Si 3 N 4 @RGO Hybrids for Epoxy Coatings With Enhanced Anticorrosion Performance
Abstract
The reduced graphene oxide (RGO)‐encapsulated functionalized silicon nitride hybrids (f‐Si 3 N 4 @RGO) were fabricated from sodium borohydride reduction of electrostatically assembled f‐Si 3 N 4 @GO hybrids with the help of silane coupling agent. The waterborne epoxy coating with 2 wt% f‐Si 3 N 4 @RGO was prepared by a room temperature curing process. The corrosion resistance properties of the coating were investigated. In the f‐Si 3 N 4 @RGO/epoxy coating, the unique structure of f‐Si 3 N 4 particles firmly embedded in the RGO sheets could effectively prevent the agglomeration of graphene in the epoxy and construct shielding barrier at the coating‐tinplate interface. The results showed that the anticorrosive performance of the coating was significantly enhanced by incorporation of f‐Si 3 N 4 @RGO hybrids to epoxy. This superior f‐Si 3 N 4 @RGO structure with its prominent dispersion could make full use of the enhancement effect of the different components and thus endowed the waterborne epoxy coating with good shielding properties. POLYM. COMPOS., 2018. © 2018 Society of Plastics Engineers
- Authors:
-
[1];
- School of Materials Science and Engineering University of Jinan Jinan 250022 People's Republic of China
- Library University of Jinan Jinan 250022 People's Republic of China
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1484535
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Polymer Composites
- Additional Journal Information:
- Journal Name: Polymer Composites Journal Volume: 40 Journal Issue: 5; Journal ID: ISSN 0272-8397
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Ge, Heyi, Wang, Ting, and Cheng, Shilin. Si 3 N 4 @RGO Hybrids for Epoxy Coatings With Enhanced Anticorrosion Performance. United States: N. p., 2018.
Web. doi:10.1002/pc.24986.
Ge, Heyi, Wang, Ting, & Cheng, Shilin. Si 3 N 4 @RGO Hybrids for Epoxy Coatings With Enhanced Anticorrosion Performance. United States. https://doi.org/10.1002/pc.24986
Ge, Heyi, Wang, Ting, and Cheng, Shilin. Tue .
"Si 3 N 4 @RGO Hybrids for Epoxy Coatings With Enhanced Anticorrosion Performance". United States. https://doi.org/10.1002/pc.24986.
@article{osti_1484535,
title = {Si 3 N 4 @RGO Hybrids for Epoxy Coatings With Enhanced Anticorrosion Performance},
author = {Ge, Heyi and Wang, Ting and Cheng, Shilin},
abstractNote = {The reduced graphene oxide (RGO)‐encapsulated functionalized silicon nitride hybrids (f‐Si 3 N 4 @RGO) were fabricated from sodium borohydride reduction of electrostatically assembled f‐Si 3 N 4 @GO hybrids with the help of silane coupling agent. The waterborne epoxy coating with 2 wt% f‐Si 3 N 4 @RGO was prepared by a room temperature curing process. The corrosion resistance properties of the coating were investigated. In the f‐Si 3 N 4 @RGO/epoxy coating, the unique structure of f‐Si 3 N 4 particles firmly embedded in the RGO sheets could effectively prevent the agglomeration of graphene in the epoxy and construct shielding barrier at the coating‐tinplate interface. The results showed that the anticorrosive performance of the coating was significantly enhanced by incorporation of f‐Si 3 N 4 @RGO hybrids to epoxy. This superior f‐Si 3 N 4 @RGO structure with its prominent dispersion could make full use of the enhancement effect of the different components and thus endowed the waterborne epoxy coating with good shielding properties. POLYM. COMPOS., 2018. © 2018 Society of Plastics Engineers},
doi = {10.1002/pc.24986},
journal = {Polymer Composites},
number = 5,
volume = 40,
place = {United States},
year = {2018},
month = {12}
}
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