Effect of Synthetic Method and Annealing Temperature on the Structure of Hollandite-Type Oxides

Ebinumoliseh, Ifeoma; Grosvenor, Andrew P.

doi:10.1021/acs.inorgchem.8b02464

Title: Effect of Synthetic Method and Annealing Temperature on the Structure of Hollandite-Type Oxides

Journal Article · 30 October 2018 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.8b02464 · OSTI ID:1484809

Ebinumoliseh, Ifeoma ^[1];

^[1]

Univ. of Saskatchewan, Saskatoon, SK (Canada)

Hollandite is a class of metal oxide material with the general formula A₂B₈O₁₆. Several methods have been used in the synthesis of this type of metal oxide, and the synthetic methods reported have typically employed high annealing temperatures between 1200 and 1300 °C. Appropriate synthetic methods must be employed to successfully synthesize these hollandite-type oxides at lower annealing temperatures. Hollandite compounds have been synthesized using ceramic (high annealing temperature only) and coprecipitation (high and low annealing temperatures) methods. Annealing temperatures ranging from 1200 to 700 °C have been employed in the thermal treatment process. In this work, powder X-ray diffraction and X-ray absorption near-edge spectroscopy (XANES) were conducted on hollandite-type oxides (Ba_xAl_2xTi_8–2xO_16–δ; x = 1.2; and Ba_xAl_xFe_xTi_8–2xO_16–δ, Ba_xFe_2xTi_8–2xO_16–δ; x = 1.16). Structural comparisons between materials annealed in the temperature range from 1200 to 800 °C were made, and an examination of the XANES spectra and powder X-ray diffraction patterns has provided confirmation of the absence of significant structural changes in these hollandite materials. This study has shown that hollandite-type materials can be formed using annealing temperatures as low as 700–800 °C when a coprecipitation method is used, with little change to the local and long-range structures being detected.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: Canadian Institutes of Health Research (CIHR); Government of Saskatchewan; National Research Council Canada (NRC); Natural Sciences and Engineering Research Council of Canada (NSERC); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); Western Economic Diversification Canada

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1484809

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 22 Vol. 57; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: ENGLISH

References (51)

