skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Luminescence characteristics of rare-earth-doped barium hexafluorogermanate BaGeF 6 nanowires: fast subnanosecond decay time and high sensitivity in H 2 O 2 detection

Abstract

The decay time of BaGeF6nanowires codoped with rare earths is found in the order of subnanoseconds, being one of the shortest decay time records from inorganic scintillators. Their luminescence emissions are highly sensitive for H2O2detection.

Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States); Oak Ridge Inst. for Science and Education (ORISE), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Science Foundation (NSF); U.S. Department of Defense (DOD)
OSTI Identifier:
1483339
Alternate Identifier(s):
OSTI ID: 1560050; OSTI ID: 1580741
Grant/Contract Number:  
AC02-06CH11357; W911NF-09-1-0011; W911NF-14-1-0060; W911NF-15-1-0566
Resource Type:
Published Article
Journal Name:
RSC Advances
Additional Journal Information:
Journal Name: RSC Advances Journal Volume: 8 Journal Issue: 69; Journal ID: ISSN 2046-2069
Publisher:
Royal Society of Chemistry
Country of Publication:
United Kingdom
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Luminescence characteristics of rare-earth-doped barium hexafluorogermanate BaGeF 6 nanowires: fast subnanosecond decay time and high sensitivity in H 2 O 2 detection. United Kingdom: N. p., 2018. Web. doi:10.1039/C8RA07806H.
Luminescence characteristics of rare-earth-doped barium hexafluorogermanate BaGeF 6 nanowires: fast subnanosecond decay time and high sensitivity in H 2 O 2 detection. United Kingdom. doi:10.1039/C8RA07806H.
Mon . "Luminescence characteristics of rare-earth-doped barium hexafluorogermanate BaGeF 6 nanowires: fast subnanosecond decay time and high sensitivity in H 2 O 2 detection". United Kingdom. doi:10.1039/C8RA07806H.
@article{osti_1483339,
title = {Luminescence characteristics of rare-earth-doped barium hexafluorogermanate BaGeF 6 nanowires: fast subnanosecond decay time and high sensitivity in H 2 O 2 detection},
author = {None, None},
abstractNote = {The decay time of BaGeF6nanowires codoped with rare earths is found in the order of subnanoseconds, being one of the shortest decay time records from inorganic scintillators. Their luminescence emissions are highly sensitive for H2O2detection.},
doi = {10.1039/C8RA07806H},
journal = {RSC Advances},
number = 69,
volume = 8,
place = {United Kingdom},
year = {2018},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8RA07806H

Citation Metrics:
Cited by: 1 work
Citation information provided by
Web of Science

Figures / Tables:

Fig. 1 Fig. 1: Pure BGF nanowires. (a and b) SEM images in low and high magnification; (c and d) TEM images; (e) enlarged image from (d) and SAD pattern showing crystallographic direction; and (f) EDS spectrum.

Save / Share:

Works referenced in this record:

Aligned AlN Nanorods with Multi-tipped Surfaces—Growth, Field-Emission, and Cathodoluminescence Properties
journal, March 2006


Performance of UV and UV/H2O2 processes for the removal of pharmaceuticals detected in secondary effluent of a sewage treatment plant in Japan
journal, July 2009


Sensitized fluorescence of Ce3+/Mn2+ system in phosphate glass
journal, May 2003


VUV excitation and emission of Pr3+ in BaSiF6 and selecting host lattices with emission
journal, June 2002


Luminescence properties of Na 2 SiF 6 :Mn 4+ red phosphors for high colour-rendering white LED applications synthesized via a simple exothermic reduction reaction
journal, January 2017

  • Lang, Tian-Chun; Han, Tao; Peng, Ling-Ling
  • Materials Chemistry Frontiers, Vol. 1, Issue 5
  • DOI: 10.1039/C6QM00284F

Photoluminescence and Raman scattering spectroscopies of BaSiF 6 :Mn 4+ red phosphor
journal, May 2013

  • Sekiguchi, Daisuke; Nara, Jun-ichi; Adachi, Sadao
  • Journal of Applied Physics, Vol. 113, Issue 18
  • DOI: 10.1063/1.4803880

Large-Scale Hexagonal-Patterned Growth of Aligned ZnO Nanorods for Nano-optoelectronics and Nanosensor Arrays
journal, March 2004

  • Wang, Xudong; Summers, Christopher J.; Wang, Zhong Lin
  • Nano Letters, Vol. 4, Issue 3
  • DOI: 10.1021/nl035102c

Materials Data on BaSiF6 (SG:166) by Materials Project
dataset, January 2014

  • Persson, Kristin
  • LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
  • DOI: 10.17188/1270502

Synthesis and Photoluminescence Properties of BaSnF 6 :Mn 4+ Red Phosphor
journal, January 2016

