Mechanistic Insights into Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride Nanoparticles
Abstract
Renewable production of ammonia, a building block for most fertilizers, via the electrochemical nitrogen reduction reaction (ENRR) is desirable; however, a selective electrocatalyst is lacking. Here we show that vanadium nitride (VN) nanoparticles are active, selective, and stable ENRR catalysts with an ENRR rate and a Faradaic efficiency (FE) of 3.3 × 10–10 mol s–1 cm–2 and 6.0% at -0.1 V within 1 h, respectively. ENRR with 15N2 as the feed produces both 14NH3 and 15NH3, which indicates that the reaction follows a Mars–van Krevelen mechanism. Ex situ X-ray photoelectron spectroscopy characterization of fresh and spent catalysts reveals that multiple vanadium oxide, oxynitride, and nitride species are present on the surface and identified VN0.7O0.45 as the active phase in the ENRR. Operando X-ray absorption spectroscopy and catalyst durability test results corroborate this hypothesis and indicate that the conversion of VN0.7O0.45 to the VN phase leads to catalyst deactivation. We hypothesize that only the surface N sites adjacent to a surface O are active in the ENRR. Finally, an ammonia production rate of 1.1 × 10–10 mol s–1 cm–2 can be maintained for 116 h, with a steady-state turnover number of 431.
- Authors:
-
[1];
[1];
[1]
- Univ. of Delaware, Newark, DE (United States). Center for Catalytic Science and Technology, Dept. of Chemical and Biomolecular Engineering
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division; Columbia Univ., New York, NY (United States). Dept. of Chemical Engineering
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1484883
- Report Number(s):
- BNL-209653-2018-JAAM
Journal ID: ISSN 0002-7863
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 140; Journal Issue: 41; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
Citation Formats
Yang, Xuan, Nash, Jared, Anibal, Jacob, Dunwell, Marco, Kattel, Shyam, Stavitski, Eli, Attenkofer, Klaus, Chen, Jingguang G., Yan, Yushan, and Xu, Bingjun. Mechanistic Insights into Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride Nanoparticles. United States: N. p., 2018.
Web. https://doi.org/10.1021/jacs.8b08379.
Yang, Xuan, Nash, Jared, Anibal, Jacob, Dunwell, Marco, Kattel, Shyam, Stavitski, Eli, Attenkofer, Klaus, Chen, Jingguang G., Yan, Yushan, & Xu, Bingjun. Mechanistic Insights into Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride Nanoparticles. United States. https://doi.org/10.1021/jacs.8b08379
Yang, Xuan, Nash, Jared, Anibal, Jacob, Dunwell, Marco, Kattel, Shyam, Stavitski, Eli, Attenkofer, Klaus, Chen, Jingguang G., Yan, Yushan, and Xu, Bingjun. Sun .
"Mechanistic Insights into Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride Nanoparticles". United States. https://doi.org/10.1021/jacs.8b08379. https://www.osti.gov/servlets/purl/1484883.
@article{osti_1484883,
title = {Mechanistic Insights into Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride Nanoparticles},
author = {Yang, Xuan and Nash, Jared and Anibal, Jacob and Dunwell, Marco and Kattel, Shyam and Stavitski, Eli and Attenkofer, Klaus and Chen, Jingguang G. and Yan, Yushan and Xu, Bingjun},
abstractNote = {Renewable production of ammonia, a building block for most fertilizers, via the electrochemical nitrogen reduction reaction (ENRR) is desirable; however, a selective electrocatalyst is lacking. Here we show that vanadium nitride (VN) nanoparticles are active, selective, and stable ENRR catalysts with an ENRR rate and a Faradaic efficiency (FE) of 3.3 × 10–10 mol s–1 cm–2 and 6.0% at -0.1 V within 1 h, respectively. ENRR with 15N2 as the feed produces both 14NH3 and 15NH3, which indicates that the reaction follows a Mars–van Krevelen mechanism. Ex situ X-ray photoelectron spectroscopy characterization of fresh and spent catalysts reveals that multiple vanadium oxide, oxynitride, and nitride species are present on the surface and identified VN0.7O0.45 as the active phase in the ENRR. Operando X-ray absorption spectroscopy and catalyst durability test results corroborate this hypothesis and indicate that the conversion of VN0.7O0.45 to the VN phase leads to catalyst deactivation. We hypothesize that only the surface N sites adjacent to a surface O are active in the ENRR. Finally, an ammonia production rate of 1.1 × 10–10 mol s–1 cm–2 can be maintained for 116 h, with a steady-state turnover number of 431.},
doi = {10.1021/jacs.8b08379},
journal = {Journal of the American Chemical Society},
number = 41,
volume = 140,
place = {United States},
year = {2018},
month = {9}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 54 works
Citation information provided by
Web of Science
Web of Science
Figures / Tables:
Figure S1-1: Nitrogen adsorption isotherm for VN nanoparticles. The Brunauer−Emmett−Teller (BET) surface area is 177 m2 g−1.