Hot-Pressed Glass Matrix Composites Containing Pyrochlore Phase Particles for Nuclear Waste Encapsulation Boccaccini, A. R.; Atiq, S.; Grimes, R. W. Advanced Engineering Materials, Vol. 5, Issue 7 https://doi.org/10.1002/adem.200300352	journal	July 2003
Defects induced by electron irradiation in hollandite ceramics, specific radioactive cesium-host wasteforms: a 57Fe Mössbauer study Nguyen, N.; Ducouret, A.; Studer, F. Hyperfine Interactions, Vol. 166, Issue 1-4 https://doi.org/10.1007/s10751-006-9313-6	journal	October 2006
The effect of caesium on barium hollandites studied by neutron diffraction and magic-angle spinning (MAS) nuclear magnetic resonance Whittle, Karl R.; Ashbrook, Sharon E.; Lumpkin, Gregory R. Journal of Materials Science, Vol. 42, Issue 22 https://doi.org/10.1007/s10853-007-1815-3	journal	November 2007
Glassy Wasteforms for Nuclear Waste Immobilization Ojovan, Michael I.; Lee, William E. Metallurgical and Materials Transactions A, Vol. 42, Issue 4 https://doi.org/10.1007/s11661-010-0525-7	journal	November 2010
Radius ratio tolerance factors and the stability of hollandites Kesson, S. E.; White, T. J. Journal of Solid State Chemistry, Vol. 63, Issue 1 https://doi.org/10.1016/0022-4596(86)90160-X	journal	June 1986
Radiation effects in nuclear waste forms for high-level radioactive waste Ewing, R. C.; Weber, W. J.; Clinard, F. W. Progress in Nuclear Energy, Vol. 29, Issue 2 https://doi.org/10.1016/0149-1970(94)00016-Y	journal	January 1995
X-ray absorption and photoemission electron spectroscopic investigation of crystalline and amorphous barium silicates Bender, S.; Franke, R.; Hartmann, E. Journal of Non-Crystalline Solids, Vol. 298, Issue 2-3 https://doi.org/10.1016/S0022-3093(02)00943-2	journal	March 2002
Ultra-fine Ba2Ti9O20 microwave dielectric materials synthesized by chemical process Chu, Li-Wen; Hsiue, Ging-Ho; Chiang, Yi-Jen Journal of the European Ceramic Society, Vol. 24, Issue 6 https://doi.org/10.1016/S0955-2219(03)00469-2	journal	January 2004
Co-precipitation in aqueous solution synthesis of magnetite nanoparticles using iron(III) salts as precursors Khalil, Mutasim I. Arabian Journal of Chemistry, Vol. 8, Issue 2 https://doi.org/10.1016/j.arabjc.2015.02.008	journal	March 2015
Processing glass–pyrochlore composites for nuclear waste encapsulation Pace, S.; Cannillo, V.; Wu, J. Journal of Nuclear Materials, Vol. 341, Issue 1 https://doi.org/10.1016/j.jnucmat.2005.01.005	journal	May 2005
Preparation and characterization of (Ba,Cs)(M,Ti)8O16 (M=Al3+, Fe3+, Ga3+, Cr3+, Sc3+, Mg2+) hollandite ceramics developed for radioactive cesium immobilization Aubin-Chevaldonnet, V.; Caurant, D.; Dannoux, A. Journal of Nuclear Materials, Vol. 366, Issue 1-2 https://doi.org/10.1016/j.jnucmat.2006.12.051	journal	June 2007
Alteration kinetics of the glass-ceramic zirconolite and role of the alteration film – Comparison with the SON68 glass Martin, C.; Ribet, I.; Frugier, P. Journal of Nuclear Materials, Vol. 366, Issue 1-2 https://doi.org/10.1016/j.jnucmat.2007.02.002	journal	June 2007
The effects of γ-radiation on model vitreous wasteforms intended for the disposal of intermediate and high level radioactive wastes in the United Kingdom McGann, O. J.; Bingham, P. A.; Hand, R. J. Journal of Nuclear Materials, Vol. 429, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2012.04.007	journal	October 2012
Synthesis, characterization and thermochemistry of Cs-, Rb- and Sr-substituted barium aluminium titanate hollandites Xu, H.; Wu, L.; Zhu, J. Journal of Nuclear Materials, Vol. 459 https://doi.org/10.1016/j.jnucmat.2015.01.014	journal	April 2015
Structural characterization of the hollandite host lattice for the confinement of radioactive cesium: Quantification of the amorphous phase taking into account the incommensurate modulated character of the crystallized part Leinekugel-le-Cocq-Errien, A. Y.; Deniard, P.; Jobic, S. Journal of Solid State Chemistry, Vol. 180, Issue 1 https://doi.org/10.1016/j.jssc.2006.10.013	journal	January 2007
An X-ray absorption spectroscopic study of the metal site preference in Al1−Ga FeO3 Walker, James D. S.; Grosvenor, Andrew P. Journal of Solid State Chemistry, Vol. 197 https://doi.org/10.1016/j.jssc.2012.09.015	journal	January 2013
