Evolution of magnetic and orbital properties in the magnetically diluted A-site spinel Cu1–xZnxRh2O4

Zakrzewski, A. V.; Gangopadhyay, S.; MacDougall, Gregory J.; Aczel, Adam A.; Calder, Stuart A.; Williams, Travis J.

doi:10.1103/PhysRevB.97.214411

Title: Evolution of magnetic and orbital properties in the magnetically diluted $A$ -site spinel ${Cu}_{1 - x} {Zn}_{x} {Rh}_{2} O_{4}$

Abstract

In frustrated spinel antiferromagnets, dilution with nonmagnetic ions can be a powerful strategy for probing unconventional spin states or uncovering interesting phenomena. Here, we present x-ray, neutron scattering, and thermodynamic studies of the effects of magnetic dilution of the tetragonally distorted A-site spinel antiferromagnet, CuRh₂O₄, with nonmagnetic Zn²⁺ ions. Our data confirm the helical spin order recently identified at low temperatures in this material, and further demonstrate a systematic suppression of the associated Néel temperature with increasing site dilution towards a continuous transition with critical doping of x_spin ~0.44. Interestingly, this critical doping is demonstrably distinct from a second structural critical point at x_JT ~0.6, which is consistent with the suppression of orbital order on the A site through a classical percolative mechanism. In conclusion, this anomalously low value for x_spin is confirmed via multiple measurements, and is inconsistent with predictions of classical percolation theory, suggesting that the spin transition in this material is driven by an enhancement of preexisting spin fluctuations with weak dilution.

Authors:

Zakrzewski, A. V. ^[1]; Gangopadhyay, S. ^[1]; MacDougall, Gregory J. ^[1];

^[2];

^[2]

Univ. of Illinois at Urbana-Champaign, Urbana, IL (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: Mon Jun 11 00:00:00 EDT 2018

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1484133

Alternate Identifier(s):: OSTI ID: 1441121

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 97; Journal Issue: 21; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Zakrzewski, A. V., Gangopadhyay, S., MacDougall, Gregory J., Aczel, Adam A., Calder, Stuart A., and Williams, Travis J. Evolution of magnetic and orbital properties in the magnetically diluted A-site spinel Cu1–xZnxRh2O4.  United States: N. p., 2018. 
Web.  doi:10.1103/PhysRevB.97.214411.

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                    Zakrzewski, A. V., Gangopadhyay, S., MacDougall, Gregory J., Aczel, Adam A., Calder, Stuart A., & Williams, Travis J. Evolution of magnetic and orbital properties in the magnetically diluted A-site spinel Cu1–xZnxRh2O4.  United States.  https://doi.org/10.1103/PhysRevB.97.214411

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                    Zakrzewski, A. V., Gangopadhyay, S., MacDougall, Gregory J., Aczel, Adam A., Calder, Stuart A., and Williams, Travis J. Mon .  
"Evolution of magnetic and orbital properties in the magnetically diluted A-site spinel Cu1–xZnxRh2O4".  United States.  https://doi.org/10.1103/PhysRevB.97.214411.  https://www.osti.gov/servlets/purl/1484133.

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@article{osti_1484133,

  title        = {Evolution of magnetic and orbital properties in the magnetically diluted A-site spinel Cu1–xZnxRh2O4},

  author       = {Zakrzewski, A. V. and Gangopadhyay, S. and MacDougall, Gregory J. and Aczel, Adam A. and Calder, Stuart A. and Williams, Travis J.},

  abstractNote = {In frustrated spinel antiferromagnets, dilution with nonmagnetic ions can be a powerful strategy for probing unconventional spin states or uncovering interesting phenomena. Here, we present x-ray, neutron scattering, and thermodynamic studies of the effects of magnetic dilution of the tetragonally distorted A-site spinel antiferromagnet, CuRh2O4, with nonmagnetic Zn2+ ions. Our data confirm the helical spin order recently identified at low temperatures in this material, and further demonstrate a systematic suppression of the associated Néel temperature with increasing site dilution towards a continuous transition with critical doping of xspin ~0.44. Interestingly, this critical doping is demonstrably distinct from a second structural critical point at xJT ~0.6, which is consistent with the suppression of orbital order on the A site through a classical percolative mechanism. In conclusion, this anomalously low value for xspin is confirmed via multiple measurements, and is inconsistent with predictions of classical percolation theory, suggesting that the spin transition in this material is driven by an enhancement of preexisting spin fluctuations with weak dilution.},

  doi          = {10.1103/PhysRevB.97.214411},

  journal      = {Physical Review B},

  number       = 21,

  volume       = 97,

  place        = {United States},

  year         = {Mon Jun 11 00:00:00 EDT 2018},

  month        = {Mon Jun 11 00:00:00 EDT 2018}

}

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https://doi.org/10.1103/PhysRevB.97.214411

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Cited by: 7 works

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Figures / Tables:

FIG. 1: (a) Room temperature crystal structure of tetragonally-distorted spinel CuRh₂O₄. Green spheres are Cu²⁺ ions; Blue Rh³⁺; Red O^2- . A-site tetrahedra and B-site octahedra are depicted with green and blue faces, respectively. (b) Connectivity of nearest-neighbor Cu²⁺ sites. (c) Crystal field splitting of d-orbital energy levels of A-sitesmore »

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Title: Evolution of magnetic and orbital properties in the magnetically diluted A -site spinel Cu 1 – x Zn x Rh 2 O 4

Abstract

Citation Formats

Figures / Tables:

Quantum Order by Disorder in Frustrated Diamond Lattice Antiferromagnets journal, July 2008

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Spiral spin-liquid and the emergence of a vortex-like state in MnSc2S4 journal, October 2016

Revisiting the ground state of CoAl 2 O 4 : Comparison to the conventional antiferromagnet MnAl 2 O 4 journal, November 2016

The high-resolution powder diffractometer at the high flux isotope reactor journal, March 2010

Geometric frustration in the cubic spinels M Al 2 O 4 ( M = Co , Fe, and Mn) journal, November 2005

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Ordering due to disorder in a frustrated vector antiferromagnet journal, April 1989

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Title: Evolution of magnetic and orbital properties in the magnetically diluted $A$ -site spinel ${Cu}_{1 - x} {Zn}_{x} {Rh}_{2} O_{4}$

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Spin excitations in frustrated $A$ -site spinels investigated with inelastic neutron scattering
journal, April 2009

Ordering due to disorder in a frustrated vector antiferromagnet
journal, April 1989

A magnetic study of frustrated and
journal, May 2006

Magnetic properties of normal spinels with only a-a interactions
journal, January 1964

Impurity effects in highly frustrated diamond-lattice antiferromagnets
journal, August 2011

Spin and orbital frustration in ${FeSc}_{2} S_{4}$ probed by ${}^{45}{Sc}$ NMR
journal, April 2006

Order as an effect of disorder
journal, January 1980