All figures and tables
(27 total)
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
How a century of ammonia synthesis changed the world
journal, September 2008
- Erisman, Jan Willem; Sutton, Mark A.; Galloway, James
- Nature Geoscience, Vol. 1, Issue 10
Ammonia synthesis from N 2 and H 2 O using a lithium cycling electrification strategy at atmospheric pressure
journal, January 2017
- McEnaney, Joshua M.; Singh, Aayush R.; Schwalbe, Jay A.
- Energy & Environmental Science, Vol. 10, Issue 7
Beyond fossil fuel–driven nitrogen transformations
journal, May 2018
- Chen, Jingguang G.; Crooks, Richard M.; Seefeldt, Lance C.
- Science, Vol. 360, Issue 6391
The electric discharge and the production of nitric acid
journal, April 1909
- Cramp, W.; Hoyle, B.
- Journal of the Institution of Electrical Engineers, Vol. 42, Issue 194
Ammonia Synthesis at Atmospheric Pressure
journal, October 1998
- Marnellos, G.
- Science, Vol. 282, Issue 5386
Solid-state electrochemical synthesis of ammonia: a review
journal, April 2011
- Amar, Ibrahim A.; Lan, Rong; Petit, Christophe T. G.
- Journal of Solid State Electrochemistry, Vol. 15, Issue 9
Electrochemical synthesis of ammonia at atmospheric pressure and low temperature in a solid polymer electrolyte cell
journal, January 2000
- Kordali, V.; Kyriacou, G.; Lambrou, Ch.
- Chemical Communications, Issue 17
Synthesis of ammonia directly from air and water at ambient temperature and pressure
journal, January 2013
- Lan, Rong; Irvine, John T. S.; Tao, Shanwen
- Scientific Reports, Vol. 3, Issue 1
Electrochemical Nitrogen Reduction Reaction on Noble Metal Catalysts in Proton and Hydroxide Exchange Membrane Electrolyzers
journal, January 2017
- Nash, Jared; Yang, Xuan; Anibal, Jacob
- Journal of The Electrochemical Society, Vol. 164, Issue 14
Electrochemical Reduction of N 2 under Ambient Conditions for Artificial N 2 Fixation and Renewable Energy Storage Using N 2 /NH 3 Cycle
journal, November 2016
- Bao, Di; Zhang, Qi; Meng, Fan-Lu
- Advanced Materials, Vol. 29, Issue 3
Au Sub-Nanoclusters on TiO 2 toward Highly Efficient and Selective Electrocatalyst for N 2 Conversion to NH 3 at Ambient Conditions
journal, February 2017
- Shi, Miao-Miao; Bao, Di; Wulan, Ba-Ri
- Advanced Materials, Vol. 29, Issue 17
Ammonia synthesis at low temperatures
journal, March 2000
- Rod, T. H.; Logadottir, A.; Nørskov, J. K.
