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Title: Anion control of tautomeric equilibria: Fe–H vs. N–H influenced by NH⋯F hydrogen bonding

Addition of excess BF 4 to the iron hydride [Fe(P Et N Me P Et )(CO) 3 H] + [B(C 6 F 5 ) 4 ] leads to the NH tautomer, due to NH⋯F hydrogen bonding.
Authors:
 [1] ; ORCiD logo [1] ; ORCiD logo [1] ; ORCiD logo [1]
  1. Center for Molecular Electrocatalysis, Pacific Northwest National Laboratory, Richland, USA
Publication Date:
Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1483140

Chambers, Geoffrey M., Johnson, Samantha I., Raugei, Simone, and Bullock, R. Morris. Anion control of tautomeric equilibria: Fe–H vs. N–H influenced by NH⋯F hydrogen bonding. United Kingdom: N. p., Web. doi:10.1039/C8SC04239J.
Chambers, Geoffrey M., Johnson, Samantha I., Raugei, Simone, & Bullock, R. Morris. Anion control of tautomeric equilibria: Fe–H vs. N–H influenced by NH⋯F hydrogen bonding. United Kingdom. doi:10.1039/C8SC04239J.
Chambers, Geoffrey M., Johnson, Samantha I., Raugei, Simone, and Bullock, R. Morris. 2019. "Anion control of tautomeric equilibria: Fe–H vs. N–H influenced by NH⋯F hydrogen bonding". United Kingdom. doi:10.1039/C8SC04239J.
@article{osti_1483140,
title = {Anion control of tautomeric equilibria: Fe–H vs. N–H influenced by NH⋯F hydrogen bonding},
author = {Chambers, Geoffrey M. and Johnson, Samantha I. and Raugei, Simone and Bullock, R. Morris},
abstractNote = {Addition of excess BF 4 − to the iron hydride [Fe(P Et N Me P Et )(CO) 3 H] + [B(C 6 F 5 ) 4 ] − leads to the NH tautomer, due to NH⋯F hydrogen bonding.},
doi = {10.1039/C8SC04239J},
journal = {Chemical Science},
number = ,
volume = ,
place = {United Kingdom},
year = {2019},
month = {1}
}

Works referenced in this record:

Moving Protons with Pendant Amines: Proton Mobility in a Nickel Catalyst for Oxidation of Hydrogen
journal, September 2011
  • O�Hagan, Molly; Shaw, Wendy J.; Raugei, Simone
  • Journal of the American Chemical Society, Vol. 133, Issue 36, p. 14301-14312
  • DOI: 10.1021/ja201838x