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Title: Binary Superlattice Design by Controlling DNA-Mediated Interactions

Abstract

Most binary superlattices created using DNA functionalization rely on particle size differences to achieve compositional order and structural diversity. Here we study two-dimensional (2D) assembly of DNA-functionalized micron-sized particles (DFPs), and employ a strategy that leverages the tunable disparity in interparticle interactions, and thus enthalpic driving forces, to open new avenues for design of binary superlattices that do not rely on the ability to tune particle size (i.e., entropic driving forces). Our strategy employs tailored blends of complementary strands of ssDNA to control interparticle interactions between micron-sized silica particles in a binary mixture to create compositionally diverse 2D lattices. We show that the particle arrangement can be further controlled by changing the stoichiometry of the binary mixture in certain cases. With this approach, we demonstrate the ability to program the particle assembly into square, pentagonal, and hexagonal lattices. In addition, different particle types can be compositionally ordered in square checkerboard and hexagonal–alternating string, honeycomb, and Kagome arrangements.

Authors:
 [1];  [1];  [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Lehigh Univ., Bethlehem, PA (United States). Dept. of Chemical and Biomolecular Engineering
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1484291
Grant/Contract Number:  
[SC0013979; AC02-05CH11231]
Resource Type:
Accepted Manuscript
Journal Name:
Langmuir
Additional Journal Information:
[ Journal Volume: 34; Journal Issue: 3]; Journal ID: ISSN 0743-7463
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 59 BASIC BIOLOGICAL SCIENCES

Citation Formats

Song, Minseok, Ding, Yajun, Zerze, Hasan, Snyder, Mark A., and Mittal, Jeetain. Binary Superlattice Design by Controlling DNA-Mediated Interactions. United States: N. p., 2017. Web. doi:10.1021/acs.langmuir.7b02835.
Song, Minseok, Ding, Yajun, Zerze, Hasan, Snyder, Mark A., & Mittal, Jeetain. Binary Superlattice Design by Controlling DNA-Mediated Interactions. United States. doi:10.1021/acs.langmuir.7b02835.
Song, Minseok, Ding, Yajun, Zerze, Hasan, Snyder, Mark A., and Mittal, Jeetain. Wed . "Binary Superlattice Design by Controlling DNA-Mediated Interactions". United States. doi:10.1021/acs.langmuir.7b02835. https://www.osti.gov/servlets/purl/1484291.
@article{osti_1484291,
title = {Binary Superlattice Design by Controlling DNA-Mediated Interactions},
author = {Song, Minseok and Ding, Yajun and Zerze, Hasan and Snyder, Mark A. and Mittal, Jeetain},
abstractNote = {Most binary superlattices created using DNA functionalization rely on particle size differences to achieve compositional order and structural diversity. Here we study two-dimensional (2D) assembly of DNA-functionalized micron-sized particles (DFPs), and employ a strategy that leverages the tunable disparity in interparticle interactions, and thus enthalpic driving forces, to open new avenues for design of binary superlattices that do not rely on the ability to tune particle size (i.e., entropic driving forces). Our strategy employs tailored blends of complementary strands of ssDNA to control interparticle interactions between micron-sized silica particles in a binary mixture to create compositionally diverse 2D lattices. We show that the particle arrangement can be further controlled by changing the stoichiometry of the binary mixture in certain cases. With this approach, we demonstrate the ability to program the particle assembly into square, pentagonal, and hexagonal lattices. In addition, different particle types can be compositionally ordered in square checkerboard and hexagonal–alternating string, honeycomb, and Kagome arrangements.},
doi = {10.1021/acs.langmuir.7b02835},
journal = {Langmuir},
number = [3],
volume = [34],
place = {United States},
year = {2017},
month = {10}
}

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