- The Journal of Chemical Physics, Vol. 112, Issue 12
A theoretical evaluation of possible transition metal electro-catalysts for N 2 reduction
journal, January 2012
- Skúlason, Egill; Bligaard, Thomas; Gudmundsdóttir, Sigrídur
- Phys. Chem. Chem. Phys., Vol. 14, Issue 3
The Challenge of Electrochemical Ammonia Synthesis: A New Perspective on the Role of Nitrogen Scaling Relations
journal, June 2015
- Montoya, Joseph H.; Tsai, Charlie; Vojvodic, Aleksandra
- ChemSusChem, Vol. 8, Issue 13
Ambient ammonia synthesis via palladium-catalyzed electrohydrogenation of dinitrogen at low overpotential
journal, May 2018
- Wang, Jun; Yu, Liang; Hu, Lin
- Nature Communications, Vol. 9, Issue 1
Favoring the unfavored: Selective electrochemical nitrogen fixation using a reticular chemistry approach
journal, March 2018
- Lee, Hiang Kwee; Koh, Charlynn Sher Lin; Lee, Yih Hong
- Science Advances, Vol. 4, Issue 3
Enhancing the rate of electrochemical nitrogen reduction reaction for ammonia synthesis under ambient conditions using hollow gold nanocages
journal, July 2018
- Nazemi, Mohammadreza; Panikkanvalappil, Sajanlal R.; El-Sayed, Mostafa A.
- Nano Energy, Vol. 49
Electrochemical reduction of aqueous nitrogen (N 2 ) at a low overpotential on (110)-oriented Mo nanofilm
journal, January 2017
- Yang, Dashuai; Chen, Ting; Wang, Zhijiang
- Journal of Materials Chemistry A, Vol. 5, Issue 36
Transition Metal Nitride Catalysts for Electrochemical Reduction of Nitrogen to Ammonia at Ambient Conditions
journal, January 2015
- Abghoui, Younes; Skúlasson, Egill
- Procedia Computer Science, Vol. 51
Electroreduction of N 2 to Ammonia at Ambient Conditions on Mononitrides of Zr, Nb, Cr, and V: A DFT Guide for Experiments
journal, December 2015
- Abghoui, Younes; Garden, Anna L.; Howalt, Jakob G.
- ACS Catalysis, Vol. 6, Issue 2
Electrochemical synthesis of ammonia via Mars-van Krevelen mechanism on the (111) facets of group III–VII transition metal mononitrides
journal, May 2017
- Abghoui, Younes; Skúlason, Egill
- Catalysis Today, Vol. 286
Computational Predictions of Catalytic Activity of Zincblende (110) Surfaces of Metal Nitrides for Electrochemical Ammonia Synthesis
journal, March 2017
- Abghoui, Younes; Skúlason, Egill
- The Journal of Physical Chemistry C, Vol. 121, Issue 11
Highly efficient electrochemical ammonia synthesis via nitrogen reduction reactions on a VN nanowire array under ambient conditions
journal, January 2018
- Zhang, Xiaoping; Kong, Rong-Mei; Du, Huitong
- Chemical Communications, Vol. 54, Issue 42
Metal Nitride and Metal Carbide Nanoparticles by a Soft Urea Pathway
journal, November 2009
- Giordano, Cristina; Erpen, Christian; Yao, Weitang
- Chemistry of Materials, Vol. 21, Issue 21
VN hollow spheres assembled from porous nanosheets for high-performance lithium storage and the oxygen reduction reaction
journal, January 2016
- Zhao, Di; Cui, Zhentao; Wang, Shuguang
- Journal of Materials Chemistry A, Vol. 4, Issue 20
Determination of the V2p XPS binding energies for different vanadium oxidation states (V5+ to V0+)
journal, April 2004
- Silversmit, Geert; Depla, Diederik; Poelman, Hilde
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 135, Issue 2-3
Oxidation of vanadium nitride and titanium nitride coatings
journal, February 2007
- Glaser, A.; Surnev, S.; Netzer, F. P.
- Surface Science, Vol. 601, Issue 4
Titanium nitride oxidation chemistry: An x‐ray photoelectron spectroscopy study
journal, October 1992
- Saha, Naresh C.; Tompkins, Harland G.