  • Hoshino, Ryosuke; Nakamura, Toshihiro; Adachi, Sadao
  • ECS Journal of Solid State Science and Technology, Vol. 5, Issue 3
  • DOI: 10.1149/2.0151603jss

LaGaO 3 :A (A = Sm 3+ and/or Tb 3+ ) as promising phosphors for field emission displays
journal, January 2008

  • Liu, Xiaoming; Lin, Jun
  • J. Mater. Chem., Vol. 18, Issue 2
  • DOI: 10.1039/B709929K

Rare earth fluorides upconversion nanophosphors: from synthesis to applications in bioimaging
journal, January 2013

  • Wang, Song; Feng, Jing; Song, Shuyan
  • CrystEngComm, Vol. 15, Issue 36
  • DOI: 10.1039/c3ce40679b

Structures of Complex Fluorides. 1 Barium Fluosilicate and Barium Fluogermanate
journal, November 1940

  • Hoard, J. L.; Vincent, W. B.
  • Journal of the American Chemical Society, Vol. 62, Issue 11
  • DOI: 10.1021/ja01868a060

Rare-earth-doped biological composites as in vivo shortwave infrared reporters
journal, July 2013

  • Naczynski, D. J.; Tan, M. C.; Zevon, M.
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3199

Thermal decomposition of N2H6GeF6 · H2O, isolation and characterization of intermediates
journal, November 1985


Characterizations and optical properties of Sm3+-doped Sr2SiO4 phosphors
journal, September 2012


Uniform Alkaline Earth Fluoride Nanocrystals with Diverse Shapes Grown from Thermolysis of Metal Trifluoroacetates in Hot Surfactant Solutions
journal, April 2009

  • Du, Ya-Ping; Sun, Xiao; Zhang, Ya-Wen
  • Crystal Growth & Design, Vol. 9, Issue 4
  • DOI: 10.1021/cg801371r

Photoluminescence and Energy Transfer of Ce 3+ , Tb 3+ , and Eu 3+ Doped KBaY(BO 3 ) 2 as Near-Ultraviolet-Excited Color-Tunable Phosphors
journal, July 2015

  • Zhang, Xinguo; Gong, Menglian
  • Industrial & Engineering Chemistry Research, Vol. 54, Issue 31
  • DOI: 10.1021/acs.iecr.5b01576

Synthesis and photoluminescence spectroscopy of BaGeF6:Mn4+ red phosphor
journal, April 2015


Down-Conversion Nitride Materials for Solid State Lighting: Recent Advances and Perspectives
journal, February 2018


Hydrogen-Peroxide-Based Fuel Cells for Space Power Systems
journal, May 2008

  • Luo, Nie; Miley, George H.; Gimlin, Richard J.
  • Journal of Propulsion and Power, Vol. 24, Issue 3
  • DOI: 10.2514/1.31522

Computational Models of Reactive Oxygen Species as Metabolic Byproducts and Signal-Transduction Modulators
journal, November 2016

  • Pereira, Elizabeth J.; Smolko, Christian M.; Janes, Kevin A.
  • Frontiers in Pharmacology, Vol. 7
  • DOI: 10.3389/fphar.2016.00457

Mn 4+ -activated BaSiF 6 red phosphor: Hydrothermal synthesis and dependence of its luminescent properties on reaction conditions
journal, February 2016


Photoluminescent properties of K2GeF6:Mn4+ red phosphor synthesized from aqueous HF/KMnO4 solution
journal, July 2009

  • Adachi, Sadao; Takahashi, Toru
  • Journal of Applied Physics, Vol. 106, Issue 1
  • DOI: 10.1063/1.3160303

Red-emitting phosphors Na 2 XF 6 :Mn 4+ (X = Si, Ge, Ti) with high colour-purity for warm white-light-emitting diodes
journal, January 2015

  • Wang, Zhengliang; Liu, Yong; Zhou, Yayun
  • RSC Advances, Vol. 5, Issue 72
  • DOI: 10.1039/C5RA10568D

Properties of Mn[sup 4+]-Activated Hexafluorotitanate Phosphors
journal, January 2011

  • Xu, Yan Kai; Adachi, Sadao
  • Journal of The Electrochemical Society, Vol. 158, Issue 3
  • DOI: 10.1149/1.3530793

Hydrothermal synthesis and luminescent properties of BaTiF 6 :Mn 4+ red phosphor for LED backlighting
journal, January 2016


Probing the Influence of Disorder on Lanthanide Luminescence Using Eu-Doped LaPO 4 Nanoparticles
journal, August 2017

  • van Hest, Jacobine J. H. A.; Blab, Gerhard A.; Gerritsen, Hans C.
  • The Journal of Physical Chemistry C, Vol. 121, Issue 35
  • DOI: 10.1021/acs.jpcc.7b06549

Preparation and luminescence properties of Ce3+ and Ce3+/Tb3+-activated Y4Si2O7N2 phosphors
journal, January 2013


