DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Synthesis and electrochemical properties of Li1.3Nb0.3Cr0.4O2 as a high-capacity cathode material for rechargeable lithium batteries

Abstract

A cation-disordered Li-excess material (Li 1.3 Cr 0.4 Nb 0.3 O 2 ) delivers a high reversible capacity, originating from a Cr 3+ /Cr 6+ three-electron redox reaction.

Authors:
 [1];  [1];  [1];  [1];  [1]; ORCiD logo [1];  [2]; ORCiD logo [2]; ORCiD logo [1]
  1. Fudan Univ., Shanghai (People's Republic of China)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE
OSTI Identifier:
1483754
Alternate Identifier(s):
OSTI ID: 1482851
Report Number(s):
BNL-209508-2018-JAAM
Journal ID: ISSN 1359-7345
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 54; Journal Issue: 98; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; Li-rich cathode; Li batteries

Citation Formats

Wang, Weiwen, Meng, Jingke, Yue, Xinyang, Wang, Qinchao, Wang, Xinxin, Zhou, Yongning, Yang, Xiaoqing, Shadike, Zulipiya, and Fu, Zhengwen. Synthesis and electrochemical properties of Li1.3Nb0.3Cr0.4O2 as a high-capacity cathode material for rechargeable lithium batteries. United States: N. p., 2018. Web. doi:10.1039/C8CC07660J.
Wang, Weiwen, Meng, Jingke, Yue, Xinyang, Wang, Qinchao, Wang, Xinxin, Zhou, Yongning, Yang, Xiaoqing, Shadike, Zulipiya, & Fu, Zhengwen. Synthesis and electrochemical properties of Li1.3Nb0.3Cr0.4O2 as a high-capacity cathode material for rechargeable lithium batteries. United States. https://doi.org/10.1039/C8CC07660J
Wang, Weiwen, Meng, Jingke, Yue, Xinyang, Wang, Qinchao, Wang, Xinxin, Zhou, Yongning, Yang, Xiaoqing, Shadike, Zulipiya, and Fu, Zhengwen. Thu . "Synthesis and electrochemical properties of Li1.3Nb0.3Cr0.4O2 as a high-capacity cathode material for rechargeable lithium batteries". United States. https://doi.org/10.1039/C8CC07660J. https://www.osti.gov/servlets/purl/1483754.
@article{osti_1483754,
title = {Synthesis and electrochemical properties of Li1.3Nb0.3Cr0.4O2 as a high-capacity cathode material for rechargeable lithium batteries},
author = {Wang, Weiwen and Meng, Jingke and Yue, Xinyang and Wang, Qinchao and Wang, Xinxin and Zhou, Yongning and Yang, Xiaoqing and Shadike, Zulipiya and Fu, Zhengwen},
abstractNote = {A cation-disordered Li-excess material (Li 1.3 Cr 0.4 Nb 0.3 O 2 ) delivers a high reversible capacity, originating from a Cr 3+ /Cr 6+ three-electron redox reaction.},
doi = {10.1039/C8CC07660J},
journal = {ChemComm},
number = 98,
volume = 54,
place = {United States},
year = {Thu Nov 08 00:00:00 EST 2018},
month = {Thu Nov 08 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 8 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Reversible anionic redox chemistry in high-capacity layered-oxide electrodes
journal, July 2013

  • Sathiya, M.; Rousse, G.; Ramesha, K.
  • Nature Materials, Vol. 12, Issue 9
  • DOI: 10.1038/nmat3699

In Situ X-Ray Absorption Study of a Layered Manganese-Chromium Oxide-Based Cathode Material
journal, January 2002

  • Balasubramanian, M.; McBreen, J.; Davidson, I. J.
  • Journal of The Electrochemical Society, Vol. 149, Issue 2
  • DOI: 10.1149/1.1431962

High-Capacity Cathode Material with High Voltage for Li-Ion Batteries
journal, January 2018


Structural Changes in Li 2 MnO 3 Cathode Material for Li-Ion Batteries
journal, December 2013

  • Rana, Jatinkumar; Stan, Marian; Kloepsch, Richard
  • Advanced Energy Materials, Vol. 4, Issue 5
  • DOI: 10.1002/aenm.201300998

Nanoionics: ion transport and electrochemical storage in confined systems
journal, November 2005

  • Maier, J.
  • Nature Materials, Vol. 4, Issue 11, p. 805-815
  • DOI: 10.1038/nmat1513

Recent advances in the electrolytes for interfacial stability of high-voltage cathodes in lithium-ion batteries
journal, January 2015

  • Choi, Nam-Soon; Han, Jung-Gu; Ha, Se-Young
  • RSC Advances, Vol. 5, Issue 4
  • DOI: 10.1039/C4RA11575A

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976


Reversible Three-Electron Redox Reaction of Mo 3+ /Mo 6+ for Rechargeable Lithium Batteries
journal, March 2017


Lithium-free transition metal monoxides for positive electrodes in lithium-ion batteries
journal, January 2017


Structure of the incommensurate composite crystal [Sr 2 Cu 2 O 3 ][CuO 2 ] x ( x = 1.436)
journal, February 1994

  • Ukei, K.; Shishido, T.; Fukuda, T.
  • Acta Crystallographica Section B Structural Science, Vol. 50, Issue 1
  • DOI: 10.1107/S010876819300905X

Performance and design considerations for lithium excess layered oxide positive electrode materials for lithium ion batteries
journal, January 2016

  • Hy, Sunny; Liu, Haodong; Zhang, Minghao
  • Energy & Environmental Science, Vol. 9, Issue 6
  • DOI: 10.1039/C5EE03573B

Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries
journal, February 2006

  • Kang, Kisuk; Shirley Meng, Ying; Breger, Julien
  • Science, Vol. 311, Issue 5763, p. 977-980
  • DOI: 10.1126/science.1122152

The origin of electrochemical activity in Li2MnO3
journal, October 2002

  • Robertson, Alastair D.; Bruce, Peter G.
  • Chemical Communications, Issue 23
  • DOI: 10.1039/b207945c

Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries
journal, January 2014


The Effect of Cation Disorder on the Average Li Intercalation Voltage of Transition-Metal Oxides
journal, May 2016


Crystal Habit-Tuned Nanoplate Material of Li[Li1/3-2x/3NixMn2/3-x/3]O2 for High-Rate Performance Lithium-Ion Batteries
journal, August 2010


Origin of stabilization and destabilization in solid-state redox reaction of oxide ions for lithium-ion batteries
journal, December 2016

  • Yabuuchi, Naoaki; Nakayama, Masanobu; Takeuchi, Mitsue
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms13814

Promise and reality of post-lithium-ion batteries with high energy densities
journal, March 2016


High-capacity electrode materials for rechargeable lithium batteries: Li 3 NbO 4 -based system with cation-disordered rocksalt structure
journal, June 2015

  • Yabuuchi, Naoaki; Takeuchi, Mitsue; Nakayama, Masanobu
  • Proceedings of the National Academy of Sciences, Vol. 112, Issue 25
  • DOI: 10.1073/pnas.1504901112

Atomic Structure of Li 2 MnO 3 after Partial Delithiation and Re-Lithiation
journal, June 2013


Electrochemical intercalation activity of layered NaCrO2 vs. LiCrO2
journal, March 2010


Approaching the limits of cationic and anionic electrochemical activity with the Li-rich layered rocksalt Li3IrO4
journal, December 2017


In Situ and Ex Situ XRD Investigation of Li[Cr[sub x]Li[sub 1/3−x/3]Mn[sub 2/3−2x/3]]O[sub 2] (x=1/3) Cathode Material
journal, January 2003

  • Lu, Zhonghua; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 150, Issue 8
  • DOI: 10.1149/1.1584439

The Origin of Electrochemical Activity in Li2MnO3.
journal, March 2003


Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries.
journal, May 2006