- Journal of Applied Physics, Vol. 72, Issue 7
Effect of low-temperature biochar derived from pig manure and poultry litter on mobile and organic matter-bound forms of Cu, Cd, Pb and Zn in sandy soil
journal, July 2016
- Gondek, K.; Mierzwa-Hersztek, M.
- Soil Use and Management, Vol. 32, Issue 3
Mobility of heavy metals in sandy soil after application of composts produced from maize straw, sewage sludge and biochar
journal, March 2018
- Gondek, K.; Mierzwa-Hersztek, M.; Kopeć, M.
- Journal of Environmental Management, Vol. 210
Synthesis, Crystal Structure, and Magnetic Properties of a Vanadium Oxide Nitride with Pseudobrookite-type Structure
journal, October 2009
- Nakhal, S.; Hermes, W.; Ressler, T.
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 635, Issue 12
X-ray Absorption Near-Edge Structure (XANES) Spectroscopy
journal, January 2014
- Henderson, G. S.; de Groot, F. M. F.; Moulton, B. J. A.
- Reviews in Mineralogy and Geochemistry, Vol. 78, Issue 1
Works referencing / citing this record:
Recent progress in electrocatalytic nitrogen reduction
journal, January 2019
- Guo, Xiaoxi; Du, Huitong; Qu, Fengli
- Journal of Materials Chemistry A, Vol. 7, Issue 8
Biomass-derived oxygen-doped hollow carbon microtubes for electrocatalytic N 2 -to-NH 3 fixation under ambient conditions
journal, January 2019
- Wu, Tengteng; Li, Peipei; Wang, Huanbo
- Chemical Communications, Vol. 55, Issue 18
The Crucial Role of Charge Accumulation and Spin Polarization in Activating Carbon‐Based Catalysts for Electrocatalytic Nitrogen Reduction
journal, February 2020
- Yang, Yuanyuan; Zhang, Lifu; Hu, Zhenpeng
- Angewandte Chemie International Edition, Vol. 59, Issue 11
High Efficiency Electrochemical Nitrogen Fixation Achieved with a Lower Pressure Reaction System by Changing the Chemical Equilibrium
journal, September 2019
- Cheng, Hui; Cui, Peixin; Wang, Fangrui
- Angewandte Chemie, Vol. 131, Issue 43
Recent Advanced Materials for Electrochemical and Photoelectrochemical Synthesis of Ammonia from Dinitrogen: One Step Closer to a Sustainable Energy Future
journal, September 2019
- Yan, Zihao; Ji, Mengxia; Xia, Jiexiang
- Advanced Energy Materials, Vol. 10, Issue 11
Ammonia Synthesis Under Ambient Conditions: Selective Electroreduction of Dinitrogen to Ammonia on Black Phosphorus Nanosheets
journal, January 2019
- Zhang, Lili; Ding, Liang-Xin; Chen, Gao-Feng
- Angewandte Chemie International Edition, Vol. 58, Issue 9
Unusual electrochemical N 2 reduction activity in an earth-abundant iron catalyst via phosphorous modulation
journal, January 2020
- Zhu, Xiaojuan; Wu, Tongwei; Ji, Lei
- Chemical Communications, Vol. 56, Issue 5
Carbon‐Nanoplated CoS@TiO 2 Nanofibrous Membrane: An Interface‐Engineered Heterojunction for High‐Efficiency Electrocatalytic Nitrogen Reduction
journal, December 2019
- Liu, Yi‐Tao; Chen, Xingxing; Yu, Jianyong
- Angewandte Chemie International Edition, Vol. 58, Issue 52
Elementary kinetics of nitrogen electroreduction to ammonia on late transition metals
journal, January 2019
- Rostamikia, Gholamreza; Maheshwari, Sharad; Janik, Michael J.
