Spectroscopic Studies on the Metal-Insulator Transition Mechanism in Correlated Materials

Kim, So Yeun; Lee, Min -Cheol; Han, Garam; Kratochvilova, Marie; Yun, Seokhwan; Moon, Soon Jae; Sohn, Changhee; Park, Je -Geun; Kim, Changyoung; Noh, Tae Won

doi:10.1002/adma.201704777

Title: Spectroscopic Studies on the Metal-Insulator Transition Mechanism in Correlated Materials

Abstract

Here, the metal–insulator transition (MIT) in correlated materials is a novel phenomenon that accompanies a large change in resistivity, often many orders of magnitude. It is important in its own right but its switching behavior in resistivity can be useful for device applications. From the material physics point of view, the starting point of the research on the MIT should be to understand the microscopic mechanism. Here, an overview of recent efforts to unravel the microscopic mechanisms for various types of MITs in correlated materials is provided. Research has focused on transition metal oxides (TMOs), but transition metal chalcogenides have also been studied. Along the way, a new class of MIT materials is discovered, the so–called relativistic Mott insulators in 5d TMOs. Distortions in the MO₆ (M = transition metal) octahedron are found to have a large and peculiar effect on the band structure in an orbital dependent way, possibly paving a way to the orbital selective Mott transition. In the final section, the character of the materials suitable for applications is summarized, followed by a brief discussion of some of the efforts to control MITs in correlated materials, including a dynamical approach using light.

Authors:

Kim, So Yeun ^[1]; Lee, Min -Cheol ^[1];

^[1]; Kratochvilova, Marie ^[1]; Yun, Seokhwan ^[1]; Moon, Soon Jae ^[2];

^[3]; Park, Je -Geun ^[1]; Kim, Changyoung ^[1]; Noh, Tae Won ^[1]

Institute for Basic Science, Seoul (Republic of Korea); Seoul National Univ., Seoul (Republic of Korea)
Hanyang Univ., Seoul (Republic of Korea)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: Tue May 15 00:00:00 EDT 2018

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1484985

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Advanced Materials

Additional Journal Information:: Journal Volume: 30; Journal Issue: 42; Journal ID: ISSN 0935-9648

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; electron–electron correlation; metal–insulator transition; spectroscopy; transition-metal oxides

Citation Formats


                    Kim, So Yeun, Lee, Min -Cheol, Han, Garam, Kratochvilova, Marie, Yun, Seokhwan, Moon, Soon Jae, Sohn, Changhee, Park, Je -Geun, Kim, Changyoung, and Noh, Tae Won. Spectroscopic Studies on the Metal-Insulator Transition Mechanism in Correlated Materials.  United States: N. p., 2018. 
Web.  doi:10.1002/adma.201704777.

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                    Kim, So Yeun, Lee, Min -Cheol, Han, Garam, Kratochvilova, Marie, Yun, Seokhwan, Moon, Soon Jae, Sohn, Changhee, Park, Je -Geun, Kim, Changyoung, & Noh, Tae Won. Spectroscopic Studies on the Metal-Insulator Transition Mechanism in Correlated Materials.  United States.  https://doi.org/10.1002/adma.201704777

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                    Kim, So Yeun, Lee, Min -Cheol, Han, Garam, Kratochvilova, Marie, Yun, Seokhwan, Moon, Soon Jae, Sohn, Changhee, Park, Je -Geun, Kim, Changyoung, and Noh, Tae Won. Tue .  
"Spectroscopic Studies on the Metal-Insulator Transition Mechanism in Correlated Materials".  United States.  https://doi.org/10.1002/adma.201704777.  https://www.osti.gov/servlets/purl/1484985.

