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Title: Pristine or Highly Defective? Understanding the Role of Graphene Structure for Stable Lithium Metal Plating

ORCiD logo [1];  [1];  [2];  [1];  [1];  [3];  [4]; ORCiD logo [5]
  1. Institute of New‐Energy and Low‐Carbon Technology Sichuan University Chengdu Sichuan 610065 China
  2. College of Materials Science and Technology Sichuan University Chengdu Sichuan 610065 China
  3. Institute of New‐Energy and Low‐Carbon Technology Sichuan University Chengdu Sichuan 610065 China, College of Materials Science and Technology Sichuan University Chengdu Sichuan 610065 China
  4. Chemical &, Biomolecular Engineering and Mechanical Engineering Clarkson University Potsdam NY 13699 USA
  5. Institute of New‐Energy and Low‐Carbon Technology Sichuan University Chengdu Sichuan 610065 China, Chemical &, Biomolecular Engineering and Mechanical Engineering Clarkson University Potsdam NY 13699 USA
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Advanced Energy Materials
Additional Journal Information:
Journal Name: Advanced Energy Materials Journal Volume: 9 Journal Issue: 3; Journal ID: ISSN 1614-6832
Wiley Blackwell (John Wiley & Sons)
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Liu, Wei, Xia, Yuting, Wang, Wenwu, Wang, Yizhe, Jin, Jialun, Chen, Yungui, Paek, Eunsu, and Mitlin, David. Pristine or Highly Defective? Understanding the Role of Graphene Structure for Stable Lithium Metal Plating. Germany: N. p., 2018. Web.
Liu, Wei, Xia, Yuting, Wang, Wenwu, Wang, Yizhe, Jin, Jialun, Chen, Yungui, Paek, Eunsu, & Mitlin, David. Pristine or Highly Defective? Understanding the Role of Graphene Structure for Stable Lithium Metal Plating. Germany.
Liu, Wei, Xia, Yuting, Wang, Wenwu, Wang, Yizhe, Jin, Jialun, Chen, Yungui, Paek, Eunsu, and Mitlin, David. Tue . "Pristine or Highly Defective? Understanding the Role of Graphene Structure for Stable Lithium Metal Plating". Germany.
title = {Pristine or Highly Defective? Understanding the Role of Graphene Structure for Stable Lithium Metal Plating},
author = {Liu, Wei and Xia, Yuting and Wang, Wenwu and Wang, Yizhe and Jin, Jialun and Chen, Yungui and Paek, Eunsu and Mitlin, David},
abstractNote = {},
doi = {10.1002/aenm.201802918},
journal = {Advanced Energy Materials},
number = 3,
volume = 9,
place = {Germany},
year = {2018},
month = {11}

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Mechanisms for Lithium Insertion in Carbonaceous Materials
journal, October 1995

Ultrasonication Induces Oxygenated Species and Defects onto Exfoliated Graphene
journal, October 2013

  • Skaltsas, Theodosis; Ke, Xiaoxing; Bittencourt, Carla
  • The Journal of Physical Chemistry C, Vol. 117, Issue 44
  • DOI: 10.1021/jp4057048

Ultrathin Two-Dimensional Atomic Crystals as Stable Interfacial Layer for Improvement of Lithium Metal Anode
journal, September 2014

  • Yan, Kai; Lee, Hyun-Wook; Gao, Teng
  • Nano Letters, Vol. 14, Issue 10
  • DOI: 10.1021/nl503125u

2D Frameworks of C 2 N and C 3 N as New Anode Materials for Lithium-Ion Batteries
journal, July 2017

Na Reactivity toward Carbonate-Based Electrolytes: The Effect of FEC as Additive
journal, January 2016

  • Dugas, R.; Ponrouch, A.; Gachot, G.
  • Journal of The Electrochemical Society, Vol. 163, Issue 10
  • DOI: 10.1149/2.0981610jes

Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide
journal, June 2007

The reduction of graphene oxide
journal, August 2012

Conductive porous carbon film as a lithium metal storage medium
journal, September 2015

Electrochemical Properties of Sulfurized-Polyacrylonitrile Cathode for Lithium–Sulfur Batteries: Effect of Polyacrylic Acid Binder and Fluoroethylene Carbonate Additive
journal, October 2017

  • Kim, Hee Min; Hwang, Jang-Yeon; Aurbach, Doron
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 21
  • DOI: 10.1021/acs.jpclett.7b02354

