Magnetic properties of the itinerant A- type antiferromagnet CaCo2P2 studied by Co59 and P31 nuclear magnetic resonance

Higa, N.; Ding, Q. -P.; Teruya, A.; Yogi, M.; Hedo, M.; Nakama, T.; Ōnuki, Y.; Furukawa, Y.

doi:10.1103/PhysRevB.98.184433

Title: Magnetic properties of the itinerant A- type antiferromagnet ${CaCo}_{2} P_{2}$ studied by ${}^{59}{Co}$ and ${}^{31}P$ nuclear magnetic resonance

Abstract

⁵⁹Co and ³¹P nuclear magnetic resonance (NMR) measurements in external magnetic and zero magnetic fields have been performed to investigate the magnetic properties of the A-type antiferromagnetic (AFM) CaCo₂P₂. NMR data, especially the nuclear spin lattice relaxation rates 1/T₁ exhibiting a clear peak, provide clear evidence for the AFM transition at a Néel temperature of T_N ~ 110 K. The magnetic fluctuations in the paramagnetic state were found to be three-dimensional ferromagnetic, suggesting ferromagnetic interaction between Co spins in the ab plane characterizes the spin correlations in the paramagnetic state. In the AFM state below TN, we have observed ⁵⁹Co and ³¹P NMR signals under zero magnetic field. From ⁵⁹Co NMR data, the ordered magnetic moments of Co are found to be in ab plane and are estimated to be 0.35 μ_B at 4.2 K. Furthermore, the external field dependence of ⁵⁹Co NMR spectrum in the AFM state suggests a very weak magnetic anisotropy of the Co ions and also provides microscopic evidence of canting the Co-ordered moments along the external magnetic field directions. The magnetic state of the Co ions in CaCo₂ P₂ is well explained by the local-moment picture in the AFM state, although the system is metallic,more » as seen by 1/T₁T = constant behavior.« less

Authors:

Higa, N. ^[1]; Ding, Q. -P. ^[2]; Teruya, A. ^[3]; Yogi, M. ^[3]; Hedo, M. ^[3]; Nakama, T. ^[3]; Ōnuki, Y. ^[3]; Furukawa, Y. ^[2]

Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Univ. of the Ryukyus, Okinawa (Japan). Dept. of Physics and Earth Sciences
Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy
Univ. of the Ryukyus, Okinawa (Japan). Dept. of Physics and Earth Sciences

Publication Date:: Fri Nov 30 00:00:00 EST 2018

Research Org.:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Japan Society for the Promotion of Science KAKENHI

OSTI Identifier:: 1487220

Alternate Identifier(s):: OSTI ID: 1484062

Report Number(s):: IS-J-9826
Journal ID: ISSN 2469-9950; PRBMDO

Grant/Contract Number:: AC02-07CH11358; JP15K21732; JP15H05885; JP16H01078

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 98; Journal Issue: 18; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Higa, N., Ding, Q. -P., Teruya, A., Yogi, M., Hedo, M., Nakama, T., Ōnuki, Y., and Furukawa, Y. Magnetic properties of the itinerant A- type antiferromagnet CaCo2P2 studied by Co59 and P31 nuclear magnetic resonance.  United States: N. p., 2018. 
Web.  doi:10.1103/PhysRevB.98.184433.

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                    Higa, N., Ding, Q. -P., Teruya, A., Yogi, M., Hedo, M., Nakama, T., Ōnuki, Y., & Furukawa, Y. Magnetic properties of the itinerant A- type antiferromagnet CaCo2P2 studied by Co59 and P31 nuclear magnetic resonance.  United States.  https://doi.org/10.1103/PhysRevB.98.184433

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                    Higa, N., Ding, Q. -P., Teruya, A., Yogi, M., Hedo, M., Nakama, T., Ōnuki, Y., and Furukawa, Y. Fri .  
"Magnetic properties of the itinerant A- type antiferromagnet CaCo2P2 studied by Co59 and P31 nuclear magnetic resonance".  United States.  https://doi.org/10.1103/PhysRevB.98.184433.  https://www.osti.gov/servlets/purl/1487220.

