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Title: Empowering multicomponent cathode materials for sodium ion batteries by exploring three-dimensional compositional heterogeneities

Abstract

Affordable sodium ion batteries hold great promise for revolutionizing stationary energy storage technologies. Sodium layered cathode materials are usually multicomponent transition metal (TM) oxides and each TM plays a unique role in the operating cathode chemistry, e.g., redox activity, structural stabilization. Engineering the three-dimensional (3D) distribution of TM cations in individual cathode particles can take advantage of a depth-dependent charging mechanism and enable a path towards tuning local TM–O chemical environments and building resilience against cathode–electrolyte interfacial reactions that are responsible for capacity fading, voltage decay and safety hazards. In this study, we create 3D compositional heterogeneity in a ternary and biphasic (O3–P3) sodium layered cathode material (Na0.9Cu0.2Fe0.28Mn0.52O2). The cells containing this material deliver stable voltage profiles, and discharge capacities of 125 mA h g–1 at C/10 with almost no capacity fading after 100 cycles and 75 mA h g–1 at 1C with negligible capacity fading after 200 cycles. The direct performance comparison shows that this material outperforms other materials with similar global compositions but different mesoscale chemical distributions. Synchrotron X-ray spectroscopy/imaging and density functional theory studies reveal depth-dependent chemical environments due to changes to factors such as charge compensation and strength of orbital hybridization. Finally, 3D spectroscopic tomography illuminatesmore » the path towards optimizing multicomponent sodium layered cathode materials, to prevent the migration of TMs upon prolonged cycling. Furthermore, the study reports an inaugural effort of multifaceted and counterintuitive investigation of sodium layered cathode materials and strongly implies that there is plenty of room at the bottom by tuning nano/meso scale chemical distributions for stable cathode chemistry.« less

