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Title: Photoelectron spectroscopy of solvated dicarboxylate and alkali metal ion clusters, M + [O 2 C(CH 2 ) 2 CO 2 ] 2− [H 2 O] n (M = Na, K; n = 1–6)

We present results of combined experimental photoelectron spectroscopy and theoretical modeling studies of solvated dicarboxylate species ( O 2 C(CH 2 ) 2 CO 2 ) in complex with Na + and K + metal cations.
Authors:
 [1] ;  [2] ; ORCiD logo [2] ;  [3] ; ORCiD logo [2]
  1. College of Environmental and Chemical Engineering, Xi’an Polytechnic University, Xi’an, China, Physical Sciences Division
  2. Physical Sciences Division, Pacific Northwest National Laboratory, Washington 99352, USA
  3. Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Washington 99352, USA
Publication Date:
Type:
Publisher's Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics Journal Volume: 20 Journal Issue: 46; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1482259

Li, Ren-Zhong, Deng, Shihu H. M., Hou, Gao-Lei, Valiev, Marat, and Wang, Xue-Bin. Photoelectron spectroscopy of solvated dicarboxylate and alkali metal ion clusters, M + [O 2 C(CH 2 ) 2 CO 2 ] 2− [H 2 O] n (M = Na, K; n = 1–6). United Kingdom: N. p., Web. doi:10.1039/C8CP03896A.
Li, Ren-Zhong, Deng, Shihu H. M., Hou, Gao-Lei, Valiev, Marat, & Wang, Xue-Bin. Photoelectron spectroscopy of solvated dicarboxylate and alkali metal ion clusters, M + [O 2 C(CH 2 ) 2 CO 2 ] 2− [H 2 O] n (M = Na, K; n = 1–6). United Kingdom. doi:10.1039/C8CP03896A.
Li, Ren-Zhong, Deng, Shihu H. M., Hou, Gao-Lei, Valiev, Marat, and Wang, Xue-Bin. 2018. "Photoelectron spectroscopy of solvated dicarboxylate and alkali metal ion clusters, M + [O 2 C(CH 2 ) 2 CO 2 ] 2− [H 2 O] n (M = Na, K; n = 1–6)". United Kingdom. doi:10.1039/C8CP03896A.
@article{osti_1482259,
title = {Photoelectron spectroscopy of solvated dicarboxylate and alkali metal ion clusters, M + [O 2 C(CH 2 ) 2 CO 2 ] 2− [H 2 O] n (M = Na, K; n = 1–6)},
author = {Li, Ren-Zhong and Deng, Shihu H. M. and Hou, Gao-Lei and Valiev, Marat and Wang, Xue-Bin},
abstractNote = {We present results of combined experimental photoelectron spectroscopy and theoretical modeling studies of solvated dicarboxylate species ( − O 2 C(CH 2 ) 2 CO 2 − ) in complex with Na + and K + metal cations.},
doi = {10.1039/C8CP03896A},
journal = {Physical Chemistry Chemical Physics},
number = 46,
volume = 20,
place = {United Kingdom},
year = {2018},
month = {11}
}

Works referenced in this record:

Density?functional thermochemistry. III. The role of exact exchange
journal, April 1993
  • Becke, Axel D.
  • The Journal of Chemical Physics, Vol. 98, Issue 7, p. 5648-5652
  • DOI: 10.1063/1.464913

Semiempirical GGA-type density functional constructed with a long-range dispersion correction
journal, January 2006
  • Grimme, Stefan
  • