Incorporation of benzimidazole linked polymers into Matrimid to yield mixed matrix membranes with enhanced CO2/N2 selectivity

Tessema, Tsemre Dingel M.; Venna, Surendar R.; Dahe, Ganpat; Hopkinson, David P.; El-Kaderi, Hani M.; Sekizkardes, Ali K.

doi:10.1016/j.memsci.2018.02.054

Title: Incorporation of benzimidazole linked polymers into Matrimid to yield mixed matrix membranes with enhanced CO₂/N₂ selectivity

Journal Article · 05 March 2018 · Journal of Membrane Science

DOI: https://doi.org/10.1016/j.memsci.2018.02.054 · OSTI ID:1482370

Tessema, Tsemre Dingel M. ^[1]; Venna, Surendar R. ^[2]; Dahe, Ganpat ^[3]; Hopkinson, David P. ^[3]; El-Kaderi, Hani M. ^[1]; Sekizkardes, Ali K. ^[2]

Virginia Commonwealth Univ., Richmond, VA (United States). Department of Chemistry
National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); AECOM, Pittsburgh, PA (United States)
National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)

In this study, two different highly cross-linked benzimidazole linked polymers (BILPs) displaying high surface area were successfully incorporated into Matrimid polymer to form a series of new mixed matrix membranes (MMMs). The surface functionality of the BILPs, BILP-4 and BILP-101, were exploited to assure the interaction with the Matrimid matrix and produce robust MMMs, which displayed significantly improved CO₂ gas permeability. The ideal selectivities for CO₂/N₂ were calculated with enhancements as high as 34% at 15 wt% BILP loading. While BILP-4 and BILP-101 have similar structures and functionality, the two materials have notably different surface areas and CO₂ adsorption capacity. Despite the differences in their gas adsorption properties, MMMs composed of Matrimid/BILP-4 and Matrimid/BILP-101 had very similar gas transport properties. Lastly, these results suggest that the functional groups of the filler particle and the resulting interaction with the polymer matrix may have had more influence on the gas separation properties of the mixed matrix membrane than the adsorption properties of the fillers.

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Research Organization:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV, and Albany, OR (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Grant/Contract Number:: FE0004000; SC0002576

OSTI ID:: 1482370

Journal Information:: Journal of Membrane Science, Journal Name: Journal of Membrane Science Journal Issue: C Vol. 554; ISSN 0376-7388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (28)