- Catalysis Science & Technology, Vol. 9, Issue 1
Oxygen vacancy-engineered Fe 2 O 3 nanocubes via a task-specific ionic liquid for electrocatalytic N 2 fixation
journal, January 2019
- Zhang, Chenyun; Liu, Shuai; Chen, Tingting
- Chemical Communications, Vol. 55, Issue 51
ZnO Quantum Dots Coupled with Graphene toward Electrocatalytic N 2 Reduction: Experimental and DFT Investigations
journal, August 2019
- Liu, Ya‐ping; Li, Yu‐biao; Huang, Da‐jian
- Chemistry – A European Journal, Vol. 25, Issue 51
Experimental and theoretical understanding on electrochemical activation and inactivation processes of Nb 3 O 7 (OH) for ambient electrosynthesis of NH 3
journal, January 2019
- Wu, Tianxing; Han, Miaomiao; Zhu, Xiaoguang
- Journal of Materials Chemistry A, Vol. 7, Issue 28
DyF 3 : An Efficient Electrocatalyst for N 2 Fixation to NH 3 under Ambient Conditions
journal, January 2020
- Li, Yuanfang; Li, Tingshuai; Zhu, Xiaojuan
- Chemistry – An Asian Journal, Vol. 15, Issue 4
Oxygen Doping Induced by Nitrogen Vacancies in Nb 4 N 5 Enables Highly Selective CO 2 Reduction
journal, November 2019
- Fu, Jiantao; Bao, Haihong; Liu, Yifan
- Small, Vol. 16, Issue 2
Biomass Valorization via Paired Electrosynthesis Over Vanadium Nitride‐Based Electrocatalysts
journal, August 2019
- Li, Suiqin; Sun, Xiang; Yao, Zihao
- Advanced Functional Materials, Vol. 29, Issue 42
A Combined Theory‐Experiment Analysis of the Surface Species in Lithium‐Mediated NH 3 Electrosynthesis
journal, January 2020
- Schwalbe, Jay A.; Statt, Michael J.; Chosy, Cullen
- ChemElectroChem, Vol. 7, Issue 7
Ti 3+ self-doped TiO 2−x nanowires for efficient electrocatalytic N 2 reduction to NH 3
journal, January 2020
- Li, Bingyue; Zhu, Xiaojuan; Wang, Jianwei
- Chemical Communications, Vol. 56, Issue 7
Nitrogen Vacancies on 2D Layered W 2 N 3 : A Stable and Efficient Active Site for Nitrogen Reduction Reaction
journal, June 2019
- Jin, Huanyu; Li, Laiquan; Liu, Xin
- Advanced Materials
Advanced Non‐metallic Catalysts for Electrochemical Nitrogen Reduction under Ambient Conditions
journal, July 2019
- Zhang, Lili; Chen, Gao‐Feng; Ding, Liang‐Xin
- Chemistry – A European Journal, Vol. 25, Issue 54
Self-organized growth of flower-like SnS 2 and forest-like ZnS nanoarrays on nickel foam for synergistic superiority in electrochemical ammonia synthesis
journal, January 2019
- Chen, Xingxing; Liu, Yi-Tao; Ma, Chunlan
- Journal of Materials Chemistry A, Vol. 7, Issue 39
Photocatalytic and electrocatalytic approaches towards atmospheric nitrogen reduction to ammonia under ambient conditions
journal, April 2019
- John, Jude; Lee, Dong-Kyu; Sim, Uk
- Nano Convergence, Vol. 6, Issue 1
Unlocking the Potential of Disordered Rocksalts for Aqueous Zinc‐Ion Batteries
journal, September 2019
- Ding, Junwei; Du, Zhiguo; Li, Bin
- Advanced Materials, Vol. 31, Issue 44
Crystal‐Phase‐Engineered PdCu Electrocatalyst for Enhanced Ammonia Synthesis
journal, January 2020
- Tong, Wu; Huang, Bolong; Wang, Pengtang
- Angewandte Chemie, Vol. 132, Issue 7
Ambient electrocatalytic nitrogen reduction on a MoO 2 /graphene hybrid: experimental and DFT studies
journal, January 2019
- Wang, Jing; Liu, Ya-ping; Zhang, Hu
- Catalysis Science & Technology, Vol. 9, Issue 16