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@article{osti_1484985,

  title        = {Spectroscopic Studies on the Metal-Insulator Transition Mechanism in Correlated Materials},

  author       = {Kim, So Yeun and Lee, Min -Cheol and Han, Garam and Kratochvilova, Marie and Yun, Seokhwan and Moon, Soon Jae and Sohn, Changhee and Park, Je -Geun and Kim, Changyoung and Noh, Tae Won},

  abstractNote = {Here, the metal–insulator transition (MIT) in correlated materials is a novel phenomenon that accompanies a large change in resistivity, often many orders of magnitude. It is important in its own right but its switching behavior in resistivity can be useful for device applications. From the material physics point of view, the starting point of the research on the MIT should be to understand the microscopic mechanism. Here, an overview of recent efforts to unravel the microscopic mechanisms for various types of MITs in correlated materials is provided. Research has focused on transition metal oxides (TMOs), but transition metal chalcogenides have also been studied. Along the way, a new class of MIT materials is discovered, the so–called relativistic Mott insulators in 5d TMOs. Distortions in the MO6 (M = transition metal) octahedron are found to have a large and peculiar effect on the band structure in an orbital dependent way, possibly paving a way to the orbital selective Mott transition. In the final section, the character of the materials suitable for applications is summarized, followed by a brief discussion of some of the efforts to control MITs in correlated materials, including a dynamical approach using light.},

  doi          = {10.1002/adma.201704777},

  journal      = {Advanced Materials},

  number       = 42,

  volume       = 30,

  place        = {United States},

  year         = {Tue May 15 00:00:00 EDT 2018},

  month        = {Tue May 15 00:00:00 EDT 2018}

}

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Figures / Tables:

Table 1: Various types of MIT with the origin of the transition as well as resulting emergent phenomena.

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DOI: 10.1147/rd.143.0251

Classical dimers and dimerized superstructure in orbitally degenerate honeycomb antiferromagnet
text, January 2008

Jackeli, G.; Khomskii, D. I.
arXiv
DOI: 10.48550/arxiv.0802.2692

Monte Carlo study of an unconventional superconducting phase in Ir-oxide J_{eff}=1/2 Mott insulators induced by carrier doping
text, January 2012

Watanabe, Hiroshi; Shirakawa, Tomonori; Yunoki, Seiji
arXiv
DOI: 10.48550/arxiv.1212.1546

Tuning electronic structures via epitaxial strain in Sr2IrO4 thin films
text, January 2013

Nichols, J.; Terzic, J.; Bittle, E. G.
arXiv
DOI: 10.48550/arxiv.1302.0918

Correlated quantum phenomena in the strong spin-orbit regime
text, January 2013

Witczak-Krempa, William; Chen, Gang; Kim, Yong Baek
arXiv
DOI: 10.48550/arxiv.1305.2193

Tuning Magnetic Coupling in Sr$_2$IrO$_4$ Thin Films with Epitaxial Strain
text, January 2013

Lupascu, A.; Clancy, J. P.; Gretarsson, H.
arXiv
DOI: 10.48550/arxiv.1312.4005

Odd-parity triplet superconductivity in multi-orbital materials with strong spin-orbit coupling: applications to doped Sr2IrO4
text, January 2014

Meng, Zi Yang; Kim, Yong Baek; Kee, Hae-Young
arXiv
DOI: 10.48550/arxiv.1404.2290

All-in/all-out magnetic domains: X-ray diffraction imaging and magnetic field control
text, January 2014

Tardif, Samuel; Takeshita, Soshi; Ohsumi, Hiroyuki
arXiv
DOI: 10.48550/arxiv.1407.5401

Robust singlet dimers with fragile ordering in two-dimensional honeycomb lattice of Li$_2$RuO$_3$
text, January 2016

Park, Junghwan; Tan, Teck-Yee; Adroja, D. T.
arXiv
DOI: 10.48550/arxiv.1604.04019

Electron interactions, spin-orbit coupling, intersite correlations in pyrochlore iridates
text, January 2016

Wang, Runzhi; Go, Ara; Millis, Andrew J.
arXiv
DOI: 10.48550/arxiv.1611.07997

The low-temperature highly correlated quantum phase in the charge-density-wave 1T-TaS_2 compound
text, January 2017

Kratochvilova, Marie; Hillier, Adrian D.; Wildes, Andrew R.
arXiv
DOI: 10.48550/arxiv.1706.04735

Electronic structure of the pyrochlore metals Cd2Os2O7 and Cd2Re2O7
text, January 2001

Singh, D. J.; Blaha, P.; Schwarz, K.
arXiv
DOI: 10.48550/arxiv.cond-mat/0108226

Prominent quasi-particle peak in the photoemission spectrum of the metallic phase of V_2O_3
text, January 2002

Mo, S. -K.; Denlinger, J. D.; Kim, H. -D.
arXiv
DOI: 10.48550/arxiv.cond-mat/0212110

