Si 3 N 4 @RGO Hybrids for Epoxy Coatings With Enhanced Anticorrosion Performance
Abstract
The reduced graphene oxide (RGO)‐encapsulated functionalized silicon nitride hybrids (f‐Si 3 N 4 @RGO) were fabricated from sodium borohydride reduction of electrostatically assembled f‐Si 3 N 4 @GO hybrids with the help of silane coupling agent. The waterborne epoxy coating with 2 wt% f‐Si 3 N 4 @RGO was prepared by a room temperature curing process. The corrosion resistance properties of the coating were investigated. In the f‐Si 3 N 4 @RGO/epoxy coating, the unique structure of f‐Si 3 N 4 particles firmly embedded in the RGO sheets could effectively prevent the agglomeration of graphene in the epoxy and construct shielding barrier at the coating‐tinplate interface. The results showed that the anticorrosive performance of the coating was significantly enhanced by incorporation of f‐Si 3 N 4 @RGO hybrids to epoxy. This superior f‐Si 3 N 4 @RGO structure with its prominent dispersion could make full use of the enhancement effect of the different components and thus endowed the waterborne epoxy coating with good shielding properties. POLYM. COMPOS., 2018. © 2018 Society of Plastics Engineers
- Authors:
-
- School of Materials Science and Engineering University of Jinan Jinan 250022 People's Republic of China
- Library University of Jinan Jinan 250022 People's Republic of China
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1484535
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Polymer Composites
- Additional Journal Information:
- Journal Name: Polymer Composites Journal Volume: 40 Journal Issue: 5; Journal ID: ISSN 0272-8397
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Ge, Heyi, Wang, Ting, and Cheng, Shilin. Si 3 N 4 @RGO Hybrids for Epoxy Coatings With Enhanced Anticorrosion Performance. United States: N. p., 2018.
Web. doi:10.1002/pc.24986.
Ge, Heyi, Wang, Ting, & Cheng, Shilin. Si 3 N 4 @RGO Hybrids for Epoxy Coatings With Enhanced Anticorrosion Performance. United States. https://doi.org/10.1002/pc.24986
Ge, Heyi, Wang, Ting, and Cheng, Shilin. Tue .
"Si 3 N 4 @RGO Hybrids for Epoxy Coatings With Enhanced Anticorrosion Performance". United States. https://doi.org/10.1002/pc.24986.
@article{osti_1484535,
title = {Si 3 N 4 @RGO Hybrids for Epoxy Coatings With Enhanced Anticorrosion Performance},
author = {Ge, Heyi and Wang, Ting and Cheng, Shilin},
abstractNote = {The reduced graphene oxide (RGO)‐encapsulated functionalized silicon nitride hybrids (f‐Si 3 N 4 @RGO) were fabricated from sodium borohydride reduction of electrostatically assembled f‐Si 3 N 4 @GO hybrids with the help of silane coupling agent. The waterborne epoxy coating with 2 wt% f‐Si 3 N 4 @RGO was prepared by a room temperature curing process. The corrosion resistance properties of the coating were investigated. In the f‐Si 3 N 4 @RGO/epoxy coating, the unique structure of f‐Si 3 N 4 particles firmly embedded in the RGO sheets could effectively prevent the agglomeration of graphene in the epoxy and construct shielding barrier at the coating‐tinplate interface. The results showed that the anticorrosive performance of the coating was significantly enhanced by incorporation of f‐Si 3 N 4 @RGO hybrids to epoxy. This superior f‐Si 3 N 4 @RGO structure with its prominent dispersion could make full use of the enhancement effect of the different components and thus endowed the waterborne epoxy coating with good shielding properties. POLYM. COMPOS., 2018. © 2018 Society of Plastics Engineers},
doi = {10.1002/pc.24986},
journal = {Polymer Composites},
number = 5,
volume = 40,
place = {United States},
year = {2018},
month = {12}
}
https://doi.org/10.1002/pc.24986
Web of Science
Works referenced in this record:
Self-assembled graphene oxide microcapsules in Pickering emulsions for self-healing waterborne polyurethane coatings
journal, October 2017
- Li, Jing; Feng, Qingkang; Cui, Jincan
- Composites Science and Technology, Vol. 151
Colloidal Suspensions of Highly Reduced Graphene Oxide in a Wide Variety of Organic Solvents
journal, April 2009
- Park, Sungjin; An, Jinho; Jung, Inhwa
- Nano Letters, Vol. 9, Issue 4, p. 1593-1597
Preparation of graphene oxide modified by titanium dioxide to enhance the anti-corrosion performance of epoxy coatings
journal, August 2015
- Yu, Zongxue; Di, Haihui; Ma, Yu
- Surface and Coatings Technology, Vol. 276
Hydrothermal synthesis of CuO/functionalized graphene nanocomposites for dye degradation
journal, February 2013
- Yusoff, N.; Huang, N. M.; Muhamad, M. R.