Gas permeability properties of Matrimid® membranes containing the metal-organic framework Cu–BPY–HFS Zhang, Yanfeng; Musselman, Inga H.; Ferraris, John P. Journal of Membrane Science, Vol. 313, Issue 1-2 https://doi.org/10.1016/j.memsci.2008.01.005	journal	April 2008
Enhanced Carbon Dioxide Capture from Landfill Gas Using Bifunctionalized Benzimidazole-Linked Polymers Islamoglu, Timur; Behera, Swayamprabha; Kahveci, Zafer ACS Applied Materials & Interfaces, Vol. 8, Issue 23 https://doi.org/10.1021/acsami.6b05326	journal	June 2016
Separation of CO ₂ from Flue Gas: A Review Aaron, Douglas; Tsouris, Costas Separation Science and Technology, Vol. 40, Issue 1-3 https://doi.org/10.1081/SS-200042244	journal	January 2005
Enhanced performance of mixed matrix membrane by incorporating a highly compatible covalent organic framework into poly(vinylamine) for hydrogen purification Cao, Xiaochang; Qiao, Zhihua; Wang, Zhi International Journal of Hydrogen Energy, Vol. 41, Issue 21 https://doi.org/10.1016/j.ijhydene.2016.01.137	journal	June 2016
Ionic cross-linked polyether and silica gel mixed matrix membranes for CO2 separation from flue gas Sekizkardes, Ali K.; Zhou, Xu; Nulwala, Hunaid B. Separation and Purification Technology, Vol. 191 https://doi.org/10.1016/j.seppur.2017.09.046	journal	January 2018
Zeolite-filled polyimide membrane containing 2,4,6-triaminopyrimidine Yong, Hyun Hang; Park, Hyun Chae; Kang, Yong Soo Journal of Membrane Science, Vol. 188, Issue 2 https://doi.org/10.1016/S0376-7388(00)00659-1	journal	July 2001
Highly Selective and Permeable Porous Organic Framework Membrane for CO ₂ Capture Gao, Xue; Zou, Xiaoqin; Ma, Heping Advanced Materials, Vol. 26, Issue 22 https://doi.org/10.1002/adma.201400020	journal	March 2014
Synthesis and Characterization of Diaminophenylindane Based Polyimides via Ester-Acid Solution Imidization Farr, I. V.; Glass, T. E.; Ji, Q. High Performance Polymers, Vol. 9, Issue 3 https://doi.org/10.1088/0954-0083/9/3/012	journal	September 1997
Pyrene-directed growth of nanoporous benzimidazole-linked nanofibers and their application to selective CO2 capture and separation Rabbani, Mohammad Gulam; Sekizkardes, Ali Kemal; El-Kadri, Oussama M. Journal of Materials Chemistry, Vol. 22, Issue 48 https://doi.org/10.1039/c2jm34922a	journal	January 2012
The synthesis and characterization of polyimide homopolymers based on 5(6)-amino-1-(4-aminophenyl)-1,3,3-trimethylindane Farr, I. V.; Kratzner, D.; Glass, T. E. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 38, Issue 15 https://doi.org/10.1002/1099-0518(20000801)38:15<2840::AID-POLA240>3.0.CO;2-N	journal	January 2000
Fabrication of MMMs with improved gas separation properties using externally-functionalized MOF particles Venna, Surendar R.; Lartey, Michael; Li, Tao Journal of Materials Chemistry A, Vol. 3, Issue 9 https://doi.org/10.1039/C4TA05225K	journal	January 2015
A High-Performance Gas-Separation Membrane Containing Submicrometer-Sized Metal-Organic Framework Crystals Bae, Tae-Hyun; Lee, Jong Suk; Qiu, Wulin Angewandte Chemie International Edition, Vol. 49, Issue 51, p. 9863-9866 https://doi.org/10.1002/anie.201006141	journal	November 2010
Carbon Dioxide Separation from Flue Gases: A Technological Review Emphasizing Reduction in Greenhouse Gas Emissions Songolzadeh, Mohammad; Soleimani, Mansooreh; Takht Ravanchi, Maryam The Scientific World Journal, Vol. 2014 https://doi.org/10.1155/2014/828131	journal	January 2014
Synthesis and Characterization of Porous Benzimidazole-Linked Polymers and Their Performance in Small Gas Storage and Selective Uptake Rabbani, Mohammad Gulam; El-Kaderi, Hani M. Chemistry of Materials, Vol. 24, Issue 8 https://doi.org/10.1021/cm300407h	journal	April 2012
Mixed matrix membranes comprising polymers of intrinsic microporosity and covalent organic framework for gas separation Wu, Xingyu; Tian, Zhizhang; Wang, Shaofei Journal of Membrane Science, Vol. 528 https://doi.org/10.1016/j.memsci.2017.01.042	journal	April 2017
Mixed matrix membranes of Matrimid 5218 loaded with zeolite 4A for pervaporation separation of water–isopropanol mixtures Khosravi, T.; Mosleh, S.; Bakhtiari, O. Chemical Engineering Research and Design, Vol. 90, Issue 12 https://doi.org/10.1016/j.cherd.2012.06.005	journal	December 2012
Contribution of Antarctica to past and future sea-level rise DeConto, Robert M.; Pollard, David Nature, Vol. 531, Issue 7596 https://doi.org/10.1038/nature17145	journal	March 2016
The development of high performance P84 co-polyimide hollow fibers for pervaporation dehydration of isopropanol Liu, Ruixue; Qiao, Xiangyi; Chung, Tai-Shung Chemical Engineering Science, Vol. 60, Issue 23 https://doi.org/10.1016/j.ces.2005.05.066	journal	December 2005
New insights into carbon dioxide interactions with benzimidazole-linked polymers Altarawneh, Suha; Behera, S.; Jena, Puru Chem. Commun., Vol. 50, Issue 27 https://doi.org/10.1039/C3CC45901B	journal	January 2014
Separation of carbon dioxide from flue gas by mixed matrix membranes using dual phase microporous polymeric constituents Sekizkardes, Ali K.; Kusuma, Victor A.; Dahe, Ganpat Chemical Communications, Vol. 52, Issue 79 https://doi.org/10.1039/C6CC04811K	journal	January 2016
Effect of condensable impurity in CO2/CH4 gas feeds on performance of mixed matrix membranes using carbon molecular sieves Vu, De Q.; Koros, William J.; Miller, Stephen J. Journal of Membrane Science, Vol. 221, Issue 1-2 https://doi.org/10.1016/S0376-7388(03)00245-X	journal	August 2003
An ultra-microporous organic polymer for high performance carbon dioxide capture and separation Sekizkardes, Ali Kemal; Culp, Jeffrey T.; Islamoglu, Timur Chemical Communications, Vol. 51, Issue 69 https://doi.org/10.1039/C5CC04656D	journal	January 2015
Non-ideal effects in organic–inorganic materials for gas separation membranes Moore, Theodore T.; Koros, William J. Journal of Molecular Structure, Vol. 739, Issue 1-3 https://doi.org/10.1016/j.molstruc.2004.05.043	journal	April 2005
Polyphosphazene polymer development for mixed matrix membranes using SIFSIX-Cu-2i as performance enhancement filler particles Venna, Surendar R.; Spore, Alex; Tian, Zhicheng Journal of Membrane Science, Vol. 535 https://doi.org/10.1016/j.memsci.2017.04.033	journal	August 2017
Crosslinked mixed matrix membranes for the purification of natural gas: Effects of sieve surface modification Hillock, Alexis M. W.; Miller, Stephen J.; Koros, William J. Journal of Membrane Science, Vol. 314, Issue 1-2 https://doi.org/10.1016/j.memsci.2008.01.046	journal	April 2008
Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials Alexandre, Michael; Dubois, Philippe Materials Science and Engineering: R: Reports, Vol. 28, Issue 1-2 https://doi.org/10.1016/S0927-796X(00)00012-7	journal	June 2000
The upper bound revisited Robeson, Lloyd M. Journal of Membrane Science, Vol. 320, Issue 1-2, p. 390-400 https://doi.org/10.1016/j.memsci.2008.04.030	journal	July 2008
Characterization of permeability and sorption in Matrimid/C60 mixed matrix membranes Chung, Tai-Shung; Chan, Sun Sun; Wang, Rong Journal of Membrane Science, Vol. 211, Issue 1 https://doi.org/10.1016/S0376-7388(02)00385-X	journal	January 2003

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