Authors:
ORCiD logo [1];  [2];  [3];  [1];  [4];  [1];  [5];  [2];  [4];  [4];  [2];  [2]; ORCiD logo [3]; ORCiD logo [2]; ORCiD logo [1]
+ Show Author Affiliations
  1. Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
  2. SLAC National Accelerator Lab., Menlo Park, CA (United States)
  3. Xiamen Univ., Xiamen (China); Xiamen Univ. Malaysia, Sepang (Malaysia)
  4. Argonne National Lab. (ANL), Argonne, IL (United States)
  5. City Univ. of Hong Kong, Kowloon (Hong Kong)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC); Virginia Tech University; National Natural Science Foundation of China (NNSFC)
OSTI Identifier:
1484286
Alternate Identifier(s):
OSTI ID: 1457067
Grant/Contract Number:  
AC02-06CH11357; AC02-76SF00515
Resource Type:
Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Volume: 11; Journal Issue: 9; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Rahman, Muhammad Mominur, Xu, Yahong, Cheng, Hao, Shi, Qianli, Kou, Ronghui, Mu, Linqin, Liu, Qi, Xia, Sihao, Xiao, Xianghui, Sun, Cheng -Jun, Sokaras, Dimosthenis, Nordlund, Dennis, Zheng, Jin -Cheng, Liu, Yijin, and Lin, Feng. Empowering multicomponent cathode materials for sodium ion batteries by exploring three-dimensional compositional heterogeneities. United States: N. p., 2018. Web. doi:10.1039/c8ee00309b.
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Rahman, Muhammad Mominur, Xu, Yahong, Cheng, Hao, Shi, Qianli, Kou, Ronghui, Mu, Linqin, Liu, Qi, Xia, Sihao, Xiao, Xianghui, Sun, Cheng -Jun, Sokaras, Dimosthenis, Nordlund, Dennis, Zheng, Jin -Cheng, Liu, Yijin, & Lin, Feng. Empowering multicomponent cathode materials for sodium ion batteries by exploring three-dimensional compositional heterogeneities. United States. doi:https://doi.org/10.1039/c8ee00309b
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Rahman, Muhammad Mominur, Xu, Yahong, Cheng, Hao, Shi, Qianli, Kou, Ronghui, Mu, Linqin, Liu, Qi, Xia, Sihao, Xiao, Xianghui, Sun, Cheng -Jun, Sokaras, Dimosthenis, Nordlund, Dennis, Zheng, Jin -Cheng, Liu, Yijin, and Lin, Feng. Mon . "Empowering multicomponent cathode materials for sodium ion batteries by exploring three-dimensional compositional heterogeneities". United States. doi:https://doi.org/10.1039/c8ee00309b. https://www.osti.gov/servlets/purl/1484286.
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@article{osti_1484286,
title = {Empowering multicomponent cathode materials for sodium ion batteries by exploring three-dimensional compositional heterogeneities},
author = {Rahman, Muhammad Mominur and Xu, Yahong and Cheng, Hao and Shi, Qianli and Kou, Ronghui and Mu, Linqin and Liu, Qi and Xia, Sihao and Xiao, Xianghui and Sun, Cheng -Jun and Sokaras, Dimosthenis and Nordlund, Dennis and Zheng, Jin -Cheng and Liu, Yijin and Lin, Feng},
abstractNote = {Affordable sodium ion batteries hold great promise for revolutionizing stationary energy storage technologies. Sodium layered cathode materials are usually multicomponent transition metal (TM) oxides and each TM plays a unique role in the operating cathode chemistry, e.g., redox activity, structural stabilization. Engineering the three-dimensional (3D) distribution of TM cations in individual cathode particles can take advantage of a depth-dependent charging mechanism and enable a path towards tuning local TM–O chemical environments and building resilience against cathode–electrolyte interfacial reactions that are responsible for capacity fading, voltage decay and safety hazards. In this study, we create 3D compositional heterogeneity in a ternary and biphasic (O3–P3) sodium layered cathode material (Na0.9Cu0.2Fe0.28Mn0.52O2). The cells containing this material deliver stable voltage profiles, and discharge capacities of 125 mA h g–1 at C/10 with almost no capacity fading after 100 cycles and 75 mA h g–1 at 1C with negligible capacity fading after 200 cycles. The direct performance comparison shows that this material outperforms other materials with similar global compositions but different mesoscale chemical distributions. Synchrotron X-ray spectroscopy/imaging and density functional theory studies reveal depth-dependent chemical environments due to changes to factors such as charge compensation and strength of orbital hybridization. Finally, 3D spectroscopic tomography illuminates the path towards optimizing multicomponent sodium layered cathode materials, to prevent the migration of TMs upon prolonged cycling. Furthermore, the study reports an inaugural effort of multifaceted and counterintuitive investigation of sodium layered cathode materials and strongly implies that there is plenty of room at the bottom by tuning nano/meso scale chemical distributions for stable cathode chemistry.},
doi = {10.1039/c8ee00309b},
journal = {Energy & Environmental Science},
number = 9,
volume = 11,
place = {United States},
year = {2018},
month = {6}
}
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DOI:  https://doi.org/10.1039/c8ee00309b
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Figures / Tables:

Figure 1 Figure 1: Physicochemical characterization of the pristine CFM-Cu powder. (a) XRD pattern of the pristine CFM-Cu powder. (b) SEM micrographs of the pristine CFM-Cu powder. (c) Soft XAS spectra (TEY mode) of the pristine CFM-Cu powder, where the peak labeled with “*” originated from the surface carbonate species.
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Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Electrochemical investigation of the P2–NaxCoO2 phase diagram
journal, December 2010

  • Berthelot, R.; Carlier, D.; Delmas, C.
  • Nature Materials, Vol. 10, Issue 1
  • DOI: 10.1038/nmat2920

Toward Na-ion Batteries—Synthesis and Characterization of a Novel High Capacity Na Ion Intercalation Material
journal, January 2013

  • Buchholz, Daniel; Moretti, Arianna; Kloepsch, Richard
  • Chemistry of Materials, Vol. 25, Issue 2
  • DOI: 10.1021/cm3029615

Generating derivative structures at a fixed concentration
journal, June 2012

Measurements of Interdiffusion Coefficients of Transition Metals in Layered Li–Ni–Mn–Co Oxide Core–Shell Materials during Sintering
journal, November 2015

Lithium Batteries and Cathode Materials
journal, October 2004

  • Whittingham, M. Stanley
  • Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302
  • DOI: 10.1021/cr020731c