Equations of state of Na–K–Al host phases and implications for MORB density in the lower mantle Guignot, Nicolas; Andrault, Denis Physics of the Earth and Planetary Interiors, Vol. 143-144 https://doi.org/10.1016/j.pepi.2003.09.014	journal	June 2004
How temperature influences the stoichiometry of CeTi2O6 Huynh, Lana T.; Eger, Shaylin B.; Walker, James D. S. Solid State Sciences, Vol. 14, Issue 6 https://doi.org/10.1016/j.solidstatesciences.2012.03.030	journal	June 2012
The HighScore suite Degen, Thomas; Sadki, Mustapha; Bron, Egbert Powder Diffraction, Vol. 29, Issue S2 https://doi.org/10.1017/S0885715614000840	journal	October 2014
Synthesis and Characterization of Octahedral Molecular Sieves (OMS-2) Having the Hollandite Structure DeGuzman, Roberto N.; Shen, Yan-Fei; Neth, Edward J. Chemistry of Materials, Vol. 6, Issue 6 https://doi.org/10.1021/cm00042a019	journal	June 1994
Characterization of Manganese Oxide Octahedral Molecular Sieve (M−OMS-2) Materials with Different Metal Cation Dopants Chen, Xiao; Shen, Yan-Fei; Suib, Steven L. Chemistry of Materials, Vol. 14, Issue 2 https://doi.org/10.1021/cm000868o	journal	February 2002
Synthesis and Characterization of Silver Hollandite and Its Application in Emission Control Li, Liyu; King, David L. Chemistry of Materials, Vol. 17, Issue 17 https://doi.org/10.1021/cm0506508	journal	August 2005
High-Resolution X-ray Emission and X-ray Absorption Spectroscopy de Groot, Frank Chemical Reviews, Vol. 101, Issue 6 https://doi.org/10.1021/cr9900681	journal	June 2001
A Multiplet Analysis of Fe K-Edge 1s → 3d Pre-Edge Features of Iron Complexes Westre, Tami E.; Kennepohl, Pierre; DeWitt, Jane G. Journal of the American Chemical Society, Vol. 119, Issue 27 https://doi.org/10.1021/ja964352a	journal	July 1997
Formation Pathways of Magnetite Nanoparticles by Coprecipitation Method Ahn, Taebin; Kim, Jong Hun; Yang, Hee-Man The Journal of Physical Chemistry C, Vol. 116, Issue 10 https://doi.org/10.1021/jp211843g	journal	March 2012
XANES and XPS investigations of (TiO ₂ ) _x (SiO ₂ ) _1−x : the contribution of final-state relaxation to shifts in absorption and binding energies Gaultois, Michael W.; Grosvenor, Andrew P. J. Mater. Chem., Vol. 21, Issue 6 https://doi.org/10.1039/C0JM03464A	journal	January 2011
XANES and XPS investigations of the local structure and final-state effects in amorphous metal silicates: (ZrO ₂ ) _x (TiO ₂ ) _y (SiO ₂ ) _1−x−y Gaultois, Michael W.; Grosvenor, Andrew P. Phys. Chem. Chem. Phys., Vol. 14, Issue 1 https://doi.org/10.1039/C1CP22717C	journal	January 2012
A study of the electronic structure and structural stability of Gd ₂ Ti ₂ O ₇ based glass-ceramic composites Aluri, Esther Rani; Grosvenor, Andrew P. RSC Advances, Vol. 5, Issue 99 https://doi.org/10.1039/C5RA10720B	journal	January 2015
Effects of bond character on the electronic structure of brownmillerite-phase oxides, Ca2B′xFe2−xO5 (B′ = Al, Ga): an X-ray absorption and electron energy loss spectroscopic study Grosvenor, Andrew P.; Ramezanipour, Farshid; Derakhshan, Shahab Journal of Materials Chemistry, Vol. 19, Issue 48 https://doi.org/10.1039/b914983j	journal	January 2009
VLS-PGM Beamline at the Canadian Light Source Hu, Y. F.; Zuin, L.; Reininger, R. SYNCHROTRON RADIATION INSTRUMENTATION: Ninth International Conference on Synchrotron Radiation Instrumentation, AIP Conference Proceedings https://doi.org/10.1063/1.2436116	conference	January 2007
Preliminary Commissioning and Performance of the Soft X-ray Micro-characterization Beamline at the Canadian Light Source Hu, Y. F.; Coulthard, I.; Chevrier, D. SRI 2009, 10TH INTERNATIONAL CONFERENCE ON RADIATION INSTRUMENTATION, AIP Conference Proceedings https://doi.org/10.1063/1.3463208	conference	January 2010
Interpretation of the Al K- and L _II/III -edges of aluminium oxides: differences between tetrahedral and octahedral Al explained by different local symmetries Bokhoven, J. A. van; Nabi, T.; Sambe, H. Journal of Physics: Condensed Matter, Vol. 13, Issue 45 https://doi.org/10.1088/0953-8984/13/45/311	journal	October 2001
High-resolution Al L _2,3 -edge x-ray absorption near edge structure spectra of Al-containing crystals and glasses: coordination number and bonding information from edge components Weigel, C.; Calas, G.; Cormier, L. Journal of Physics: Condensed Matter, Vol. 20, Issue 13 https://doi.org/10.1088/0953-8984/20/13/135219	journal	March 2008