Complexity in Strongly Correlated Electronic Systems
text, January 2005

Dagotto, Elbio
arXiv
DOI: 10.48550/arxiv.cond-mat/0509041

New Type Phase Transition of Li2RuO3 with Honeycomb Structure
text, January 2006

Miura, Yoko; Yasui, Yukio; Sato, Masatoshi
arXiv
DOI: 10.48550/arxiv.cond-mat/0612026

Works referencing / citing this record:

Atomic‐Scale Metal–Insulator Transition in SrRuO ₃ Ultrathin Films Triggered by Surface Termination Conversion
journal, December 2019

Lee, Han Gyeol; Wang, Lingfei; Si, Liang
Advanced Materials, Vol. 32, Issue 8
DOI: 10.1002/adma.201905815

Strong and Tunable Electrical Anisotropy in Type‐II Weyl Semimetal Candidate WP ₂ with Broken Inversion Symmetry
journal, September 2019

Su, Bo; Song, Yanpeng; Hou, Yanhui
Advanced Materials, Vol. 31, Issue 44
DOI: 10.1002/adma.201903498

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Multiple nearly degenerate states in transition-metal oxides (TMOs) produce very complicated phase diagrams1. Small perturbations can often lead to dramatic property change and even exotic functionalities such as superconductivity and colossal magnetoresistance (CMR)2,3,4. Many of these emergent properties displayed by these correlated materials are believed to be intimately associated with the electronic inhomogeneities that can self-organize into spatially separated electronic phases. Direct imaging of the phase separations (PS) has thus become vital to elucidating the underlying mechanisms, and the successful observation of the PS in manganites has led to a breakthrough understanding of CMR5,6. Here, we present real-space visualizations ofmore »« less
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Title: Spectroscopic Studies on the Metal-Insulator Transition Mechanism in Correlated Materials

Abstract

Citation Formats

Figures / Tables:

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Strongly correlated perovskite fuel cells journal, May 2016

Na 2 IrO 3 as a Novel Relativistic Mott Insulator with a 340-meV Gap journal, December 2012

Electron microscopy of phase transformations in 1 T - TaS 2 journal, August 1991

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Quantum critical behaviour in a high-Tc superconductor journal, September 2003

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Valence bond liquid phase in the honeycomb lattice material Li 2 Ru O 3 journal, February 2014

Prominent Quasiparticle Peak in the Photoemission Spectrum of the Metallic Phase of V 2 O 3 journal, May 2003

Temperature dependence of the first-order metal-insulator transition in VO2 and programmable critical temperature sensor journal, January 2007

Robust ferromagnetism carried by antiferromagnetic domain walls journal, February 2017

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Universal Electric-Field-Driven Resistive Transition in Narrow-Gap Mott Insulators journal, May 2013

Tuning Magnetic Coupling in Sr 2 IrO 4 Thin Films with Epitaxial Strain journal, April 2014

Systematic study of insulator-metal transitions in perovskites RNiO3 (R=Pr,Nd,Sm,Eu) due to closing of charge-transfer gap journal, April 1992

Role of Orbitals in the Physics of Correlated Electron Systems journal, January 2005

Superconducting phase of La 2 Cu O 4 + δ : A superconducting composition resulting from phase separation journal, December 1988

Electronic structures of hexagonal R Mn O 3 ( R = Gd , Tb, Dy, and Ho) thin films: Optical spectroscopy and first-principles calculations journal, January 2008

Fermi arcs in a doped pseudospin-1/2 Heisenberg antiferromagnet journal, June 2014

Control of the metal–insulator transition in vanadium dioxide by modifying orbital occupancy journal, September 2013

Critical features of colossal magnetoresistive manganites journal, February 2006

Phase diagram of the ultrafast photoinduced insulator-metal transition in vanadium dioxide journal, April 2012

Orbital-Selective Mass Enhancements in Multiband Ca 2 − x Sr x RuO 4 Systems Analyzed by the Extended Drude Model journal, February 2006

Voltage-Triggered Ultrafast Phase Transition in Vanadium Dioxide Switches journal, February 2013

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The Resonating Valence Bond State in La2CuO4 and Superconductivity journal, March 1987

