Block co-polyMOFs: morphology control of polymer–MOF hybrid materials

Ayala, Sergio; Bentz, Kyle C.; Cohen, Seth M.

doi:10.1039/C8SC04250K

Title: Block co-polyMOFs: morphology control of polymer–MOF hybrid materials

Abstract

Block copolymers were used to generate metal–organic frameworks (MOFs) as novel materials (block co-polyMOFs, BCPMOFs) with controlled morphologies.

Authors:

Ayala, Sergio ^[1];

^[1];

^[1]

Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, USA

Publication Date:: 2018-11-30

Research Org.:: Univ. of California, San Diego, La Jolla, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; Inamori Foundation; USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1484919

Alternate Identifier(s):: OSTI ID: 1610002; OSTI ID: 1779878

Grant/Contract Number:: FG02-08ER46519; ECCS-1542148

Resource Type:: Published Article

Journal Name:: Chemical Science

Additional Journal Information:: Journal Name: Chemical Science Journal Volume: 10 Journal Issue: 6; Journal ID: ISSN 2041-6520

Publisher:: Royal Society of Chemistry

Country of Publication:: United Kingdom

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Chemistry

Citation Formats


                    Ayala, Sergio, Bentz, Kyle C., and Cohen, Seth M. Block co-polyMOFs: morphology control of polymer–MOF hybrid materials.  United Kingdom: N. p., 2018. 
Web.  doi:10.1039/C8SC04250K.

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                    Ayala, Sergio, Bentz, Kyle C., & Cohen, Seth M. Block co-polyMOFs: morphology control of polymer–MOF hybrid materials.  United Kingdom.  https://doi.org/10.1039/C8SC04250K

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                    Ayala, Sergio, Bentz, Kyle C., and Cohen, Seth M. Fri .  
"Block co-polyMOFs: morphology control of polymer–MOF hybrid materials".  United Kingdom.  https://doi.org/10.1039/C8SC04250K.

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@article{osti_1484919,

  title        = {Block co-polyMOFs: morphology control of polymer–MOF hybrid materials},

  author       = {Ayala, Sergio and Bentz, Kyle C. and Cohen, Seth M.},

  abstractNote = {Block copolymers were used to generate metal–organic frameworks (MOFs) as novel materials (block co-polyMOFs, BCPMOFs) with controlled morphologies.},

  doi          = {10.1039/C8SC04250K},

  journal      = {Chemical Science},

  number       = 6,

  volume       = 10,

  place        = {United Kingdom},

  year         = {2018},

  month        = {11}

}

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Title: Block co-polyMOFs: morphology control of polymer–MOF hybrid materials

Abstract

Citation Formats

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polyMOFs: A Class of Interconvertible Polymer-Metal-Organic-Framework Hybrid Materials journal, April 2015

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Synthesis of Coordination Polymer Nanoparticles using Self-Assembled Block Copolymers as Template journal, November 2017

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50th Anniversary Perspective : Block Polymers—Pure Potential journal, December 2016

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On the Origins of Morphological Complexity in Block Copolymer Surfactants
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Hierarchical structure and porosity in UiO-66 polyMOFs
journal, January 2017

Self-assembly of block copolymers
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journal, June 2014

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journal, January 2013

Solvent determines the formation and properties of metal–organic frameworks
journal, January 2015

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journal, August 2015

Hypercrosslinked porous polymer materials: design, synthesis, and applications
journal, January 2017

Acyclic diene metathesis polymerization: History, methods and applications
journal, June 2017

Metal–organic frameworks for membrane-based separations
journal, November 2016

Double-Hydrophilic Block Copolymers: Synthesis and Application as Novel Surfactants and Crystal Growth Modifiers
journal, February 2001

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journal, November 2007

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journal, June 2018

Supramolecular Metallopolymers: From Linear Materials to Infinite Networks
journal, October 2018

High-throughput screening of solid-state catalysts for nerve agent degradation
journal, January 2018

Morphogenesis of Metal–Organic Mesocrystals Mediated by Double Hydrophilic Block Copolymers
journal, February 2018

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journal, January 2017

Mixing of immiscible polymers using nanoporous coordination templates
journal, July 2015

Conductive Block Copolymers Integrated into Polynorbornene-Derived Scaffolds
journal, August 2008

Synthesis of Coordination Polymer Nanoparticles using Self-Assembled Block Copolymers as Template
journal, November 2017

Modulated synthesis of monodisperse MOF-5 crystals with tunable sizes and shapes
journal, July 2018

50th Anniversary Perspective : Block Polymers—Pure Potential
journal, December 2016

Block co-polyMOFs: assembly of polymer–polyMOF hybrids via iterative exponential growth and “click” chemistry
journal, January 2017

Secondary building units, nets and bonding in the chemistry of metal–organic frameworks
journal, January 2009

A Method for the Preparation of Highly Porous, Nanosized Crystals of Isoreticular Metal−Organic Frameworks
journal, January 2011

Tuning Dynamic Mechanical Response in Metallopolymer Networks through Simultaneous Control of Structural and Temporal Properties of the Networks
journal, August 2016

Transformation of Metal–Organic Framework to Polymer Gel by Cross-Linking the Organic Ligands Preorganized in Metal–Organic Framework
journal, March 2013

Practical water production from desert air
journal, June 2018

A new method to position and functionalize metal-organic framework crystals
journal, March 2011

Isoreticular expansion of polyMOFs achieves high surface area materials
journal, January 2017

Precisely Defined Amphiphilic Graft Copolymers
journal, November 2007

Growth-Controlled Formation of Porous Coordination Polymer Particles
journal, December 2008

Controlled Synthesis of Porous Coordination-Polymer Microcrystals with Definite Morphologies and Sizes under Mild Conditions
journal, September 2014

A dynamic and multi-responsive porous flexible metal–organic material
journal, August 2018

Block Co-PolyMOCs by Stepwise Self-Assembly
journal, August 2016

Poly(isophthalic acid)(ethylene oxide) as a Macromolecular Modulator for Metal–Organic Polyhedra
journal, July 2016

Polymer-assisted synthesis of nanocrystalline copper-based metal–organic framework for amine oxidation
journal, March 2011

Discovery, development, and functionalization of Zr( iv )-based metal–organic frameworks
journal, January 2012

Structuring of metal–organic frameworks at the mesoscopic/macroscopic scale
journal, January 2014

Polymer–Metal–Organic Frameworks (polyMOFs) as Water Tolerant Materials for Selective Carbon Dioxide Separations
journal, January 2016

A general and efficient approach for tuning the crystal morphology of classical MOFs
journal, January 2018

Effect of Organic Polymer Additive on Crystallization of Porous Coordination Polymer
journal, February 2006

Metal–organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents
journal, January 2017

Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites
journal, September 2011

Synthesis and characterization of metallo-supramolecular polymers
journal, January 2016

Colloidal inverse bicontinuous cubic membranes of block copolymers with tunable surface functional groups
journal, May 2014

Controlling Mineral Morphologies and Structures in Biological and Synthetic Systems
journal, November 2008