Layered Na x Cr x Ti 1– x O 2 as Bifunctional Electrode Materials for Rechargeable Sodium Batteries
journal, September 2016

Study of the Cathode–Electrolyte Interface of LiMn[sub 1.5]Ni[sub 0.5]O[sub 4] Synthesized by a Sol–Gel Method for Li-Ion Batteries
journal, January 2010

  • Duncan, Hugues; Abu-Lebdeh, Yaser; Davidson, Isobel J.
  • Journal of The Electrochemical Society, Vol. 157, Issue 4
  • DOI: 10.1149/1.3321710

O3-type Na[Fe 1/3 Ni 1/3 Ti 1/3 ]O 2 cathode material for rechargeable sodium ion batteries
journal, January 2016

  • Wang, Jun; He, Xin; Zhou, Dong
  • Journal of Materials Chemistry A, Vol. 4, Issue 9
  • DOI: 10.1039/C5TA10520J

Surface transformation by a “cocktail” solvent enables stable cathode materials for sodium ion batteries
journal, January 2018

  • Mu, Linqin; Rahman, Muhammad Mominur; Zhang, Yan
  • Journal of Materials Chemistry A, Vol. 6, Issue 6
  • DOI: 10.1039/C7TA08410B

Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries
journal, March 2014

  • Lin, Feng; Markus, Isaac M.; Nordlund, Dennis
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4529

Study on the Reversible Electrode Reaction of Na 1– x Ni 0.5 Mn 0.5 O 2 for a Rechargeable Sodium-Ion Battery
journal, May 2012

  • Komaba, Shinichi; Yabuuchi, Naoaki; Nakayama, Tetsuri
  • Inorganic Chemistry, Vol. 51, Issue 11
  • DOI: 10.1021/ic300357d

Metal segregation in hierarchically structured cathode materials for high-energy lithium batteries
journal, January 2016

Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights
journal, October 2015

  • Gauthier, Magali; Carney, Thomas J.; Grimaud, Alexis
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 22
  • DOI: 10.1021/acs.jpclett.5b01727

Synthesis and Characterization of Li[(Ni 0.8 Co 0.1 Mn 0.1 ) 0.8 (Ni 0.5 Mn 0.5 ) 0.2 ]O 2 with the Microscale Core−Shell Structure as the Positive Electrode Material for Lithium Batteries
journal, September 2005

  • Sun, Yang-Kook; Myung, Seung-Taek; Kim, Myung-Hoon
  • Journal of the American Chemical Society, Vol. 127, Issue 38
  • DOI: 10.1021/ja053675g

Mechanical and Structural Degradation of LiNi x Mn y Co z O 2 Cathode in Li-Ion Batteries: An Experimental Study
journal, January 2017

  • Xu, Rong; Sun, Hong; de Vasconcelos, Luize Scalco
  • Journal of The Electrochemical Society, Vol. 164, Issue 13
  • DOI: 10.1149/2.1751713jes

The effects of TiO2 coating on the electrochemical performance of Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode material for lithium-ion battery
journal, September 2008

Future generations of cathode materials: an automotive industry perspective
journal, January 2015

  • Andre, Dave; Kim, Sung-Jin; Lamp, Peter
  • Journal of Materials Chemistry A, Vol. 3, Issue 13
  • DOI: 10.1039/C5TA00361J

Excellent Comprehensive Performance of Na-Based Layered Oxide Benefiting from the Synergetic Contributions of Multimetal Ions
journal, April 2017

  • Yao, Hu-Rong; Wang, Peng-Fei; Wang, Yi
  • Advanced Energy Materials, Vol. 7, Issue 15
  • DOI: 10.1002/aenm.201700189

Phase retrieval using polychromatic illumination for transmission X-ray microscopy
journal, January 2011

  • Liu, Yijin; Andrews, Joy C.; Wang, Junyue
  • Optics Express, Vol. 19, Issue 2
  • DOI: 10.1364/OE.19.000540

Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study
journal, January 1998

  • Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y.
  • Physical Review B, Vol. 57, Issue 3, p. 1505-1509
  • DOI: 10.1103/PhysRevB.57.1505

Na-ion batteries, recent advances and present challenges to become low cost energy storage systems
journal, January 2012

