Copolyesters developed from bio‐based 2,5‐furandicarboxylic acid: Synthesis, sequence distribution, mechanical, and barrier properties of poly(propylene‐ co ‐1,4‐cyclohexanedimethylene 2,5‐furandicarboxylate)s
Abstract
ABSTRACT A series of poly(propylene‐ co ‐1,4‐cyclohexanedimethylene 2,5‐furandicarboxylate)s (PPCFs) with different compositions were synthesized from bio‐based aromatic monomer 2,5‐furandicarboxylic acid and 1,3‐propanediol (PDO), along with 1,4‐cyclohexanedimethylene (CHDM). The chemical structure, composition, and sequence distribution of PPCFs were determined by nuclear magnetic resonance ( 1 H NMR and 13 C NMR). Results showed that the compositions of copolyesters depended on the feed molar ratio of PDO and CHDM, and all the obtained PPCFs copolyesters had triad component in a random sequential structure. With the addition of CHDM, the gas barrier properties of poly(propylene 2,5‐furandicarboxylate) (PPF) deteriorated. However, when the content of CHDM reached 79%, PPCF79 still showed the CO 2 and O 2 barrier improvement factor of 4.5 and 3.25, respectively, which were better than those of poly(ethylene naphthalate), a well‐known polymer with barrier property. Besides, PPCF79 showed good performance on tensile modulus, tensile strength, elongation at break, and the crystallization enthalpy was improved from 3.2 J g −1 for PPF to 30.7 J g −1 for PPCF79. It has the potential to serve as a promising bio‐based polymer with excellent comprehensive performance. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136 , 47291.
- Authors:
-
- Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences Ningbo Zhejiang 315201 People's Republic of China, Key Laboratory of Bio‐based Polymeric Materials Ningbo Zhejiang 315201 People's Republic of China
- Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences Ningbo Zhejiang 315201 People's Republic of China, Key Laboratory of Bio‐based Polymeric Materials Ningbo Zhejiang 315201 People's Republic of China, University of Chinese Academy of Sciences Huairou Beijing 100049 People's Republic of China
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1483321
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Journal of Applied Polymer Science
- Additional Journal Information:
- Journal Name: Journal of Applied Polymer Science Journal Volume: 136 Journal Issue: 13; Journal ID: ISSN 0021-8995
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Jia, Zhen, Wang, Jinggang, Sun, Liyuan, Liu, Fei, Zhu, Jin, and Liu, Xiaoqing. Copolyesters developed from bio‐based 2,5‐furandicarboxylic acid: Synthesis, sequence distribution, mechanical, and barrier properties of poly(propylene‐ co ‐1,4‐cyclohexanedimethylene 2,5‐furandicarboxylate)s. United States: N. p., 2018.
Web. doi:10.1002/app.47291.
Jia, Zhen, Wang, Jinggang, Sun, Liyuan, Liu, Fei, Zhu, Jin, & Liu, Xiaoqing. Copolyesters developed from bio‐based 2,5‐furandicarboxylic acid: Synthesis, sequence distribution, mechanical, and barrier properties of poly(propylene‐ co ‐1,4‐cyclohexanedimethylene 2,5‐furandicarboxylate)s. United States. https://doi.org/10.1002/app.47291
Jia, Zhen, Wang, Jinggang, Sun, Liyuan, Liu, Fei, Zhu, Jin, and Liu, Xiaoqing. Sun .
"Copolyesters developed from bio‐based 2,5‐furandicarboxylic acid: Synthesis, sequence distribution, mechanical, and barrier properties of poly(propylene‐ co ‐1,4‐cyclohexanedimethylene 2,5‐furandicarboxylate)s". United States. https://doi.org/10.1002/app.47291.
@article{osti_1483321,
title = {Copolyesters developed from bio‐based 2,5‐furandicarboxylic acid: Synthesis, sequence distribution, mechanical, and barrier properties of poly(propylene‐ co ‐1,4‐cyclohexanedimethylene 2,5‐furandicarboxylate)s},
author = {Jia, Zhen and Wang, Jinggang and Sun, Liyuan and Liu, Fei and Zhu, Jin and Liu, Xiaoqing},
abstractNote = {ABSTRACT A series of poly(propylene‐ co ‐1,4‐cyclohexanedimethylene 2,5‐furandicarboxylate)s (PPCFs) with different compositions were synthesized from bio‐based aromatic monomer 2,5‐furandicarboxylic acid and 1,3‐propanediol (PDO), along with 1,4‐cyclohexanedimethylene (CHDM). The chemical structure, composition, and sequence distribution of PPCFs were determined by nuclear magnetic resonance ( 1 H NMR and 13 C NMR). Results showed that the compositions of copolyesters depended on the feed molar ratio of PDO and CHDM, and all the obtained PPCFs copolyesters had triad component in a random sequential structure. With the addition of CHDM, the gas barrier properties of poly(propylene 2,5‐furandicarboxylate) (PPF) deteriorated. However, when the content of CHDM reached 79%, PPCF79 still showed the CO 2 and O 2 barrier improvement factor of 4.5 and 3.25, respectively, which were better than those of poly(ethylene naphthalate), a well‐known polymer with barrier property. Besides, PPCF79 showed good performance on tensile modulus, tensile strength, elongation at break, and the crystallization enthalpy was improved from 3.2 J g −1 for PPF to 30.7 J g −1 for PPCF79. It has the potential to serve as a promising bio‐based polymer with excellent comprehensive performance. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136 , 47291.},
doi = {10.1002/app.47291},
journal = {Journal of Applied Polymer Science},
number = 13,
volume = 136,
place = {United States},
year = {Sun Nov 25 00:00:00 EST 2018},
month = {Sun Nov 25 00:00:00 EST 2018}
}
https://doi.org/10.1002/app.47291
Web of Science
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