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@article{osti_1487220,

  title        = {Magnetic properties of the itinerant A- type antiferromagnet CaCo2P2 studied by Co59 and P31 nuclear magnetic resonance},

  author       = {Higa, N. and Ding, Q. -P. and Teruya, A. and Yogi, M. and Hedo, M. and Nakama, T. and Ōnuki, Y. and Furukawa, Y.},

  abstractNote = {59Co and 31P nuclear magnetic resonance (NMR) measurements in external magnetic and zero magnetic fields have been performed to investigate the magnetic properties of the A-type antiferromagnetic (AFM) CaCo2P2. NMR data, especially the nuclear spin lattice relaxation rates 1/T1 exhibiting a clear peak, provide clear evidence for the AFM transition at a Néel temperature of TN ~ 110 K. The magnetic fluctuations in the paramagnetic state were found to be three-dimensional ferromagnetic, suggesting ferromagnetic interaction between Co spins in the ab plane characterizes the spin correlations in the paramagnetic state. In the AFM state below TN, we have observed 59Co and 31P NMR signals under zero magnetic field. From 59Co NMR data, the ordered magnetic moments of Co are found to be in ab plane and are estimated to be 0.35 μB at 4.2 K. Furthermore, the external field dependence of 59Co NMR spectrum in the AFM state suggests a very weak magnetic anisotropy of the Co ions and also provides microscopic evidence of canting the Co-ordered moments along the external magnetic field directions. The magnetic state of the Co ions in CaCo2 P2 is well explained by the local-moment picture in the AFM state, although the system is metallic, as seen by 1/T1T = constant behavior.},

  doi          = {10.1103/PhysRevB.98.184433},

  journal      = {Physical Review B},

  number       = 18,

  volume       = 98,

  place        = {United States},

  year         = {Fri Nov 30 00:00:00 EST 2018},

  month        = {Fri Nov 30 00:00:00 EST 2018}

}

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Title: Magnetic properties of the itinerant A- type antiferromagnet CaCo 2 P 2 studied by Co 59 and P 31 nuclear magnetic resonance

Abstract

Citation Formats

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NMR Study of Antiferromagnetic Spinel C o C o 2 O 4 in Paramagnetic and Ordered State journal, December 1996

V 51 NMR study of the kagome staircase compound Ni 3 V 2 O 8 journal, April 2010

Tetragonal magnetic phase in Ba 1 − x K x Fe 2 As 2 from x-ray and neutron diffraction journal, September 2015

Experimental evidence of a collinear antiferromagnetic ordering in the frustrated CoAl 2 O 4 spinel journal, November 2013

Ferromagnetism in the ThCr2Si2 type phosphide LaCo2P2 journal, November 1994

Superconductivity-induced re-entrance of the orthorhombic distortion in Ba1−xKxFe2As2 journal, July 2015

NMR investigation of spin correlations in BaCo 2 As 2 journal, July 2014

Variation of magnetic ground state of Sr 1 − x Ca x Co 2 P 2 determined with μ + SR journal, April 2015

Stabilization of an ambient-pressure collapsed tetragonal phase in CaFe 2 As 2 and tuning of the orthorhombic-antiferromagnetic transition temperature by over 70 K via control of nanoscale precipitates journal, April 2011

NMR investigation of spin fluctuations in the itinerant-electron magnetic compound Sr 1 − x Ca x Co 2 P 2 journal, February 2017

Anomalous itinerant-electron metamagnetic transition in the layered Sr 1 − x Ca x Co 2 P 2 system journal, July 2014

Pressure-induced volume-collapsed tetragonal phase of CaFe 2 As 2 as seen via neutron scattering journal, November 2008

Substitution Effects in the Itinerant Electron Metamagnetic Compound SrCo2P2 journal, January 2015

Antiferromagnetic Nuclear Resonance of 51 V in LaVO 3 and YVO 3 journal, October 1994

FeAs-Based Superconductivity: A Case Study of the Effects of Transition Metal Doping on BaFe 2 As 2 journal, August 2010

59Co NMR in Co2+ ion at tetrahedral site journal, April 1968

Competing Magnetic Fluctuations in Iron Pnictide Superconductors: Role of Ferromagnetic Spin Correlations Revealed by NMR journal, September 2015