Li-ion battery materials: present and future
journal, June 2015

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review
journal, July 2017

Mesoporous nitrogen-rich carbons derived from protein for ultra-high capacity battery anodes and supercapacitors
journal, January 2013

  • Li, Zhi; Xu, Zhanwei; Tan, Xuehai
  • Energy & Environmental Science, Vol. 6, Issue 3
  • DOI: 10.1039/c2ee23599d

Defect-induced plating of lithium metal within porous graphene networks
journal, April 2014

  • Mukherjee, Rahul; Thomas, Abhay V.; Datta, Dibakar
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4710

An Improved Li-SeS 2 Battery with High Energy Density and Long Cycle Life
journal, April 2017

  • Li, Zhen; Zhang, Jintao; Wu, Hao Bin
  • Advanced Energy Materials, Vol. 7, Issue 15
  • DOI: 10.1002/aenm.201700281

A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries
journal, September 2010

Carbon Anode Materials for Advanced Sodium-Ion Batteries
journal, March 2017

  • Hou, Hongshuai; Qiu, Xiaoqing; Wei, Weifeng
  • Advanced Energy Materials, Vol. 7, Issue 24
  • DOI: 10.1002/aenm.201602898

Flow-induced orientation of non-spherical particles: Effect of aspect ratio and medium rheology
journal, November 2008

High-Density Sodium and Lithium Ion Battery Anodes from Banana Peels
journal, June 2014

  • Lotfabad, Elmira Memarzadeh; Ding, Jia; Cui, Kai
  • ACS Nano, Vol. 8, Issue 7, p. 7115-7129
  • DOI: 10.1021/nn502045y

Modifying the Size of Ultrasound-Induced Liquid-Phase Exfoliated Graphene: From Nanosheets to Nanodots
journal, November 2016

  • Ciesielski, Artur; Haar, Sébastien; Aliprandi, Alessandro
  • ACS Nano, Vol. 10, Issue 12
  • DOI: 10.1021/acsnano.6b03823

Mechanism of Na-Ion Storage in Hard Carbon Anodes Revealed by Heteroatom Doping
journal, May 2017

  • Li, Zhifei; Bommier, Clement; Chong, Zhi Sen
  • Advanced Energy Materials, Vol. 7, Issue 18
  • DOI: 10.1002/aenm.201602894

Reviving Lithium-Metal Anodes for Next-Generation High-Energy Batteries
journal, June 2017

Nanoscale Nucleation and Growth of Electrodeposited Lithium Metal
journal, January 2017

On the Nature of Defects in Liquid-Phase Exfoliated Graphene
journal, July 2014

  • Bracamonte, M. V.; Lacconi, G. I.; Urreta, S. E.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 28
  • DOI: 10.1021/jp501930a

Lithiophilic Sites in Doped Graphene Guide Uniform Lithium Nucleation for Dendrite-Free Lithium Metal Anodes
journal, May 2017

  • Zhang, Rui; Chen, Xiao-Ru; Chen, Xiang
  • Angewandte Chemie International Edition, Vol. 56, Issue 27
  • DOI: 10.1002/anie.201702099

Chemical Mass Production of Graphene Nanoplatelets in ∼100% Yield
journal, November 2015

A Scalable Approach to Dendrite-Free Lithium Anodes via Spontaneous Reduction of Spray-Coated Graphene Oxide Layers
journal, May 2018

Hybrid Lithium-Sulfur Batteries with an Advanced Gel Cathode and Stabilized Lithium-Metal Anode
journal, May 2018

  • Xu, Henghui; Wang, Shaofei; Manthiram, Arumugam
  • Advanced Energy Materials, Vol. 8, Issue 23
  • DOI: 10.1002/aenm.201800813

Synergistic Effect of Graphene Oxide for Impeding the Dendritic Plating of Li
journal, February 2018

  • Foroozan, Tara; Soto, Fernando A.; Yurkiv, Vitaliy
  • Advanced Functional Materials, Vol. 28, Issue 15
  • DOI: 10.1002/adfm.201705917

Facile and Scalable Synthesis Method for High-Quality Few-Layer Graphene through Solution-Based Exfoliation of Graphite
journal, January 2017

  • Wee, Boon-Hong; Wu, Tong-Fei; Hong, Jong-Dal
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 5
  • DOI: 10.1021/acsami.6b11771

High-Performance All-Solid-State Lithium-Sulfur Batteries Enabled by Amorphous Sulfur-Coated Reduced Graphene Oxide Cathodes
journal, May 2017

  • Yao, Xiayin; Huang, Ning; Han, Fudong
  • Advanced Energy Materials, Vol. 7, Issue 17
  • DOI: 10.1002/aenm.201602923

Vinylene carbonate–LiNO3: A hybrid additive in carbonic ester electrolytes for SEI modification on Li metal anode
journal, February 2015

Preparation of Graphitic Oxide
journal, March 1958

  • Hummers, William S.; Offeman, Richard E.
  • Journal of the American Chemical Society, Vol. 80, Issue 6, p. 1339-1339
  • DOI: 10.1021/ja01539a017

Selenium Impregnated Monolithic Carbons as Free-Standing Cathodes for High Volumetric Energy Lithium and Sodium Metal Batteries
journal, November 2017

Very Stable Lithium Metal Stripping–Plating at a High Rate and High Areal Capacity in Fluoroethylene Carbonate-Based Organic Electrolyte Solution
journal, May 2017

Stabilized Lithium–Metal Surface in a Polysulfide-Rich Environment of Lithium–Sulfur Batteries
journal, July 2014

  • Zu, Chenxi; Manthiram, Arumugam
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 15
  • DOI: 10.1021/jz501352e

Ultrahigh-throughput exfoliation of graphite into pristine ‘single-layer’ graphene using microwaves and molecularly engineered ionic liquids
journal, August 2015

  • Matsumoto, Michio; Saito, Yusuke; Park, Chiyoung
  • Nature Chemistry, Vol. 7, Issue 9
  • DOI: 10.1038/nchem.2315

Self-heating–induced healing of lithium dendrites
journal, March 2018

Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon Foams
journal, July 2013

  • Shao, Yuyan; Xiao, Jie; Wang, Wei
  • Nano Letters, Vol. 13, Issue 8
  • DOI: 10.1021/nl401995a

Insight into lithium–metal anodes in lithium–sulfur batteries with a fluorinated ether electrolyte
journal, January 2015

  • Zu, Chenxi; Azimi, Nasim; Zhang, Zhengcheng
  • Journal of Materials Chemistry A, Vol. 3, Issue 28
  • DOI: 10.1039/C5TA03195H

Kinetically Enhanced Bubble-Exfoliation of Graphite toward High-Yield Preparation of High-Quality Graphene
journal, October 2017

Guidelines for Exfoliation, Characterization and Processing of Layered Materials Produced by Liquid Exfoliation
journal, November 2016

A Review of Solid Electrolyte Interphases on Lithium Metal Anode
journal, November 2015

Stable lithium electrodeposition in liquid and nanoporous solid electrolytes
journal, August 2014

  • Lu, Yingying; Tu, Zhengyuan; Archer, Lynden A.
  • Nature Materials, Vol. 13, Issue 10
  • DOI: 10.1038/nmat4041

Exfoliation of Graphite into Graphene in Aqueous Solutions of Inorganic Salts
journal, April 2014

  • Parvez, Khaled; Wu, Zhong-Shuai; Li, Rongjin
  • Journal of the American Chemical Society, Vol. 136, Issue 16
  • DOI: 10.1021/ja5017156

High-Performance Sodium Ion Batteries Based on a 3D Anode from Nitrogen-Doped Graphene Foams
journal, February 2015

  • Xu, Jiantie; Wang, Min; Wickramaratne, Nilantha P.
  • Advanced Materials, Vol. 27, Issue 12
  • DOI: 10.1002/adma.201405370

The electrochemistry of activated carbonaceous materials: past, present, and future
journal, May 2011

  • Noked, Malachi; Soffer, Abraham; Aurbach, Doron
  • Journal of Solid State Electrochemistry, Vol. 15, Issue 7-8
  • DOI: 10.1007/s10008-011-1411-y

High Areal Capacity and Lithium Utilization in Anodes Made of Covalently Connected Graphite Microtubes
journal, August 2017

Role of LiNO3 in rechargeable lithium/sulfur battery
journal, May 2012

Origin of non-SEI related coulombic efficiency loss in carbons tested against Na and Li
journal, January 2014

  • Memarzadeh Lotfabad, Elmira; Kalisvaart, Peter; Kohandehghan, Alireza
  • J. Mater. Chem. A, Vol. 2, Issue 46
  • DOI: 10.1039/C4TA04995K

Internal structure – Na storage mechanisms – Electrochemical performance relations in carbons
journal, August 2018

The chemical and structural analysis of graphene oxide with different degrees of oxidation
journal, March 2013