Discussion of the paper by de Boer and Verwey journal, August 1937

Semi-conductors with partially and with completely filled 3 d -lattice bands journal, August 1937

Critical phenomena and femtosecond ordering dynamics associated with electronic and spin-ordered phases in YVO 3 and GdVO 3 journal, February 2010

Weak Ferromagnetism and Antiferromagnetism in the Insulator Phase of NiS 2- x Se x with pyrite Structure journal, October 1985

Interplane coupling in the quasi-two-dimensional 1 T − TaS 2 journal, March 2003

Angle-resolved photoemission studies of the cuprate superconductors journal, April 2003

All-In–All-Out Magnetic Domains: X-Ray Diffraction Imaging and Magnetic Field Control journal, April 2015

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Interplay of Spin-Orbit Interactions, Dimensionality, and Octahedral Rotations in Semimetallic SrIrO 3 journal, January 2015

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Magnetic Phase Diagram and Metal-Insulator Transition of NiS 2 - x Se x journal, May 2000

Strain controlled metal-insulator transition in epitaxial NdNiO 3 thin films journal, December 2013

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First-Order Isostructural Mott Transition in Highly Compressed MnO journal, March 2005

Searching for the Slater transition in the pyrochlore Cd 2 Os 2 O 7 with infrared spectroscopy journal, July 2002

Systematic Development of the Spectral Function in the 3 d 1 Mott-Hubbard System Ca 1 − x Sr x VO 3 journal, March 1995

Tuning electronic structure via epitaxial strain in Sr 2 IrO 4 thin films journal, April 2013

Complexity in Strongly Correlated Electronic Systems journal, July 2005

Variation of Charge Dynamics in the Course of Metal-Insulator Transition for Pyrochlore-Type Nd 2 Ir 2 O 7 journal, September 2012

Strain-induced tuning of metal–insulator transition in NdNiO3 journal, May 2002

Continuous metal-insulator transition in the pyrochlore Cd 2 Os 2 O 7 journal, April 2001

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Bandwidth control in a perovskite-type 3 d 1 -correlated metal Ca 1 − x Sr x VO 3 . I. Evolution of the electronic properties and effective mass journal, August 1998

Direct Observation of the Bandwidth Control Mott Transition in the NiS 2 − x Se x Multiband System journal, February 2014

Engineering a Spin-Orbital Magnetic Insulator by Tailoring Superlattices journal, June 2015

Hallmarks of the Mott-metal crossover in the hole-doped pseudospin-1/2 Mott insulator Sr2IrO4 journal, April 2016

Reversible phase modulation and hydrogen storage in multivalent VO2 epitaxial thin films journal, July 2016

Orbital-dependent polaron formation in the relativistic Mott insulator Sr 2 IrO 4 journal, July 2014

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A metallic mosaic phase and the origin of Mott-insulating state in 1T-TaS2 journal, March 2016

Three-dimensional metallic and two-dimensional insulating behavior in octahedral tantalum dichalcogenides journal, July 2014

Photoemission study of composition- and temperature-induced metal-insulator transitions in Cr-doped $V_{2}$ $O_{3}$
journal, July 1994

Perspective: Materials informatics and big data: Realization of the “fourth paradigm” of science in materials science
journal, April 2016

Oxygen vacancy induced re-entrant spin glass behavior in multiferroic ErMnO3 thin films
journal, October 2008

Control of the electronic phase of a manganite by mode-selective vibrational excitation
journal, September 2007

Destruction of the Mott insulating ground state of ${Ca}_{2} {RuO}_{4}$ by a structural transition
journal, September 1999

Temperature-Dependent Fermi Surface Evolution in Heavy Fermion ${CeIrIn}_{5}$
journal, January 2012

Suppression of metal-insulator transition at high pressure and pressure-induced magnetic ordering in pyrochlore oxide Nd $_{2}$ Ir $_{2}$ O $_{7}$
journal, January 2011

Magnetically induced
journal, October 2016

X-ray photoelectron and Auger spectroscopy study of some vanadium oxides
journal, August 1979

Observation of universal strong orbital-dependent correlation effects in iron chalcogenides
journal, July 2015

Tetrahedral Magnetic Order and the Metal-Insulator Transition in the Pyrochlore Lattice of ${Cd}_{2} {Os}_{2} O_{7}$
journal, June 2012

