DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Manipulation of Edge‐Site Fe–N 2 Moiety on Holey Fe, N Codoped Graphene to Promote the Cycle Stability and Rate Capacity of Li–S Batteries

Authors:
 [1];  [2];  [2];  [1];  [1];  [2];  [2]; ORCiD logo [1]
  1. Beijing Key Laboratory for Magnetoelectric Materials and Devices (BKL‐MEMD) Beijing Innovation Center for Engineering Science and Advanced Technology (BIC‐ESAT) Department of Materials Science and Engineering College of Engineering Peking University Beijing 100871 China
  2. Centre for Clean Environmental and Energy and School of Environment and Science Griffith University Gold Coast Queensland 4222 Australia
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1485167
Grant/Contract Number:  
DE‐AC02‐76SF00515
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Name: Advanced Functional Materials Journal Volume: 29 Journal Issue: 5; Journal ID: ISSN 1616-301X
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Wang, Yazhou, Adekoya, David, Sun, Jiqing, Tang, Tianyu, Qiu, Hailong, Xu, Li, Zhang, Shanqing, and Hou, Yanglong. Manipulation of Edge‐Site Fe–N 2 Moiety on Holey Fe, N Codoped Graphene to Promote the Cycle Stability and Rate Capacity of Li–S Batteries. Germany: N. p., 2018. Web. doi:10.1002/adfm.201807485.
Wang, Yazhou, Adekoya, David, Sun, Jiqing, Tang, Tianyu, Qiu, Hailong, Xu, Li, Zhang, Shanqing, & Hou, Yanglong. Manipulation of Edge‐Site Fe–N 2 Moiety on Holey Fe, N Codoped Graphene to Promote the Cycle Stability and Rate Capacity of Li–S Batteries. Germany. https://doi.org/10.1002/adfm.201807485
Wang, Yazhou, Adekoya, David, Sun, Jiqing, Tang, Tianyu, Qiu, Hailong, Xu, Li, Zhang, Shanqing, and Hou, Yanglong. Sun . "Manipulation of Edge‐Site Fe–N 2 Moiety on Holey Fe, N Codoped Graphene to Promote the Cycle Stability and Rate Capacity of Li–S Batteries". Germany. https://doi.org/10.1002/adfm.201807485.
@article{osti_1485167,
title = {Manipulation of Edge‐Site Fe–N 2 Moiety on Holey Fe, N Codoped Graphene to Promote the Cycle Stability and Rate Capacity of Li–S Batteries},
author = {Wang, Yazhou and Adekoya, David and Sun, Jiqing and Tang, Tianyu and Qiu, Hailong and Xu, Li and Zhang, Shanqing and Hou, Yanglong},
abstractNote = {},
doi = {10.1002/adfm.201807485},
journal = {Advanced Functional Materials},
number = 5,
volume = 29,
place = {Germany},
year = {2018},
month = {12}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/adfm.201807485

Citation Metrics:
Cited by: 14 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Improved Synthesis of Graphene Oxide
journal, July 2010

  • Marcano, Daniela C.; Kosynkin, Dmitry V.; Berlin, Jacob M.
  • ACS Nano, Vol. 4, Issue 8, p. 4806-4814
  • DOI: 10.1021/nn1006368

Review on High-Loading and High-Energy Lithium-Sulfur Batteries
journal, May 2017

  • Peng, Hong-Jie; Huang, Jia-Qi; Cheng, Xin-Bing
  • Advanced Energy Materials, Vol. 7, Issue 24
  • DOI: 10.1002/aenm.201700260

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000

  • Poizot, P.; Laruelle, S.; Grugeon, S.
  • Nature, Vol. 407, Issue 6803, p. 496-499
  • DOI: 10.1038/35035045

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Fibrous Hybrid of Graphene and Sulfur Nanocrystals for High-Performance Lithium–Sulfur Batteries
journal, May 2013

  • Zhou, Guangmin; Yin, Li-Chang; Wang, Da-Wei
  • ACS Nano, Vol. 7, Issue 6
  • DOI: 10.1021/nn401228t

Lithium-Sulfur Batteries: Electrochemistry, Materials, and Prospects
journal, November 2013

