Direct Observation of Node-to-Node Communication in Zeolitic Imidazolate Frameworks

Pattengale, Brian; SantaLucia, Daniel J.; Yang, Sizhuo; Hu, Wenhui; Liu, Cunming; Zhang, Xiaoyi; Berry, John F.; Huang, Jier

doi:10.1021/jacs.8b06727

Title: Direct Observation of Node-to-Node Communication in Zeolitic Imidazolate Frameworks

Journal Article · 03 September 2018 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.8b06727 · OSTI ID:1484204

Pattengale, Brian ^[1]; SantaLucia, Daniel J. ^[2]; Yang, Sizhuo ^[1]; Hu, Wenhui ^[1]; Liu, Cunming ^[3];

^[3];

^[1];

^[1]

Marquette Univ., Milwaukee, WI (United States). Dept. of Chemistry
Univ. of Wisconsin, Madison, WI (United States). Dept. of Chemistry
Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division

Zeolitic imidazolate frameworks (ZIFs) with open-shell transition metal nodes represent a promising class of highly ordered light harvesting antennas for photoenergy applications. However, their charge transport properties within the framework, the key criterion to achieve efficient photoenergy conversion, are not yet explored. Herein, we report the first direct evidence of a charge transport pathway through node-to-node communication in both ground state and excited state ZIFs using the combination of paramagnetic susceptibility measurements and time-resolved optical and X-ray absorption spectroscopy. These findings provide unprecedented new insights into the photoactivity and charge transport nature of ZIF frameworks, paving the way for their novel application as light harvesting arrays in diverse photoenergy conversion devices.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Scientific User Facilities Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1484204

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 37 Vol. 140; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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