- Materials Letters, Vol. 93
Enhancement of corrosion protection of mild steel by chitosan/ZnO nanoparticle composite membranes
journal, July 2015
- John, Sam; Joseph, Abraham; Jose, Ajith James
- Progress in Organic Coatings, Vol. 84
Coating, mechanical and thermal properties of epoxy toluene oligomer modified epoxy resin/sepiolite composites
journal, September 2012
- Ahmetli, Gulnare; Deveci, Huseyin; Soydal, Ulku
- Progress in Organic Coatings, Vol. 75, Issue 1-2
Corrosion of copper in seawater and its aerosols in a tropical island
journal, February 2005
- Núñez, L.; Reguera, E.; Corvo, F.
- Corrosion Science, Vol. 47, Issue 2
The chemistry of graphene oxide
journal, January 2010
- Dreyer, Daniel R.; Park, Sungjin; Bielawski, Christopher W.
- Chem. Soc. Rev., Vol. 39, Issue 1
Epoxy/graphene platelets nanocomposites with two levels of interface strength
journal, March 2011
- Zaman, Izzuddin; Phan, Tam Thanh; Kuan, Hsu-Chiang
- Polymer, Vol. 52, Issue 7
Preparation and investigation of anticorrosion properties of the water-based epoxy-clay nanocoating modified by Na+-MMT and Cloisite 30B
journal, July 2012
- Bagherzadeh, M. R.; Mousavinejad, T.
- Progress in Organic Coatings, Vol. 74, Issue 3
Preparation and characterization of Jatropha Curcas oil based alkyd resin suitable for surface coating
journal, July 2012
- Boruah, Monalisha; Gogoi, Pronob; Adhikari, Binoy
- Progress in Organic Coatings, Vol. 74, Issue 3
Permeability of polymers in protective organic coatings
journal, June 2004
- Sangaj, Nivedita S.; Malshe, V. C.
- Progress in Organic Coatings, Vol. 50, Issue 1
Processable aqueous dispersions of graphene nanosheets
journal, January 2008
- Li, Dan; Müller, Marc B.; Gilje, Scott
- Nature Nanotechnology, Vol. 3, Issue 2
Effect of nanoparticles on the anticorrosion and mechanical properties of epoxy coating
journal, October 2009
- Shi, Xianming; Nguyen, Tuan Anh; Suo, Zhiyong
- Surface and Coatings Technology, Vol. 204, Issue 3
Graphene materials with different structures prepared from the same graphite by the Hummers and Brodie methods
journal, December 2013
- Botas, Cristina; Álvarez, Patricia; Blanco, Patricia
- Carbon, Vol. 65
How a bio-based epoxy monomer enhanced the properties of diglycidyl ether of bisphenol A (DGEBA)/graphene composites
journal, January 2013
- Cao, Lijun; Liu, Xiaoqing; Na, Haining
- Journal of Materials Chemistry A, Vol. 1, Issue 16
Modifying glass fibers with graphene oxide: Towards high-performance polymer composites
journal, June 2014
- Chen, Juan; Zhao, Dan; Jin, Xin
- Composites Science and Technology, Vol. 97
Core–shell SiO 2 @RGO hybrids for epoxy composites with low percolation threshold and enhanced thermo-mechanical properties
journal, January 2014
- Huang, Liang; Zhu, Pengli; Li, Gang
- J. Mater. Chem. A, Vol. 2, Issue 43
Formulation and evaluation of nano-structured polymeric coatings for corrosion protection
journal, November 2007
- Aglan, Anwar; Allie, Aldinton; Ludwick, Adriane
- Surface and Coatings Technology, Vol. 202, Issue 2
Process dependent graphene/MnO2 composites for supercapacitors
journal, August 2013
- Kim, Myeongjin; Hwang, Yongseon; Kim, Jooheon
- Chemical Engineering Journal, Vol. 230
The attachment of Fe3O4 nanoparticles to graphene oxide by covalent bonding
journal, September 2010
- He, Fuan; Fan, Jintu; Ma, Dong
- Carbon, Vol. 48, Issue 11
Room-temperature cured hydrophobic epoxy/graphene composites as corrosion inhibitor for cold-rolled steel
journal, January 2014
- Chang, Kung-Chin; Hsu, Min-Hsiang; Lu, Hsin-I
- Carbon, Vol. 66
Super Gas Barrier and Selectivity of Graphene Oxide-Polymer Multilayer Thin Films
journal, October 2012
- Yang, You-Hao; Bolling, Laura; Priolo, Morgan A.