  • Yin, Ya-Xia; Xin, Sen; Guo, Yu-Guo
  • Angewandte Chemie International Edition, Vol. 52, Issue 50
  • DOI: 10.1002/anie.201304762

Doping carbons beyond nitrogen: an overview of advanced heteroatom doped carbons with boron, sulphur and phosphorus for energy applications
journal, January 2013

  • Paraknowitsch, Jens Peter; Thomas, Arne
  • Energy & Environmental Science, Vol. 6, Issue 10
  • DOI: 10.1039/c3ee41444b

Theory, Synthesis, and Oxygen Reduction Catalysis of Fe-Porphyrin-Like Carbon Nanotube
journal, April 2011


A graphene-like metallic cathode host for long-life and high-loading lithium–sulfur batteries
journal, January 2016

  • Pang, Quan; Kundu, Dipan; Nazar, Linda F.
  • Materials Horizons, Vol. 3, Issue 2
  • DOI: 10.1039/C5MH00246J

Projector augmented-wave method
journal, December 1994


Propelling polysulfides transformation for high-rate and long-life lithium–sulfur batteries
journal, March 2017


Phase Inversion: A Universal Method to Create High-Performance Porous Electrodes for Nanoparticle-Based Energy Storage Devices
journal, October 2016

  • Yang, Xiaofei; Chen, Yuqing; Wang, Meiri
  • Advanced Functional Materials, Vol. 26, Issue 46
  • DOI: 10.1002/adfm.201604229

Electrochemical Impedance Spectroscopy Study of a Lithium/Sulfur Battery: Modeling and Analysis of Capacity Fading
journal, January 2013

  • Deng, Zhaofeng; Zhang, Zhian; Lai, Yanqing
  • Journal of The Electrochemical Society, Vol. 160, Issue 4
  • DOI: 10.1149/2.026304jes

Facile synthesis of porous LiMn2O4 spheres as cathode materials for high-power lithium ion batteries
journal, March 2013


Nanostructured cathode materials for lithium–sulfur batteries: progress, challenges and perspectives
journal, January 2017

  • Rehman, Sarish; Khan, Kishwar; Zhao, Yufeng
  • Journal of Materials Chemistry A, Vol. 5, Issue 7
  • DOI: 10.1039/C6TA10111A

3D Graphene-Foam-Reduced-Graphene-Oxide Hybrid Nested Hierarchical Networks for High-Performance Li-S Batteries
journal, December 2015


Solution Processable Holey Graphene Oxide and Its Derived Macrostructures for High-Performance Supercapacitors
journal, June 2015


High “C” rate Li-S cathodes: sulfur imbibed bimodal porous carbons
journal, January 2011

  • He, Guang; Ji, Xiulei; Nazar, Linda
  • Energy & Environmental Science, Vol. 4, Issue 8
  • DOI: 10.1039/c1ee01219c

The Effect of Crystal Face of Fe2O3 on the Electrochemical Performance for Lithium-ion Batteries
journal, July 2016

  • Chen, Minmin; Zhao, Enyue; Yan, Qingbo
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep29381

Optimization of mesoporous carbon structures for lithium–sulfur battery applications
journal, January 2011

  • Li, Xiaolin; Cao, Yuliang; Qi, Wen
  • Journal of Materials Chemistry, Vol. 21, Issue 41
  • DOI: 10.1039/c1jm12979a

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996


Three-dimensional holey-graphene/niobia composite architectures for ultrahigh-rate energy storage
journal, May 2017


Li-S Battery Analyzed by UV/Vis in Operando Mode
journal, June 2013

  • Patel, Manu U. M.; Demir-Cakan, Rezan; Morcrette, Mathieu
  • ChemSusChem, Vol. 6, Issue 7
  • DOI: 10.1002/cssc.201300142

Density functional theory calculations of XPS binding energy shift for nitrogen-containing graphene-like structures
journal, January 2013

  • Artyushkova, K.; Kiefer, B.; Halevi, B.
  • Chemical Communications, Vol. 49, Issue 25
  • DOI: 10.1039/c3cc40324f

Lithium–sulphur batteries with a microporous carbon paper as a bifunctional interlayer
journal, January 2012

  • Su, Yu-Sheng; Manthiram, Arumugam
  • Nature Communications, Vol. 3, Article No. 1166
  • DOI: 10.1038/ncomms2163