Chemical methods for the production of graphenes
journal, March 2009

  • Park, Sungjin; Ruoff, Rodney S.
  • Nature Nanotechnology, Vol. 4, Issue 4, p. 217-224
  • DOI: 10.1038/nnano.2009.58

Processable aqueous dispersions of graphene nanosheets
journal, January 2008

Supramolecular Approaches to Graphene: From Self-Assembly to Molecule-Assisted Liquid-Phase Exfoliation
journal, March 2016

Chemistry and Structure of Graphene Oxide via Direct Imaging
journal, July 2016

Sonochemistry in non-aqueous liquids
journal, January 1984

Suppression of dendritic lithium growth in lithium metal-based batteries
journal, January 2018

  • Li, Linlin; Li, Siyuan; Lu, Yingying
  • Chemical Communications, Vol. 54, Issue 50
  • DOI: 10.1039/C8CC02280A

Li 2 S- or S-Based Lithium-Ion Batteries
journal, July 2018

Opportunities and challenges for a sustainable energy future
journal, August 2012

  • Chu, Steven; Majumdar, Arun
  • Nature, Vol. 488, Issue 7411, p. 294-303
  • DOI: 10.1038/nature11475

Heterogeneous nucleation and growth of electrodeposited lithium metal on the basal plane of single-layer graphene
journal, January 2019

From Lithium-Oxygen to Lithium-Air Batteries: Challenges and Opportunities
journal, February 2016

  • Geng, Dongsheng; Ding, Ning; Hor, T. S. Andy
  • Advanced Energy Materials, Vol. 6, Issue 9
  • DOI: 10.1002/aenm.201502164

Protecting Silicon Film Anodes in Lithium-Ion Batteries Using an Atomically Thin Graphene Drape
journal, April 2017

Lithium metal anodes for rechargeable batteries
journal, January 2014

  • Xu, Wu; Wang, Jiulin; Ding, Fei
  • Energy Environ. Sci., Vol. 7, Issue 2
  • DOI: 10.1039/C3EE40795K

The Mechanism of Cavitation-Induced Scission of Single-Walled Carbon Nanotubes
journal, March 2007

  • Hennrich, Frank; Krupke, Ralph; Arnold, Katharina
  • The Journal of Physical Chemistry B, Vol. 111, Issue 8
  • DOI: 10.1021/jp065262n

Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes
journal, March 2016

  • Lin, Dingchang; Liu, Yayuan; Liang, Zheng
  • Nature Nanotechnology, Vol. 11, Issue 7
  • DOI: 10.1038/nnano.2016.32

Scanning Tunneling Microscopy and X-ray Photoelectron Spectroscopy Studies of Graphene Films Prepared by Sonication-Assisted Dispersion
journal, July 2011

  • Polyakova (Stolyarova), Elena Y.; Rim, Kwang Taeg; Eom, Daejin
  • ACS Nano, Vol. 5, Issue 8
  • DOI: 10.1021/nn1009352

Consumption of Fluoroethylene Carbonate (FEC) on Si-C Composite Electrodes for Li-Ion Batteries
journal, January 2016

  • Jung, Roland; Metzger, Michael; Haering, Dominik
  • Journal of The Electrochemical Society, Vol. 163, Issue 8
  • DOI: 10.1149/2.0951608jes

Interconnected hollow carbon nanospheres for stable lithium metal anodes
journal, July 2014

  • Zheng, Guangyuan; Lee, Seok Woo; Liang, Zheng
  • Nature Nanotechnology, Vol. 9, Issue 8
  • DOI: 10.1038/nnano.2014.152

The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth
journal, June 2015

  • Li, Weiyang; Yao, Hongbin; Yan, Kai
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8436

Organic Radical-Assisted Electrochemical Exfoliation for the Scalable Production of High-Quality Graphene
journal, October 2015

  • Yang, Sheng; Brüller, Sebastian; Wu, Zhong-Shuai
  • Journal of the American Chemical Society, Vol. 137, Issue 43
  • DOI: 10.1021/jacs.5b09000

Assembly of Graphene Sheets into Hierarchical Structures for High-Performance Energy Storage
journal, April 2011

  • Yin, Shengyan; Zhang, Yanyan; Kong, Junhua
  • ACS Nano, Vol. 5, Issue 5
  • DOI: 10.1021/nn2001728

Alkane sonochemistry
journal, June 1983

  • Suslick, Kenneth S.; Gawienowski, John J.; Schubert, Paul F.
  • The Journal of Physical Chemistry, Vol. 87, Issue 13
  • DOI: 10.1021/j100236a013