  • Palomares, Verónica; Serras, Paula; Villaluenga, Irune
  • Energy & Environmental Science, Vol. 5, Issue 3
  • DOI: 10.1039/c2ee02781j

A fast and robust algorithm for Bader decomposition of charge density
journal, June 2006

Role of surface coating on cathode materials for lithium-ion batteries
journal, January 2010

  • Chen, Zonghai; Qin, Yan; Amine, Khalil
  • Journal of Materials Chemistry, Vol. 20, Issue 36, p. 7606-7612
  • DOI: 10.1039/c0jm00154f

Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
journal, January 2013

  • Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan
  • Energy & Environmental Science, Vol. 6, Issue 8
  • DOI: 10.1039/c3ee40847g

Emerging Prototype Sodium-Ion Full Cells with Nanostructured Electrode Materials
journal, April 2017

X-ray Absorption Edge Spectroscopy and Computational Studies on LCuO 2 Species:  Superoxide−Cu II versus Peroxide−Cu III Bonding
journal, June 2006

  • Sarangi, Ritimukta; Aboelella, Nermeen; Fujisawa, Kiyoshi
  • Journal of the American Chemical Society, Vol. 128, Issue 25
  • DOI: 10.1021/ja0615223

Activation of Sodium Storage Sites in Prussian Blue Analogues via Surface Etching
journal, July 2017

Nanoscale Morphological and Chemical Changes of High Voltage Lithium–Manganese Rich NMC Composite Cathodes with Cycling
journal, July 2014

  • Yang, Feifei; Liu, Yijin; Martha, Surendra K.
  • Nano Letters, Vol. 14, Issue 8
  • DOI: 10.1021/nl502090z

Residual Lithium Carbonate Predominantly Accounts for First Cycle CO 2 and CO Outgassing of Li-Stoichiometric and Li-Rich Layered Transition-Metal Oxides
journal, November 2017

  • Renfrew, Sara E.; McCloskey, Bryan D.
  • Journal of the American Chemical Society, Vol. 139, Issue 49
  • DOI: 10.1021/jacs.7b08461

Phase Transformation and Lithiation Effect on Electronic Structure of Li x FePO 4 : An In-Depth Study by Soft X-ray and Simulations
journal, August 2012

  • Liu, Xiaosong; Liu, Jun; Qiao, Ruimin
  • Journal of the American Chemical Society, Vol. 134, Issue 33
  • DOI: 10.1021/ja303225e

Profiling the nanoscale gradient in stoichiometric layered cathode particles for lithium-ion batteries
journal, January 2014

  • Lin, Feng; Nordlund, Dennis; Markus, Isaac M.
  • Energy & Environmental Science, Vol. 7, Issue 9
  • DOI: 10.1039/C4EE01400F

Radially aligned hierarchical columnar structure as a cathode material for high energy density sodium-ion batteries
journal, April 2015

  • Hwang, Jang-Yeon; Oh, Seung-Min; Myung, Seung-Taek
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7865

Ultimate Limits to Intercalation Reactions for Lithium Batteries
journal, October 2014

  • Whittingham, M. Stanley
  • Chemical Reviews, Vol. 114, Issue 23
  • DOI: 10.1021/cr5003003

High-Performance P2-Type Na 2/3 (Mn 1/2 Fe 1/4 Co 1/4 )O 2 Cathode Material with Superior Rate Capability for Na-Ion Batteries
journal, September 2015

Decomposition of LiPF 6 in High Energy Lithium-Ion Batteries Studied with Online Electrochemical Mass Spectrometry
journal, January 2016

  • Guéguen, Aurélie; Streich, Daniel; He, Minglong
  • Journal of The Electrochemical Society, Vol. 163, Issue 6
  • DOI: 10.1149/2.0981606jes

Pseudopotentials for high-throughput DFT calculations
journal, January 2014

Research Development on Sodium-Ion Batteries
journal, October 2014

  • Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
  • Chemical Reviews, Vol. 114, Issue 23
  • DOI: 10.1021/cr500192f

Nickel-Rich Layered Lithium Transition-Metal Oxide for High-Energy Lithium-Ion Batteries
journal, March 2015