Sulfur and Nitrogen Dual-Doped Mesoporous Graphene Electrocatalyst for Oxygen Reduction with Synergistically Enhanced Performance
journal, October 2012

  • Liang, Ji; Jiao, Yan; Jaroniec, Mietek
  • Angewandte Chemie International Edition, Vol. 51, Issue 46
  • DOI: 10.1002/anie.201206720

Sulfur Hosts against the Shuttle Effect
journal, April 2018


Long-life Li/polysulphide batteries with high sulphur loading enabled by lightweight three-dimensional nitrogen/sulphur-codoped graphene sponge
journal, July 2015

  • Zhou, Guangmin; Paek, Eunsu; Hwang, Gyeong S.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8760

Porous carbon spheres and monoliths: morphology control, pore size tuning and their applications as Li-ion battery anode materials
journal, January 2014

  • Roberts, Aled D.; Li, Xu; Zhang, Haifei
  • Chem. Soc. Rev., Vol. 43, Issue 13
  • DOI: 10.1039/C4CS00071D

More Reliable Lithium-Sulfur Batteries: Status, Solutions and Prospects
journal, April 2017

  • Fang, Ruopian; Zhao, Shiyong; Sun, Zhenhua
  • Advanced Materials, Vol. 29, Issue 48
  • DOI: 10.1002/adma.201606823

Microporous bamboo biochar for lithium-sulfur batteries
journal, November 2014


Flexible Holey Graphene Paper Electrodes with Enhanced Rate Capability for Energy Storage Applications
journal, October 2011

  • Zhao, Xin; Hayner, Cary M.; Kung, Mayfair C.
  • ACS Nano, Vol. 5, Issue 11
  • DOI: 10.1021/nn202710s

Spherical Ordered Mesoporous Carbon Nanoparticles with High Porosity for Lithium-Sulfur Batteries
journal, March 2012

  • Schuster, Jörg; He, Guang; Mandlmeier, Benjamin
  • Angewandte Chemie, Vol. 124, Issue 15
  • DOI: 10.1002/ange.201107817

3D Hierarchical Porous α-Fe 2 O 3 Nanosheets for High-Performance Lithium-Ion Batteries
journal, November 2014

  • Cao, Kangzhe; Jiao, Lifang; Liu, Huiqiao
  • Advanced Energy Materials, Vol. 5, Issue 4
  • DOI: 10.1002/aenm.201401421

Liquid electrolyte lithium/sulfur battery: Fundamental chemistry, problems, and solutions
journal, June 2013


Semiempirical GGA-type density functional constructed with a long-range dispersion correction
journal, January 2006

  • Grimme, Stefan
  • Journal of Computational Chemistry, Vol. 27, Issue 15, p. 1787-1799
  • DOI: 10.1002/jcc.20495

A Comprehensive Approach toward Stable Lithium–Sulfur Batteries with High Volumetric Energy Density
journal, November 2016

  • Pang, Quan; Liang, Xiao; Kwok, Chun Yuen
  • Advanced Energy Materials, Vol. 7, Issue 6
  • DOI: 10.1002/aenm.201601630

Does the sulfur cathode require good mixing for a liquid electrolyte lithium/sulfur cell?
journal, June 2013


High Efficiency Immobilization of Sulfur on Nitrogen-Enriched Mesoporous Carbons for Li–S Batteries
journal, June 2013

  • Sun, Fugen; Wang, Jitong; Chen, Huichao
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 12
  • DOI: 10.1021/am400958x

Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction
journal, April 2017

  • Chen, Yuanjun; Ji, Shufang; Wang, Yanggang
  • Angewandte Chemie, Vol. 129, Issue 24
  • DOI: 10.1002/ange.201702473

High Reversible Lithium Storage Capacity and Structural Changes of Fe 2 O 3 Nanoparticles Confined inside Carbon Nanotubes
journal, December 2015

  • Yu, Wan-Jing; Zhang, Lili; Hou, Peng-Xiang
  • Advanced Energy Materials, Vol. 6, Issue 3
  • DOI: 10.1002/aenm.201501755

Nanostructured Metal Oxides and Sulfides for Lithium-Sulfur Batteries
journal, February 2017