Features of the operation of a bolometer based on a vanadium dioxide film in a temperature interval that includes a phase transition
journal, January 1999

Noncollinear Magnetism and Spin-Orbit Coupling in $5 d$ Pyrochlore Oxide ${Cd}_{2} {Os}_{2} O_{7}$
journal, June 2012

Ca ₂ RuO ₄ : New Mott Insulators of Layered Ruthenate
journal, July 1997

Observation of a Novel Orbital Selective Mott Transition in ${Ca}_{1.8} {Sr}_{0.2} {RuO}_{4}$
journal, August 2009

Comparison of x-ray absorption with x-ray photoemission of nickel dihalides and NiO
journal, March 1986

Anderson transitions
journal, October 2008

Strongly correlated perovskite fuel cells
journal, May 2016

${Na}_{2} {IrO}_{3}$ as a Novel Relativistic Mott Insulator with a 340-meV Gap
journal, December 2012

Electron microscopy of phase transformations in 1 T - ${TaS}_{2}$
journal, August 1991

Magnetic Effects and the Hartree-Fock Equation
journal, May 1951

Application of Gutzwiller's Variational Method to the Metal-Insulator Transition
journal, November 1970

Quantum critical behaviour in a high-Tc superconductor
journal, September 2003

Spin Superstructure and Noncoplanar Ordering in Metallic Pyrochlore Magnets with Degenerate Orbitals
journal, October 2011

Valence bond liquid phase in the honeycomb lattice material ${Li}_{2} Ru O_{3}$
journal, February 2014

Prominent Quasiparticle Peak in the Photoemission Spectrum of the Metallic Phase of $V_{2} O_{3}$
journal, May 2003

Temperature dependence of the first-order metal-insulator transition in VO2 and programmable critical temperature sensor
journal, January 2007

Robust ferromagnetism carried by antiferromagnetic domain walls
journal, February 2017

Vanadium oxides thin films and fixed-temperature heat sensor with memory
journal, June 1998

Universal Electric-Field-Driven Resistive Transition in Narrow-Gap Mott Insulators
journal, May 2013

Tuning Magnetic Coupling in ${Sr}_{2} {IrO}_{4}$ Thin Films with Epitaxial Strain
journal, April 2014

Systematic study of insulator-metal transitions in perovskites RNiO3 (R=Pr,Nd,Sm,Eu) due to closing of charge-transfer gap
journal, April 1992

Role of Orbitals in the Physics of Correlated Electron Systems
journal, January 2005

Superconducting phase of ${La}_{2} Cu O_{4 + δ}$ : A superconducting composition resulting from phase separation
journal, December 1988

Electronic structures of hexagonal $R Mn O_{3}$ ( $R = Gd$ , Tb, Dy, and Ho) thin films: Optical spectroscopy and first-principles calculations
journal, January 2008

Fermi arcs in a doped pseudospin-1/2 Heisenberg antiferromagnet
journal, June 2014

Control of the metal–insulator transition in vanadium dioxide by modifying orbital occupancy
journal, September 2013

Critical features of colossal magnetoresistive manganites
journal, February 2006

Phase diagram of the ultrafast photoinduced insulator-metal transition in vanadium dioxide
journal, April 2012

Orbital-Selective Mass Enhancements in Multiband ${Ca}_{2 - x} {Sr}_{x} {RuO}_{4}$ Systems Analyzed by the Extended Drude Model
journal, February 2006

Voltage-Triggered Ultrafast Phase Transition in Vanadium Dioxide Switches
journal, February 2013

Oxide Electronics Utilizing Ultrafast Metal-Insulator Transitions
journal, August 2011

The Resonating Valence Bond State in La2CuO4 and Superconductivity
journal, March 1987

Discussion of the paper by de Boer and Verwey
journal, August 1937

Semi-conductors with partially and with completely filled ₃ d -lattice bands
journal, August 1937

Critical phenomena and femtosecond ordering dynamics associated with electronic and spin-ordered phases in ${YVO}_{3}$ and ${GdVO}_{3}$
journal, February 2010

Weak Ferromagnetism and Antiferromagnetism in the Insulator Phase of NiS _{2- x} Se _x with pyrite Structure
journal, October 1985

Interplane coupling in the quasi-two-dimensional $1 T - {TaS}_{2}$
journal, March 2003