  • Liu, Wen; Oh, Pilgun; Liu, Xien
  • Angewandte Chemie International Edition, Vol. 54, Issue 15
  • DOI: 10.1002/anie.201409262

Nanostructured high-energy cathode materials for advanced lithium batteries
journal, October 2012

  • Sun, Yang-Kook; Chen, Zonghai; Noh, Hyung-Joo
  • Nature Materials, Vol. 11, Issue 11
  • DOI: 10.1038/nmat3435

Tailoring the surface properties of LiNi 0.4 Mn 0.4 Co 0.2 O 2 by titanium substitution for improved high voltage cycling performance
journal, January 2015

  • Wolff-Goodrich, Silas; Lin, Feng; Markus, Isaac M.
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 34
  • DOI: 10.1039/C5CP03228H

Electrochemical Properties of Monoclinic NaMnO2
journal, January 2011

  • Ma, Xiaohua; Chen, Hailong; Ceder, Gerbrand
  • Journal of The Electrochemical Society, Vol. 158, Issue 12
  • DOI: 10.1149/2.035112jes

Prototype Sodium-Ion Batteries Using an Air-Stable and Co/Ni-Free O3-Layered Metal Oxide Cathode
journal, October 2015

Orthorhombic Na[sub x]MnO[sub 2] as a Cathode Material for Secondary Sodium and Lithium Polymer Batteries
journal, January 1994

  • Doeff, Marca M.
  • Journal of The Electrochemical Society, Vol. 141, Issue 11
  • DOI: 10.1149/1.2059323

Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells
journal, December 2016

  • Gilbert, James A.; Shkrob, Ilya A.; Abraham, Daniel P.
  • Journal of The Electrochemical Society, Vol. 164, Issue 2
  • DOI: 10.1149/2.1111702jes

High-Energy Cathode Materials (Li 2 MnO 3 –LiMO 2 ) for Lithium-Ion Batteries
journal, March 2013

  • Yu, Haijun; Zhou, Haoshen
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 8
  • DOI: 10.1021/jz400032v

TXM-Wizard : a program for advanced data collection and evaluation in full-field transmission X-ray microscopy
journal, January 2012

  • Liu, Yijin; Meirer, Florian; Williams, Phillip A.
  • Journal of Synchrotron Radiation, Vol. 19, Issue 2
  • DOI: 10.1107/S0909049511049144

A High-Performance Sodium-Ion Full Cell with a Layered Oxide Cathode and a Phosphorous-Based Composite Anode
journal, December 2016

  • Oh, Seung-Min; Oh, Pilgun; Kim, Sang-Ok
  • Journal of The Electrochemical Society, Vol. 164, Issue 2
  • DOI: 10.1149/2.0931702jes

3D elemental sensitive imaging using transmission X-ray microscopy
journal, February 2012

  • Liu, Yijin; Meirer, Florian; Wang, Junyue
  • Analytical and Bioanalytical Chemistry, Vol. 404, Issue 5
  • DOI: 10.1007/s00216-012-5818-9

Nanoscale elemental sensitivity study of Nd 2 Fe 14 B using absorption correlation tomography : Nanoscale Elemental Sensitivity Study of N
journal, August 2013

  • Kao, Thomas L.; Shi, Crystal Y.; Wang, Junyue
  • Microscopy Research and Technique, Vol. 76, Issue 11
  • DOI: 10.1002/jemt.22273

Li-Substituted Co-Free Layered P2/O3 Biphasic Na 0.67 Mn 0.55 Ni 0.25 Ti 0.2– x Li x O 2 as High-Rate-Capability Cathode Materials for Sodium Ion Batteries
journal, April 2016

  • Li, Zheng-Yao; Zhang, Jicheng; Gao, Rui
  • The Journal of Physical Chemistry C, Vol. 120, Issue 17
  • DOI: 10.1021/acs.jpcc.5b11983

NaFe0.5Co0.5O2 as high energy and power positive electrode for Na-ion batteries
journal, September 2013

The rechargeable revolution: A better battery
journal, March 2014

Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

Understanding the Degradation Mechanisms of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode Material in Lithium Ion Batteries
journal, August 2013

  • Jung, Sung-Kyun; Gwon, Hyeokjo; Hong, Jihyun
  • Advanced Energy Materials, Vol. 4, Issue 1
  • DOI: 10.1002/aenm.201300787

