Effects of Sugars, Furans, and their Derivatives on Hydrodeoxygenation of Biorefinery Lignin-Rich Wastes to Hydrocarbons

Wang, Hongliang; Duan, Yuhua; Zhang, Qian; Yang, Bin

doi:10.1002/cssc.201801401

Title: Effects of Sugars, Furans, and their Derivatives on Hydrodeoxygenation of Biorefinery Lignin-Rich Wastes to Hydrocarbons

Journal Article · 02 July 2018 · ChemSusChem

DOI: https://doi.org/10.1002/cssc.201801401 · OSTI ID:1482812

Wang, Hongliang ^[1];

^[2]; Zhang, Qian ^[3];

^[4]

Washington State Univ., Pullman, WA (United States); China Agricultural Univ., Beijing (China)
National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)
Taiyuan Univ. of Technology, Shanxi (China)
Washington State Univ., Pullman, WA (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Abstract Hydrodeoxygenation of biorefinery lignin‐rich wastes to jet fuel hydrocarbons offers a significant opportunity for enhancing the overall operational efficiency, carbon conversion efficiency, economic viability, and sustainability of biofuels production. However, these wastes usually mainly contain lignin with sugars, furans, and their derivatives as “impurities”. Although several factors, including reactant structure, solvents, or the decreased ratio of catalyst to reactant, could be responsible for the jet fuel hydrocarbons yield loss, we found evidence that glucose, xylose, and 5‐hydroxymethylfurfural dramatically decreased conversion yields. For example, xylose and glucose lowered the final hydrocarbon yield by 78 and 63 %, respectively. The results revealed that these compounds could suppress metal catalysts and inhibit lignin depolymerization and hydrodeoxygenation (HDO) reactions thus decrease yields of jet fuel range hydrocarbons from biomass‐derived lignin. The first‐principles calculations and TGA results from spent catalysts validated these findings.

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Research Organization:: National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC36-08G028308; T0013G-A-Task 8; 21706277; AC05-76RL01830

OSTI ID:: 1482812

Alternate ID(s):: OSTI ID: 1460463; OSTI ID: 1545027

Report Number(s):: PNNL-SA-133525

Journal Information:: ChemSusChem, Vol. 11, Issue 15; ISSN 1864-5631

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 28 works

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