Glass matrices for vitrification of radioactive waste – an Update on R & D Efforts Raj, Kanwar; Kaushik, C. P. IOP Conference Series: Materials Science and Engineering, Vol. 2 https://doi.org/10.1088/1757-899X/2/1/012002	journal	July 2009
Comparative study on microstructure, crystallite size and lattice strain of as-deposited and thermal treatment silver silicon nitride coating on Ti6Al4V alloy Zalilah, Umi; Mahmoodian, R. IOP Conference Series: Materials Science and Engineering, Vol. 210 https://doi.org/10.1088/1757-899X/210/1/012074	journal	June 2017
Ti K -edge XANES studies of Ti coordination and disorder in oxide compounds: Comparison between theory and experiment Farges, François; Brown, Gordon E.; Rehr, J. J. Physical Review B, Vol. 56, Issue 4 https://doi.org/10.1103/PhysRevB.56.1809	journal	July 1997
Electron Population Analysis by Full-Potential X-Ray Absorption Simulations Joly, Yves; Cabaret, Delphine; Renevier, Hubert Physical Review Letters, Vol. 82, Issue 11 https://doi.org/10.1103/PhysRevLett.82.2398	journal	March 1999
VESTA : a three-dimensional visualization system for electronic and structural analysis Momma, Koichi; Izumi, Fujio Journal of Applied Crystallography, Vol. 41, Issue 3 https://doi.org/10.1107/S0021889808012016	journal	May 2008
Scherrer after sixty years: A survey and some new results in the determination of crystallite size Langford, J. I.; Wilson, A. J. C. Journal of Applied Crystallography, Vol. 11, Issue 2 https://doi.org/10.1107/S0021889878012844	journal	April 1978
An analysis of the structural characteristics of hollandite compounds Cheary, R. W. Acta Crystallographica Section B Structural Science, Vol. 42, Issue 3 https://doi.org/10.1107/S0108768186098294	journal	June 1986
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
XAFS and micro-XAFS at the PNC-CAT beamlines Heald, S. M.; Brewe, D. L.; Stern, E. A. Journal of Synchrotron Radiation, Vol. 6, Issue 3 https://doi.org/10.1107/S090904959801677X	journal	May 1999
Pre-edge structure analysis of Ti K -edge polarized X-ray absorption spectra in TiO ₂ by full-potential XANES calculations Cabaret, D.; Joly, Y.; Renevier, H. Journal of Synchrotron Radiation, Vol. 6, Issue 3 https://doi.org/10.1107/S0909049599000783	journal	May 1999
HIPed Tailored Hollandite Waste Forms for the Immobilization of Radioactive Cs and Sr Carter, Melody L.; Gillen, Andrew L.; Olufson, Kylie Journal of the American Ceramic Society, Vol. 92, Issue 5 https://doi.org/10.1111/j.1551-2916.2009.03021.x	journal	May 2009
Thermochemistry of Barium Hollandites Costa, Gustavo C. C.; Xu, Hongwu; Navrotsky, Alexandra Journal of the American Ceramic Society, Vol. 96, Issue 5 https://doi.org/10.1111/jace.12224	journal	March 2013
Investigation of CeTi ₂ O ₆ - and CaZrTi ₂ O ₇ -containing glass–ceramic composite materials Paknahad, Elham; Grosvenor, Andrew P. Canadian Journal of Chemistry, Vol. 95, Issue 11 https://doi.org/10.1139/cjc-2016-0633	journal	November 2017
Incommensurate modulations in a hollandite phase Ba _x (Al, Fe) _{2 x} Ti _{8–2 x} O ₁₆ intended for the storage of radioactive wastes: a (3+1) dimension structure determination Aubin-Chevaldonnet, Virginie; Deniard, Philippe; Evain, Michel Zeitschrift für Kristallographie, Vol. 222, Issue 8 https://doi.org/10.1524/zkri.2007.222.8.383	journal	July 2007
The Effect of γ-radiation on Mechanical Properties of Model UK Nuclear Waste Glasses McGann, Owen J.; Gandy, Amy S.; Bingham, Paul A. MRS Proceedings, Vol. 1518 https://doi.org/10.1557/opl.2013.203	journal	January 2012
Fivefold-coordinated Ti (super 4+) in metamict zirconolite and titanite; a new occurrence shown by Ti K-edge XANES spectroscopy Farges, Francois American Mineralogist, Vol. 82, Issue 1-2 https://doi.org/10.2138/am-1997-1-206	journal	February 1997
Effect of aluminum on Ti-coordination in silicate glasses: A XANES study Romano, Claudia; Paris, Eleonora; Poe, Brent T. American Mineralogist, Vol. 85, Issue 1 https://doi.org/10.2138/am-2000-0112	journal	January 2000
Crystal Structure and Magnetic Properties of the Novel Hollandite Ba1.3Co1.3Ti6.7O16 Shlyk, L.; Niewa, R. Zeitschrift für Naturforschung B, Vol. 66 https://doi.org/10.5560/ZNB.2011.66b1097	journal	January 2011