Magnetic dipole and vibronically induced electric dipole intensities of the 5 D 47 F J transitions of Tb 3+ in Cs 2 NaTbCl 6
journal, July 1978


Structural phase transitions and photoluminescence properties of oxonitridosilicate phosphors under high hydrostatic pressure
journal, October 2016

  • Lazarowska, Agata; Mahlik, Sebastian; Grinberg, Marek
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep34010

Structural studies of salts of cis and trans .mu.-fluoro-bridged polymers of pentafluorogermanate(1-) and of the pentafluorogermanate(1-) monomer
journal, September 1984

  • Mallouk, Thomas E.; Desbat, Bernard; Bartlett, Neil
  • Inorganic Chemistry, Vol. 23, Issue 20
  • DOI: 10.1021/ic00188a027

Patterned Growth of Vertically Aligned Organic Nanowire Waveguide Arrays
journal, February 2010

  • Zhao, Yong Sheng; Zhan, Peng; Kim, Jaemyung
  • ACS Nano, Vol. 4, Issue 3
  • DOI: 10.1021/nn901567z

Mn 4+ doped fluorotitanate phosphors: synthesis, optical properties and application in LED devices
journal, January 2017

  • Zhou, Qiang; Tan, Huiying; Zhang, Qiuhan
  • RSC Advances, Vol. 7, Issue 51
  • DOI: 10.1039/C7RA04369D

Fast luminescence from rare-earth-codoped BaSiF 6 nanowires with high aspect ratios
journal, January 2018

  • George, Gibin; Jackson, Shanell L.; Mobley, Zariana R.
  • Journal of Materials Chemistry C, Vol. 6, Issue 27
  • DOI: 10.1039/C8TC01651H

Cosmetic wastewater treatment by the ZVI/H 2 O 2 process
journal, December 2016


Hydrothermal Synthesis, Cubic Structure, and Luminescence Properties of BaYF 5 :RE (RE = Eu, Ce, Tb) Nanocrystals
journal, October 2010

  • Huang, Yeju; You, Hongpeng; Jia, Guang
  • The Journal of Physical Chemistry C, Vol. 114, Issue 42
  • DOI: 10.1021/jp105061x

Terbium(III) and europium(III) ions as luminescent probes and stains for biomolecular systems
journal, October 1982


K_2SiF_6:Mn^4+ as a red phosphor for displays and warm-white LEDs: a review of properties and perspectives
journal, January 2017

  • Sijbom, Heleen F.; Verstraete, Reinert; Joos, Jonas J.
  • Optical Materials Express, Vol. 7, Issue 9
  • DOI: 10.1364/OME.7.003332

Luminescent probes for detection and imaging of hydrogen peroxide
journal, April 2011

  • Schäferling, Michael; Grögel, Dominik B. M.; Schreml, Stephan
  • Microchimica Acta, Vol. 174, Issue 1-2
  • DOI: 10.1007/s00604-011-0606-3

CELL SIGNALING: H2O2, a Necessary Evil for Cell Signaling
journal, June 2006


Photoluminescence properties of Eu3+ doped BaF2 nanomaterials and BaF2:3Eu/Fe3O4 nanocomposite for hyperthermia application
journal, November 2018


Rapid and selective determination of hydrogen peroxide residues in milk by batch injection analysis with amperometric detection
journal, July 2012


A new red phosphor BaGeF 6 :Mn 4+ : hydrothermal synthesis, photo-luminescence properties, and its application in warm white LED devices
journal, January 2015

  • Zhou, Qiang; Zhou, Yayun; Liu, Yong
  • Journal of Materials Chemistry C, Vol. 3, Issue 13
  • DOI: 10.1039/C4TC02956A

New Synthesis Strategies for Luminescent YVO 4 :Eu and EuVO 4 Nanoparticles with H 2 O 2 Selective Sensing Properties
journal, July 2015


Turn-on Fluorescence Detection of H 2 O 2 and TATP
journal, November 2008

  • Germain, Meaghan E.; Knapp, Michael J.
  • Inorganic Chemistry, Vol. 47, Issue 21
  • DOI: 10.1021/ic801317x

Novel orange and reddish-orange color emitting BaGd2O4:Sm3+ nanophosphors by solvothermal reaction for LED and FED applications
journal, April 2014

  • Seeta Rama Raju, G.; Yu, Jae Su
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 124
  • DOI: 10.1016/j.saa.2014.01.016

Red Luminescence in Pr3+-Doped Calcium Titanates
journal, March 1997


    Works referencing / citing this record:

    A novel reversible fluorescent probe for the highly sensitive detection of nitro and peroxide organic explosives using electrospun BaWO 4 nanofibers
    journal, January 2019

    • George, Gibin; Edwards, Caressia S.; Hayes, Jacob I.
    • Journal of Materials Chemistry C, Vol. 7, Issue 47
    • DOI: 10.1039/c9tc05068j