January 2018
- Tapia-Ruiz, Nuria; Dose, Wesley M.; Sharma, Neeraj
- Energy & Environmental Science, Vol. 11, Issue 6
GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013
- Toby, Brian H.; Von Dreele, Robert B.
- Journal of Applied Crystallography, Vol. 46, Issue 2
Fundamental parameters line profile fitting in laboratory diffractometers
journal, January 2004
- Cheary, R. W.; Coelho, A. A.; Cline, J. P.
- Journal of Research of the National Institute of Standards and Technology, Vol. 109, Issue 1
Anion Redox Chemistry in the Cobalt Free 3d Transition Metal Oxide Intercalation Electrode Li[Li 0.2 Ni 0.2 Mn 0.6 ]O 2
journal, August 2016
- Luo, Kun; Roberts, Matthew R.; Guerrini, Niccoló
- Journal of the American Chemical Society, Vol. 138, Issue 35
Oxygen redox chemistry without excess alkali-metal ions in Na2/3[Mg0.28Mn0.72]O2
journal, January 2018
- Maitra, Urmimala; House, Robert A.; Somerville, James W.
- Nature Chemistry, Vol. 10, Issue 3
Electrochemical and Structural Study of the Layered, “Li-Excess” Lithium-Ion Battery Electrode Material Li[Li 1/9 Ni 1/3 Mn 5/9 ]O 2
journal, July 2009
- Jiang, Meng; Key, Baris; Meng, Ying S.
- Chemistry of Materials, Vol. 21, Issue 13
Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries
journal, April 2018
- Assat, Gaurav; Tarascon, Jean-Marie
- Nature Energy, Vol. 3, Issue 5
EXAFS analysis using FEFF and FEFFIT
journal, March 2001
- Newville, Matthew
- Journal of Synchrotron Radiation, Vol. 8, Issue 2
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
journal, January 2013
- Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan
- Energy & Environmental Science, Vol. 6, Issue 8
Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries
journal, January 2007
- Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S.
- Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3112-3125
Design principles for high transition metal capacity in disordered rocksalt Li-ion cathodes
journal, January 2018
- Kitchaev, Daniil A.; Lun, Zhengyan; Richards, William D.
- Energy & Environmental Science, Vol. 11, Issue 8
Structure-Induced Reversible Anionic Redox Activity in Na Layered Oxide Cathode
journal, January 2018
- Rong, Xiaohui; Liu, Jue; Hu, Enyuan
- Joule, Vol. 2, Issue 1
Structure and Magnetic Properties of the α-NaFeO 2 -Type Honeycomb Compound Na 3 Ni 2 BiO 6
journal, November 2013
- Seibel, Elizabeth M.; Roudebush, J. H.; Wu, Hui
- Inorganic Chemistry, Vol. 52, Issue 23
Sodium-Ion Batteries
journal, May 2012
- Slater, Michael D.; Kim, Donghan; Lee, Eungje
- Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
Local atomic structure of semiconductor alloys using pair distribution functions
journal, January 1997
- Chung, Jean S.; Thorpe, M. F.
- Physical Review B, Vol. 55, Issue 3
Re-entrant Lithium Local Environments and Defect Driven Electrochemistry of Li- and Mn-Rich Li-Ion Battery Cathodes
journal, February 2015
- Dogan, Fulya; Long, Brandon R.; Croy, Jason R.
- Journal of the American Chemical Society, Vol. 137, Issue 6
High-resolution X-ray diffraction, DIFFaX, NMR and first principles study of disorder in the Li2MnO3–Li[Ni1/2Mn1/2]O2 solid solution
journal, September 2005
- Bréger, Julien; Jiang, Meng; Dupré, Nicolas
- Journal of Solid State Chemistry, Vol. 178, Issue 9, p. 2575-2585
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries
journal, April 2012
- Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi
- Nature Materials, Vol. 11, Issue 6
Ionic Conduction in Cubic Na 3 TiP 3 O 9 N, a Secondary Na-Ion Battery Cathode with Extremely Low Volume Change
journal, May 2014
- Liu, Jue; Chang, Donghee; Whitfield, Pamela
- Chemistry of Materials, Vol. 26, Issue 10
Divalent Iron Nitridophosphates: A New Class of Cathode Materials for Li-Ion Batteries
journal, September 2013
- Liu, Jue; Yu, Xiqian; Hu, Enyuan
- Chemistry of Materials, Vol. 25, Issue 20
Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries
journal, December 2015
- McCalla, E.; Abakumov, A. M.; Saubanere, M.
- Science, Vol. 350, Issue 6267
An X‐Ray Study of Carbon Black
journal, June 1942
- Biscoe, J.; Warren, B. E.
- Journal of Applied Physics, Vol. 13, Issue 6
Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012
- Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
- Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
Reversible anionic redox activity in Na 3 RuO 4 cathodes: a prototype Na-rich layered oxide
journal, January 2018
- Qiao, Yu; Guo, Shaohua; Zhu, Kai
- Energy & Environmental Science, Vol. 11, Issue 2
A dedicated powder diffraction beamline at the Advanced Photon Source: Commissioning and early operational results
journal, August 2008
- Wang, Jun; Toby, Brian H.; Lee, Peter L.
- Review of Scientific Instruments, Vol. 79, Issue 8
Exploring reversible oxidation of oxygen in a manganese oxide
journal, January 2016
- Du, Ke; Zhu, Jinyou; Hu, Guorong
- Energy & Environmental Science, Vol. 9, Issue 8
LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density
journal, June 1980
- Mizushima, K.; Jones, P. C.; Wiseman, P. J.
- Materials Research Bulletin, Vol. 15, Issue 6
Accuracy of pair distribution function analysis applied to crystalline and non-crystalline materials
journal, May 1992
- Toby, B. H.; Egami, T.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 48, Issue 3
Research Development on Sodium-Ion Batteries
journal, October 2014
- Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
- Chemical Reviews, Vol. 114, Issue 23
Sodium-Ion Batteries
journal, June 2018
- Rojo, Teofilo; Hu, Yong-Sheng; Forsyth, Maria
- Advanced Energy Materials, Vol. 8, Issue 17
Works referencing / citing this record:
Understanding Challenges of Cathode Materials for Sodium‐Ion Batteries using Synchrotron‐Based X‐Ray Absorption Spectroscopy
journal, July 2019
- Chen, Mingzhe; Chou, Shu‐Lei; Dou, Shi‐Xue
- Batteries & Supercaps, Vol. 2, Issue 10
Dissociate lattice oxygen redox reactions from capacity and voltage drops of battery electrodes
journal, February 2020
- Wu, Jinpeng; Zhuo, Zengqing; Rong, Xiaohui
- Science Advances, Vol. 6, Issue 6