Cited By (2)

Low-temperature synthesis of CaZrTi ₂ O ₇ zirconolite-type materials using ceramic, coprecipitation, and sol–gel methods McCaugherty, Sarah; Grosvenor, Andrew P. Journal of Materials Chemistry C, Vol. 7, Issue 1 https://doi.org/10.1039/c8tc04560g	journal	January 2019
Temperature‐dependent electrical transport behavior and structural evolution in hollandite‐type titanium‐based oxide Feng, Tao; Li, Liping; Lv, Zhe Journal of the American Ceramic Society, Vol. 102, Issue 11 https://doi.org/10.1111/jace.16520	journal	May 2019

Similar Records

Compositional control of radionuclide retention in hollandite-based ceramic waste forms for Cs-immobilization

Journal Article · 2018 · Journal of the American Ceramic Society · OSTI ID:1566709

Zhao, Mingyang; Xu, Yun; Shuller‐Nickles, Lindsay; +7 more

A universally applicable composite modulated structure approach to ordered Ba{sub x}M{sub y}Ti{sub 8-y}O{sub 16} hollandite-type solid solutions

Journal Article · 2005 · Journal of Solid State Chemistry · OSTI ID:20725977

Carter, Melody L; Withers, Ray L

Compositional control of radionuclide retention in hollandite‐based ceramic waste forms for Cs‐immobilization

Journal Article · 2018 · Journal of the American Ceramic Society · OSTI ID:1508181

Zhao, Mingyang; Xu, Yun; Shuller‐Nickles, Lindsay; +7 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Annealing (metallurgy)
Ceramics
Materials
Physical and chemical processes
X-ray absorption near edge spectroscopy

Title: Effect of Synthetic Method and Annealing Temperature on the Structure of Hollandite-Type Oxides

Citation Formats

References (51)

Cited By (2)

Similar Records

Related Subjects