Microstructure and Mechanical Behavior of High-Entropy Alloys
Abstract
High entropy alloys (HEA) have generated interest in recent years due to their unique positioning within the alloy world. By incorporating a number of elements in high proportion, usually of equal atomic percent, they have high configurational entropy, and thus, they hold the promise of interesting and useful properties such as enhanced strength and alloy stability. The present study investigates the mechanical behavior, fracture characteristics and microstructure of two singlephase FCC high-entropy alloys (HEA's) CoCrFeNi and CoCrFeNiMn with some detailed attention given to melting, homogenization and thermo-mechanical processing. Ingots approaching 8 kg in mass were made by vacuum induction melting (VIM) to avoid the extrinsic factors inherent to small scale laboratory button samples. A computationally based homogenization heat treatment was given to both alloys in order to eliminate any solidification segregation. The alloys were then fabricated in the usual way (forging, followed by hot rolling) with typical thermo-mechanical processing parameters employed. Transmission electron microscopy (TEM) was subsequently used to assess the single phase nature of the alloys prior to mechanical testing. Tensile specimens (ASTM E8) were prepared with tensile mechanical properties obtained from room temperature through 800°C. Material from the gage section of selected tensile specimens was extracted to documentmore »
- Authors:
-
- National Energy Technology Lab. (NETL), Albany, OR (United States)
- National Energy Technology Lab. (NETL), Albany, OR (United States); AECOM, Albany, OR (United States)
- Publication Date:
- Research Org.:
- National Energy Technology Lab. (NETL), Albany, OR (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1482330
- Grant/Contract Number:
- FE0004000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Engineering and Performance
- Additional Journal Information:
- Journal Volume: 24; Journal Issue: 10; Journal ID: ISSN 1059-9495
- Publisher:
- Springer
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Licavoli, Joseph J., Gao, Michael C., Sears, John S., Jablonski, Paul D., and Hawk, Jeffrey A. Microstructure and Mechanical Behavior of High-Entropy Alloys. United States: N. p., 2015.
Web. doi:10.1007/s11665-015-1679-7.
Licavoli, Joseph J., Gao, Michael C., Sears, John S., Jablonski, Paul D., & Hawk, Jeffrey A. Microstructure and Mechanical Behavior of High-Entropy Alloys. United States. https://doi.org/10.1007/s11665-015-1679-7
Licavoli, Joseph J., Gao, Michael C., Sears, John S., Jablonski, Paul D., and Hawk, Jeffrey A. Thu .
"Microstructure and Mechanical Behavior of High-Entropy Alloys". United States. https://doi.org/10.1007/s11665-015-1679-7. https://www.osti.gov/servlets/purl/1482330.
@article{osti_1482330,
title = {Microstructure and Mechanical Behavior of High-Entropy Alloys},
author = {Licavoli, Joseph J. and Gao, Michael C. and Sears, John S. and Jablonski, Paul D. and Hawk, Jeffrey A.},
abstractNote = {High entropy alloys (HEA) have generated interest in recent years due to their unique positioning within the alloy world. By incorporating a number of elements in high proportion, usually of equal atomic percent, they have high configurational entropy, and thus, they hold the promise of interesting and useful properties such as enhanced strength and alloy stability. The present study investigates the mechanical behavior, fracture characteristics and microstructure of two singlephase FCC high-entropy alloys (HEA's) CoCrFeNi and CoCrFeNiMn with some detailed attention given to melting, homogenization and thermo-mechanical processing. Ingots approaching 8 kg in mass were made by vacuum induction melting (VIM) to avoid the extrinsic factors inherent to small scale laboratory button samples. A computationally based homogenization heat treatment was given to both alloys in order to eliminate any solidification segregation. The alloys were then fabricated in the usual way (forging, followed by hot rolling) with typical thermo-mechanical processing parameters employed. Transmission electron microscopy (TEM) was subsequently used to assess the single phase nature of the alloys prior to mechanical testing. Tensile specimens (ASTM E8) were prepared with tensile mechanical properties obtained from room temperature through 800°C. Material from the gage section of selected tensile specimens was extracted to document room and elevated temperature deformation within the HEA's. Fracture surfaces were also examined to note fracture failure modes. The tensile behavior and selected tensile properties were compared with results in the literature for similar alloys.},
doi = {10.1007/s11665-015-1679-7},
journal = {Journal of Materials Engineering and Performance},
number = 10,
volume = 24,
place = {United States},
year = {Thu Aug 27 00:00:00 EDT 2015},
month = {Thu Aug 27 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
Manufacturing of High Entropy Alloys
journal, July 2015
- Jablonski, Paul D.; Licavoli, Joseph J.; Gao, Michael C.
- JOM, Vol. 67, Issue 10
Tensile properties of high- and medium-entropy alloys
journal, August 2013
- Gali, A.; George, E. P.
- Intermetallics, Vol. 39
Microstructural development in equiatomic multicomponent alloys
journal, July 2004
- Cantor, B.; Chang, I. T. H.; Knight, P.
- Materials Science and Engineering: A, Vol. 375-377
Mechanical properties, microstructure and thermal stability of a nanocrystalline CoCrFeMnNi high-entropy alloy after severe plastic deformation
journal, September 2015
- Schuh, B.; Mendez-Martin, F.; Völker, B.
- Acta Materialia, Vol. 96
Refractory high-entropy alloys
journal, September 2010
- Senkov, O. N.; Wilks, G. B.; Miracle, D. B.