Potassium‐Ion‐Assisted Regeneration of Active Cyano Groups in Carbon Nitride Nanoribbons: Visible‐Light‐Driven Photocatalytic Nitrogen Reduction
journal, November 2019
- Wang, Weikang; Zhang, Haimin; Zhang, Shengbo
- Angewandte Chemie International Edition, Vol. 58, Issue 46
Anomalous hydrogen evolution behavior in high-pH environment induced by locally generated hydronium ions
journal, October 2019
- Wang, Xuesi; Xu, Chaochen; Jaroniec, Mietek
- Nature Communications, Vol. 10, Issue 1
Stable Confinement of Black Phosphorus Quantum Dots on Black Tin Oxide Nanotubes: A Robust, Double‐Active Electrocatalyst toward Efficient Nitrogen Fixation
journal, October 2019
- Liu, Yi‐Tao; Li, Di; Yu, Jianyong
- Angewandte Chemie, Vol. 131, Issue 46
A pyrolysis–phosphorization approach to fabricate carbon nanotubes with embedded CoP nanoparticles for ambient electrosynthesis of ammonia
journal, January 2019
- Zhang, Shengbo; Gong, Wanbing; Lv, Yang
- Chemical Communications, Vol. 55, Issue 82
Glycerol oxidation assisted electrocatalytic nitrogen reduction: ammonia and glyceraldehyde co-production on bimetallic RhCu ultrathin nanoflake nanoaggregates
journal, January 2019
- Bai, Juan; Huang, Hao; Li, Fu-Min
- Journal of Materials Chemistry A, Vol. 7, Issue 37
Synergistic Promotion of the Electrochemical Reduction of Nitrogen to Ammonia by Phosphorus and Potassium
journal, October 2019
- Zhang, Qikun; Liu, Baoliang; Yu, Liping
- ChemCatChem, Vol. 12, Issue 1
Recent Progress on Electrocatalyst and Photocatalyst Design for Nitrogen Reduction
journal, October 2018
- Li, Mengqiao; Huang, Hao; Low, Jingxiang
- Small Methods, Vol. 3, Issue 6
Electrocatalytic N 2 -to-NH 3 conversion with high faradaic efficiency enabled using a Bi nanosheet array
journal, January 2019
- Zhang, Rong; Ji, Lei; Kong, Wenhan
- Chemical Communications, Vol. 55, Issue 36
Aqueous electrocatalytic N 2 reduction for ambient NH 3 synthesis: recent advances in catalyst development and performance improvement
journal, January 2020
- Zhu, Xiaojuan; Mou, Shiyong; Peng, Qiling
- Journal of Materials Chemistry A, Vol. 8, Issue 4
Interface engineering in transition metal carbides for electrocatalytic hydrogen generation and nitrogen fixation
journal, January 2020
- Kuang, Min; Huang, Wenjing; Hegde, Chidanand
- Materials Horizons, Vol. 7, Issue 1
Co‐generation of Ammonia and H 2 from H 2 O Vapor and N 2 Using a Membrane Electrode Assembly
text, January 2020
- Kugler, Kurt; Kriescher, Stefanie M. A.; Giela, Martin
- RWTH Aachen University
Atomic Modulation, Structural Design, and Systematic Optimization for Efficient Electrochemical Nitrogen Reduction
journal, January 2020
- Huang, Yiyin; Babu, Dickson D.; Peng, Zhen
- Advanced Science, Vol. 7, Issue 4
Selective Electrochemical Reduction of Nitrogen to Ammonia by Adjusting the Three-Phase Interface
journal, November 2019
- Wang, Haiyan; Chen, Yuzhuo; Fan, Ruxue
- Research, Vol. 2019
Plasma-engineered NiO nanosheets with enriched oxygen vacancies for enhanced electrocatalytic nitrogen fixation
journal, January 2020
- Li, Yu-biao; Liu, Ya-ping; Wang, Jing
- Inorganic Chemistry Frontiers, Vol. 7, Issue 2
Crystal‐Phase‐Engineered PdCu Electrocatalyst for Enhanced Ammonia Synthesis
journal, February 2020