- Advanced Materials, Vol. 25, Issue 4
Reinforcement of graphene and its derivatives on the anticorrosive properties of waterborne polyurethane coatings
journal, June 2016
- Li, Jing; Cui, Jincan; Yang, Jiayun
- Composites Science and Technology, Vol. 129
Synthesis of Graphene and Its Applications: A Review
journal, February 2010
- Choi, Wonbong; Lahiri, Indranil; Seelaboyina, Raghunandan
- Critical Reviews in Solid State and Materials Sciences, Vol. 35, Issue 1
Electrochemical stability and surface analysis of a new alkyd paint with low content of volatile organic compounds
journal, August 2010
- Pirvu, Cristian; Demetrescu, Ioana; Drob, Paula
- Progress in Organic Coatings, Vol. 68, Issue 4
Tuning the Mechanical and Adsorption Properties of Silica with Graphene Oxide
journal, July 2014
- Singh, Vivek K.; Cura, M. Erkin; Liu, Xuwen
- ChemPlusChem, Vol. 79, Issue 10
Development of poly(isobutylene-co-isoprene)/reduced graphene oxide nanocomposites for barrier, dielectric and sensingapplications
journal, April 2013
- Kumar, Sadasivuni Kishor; Castro, Mickael; Saiter, Allisson
- Materials Letters, Vol. 96
Enhanced Epoxy/Silica Composites Mechanical Properties by Introducing Graphene Oxide to the Interface
journal, July 2012
- Chen, Li; Chai, Songgang; Liu, Kai
- ACS Applied Materials & Interfaces, Vol. 4, Issue 8
One-Step Electrochemical Synthesis of Graphene/Polyaniline Composite Film and Its Applications
journal, June 2011
- Feng, Xiao-Miao; Li, Rui-Mei; Ma, Yan-Wen
- Advanced Functional Materials, Vol. 21, Issue 15
Nanoporous titania interlayer as reservoir of corrosion inhibitors for coatings with self-healing ability
journal, February 2007
- Lamaka, S. V.; Zheludkevich, M. L.; Yasakau, K. A.
- Progress in Organic Coatings, Vol. 58, Issue 2-3
Fabrication of silica-decorated graphene oxide nanohybrids and the properties of composite epoxy coatings research
journal, January 2016
- Ma, Yu; Di, Haihui; Yu, Zongxue
- Applied Surface Science, Vol. 360
A study on the corrosion inhibition properties of silane-modified Fe2O3 nanoparticle on mild steel and its effect on the anticorrosion properties of the polyurethane coating
journal, January 2015
- Palimi, M. J.; Rostami, M.; Mahdavian, M.
- Journal of Coatings Technology and Research, Vol. 12, Issue 2
A novel “gel–sol” strategy to synthesize TiO2 nanorod combining reduced graphene oxide composites
journal, September 2013
- Shao, Lu; Quan, Shuai; Liu, Yang
- Materials Letters, Vol. 107
Electrochemical impedance spectroscopy (EIS) study of nano-alumina modified alkyd based waterborne coatings
journal, May 2012
- Dhoke, Shailesh K.; Khanna, A. S.
- Progress in Organic Coatings, Vol. 74, Issue 1
Raman Scattering from High-Frequency Phonons in Supported n -Graphene Layer Films
journal, December 2006
- Gupta, A.; Chen, G.; Joshi, P.