- Intermetallics, Vol. 18, Issue 9
The influences of temperature and microstructure on the tensile properties of a CoCrFeMnNi high-entropy alloy
journal, September 2013
- Otto, F.; Dlouhý, A.; Somsen, Ch.
- Acta Materialia, Vol. 61, Issue 15
Dynamic strain aging studied at the atomic scale
journal, March 2015
- Aboulfadl, H.; Deges, J.; Choi, P.
- Acta Materialia, Vol. 86
Incipient plasticity and dislocation nucleation of FeCoCrNiMn high-entropy alloy
journal, May 2013
- Zhu, C.; Lu, Z. P.; Nieh, T. G.
- Acta Materialia, Vol. 61, Issue 8
Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes
journal, May 2004
- Yeh, J.-W.; Chen, S.-K.; Lin, S.-J.
- Advanced Engineering Materials, Vol. 6, Issue 5, p. 299-303
Microstructures and properties of high-entropy alloys
journal, April 2014
- Zhang, Yong; Zuo, Ting Ting; Tang, Zhi
- Progress in Materials Science, Vol. 61
Steady state flow of the FeCoNiCrMn high entropy alloy at elevated temperatures
journal, December 2014
- He, J. Y.; Zhu, C.; Zhou, D. Q.
- Intermetallics, Vol. 55
High-Entropy Alloys: A Critical Review
journal, April 2014
- Tsai, Ming-Hung; Yeh, Jien-Wei
- Materials Research Letters, Vol. 2, Issue 3
Mechanism of dynamic strain aging and characterization of its effect on the low-cycle fatigue behavior in type 316L stainless steel
journal, April 2005
- Hong, Seong-Gu; Lee, Soon-Bok
- Journal of Nuclear Materials, Vol. 340, Issue 2-3
Temperature Effects on Deformation and Serration Behavior of High-Entropy Alloys (HEAs)
journal, September 2014
- Antonaglia, J.; Xie, X.; Tang, Z.
- JOM, Vol. 66, Issue 10
Annealing on the structure and properties evolution of the CoCrFeNiCuAl high-entropy alloy
journal, July 2010
- Zhang, K. B.; Fu, Z. Y.; Zhang, J. Y.
- Journal of Alloys and Compounds, Vol. 502, Issue 2
Effects of annealing treatment on phase composition and microstructure of CoCrFeNiTiAlx high-entropy alloys
journal, March 2012
- Zhang, Kuibao; Fu, Zhengyi
- Intermetallics, Vol. 22
Tensile properties of low-stacking fault energy high-entropy alloys
journal, June 2015
- Zaddach, A. J.; Scattergood, R. O.; Koch, C. C.
- Materials Science and Engineering: A, Vol. 636
Microstructural evolution after thermomechanical processing in an equiatomic, single-phase CoCrFeMnNi high-entropy alloy with special focus on twin boundaries
journal, November 2014
- Otto, F.; Hanold, N. L.; George, E. P.
- Intermetallics, Vol. 54
Microstructure and mechanical property of as-cast, -homogenized, and -deformed AlxCoCrFeNi (0≤x≤2) high-entropy alloys
journal, November 2009
- Kao, Yih-Farn; Chen, Ting-Jie; Chen, Swe-Kai
- Journal of Alloys and Compounds, Vol. 488, Issue 1
Entropy-driven phase stability and slow diffusion kinetics in an Al0.5CoCrCuFeNi high entropy alloy
journal, December 2012
- Ng, Chun; Guo, Sheng; Luan, Junhua
- Intermetallics, Vol. 31
The Practical Application of Minor Element Control in Small Scale Melts
conference, September 2013
- Jablonski, P. D.; Hawk, J. A.
- Proceedings of the 2013 International Symposium on Liquid Metal Processing and Casting
Investigation using digital image correlation of Portevin-Le Chatelier Effect in Hastelloy X under thermo-mechanical loading
journal, January 2015
- Swaminathan, B.; Abuzaid, W.; Sehitoglu, H.
- International Journal of Plasticity, Vol. 64
High temperature deformation behavior and dynamic recrystallization in CoCrFeNiMn high entropy alloy
journal, June 2015
- Stepanov, N. D.; Shaysultanov, D. G.; Yurchenko, N. Yu.
- Materials Science and Engineering: A, Vol. 636
Relative effects of enthalpy and entropy on the phase stability of equiatomic high-entropy alloys
journal, April 2013
- Otto, F.; Yang, Y.; Bei, H.
- Acta Materialia, Vol. 61, Issue 7
Homogenizing a Nickel-Based Superalloy: Thermodynamic and Kinetic Simulation and Experimental Results
journal, March 2009
- Jablonski, Paul D.; Cowen, Christopher J.
- Metallurgical and Materials Transactions B, Vol. 40, Issue 2
Works referencing / citing this record:
Microstructure and Mechanical Properties of a Refractory CoCrMoNbTi High-Entropy Alloy
journal, June 2017
- Zhang, Mina; Zhou, Xianglin; Li, Jinghao
- Journal of Materials Engineering and Performance, Vol. 26, Issue 8
Thermal and Oxidation Behavior of CoCrFeMnNi Alloy with and Without Yttrium Oxide Particle Dispersion
journal, September 2019
- Vilémová, Monika; Illková, Ksenia; Csáki, Štefan
- Journal of Materials Engineering and Performance, Vol. 28, Issue 9