P-type Na x Ni 0.22 Co 0.11 Mn 0.66 O 2 materials: linking synthesis with structure and electrochemical performance
journal, January 2014

  • Chagas, L. G.; Buchholz, D.; Vaalma, C.
  • J. Mater. Chem. A, Vol. 2, Issue 47
  • DOI: 10.1039/C4TA03946G

Intragranular cracking as a critical barrier for high-voltage usage of layer-structured cathode for lithium-ion batteries
journal, January 2017

  • Yan, Pengfei; Zheng, Jianming; Gu, Meng
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14101

Sodium-Ion Batteries
journal, May 2012

  • Slater, Michael D.; Kim, Donghan; Lee, Eungje
  • Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
  • DOI: 10.1002/adfm.201200691

Improvement of the Cathode Electrolyte Interphase on P2-Na 2/3 Ni 1/3 Mn 2/3 O 2 by Atomic Layer Deposition
journal, July 2017

  • Alvarado, Judith; Ma, Chuze; Wang, Shen
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 31
  • DOI: 10.1021/acsami.7b05326

In situ soft XAS study on nickel-based layered cathode material at elevated temperatures: A novel approach to study thermal stability
journal, October 2014

  • Yoon, Won-Sub; Haas, Otto; Muhammad, Shoaib
  • Scientific Reports, Vol. 4, Issue 1
  • DOI: 10.1038/srep06827

The Formation Mechanism of Fluorescent Metal Complexes at the Li x Ni 0.5 Mn 1.5 O 4−δ /Carbonate Ester Electrolyte Interface
journal, March 2015

  • Jarry, Angélique; Gottis, Sébastien; Yu, Young-Sang
  • Journal of the American Chemical Society, Vol. 137, Issue 10
  • DOI: 10.1021/ja5116698

Synthesis, Structure, and Electrochemical Properties of the Layered Sodium Insertion Cathode Material: NaNi 1 / 3 Mn 1 / 3 Co 1 / 3 O 2
journal, April 2012

  • Sathiya, M.; Hemalatha, K.; Ramesha, K.
  • Chemistry of Materials, Vol. 24, Issue 10
  • DOI: 10.1021/cm300466b

Understanding Transition-Metal Dissolution Behavior in LiNi 0.5 Mn 1.5 O 4 High-Voltage Spinel for Lithium Ion Batteries
journal, July 2013

  • Pieczonka, Nicholas P. W.; Liu, Zhongyi; Lu, Peng
  • The Journal of Physical Chemistry C, Vol. 117, Issue 31
  • DOI: 10.1021/jp405158m

Investigating the Intercalation Chemistry of Alkali Ions in Fluoride Perovskites
journal, February 2017

Structural Evolution and Redox Processes Involved in the Electrochemical Cycling of P2–Na 0.67 [Mn 0.66 Fe 0.20 Cu 0.14 ]O 2
journal, July 2017

Generating derivative structures from multilattices: Algorithm and application to hcp alloys
journal, July 2009

Structural classification and properties of the layered oxides
journal, January 1980

Review—SEI: Past, Present and Future
journal, January 2017

  • Peled, E.; Menkin, S.
  • Journal of The Electrochemical Society, Vol. 164, Issue 7
  • DOI: 10.1149/2.1441707jes

Chemical vapor deposition and atomic layer deposition for advanced lithium ion batteries and supercapacitors
journal, January 2015

  • Wang, Xinran; Yushin, Gleb
  • Energy & Environmental Science, Vol. 8, Issue 7
  • DOI: 10.1039/C5EE01254F

Improving the initial Coulombic efficiency of hard carbon-based anode for rechargeable batteries with high energy density
journal, May 2017

  • Zhang, Xiang; Fan, Changling; Han, Shaochang
  • Journal of Materials Science, Vol. 52, Issue 17
  • DOI: 10.1007/s10853-017-1206-3

Sodium-Ion Batteries
journal, June 2018

  • Rojo, Teofilo; Hu, Yong-Sheng; Forsyth, Maria
  • Advanced Energy Materials, Vol. 8, Issue 17
  • DOI: 10.1002/aenm.201800880
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