Reviving the lithium metal anode for high-energy batteries
journal, March 2017

  • Lin, Dingchang; Liu, Yayuan; Cui, Yi
  • Nature Nanotechnology, Vol. 12, Issue 3
  • DOI: 10.1038/nnano.2017.16

A consideration of the morphology of electrochemically deposited lithium in an organic electrolyte
journal, August 1998

Lithium-ion batteries. A look into the future
journal, January 2011

  • Scrosati, Bruno; Hassoun, Jusef; Sun, Yang-Kook
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01388b

Defect-Free, Size-Tunable Graphene for High-Performance Lithium Ion Battery
journal, July 2014

  • Park, Kwang Hyun; Lee, Dongju; Kim, Jungmo
  • Nano Letters, Vol. 14, Issue 8
  • DOI: 10.1021/nl500993q

Strength of Nanotubes, Filaments, and Nanowires From Sonication-Induced Scission
journal, October 2009

  • Huang, Yan Y.; Knowles, Tuomas P. J.; Terentjev, Eugene M.
  • Advanced Materials, Vol. 21, Issue 38–39
  • DOI: 10.1002/adma.200900498

Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism
journal, March 2013

  • Ding, Fei; Xu, Wu; Graff, Gordon L.
  • Journal of the American Chemical Society, Vol. 135, Issue 11, p. 4450-4456
  • DOI: 10.1021/ja312241y

Graphene: The Exfoliation of Graphene in Liquids by Electrochemical, Chemical, and Sonication-Assisted Techniques: A Nanoscale Study (Adv. Funct. Mater. 37/2013)
journal, October 2013

  • Xia, Zhen Yuan; Pezzini, Sergio; Treossi, Emanuele
  • Advanced Functional Materials, Vol. 23, Issue 37
  • DOI: 10.1002/adfm.201370188

High-yield production of graphene by liquid-phase exfoliation of graphite
journal, August 2008

  • Hernandez, Yenny; Nicolosi, Valeria; Lotya, Mustafa
  • Nature Nanotechnology, Vol. 3, Issue 9, p. 563-568
  • DOI: 10.1038/nnano.2008.215

Reviving rechargeable lithium metal batteries: enabling next-generation high-energy and high-power cells
journal, January 2012

  • Zhamu, Aruna; Chen, Guorong; Liu, Chenguang
  • Energy Environ. Sci., Vol. 5, Issue 2
  • DOI: 10.1039/C2EE02911A

Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries
journal, January 2017

  • Zhang, Xue-Qiang; Cheng, Xin-Bing; Chen, Xiang
  • Advanced Functional Materials, Vol. 27, Issue 10
  • DOI: 10.1002/adfm.201605989

Fluoroethylene Carbonate and Vinylene Carbonate Reduction: Understanding Lithium-Ion Battery Electrolyte Additives and Solid Electrolyte Interphase Formation
journal, November 2016

Conductive Nanostructured Scaffolds Render Low Local Current Density to Inhibit Lithium Dendrite Growth
journal, January 2016

  • Zhang, Rui; Cheng, Xin-Bing; Zhao, Chen-Zi
  • Advanced Materials, Vol. 28, Issue 11
  • DOI: 10.1002/adma.201504117

Surface-Sensitive NMR Detection of the Solid Electrolyte Interphase Layer on Reduced Graphene Oxide
journal, February 2017

Liquid-Phase Exfoliation of Graphite into Single- and Few-Layer Graphene with α-Functionalized Alkanes
journal, June 2016

  • Haar, Sébastien; Bruna, Matteo; Lian, Jian Xiang
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 14
  • DOI: 10.1021/acs.jpclett.6b01260

Review—SEI: Past, Present and Future
journal, January 2017

  • Peled, E.; Menkin, S.
  • Journal of The Electrochemical Society, Vol. 164, Issue 7
  • DOI: 10.1149/2.1441707jes

Structural evolution during the reduction of chemically derived graphene oxide
journal, June 2010

  • Bagri, Akbar; Mattevi, Cecilia; Acik, Muge
  • Nature Chemistry, Vol. 2, Issue 7, p. 581-587
  • DOI: 10.1038/nchem.686

Covalently Connected Carbon Nanostructures for Current Collectors in Both the Cathode and Anode of Li-S Batteries
journal, September 2016

Modeling dendrite growth during lithium electrodeposition at sub-ambient temperature
journal, January 2014