Super Gas Barrier and Fire Resistance of Nanoplatelet/Nanofibril Multilayer Thin Films

Qin, Shuang; Pour, Maryam Ghanad; Lazar, Simone; Köklükaya, Oruç; Gerringer, Joseph; Song, Yixuan; Wågberg, Lars; Grunlan, Jaime C.

doi:10.1002/admi.201801424

Title: Super Gas Barrier and Fire Resistance of Nanoplatelet/Nanofibril Multilayer Thin Films

Journal Article · 16 November 2018 · Advanced Materials Interfaces

DOI: https://doi.org/10.1002/admi.201801424 · OSTI ID:1482415

Qin, Shuang ^[1]; Pour, Maryam Ghanad ^[2]; Lazar, Simone ^[3]; Köklükaya, Oruç ^[2]; Gerringer, Joseph ^[1]; Song, Yixuan ^[1]; Wågberg, Lars ^[2];

^[4]

Department of Materials Science and Engineering 3123 TAMU College Station TX 77843 USA
Department of Fibre and Polymer Technology School of Engineering Sciences in Chemistry Biotechnology and Health KTH Royal Institute of Technology Teknikringen 56 SE‐100 44 Stockholm Sweden
Department of Chemistry 3123 TAMU College Station TX 77843 USA
Department of Materials Science and Engineering 3123 TAMU College Station TX 77843 USA, Department of Chemistry 3123 TAMU College Station TX 77843 USA

Abstract Cellulose nanofibrils (CNF) are abundant in the fiber cell walls of many plants and are considered a nearly inexhaustible resource. With the goal of improving the flame resistance and gas barrier properties of cellulose‐based films, cationic CNF are assembled with anionic vermiculite (VMT) clay using the layer‐by‐layer deposition process. The highly aligned VMT nanoplatelets, together with cellulose nanofibrils, form a nanobrick wall structure that exhibits high optical transparency, flame resistance, super oxygen barrier, and high modulus. A 20 CNF/VMT bilayer (BL) nanocoating, with a thickness of only 136 nm, exhibits an oxygen transmission rate of 0.013 cc (m ² day atm) ^–1 . With only 2 BL of CNF/VMT, the melting of flexible polyurethane foam exposed to a butane torch is prevented. These nanocoatings also exhibit a high elastic modulus (20 GPa) and hardness (1 GPa). This study demonstrates a unique, renewable, cellulose‐based nanocoating that could be used in a variety of packaging and protection applications.

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Sponsoring Organization:: USDOE

OSTI ID:: 1482415

Journal Information:: Advanced Materials Interfaces, Journal Name: Advanced Materials Interfaces Journal Issue: 2 Vol. 6; ISSN 2196-7350

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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