Complex phase diagram of Ba 1 − x Na x Fe 2 As 2 : A multitude of phases striving for the electronic entropy journal, January 2016

Magnetic fluctuations and superconducting properties of CaKFe 4 As 4 studied by As 75 NMR journal, September 2017

Spin Dynamics in Iron-Based Layered Superconductor ( La 0.87 Ca 0.13 ) FePO Revealed by P 31 and La 139 NMR Studies journal, August 2008

Spin Fluctuations in Itinerant Electron Magnetism book, January 1985

Principles of Magnetic Resonance book, January 1990

Antiferromagnetic ordering in the absence of structural distortion in Ba ( Fe 1 − x Mn x ) 2 As 2 journal, December 2010

The puzzle of high temperature superconductivity in layered iron pnictides and chalcogenides journal, October 2010

Title: Magnetic properties of the itinerant A- type antiferromagnet ${CaCo}_{2} P_{2}$ studied by ${}^{59}{Co}$ and ${}^{31}P$ nuclear magnetic resonance

Antiferromagnetic order in ${CaK (Fe}_{1 - x} {Ni}_{x})_{4} {As}_{4}$ and its interplay with superconductivity
journal, June 2018

Pressure-induced unconventional superconductivity near a quantum critical point in CaFe ₂ As ₂
journal, April 2010

Suppression of electron correlations in the collapsed tetragonal phase of $Ca {Fe}_{2} {As}_{2}$ under ambient pressure demonstrated by ${}^{75}{As}$ NMR/NQR measurements
journal, March 2014

Mössbauer and magnetic susceptibility investigations of strontium, lanthanum and europium transition metal phosphides with ThCr2Si2 type structure
journal, January 1988

De Haas-van Alphen Effect and Fermi Surface Properties in Ferromagnet LaCo2P2 and Related Compounds
journal, January 2015

Expansion of the tetragonal magnetic phase with pressure in the iron arsenide superconductor ${Ba}_{1 - x} K_{x} {Fe}_{2} {As}_{2}$
journal, April 2016

Static and dynamical magnetic properties of the itinerant ferromagnet ${LaCo}_{2} P_{2}$
journal, May 2015

Double-Q spin-density wave in iron arsenide superconductors
journal, January 2016

Pressure-induced Fermi-surface reconstruction in the iron-arsenide superconductor Ba $_{1 - x}$ K $_{x}$ Fe $_{2}$ As $_{2}$ : Evidence of a phase transition inside the antiferromagnetic phase
journal, October 2012

Hedgehog spin-vortex crystal stabilized in a hole-doped iron-based superconductor
journal, February 2018

The Effect of Electron-Electron Interaction on the Nuclear Spin Relaxation in Metals
journal, April 1963

Magnetically driven suppression of nematic order in an iron-based superconductor
journal, May 2014

NMR study of the new magnetic superconductor $CaK {({Fe}_{0.951} {Ni}_{0.049})}_{4} {As}_{4}$ : Microscopic coexistence of the hedgehog spin-vortex crystal and superconductivity
journal, December 2017

Iron-Based Layered Superconductor La[O _1- _x F _x ]FeAs ( x = 0.05−0.12) with T _c = 26 K
journal, March 2008

Coexistence of Competing Antiferromagnetic and Superconducting Phases in the Underdoped $Ba ({Fe}_{0.953} {Co}_{0.047})_{2} {As}_{2}$ Compound Using X-ray and Neutron Scattering Techniques
journal, August 2009

Ferromagnetic Spin Fluctuations in Two-Dimensional Metals
journal, September 1995

Antiferromagnetic order in the ThCr2Si2 type phosphides CaCo2P2 and CeCo2P2
journal, February 1998

Effects of Electron-Electron Interactions on Nuclear Spin-Lattice Relaxation Rates and Knight Shifts in Alkali and Noble Metals
journal, November 1968

Suppression of antiferromagnetism by pressure in ${CaCo}_{2}$ $P_{2}$
journal, March 2014

Evidence from neutron diffraction for superconductivity in the stabilized tetragonal phase of ${CaFe}_{2} {As}_{2}$ under uniaxial pressure
journal, May 2010

Lattice collapse and the magnetic phase diagram of ${Sr}_{1 - x} {Ca}_{x} {Co}_{2} P_{2}$
journal, October 2009