Angle-resolved photoemission studies of the cuprate superconductors
journal, April 2003

All-In–All-Out Magnetic Domains: X-Ray Diffraction Imaging and Magnetic Field Control
journal, April 2015

Epitaxial thin films of pyrochlore iridate Bi2+xIr2-yO7-δ: structure, defects and transport properties
journal, August 2017

Interplay of Spin-Orbit Interactions, Dimensionality, and Octahedral Rotations in Semimetallic ${SrIrO}_{3}$
journal, January 2015

Odd-Parity Triplet Superconducting Phase in Multiorbital Materials with a Strong Spin-Orbit Coupling: Application to Doped ${Sr}_{2} {IrO}_{4}$
journal, October 2014

Metal-insulator transition in doped Ca ₂ RuO ₄ : Potential application in bolometric detection
journal, April 2012

Magnetic Phase Diagram and Metal-Insulator Transition of NiS _{2 - x} Se _x
journal, May 2000

Strain controlled metal-insulator transition in epitaxial NdNiO ₃ thin films
journal, December 2013

Anderson Localization in Two Dimensions
journal, September 1981

First-Order Isostructural Mott Transition in Highly Compressed MnO
journal, March 2005

Searching for the Slater transition in the pyrochlore ${Cd}_{2} {Os}_{2} O_{7}$ with infrared spectroscopy
journal, July 2002

Systematic Development of the Spectral Function in the $3 d^{1}$ Mott-Hubbard System ${Ca}_{1 - x} {Sr}_{x} {VO}_{3}$
journal, March 1995

Tuning electronic structure via epitaxial strain in Sr ₂ IrO ₄ thin films
journal, April 2013

Complexity in Strongly Correlated Electronic Systems
journal, July 2005

Variation of Charge Dynamics in the Course of Metal-Insulator Transition for Pyrochlore-Type ${Nd}_{2} {Ir}_{2} O_{7}$
journal, September 2012

Strain-induced tuning of metal–insulator transition in NdNiO3
journal, May 2002

Continuous metal-insulator transition in the pyrochlore ${Cd}_{2} {Os}_{2} O_{7}$
journal, April 2001

Correlated Electron Materials and Field Effect Transistors for Logic: A Review
journal, January 2013

Bandwidth control in a perovskite-type ${3 d}^{1}$ -correlated metal ${Ca}_{1 - x} {Sr}_{x} {VO}_{3} .$ I. Evolution of the electronic properties and effective mass
journal, August 1998

Direct Observation of the Bandwidth Control Mott Transition in the ${NiS}_{2 - x} {Se}_{x}$ Multiband System
journal, February 2014

Engineering a Spin-Orbital Magnetic Insulator by Tailoring Superlattices
journal, June 2015

Hallmarks of the Mott-metal crossover in the hole-doped pseudospin-1/2 Mott insulator Sr2IrO4
journal, April 2016

Reversible phase modulation and hydrogen storage in multivalent VO2 epitaxial thin films
journal, July 2016

Orbital-dependent polaron formation in the relativistic Mott insulator ${Sr}_{2} {IrO}_{4}$
journal, July 2014

Analyse en coordonnées normales des composés A2IIIB2IVO7 (A = La, Nd; B = Zr, Hf) de structure pyrochlore
journal, January 1981

Electron and Orbital Correlations in ${C a}_{2 - x} {S r}_{x} {R u O}_{4}$ Probed by Optical Spectroscopy
journal, December 2002

A metallic mosaic phase and the origin of Mott-insulating state in 1T-TaS2
journal, March 2016

Three-dimensional metallic and two-dimensional insulating behavior in octahedral tantalum dichalcogenides
journal, July 2014

Electrodynamics of the nodal metal state in weakly doped high- $T_{c}$ cuprates
journal, August 2005

Magnetic order in the pyrochlore iridate Nd $_{2}$ Ir $_{2}$ O $_{7}$ probed by muon spin relaxation
journal, August 2013

Observation of Temperature-Induced Crossover to an Orbital-Selective Mott Phase in $A_{x} {Fe}_{2 − y} {Se}_{2}$ ( $A = K$ , Rb) Superconductors
journal, February 2013

Photoinduced Insulator-to-Metal Transition in a Perovskite Manganite
journal, June 1997