- Tong, Wu; Huang, Bolong; Wang, Pengtang
- Angewandte Chemie International Edition, Vol. 59, Issue 7
Nitrogen‐Doped NiO Nanosheet Array for Boosted Electrocatalytic N 2 Reduction
journal, August 2019
- Wang, Xiao‐hu; Wang, Jing; Li, Yu‐biao
- ChemCatChem, Vol. 11, Issue 18
Greatly Enhanced Electrocatalytic N 2 Reduction on TiO 2 via V Doping
journal, May 2019
- Wu, Tongwei; Kong, Wenhan; Zhang, Ya
- Small Methods, Vol. 3, Issue 11
Carbon‐Nanoplated CoS@TiO 2 Nanofibrous Membrane: An Interface‐Engineered Heterojunction for High‐Efficiency Electrocatalytic Nitrogen Reduction
journal, November 2019
- Liu, Yi‐Tao; Chen, Xingxing; Yu, Jianyong
- Angewandte Chemie, Vol. 131, Issue 52
Electrochemical nitrogen fixation and utilization: theories, advanced catalyst materials and system design
journal, January 2019
- Guo, Wenhan; Zhang, Kexin; Liang, Zibin
- Chemical Society Reviews, Vol. 48, Issue 24
Is It Appropriate to Use the Nafion Membrane in Electrocatalytic N 2 Reduction?
journal, August 2019
- Ren, Yongwen; Yu, Chang; Tan, Xinyi
- Small Methods, Vol. 3, Issue 12
Ambient electrochemical N 2 reduction to NH 3 under alkaline conditions enabled by a layered K 2 Ti 4 O 9 nanobelt
journal, January 2019
- Wu, Dan; Wang, Huanbo; Huang, Hong
- Chemical Communications, Vol. 55, Issue 52
Boron and nitrogen co-doped porous carbon nanofibers as metal-free electrocatalysts for highly efficient ammonia electrosynthesis
journal, January 2019
- Kong, Yan; Li, Yan; Yang, Bin
- Journal of Materials Chemistry A, Vol. 7, Issue 46
A vanadium–nickel oxynitride layer for enhanced electrocatalytic nitrogen fixation in neutral media
journal, January 2020
- Chang, Bin; Deng, Lequan; Wang, Shouzhi
- Journal of Materials Chemistry A, Vol. 8, Issue 1
Ambient dinitrogen electrocatalytic reduction for ammonia synthesis
journal, January 2019
- Chen, Aling; Xia, Bao Yu
- Journal of Materials Chemistry A, Vol. 7, Issue 41
B 4 C nanosheets decorated with in situ -derived boron-doped graphene quantum dots for high-efficiency ambient N 2 fixation
journal, January 2019
- Qiu, Wei-Bin; Luo, Yu-Xi; Liang, Ru-Ping
- Chemical Communications, Vol. 55, Issue 51
Potassium‐Ion‐Assisted Regeneration of Active Cyano Groups in Carbon Nitride Nanoribbons: Visible‐Light‐Driven Photocatalytic Nitrogen Reduction
journal, October 2019
- Wang, Weikang; Zhang, Haimin; Zhang, Shengbo
- Angewandte Chemie, Vol. 131, Issue 46
How to explore ambient electrocatalytic nitrogen reduction reliably and insightfully
journal, January 2019
- Tang, Cheng; Qiao, Shi-Zhang
- Chemical Society Reviews, Vol. 48, Issue 12
Sb 2 S 3 nanoparticles anchored on SnO 2 nanofibers: a high-performance hybrid electrocatalyst toward ammonia synthesis under ambient conditions
journal, January 2019
- Di Li, Di Li; Chen, Xingxing; Liu, Yi-Tao
- Chemical Communications, Vol. 55, Issue 92
Ambient electrohydrogenation of N 2 for NH 3 synthesis on non-metal boron phosphide nanoparticles: the critical role of P in boosting the catalytic activity
journal, January 2019
- Zhu, Xiaojuan; Wu, Tongwei; Ji, Lei
- Journal of Materials Chemistry A, Vol. 7, Issue 27
Stable Confinement of Black Phosphorus Quantum Dots on Black Tin Oxide Nanotubes: A Robust, Double‐Active Electrocatalyst toward Efficient Nitrogen Fixation