Coexistence of antiferromagnetic and ferromagnetic spin correlations in ${SrCo}_{2} {As}_{2}$ revealed by ${}^{59}{Co}$ and ${}^{75}{As}$ NMR
journal, June 2015

Disorder-promoted $C_{4}$ -symmetric magnetic order in iron-based superconductors
journal, April 2016

Superconductivity in iron compounds
journal, December 2011

Inelastic Neutron Scattering Study of a Nonmagnetic Collapsed Tetragonal Phase in Nonsuperconducting ${CaFe}_{2} {As}_{2}$ : Evidence of the Impact of Spin Fluctuations on Superconductivity in the Iron-Arsenide Compounds
journal, November 2013

NMR Study of Antiferromagnetic Spinel C o C o ₂ O ₄ in Paramagnetic and Ordered State
journal, December 1996

${}^{51}V$ NMR study of the kagome staircase compound ${Ni}_{3} V_{2} O_{8}$
journal, April 2010

Tetragonal magnetic phase in ${Ba}_{1 - x} K_{x} {Fe}_{2} {As}_{2}$ from x-ray and neutron diffraction
journal, September 2015

Experimental evidence of a collinear antiferromagnetic ordering in the frustrated CoAl $_{2}$ O $_{4}$ spinel
journal, November 2013

Ferromagnetism in the ThCr2Si2 type phosphide LaCo2P2
journal, November 1994

Superconductivity-induced re-entrance of the orthorhombic distortion in Ba1−xKxFe2As2
journal, July 2015

NMR investigation of spin correlations in ${BaCo}_{2} {As}_{2}$
journal, July 2014

Variation of magnetic ground state of ${Sr}_{1 - x} {Ca}_{x} {Co}_{2} P_{2}$ determined with $μ^{+} SR$
journal, April 2015

Stabilization of an ambient-pressure collapsed tetragonal phase in CaFe $_{2}$ As $_{2}$ and tuning of the orthorhombic-antiferromagnetic transition temperature by over 70 K via control of nanoscale precipitates
journal, April 2011

NMR investigation of spin fluctuations in the itinerant-electron magnetic compound ${Sr}_{1 - x} {Ca}_{x} {Co}_{2} P_{2}$
journal, February 2017

Anomalous itinerant-electron metamagnetic transition in the layered ${Sr}_{1 - x} {Ca}_{x} {Co}_{2} P_{2}$ system
journal, July 2014

Pressure-induced volume-collapsed tetragonal phase of ${CaFe}_{2} {As}_{2}$ as seen via neutron scattering
journal, November 2008

Substitution Effects in the Itinerant Electron Metamagnetic Compound SrCo2P2
journal, January 2015

Antiferromagnetic Nuclear Resonance of ⁵¹ V in LaVO ₃ and YVO ₃
journal, October 1994

FeAs-Based Superconductivity: A Case Study of the Effects of Transition Metal Doping on BaFe ₂ As ₂
journal, August 2010

59Co NMR in Co2+ ion at tetrahedral site
journal, April 1968

Competing Magnetic Fluctuations in Iron Pnictide Superconductors: Role of Ferromagnetic Spin Correlations Revealed by NMR
journal, September 2015

Complex phase diagram of ${Ba}_{1 - x} {Na}_{x} {Fe}_{2} {As}_{2}$ : A multitude of phases striving for the electronic entropy
journal, January 2016

Magnetic fluctuations and superconducting properties of ${CaKFe}_{4} {As}_{4}$ studied by ${}^{75}{As}$ NMR
journal, September 2017

Spin Dynamics in Iron-Based Layered Superconductor ${(La}_{0.87} {Ca}_{0.13}) FePO$ Revealed by ${}^{31}P$ and ${}^{139}{La}$ NMR Studies
journal, August 2008

Spin Fluctuations in Itinerant Electron Magnetism
book, January 1985

Principles of Magnetic Resonance
book, January 1990

Antiferromagnetic ordering in the absence of structural distortion in $Ba {({Fe}_{1 - x} {Mn}_{x})}_{2} {As}_{2}$
journal, December 2010

The puzzle of high temperature superconductivity in layered iron pnictides and chalcogenides
journal, October 2010