- Nano Letters, Vol. 6, Issue 12
Fabrication of graphene oxide–alumina hybrids to reinforce the anti-corrosion performance of composite epoxy coatings
journal, October 2015
- Yu, Zongxue; Di, Haihui; Ma, Yu
- Applied Surface Science, Vol. 351
Graphene/Polyurethane Nanocomposites for Improved Gas Barrier and Electrical Conductivity
journal, June 2010
- Kim, Hyunwoo; Miura, Yutaka; Macosko, Christopher W.
- Chemistry of Materials, Vol. 22, Issue 11
Laboratory scale investigation into the corrosion of copper in a sulphur-containing environment
journal, October 2011
- Thethwayo, B. M.; Garbers-Craig, A. M.
- Corrosion Science, Vol. 53, Issue 10
Melt Blending In situ Enhances the Interaction between Polystyrene and Graphene through π–π Stacking
journal, June 2011
- Shen, Bin; Zhai, Wentao; Chen, Cao
- ACS Applied Materials & Interfaces, Vol. 3, Issue 8
Weathering steels: From empirical development to scientific design. A review
journal, June 2014
- Morcillo, M.; Díaz, I.; Chico, B.
- Corrosion Science, Vol. 83
Efficient Reduction of Graphite Oxide by Sodium Borohydride and Its Effect on Electrical Conductance
journal, June 2009
- Shin, Hyeon‐Jin; Kim, Ki Kang; Benayad, Anass
- Advanced Functional Materials, Vol. 19, Issue 12
Preparation of a durable superhydrophobic membrane by electrospinning poly (vinylidene fluoride) (PVDF) mixed with epoxy–siloxane modified SiO2 nanoparticles: A possible route to superhydrophobic surfaces with low water sliding angle and high water contact angle
journal, July 2011
- Wang, Shuai; Li, Yapeng; Fei, Xiaoliang
- Journal of Colloid and Interface Science, Vol. 359, Issue 2
Enhanced anticorrosion coatings prepared from incorporation of well-dispersed silica nanoparticles into fluorinated polyimide matrix
journal, November 2010
- Hung, Wei-I; Weng, Chang-Jian; Lin, Yen-Hao
- Polymer Composites, Vol. 31, Issue 12
Crumpled Graphene Nanosheets as Highly Effective Barrier Property Enhancers
journal, September 2010
- Compton, Owen C.; Kim, Soyoung; Pierre, Cynthia
- Advanced Materials, Vol. 22, Issue 42
Alkyd-clay nanocomposites for improved anticorrosion and mechanical performance of coating
journal, February 2017
- Dhirde, Priyanka G.; Chada, Venkata G. R.; Mallik, B. P.
- Polymer Composites, Vol. 39, Issue 8
Synthesis and anticorrosive properties of electroactive polyimide/SiO 2 composites
journal, October 2013
- Chou, Yi-Chen; Lee, Pei-Chi; Hsu, Tzu-Fang
- Polymer Composites, Vol. 35, Issue 3
In situ one-pot synthesis of graphene–polyaniline nanofiber composite for high-performance electrochemical capacitors
journal, July 2014
- Jin, Yuhong; Fang, Mou; Jia, Mengqiu
- Applied Surface Science, Vol. 308
Graphene based materials: Past, present and future
journal, October 2011
- Singh, Virendra; Joung, Daeha; Zhai, Lei
- Progress in Materials Science, Vol. 56, Issue 8
Raman Spectrum of Graphene and Graphene Layers
journal, October 2006
- Ferrari, A. C.; Meyer, J. C.; Scardaci, V.
- Physical Review Letters, Vol. 97, Issue 18, Article No. 187401
Passivation of microbial corrosion using a graphene coating
journal, May 2013
- Krishnamurthy, A.; Gadhamshetty, V.; Mukherjee, R.
- Carbon, Vol. 56
Corrosion resistance and long-term durability of super-hydrophobic nickel film prepared by electrodeposition process
journal, June 2014
- Khorsand, S.; Raeissi, K.; Ashrafizadeh, F.
- Applied Surface Science, Vol. 305
Novel, one-step, chromate-free coatings containing anticorrosion pigments for metals—An overview and mechanistic study
journal, February 2007
- Seth, A.; van Ooij, W. J.; Puomi, P.
- Progress in Organic Coatings, Vol. 58, Issue 2-3