journal, November 2019
- Liu, Yi‐Tao; Li, Di; Yu, Jianyong
- Angewandte Chemie International Edition, Vol. 58, Issue 46
Advances in Electrocatalytic N 2 Reduction—Strategies to Tackle the Selectivity Challenge
journal, October 2018
- Chen, Gao‐Feng; Ren, Shiyu; Zhang, Lili
- Small Methods, Vol. 3, Issue 6
High-yield production of few-layer boron nanosheets for efficient electrocatalytic N 2 reduction
journal, January 2019
- Fan, Qun; Choi, Changhyeok; Yan, Chao
- Chemical Communications, Vol. 55, Issue 29
Electrochemical Ammonia Synthesis and Ammonia Fuel Cells
journal, December 2018
- Jiao, Feng; Xu, Bingjun
- Advanced Materials, Vol. 31, Issue 31
Overcoming Chemical Inertness under Ambient Conditions: A Critical View on Recent Developments in Ammonia Synthesis via Electrochemical N 2 Reduction by Asking Five Questions
journal, January 2020
- Qin, Qing; Oschatz, Martin
- ChemElectroChem, Vol. 7, Issue 4
The doping and oxidation of 2D black and blue phosphorene: a new photocatalyst for nitrogen reduction driven by visible light
journal, January 2019
- Cheng, Yuwen; Song, Yan; Zhang, Yumin
- Physical Chemistry Chemical Physics, Vol. 21, Issue 44
Lithium-mediated ammonia synthesis from water and nitrogen: a membrane-free approach enabled by an immiscible aqueous/organic hybrid electrolyte system
journal, January 2019
- Kim, Kwiyong; Chen, Yifu; Han, Jong-In
- Green Chemistry, Vol. 21, Issue 14
Ultrasmall V 8 C 7 nanoparticles embedded in conductive carbon for efficient electrocatalytic N 2 reduction toward ambient NH 3 production
journal, January 2019
- Feng, Jing; Zhu, Xiaojuan; Chen, Quanying
- Journal of Materials Chemistry A, Vol. 7, Issue 46
High Efficiency Electrochemical Nitrogen Fixation Achieved with a Lower Pressure Reaction System by Changing the Chemical Equilibrium
journal, September 2019
- Cheng, Hui; Cui, Peixin; Wang, Fangrui
- Angewandte Chemie International Edition, Vol. 58, Issue 43
Review on photocatalytic and electrocatalytic artificial nitrogen fixation for ammonia synthesis at mild conditions: Advances, challenges and perspectives
journal, May 2019
- Xue, Xiaolan; Chen, Renpeng; Yan, Changzeng
- Nano Research, Vol. 12, Issue 6
The Crucial Role of Charge Accumulation and Spin Polarization in Activating Carbon‐Based Catalysts for Electrocatalytic Nitrogen Reduction
journal, March 2020
- Yang, Yuanyuan; Zhang, Lifu; Hu, Zhenpeng
- Angewandte Chemie, Vol. 132, Issue 11
Quantification of Active Sites and Elucidation of the Reaction Mechanism of the Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride
journal, September 2019
- Yang, Xuan; Kattel, Shyam; Nash, Jared
- Angewandte Chemie International Edition, Vol. 58, Issue 39
Quantification of Active Sites and Elucidation of the Reaction Mechanism of the Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride
journal, August 2019
- Yang, Xuan; Kattel, Shyam; Nash, Jared
- Angewandte Chemie, Vol. 131, Issue 39
Co‐generation of Ammonia and H 2 from H 2 O Vapor and N 2 Using a Membrane Electrode Assembly
journal, January 2020
- Kugler, Kurt; Kriescher, Stefanie M. A.; Giela, Martin
- Chemie Ingenieur Technik, Vol. 92, Issue 1-2
Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.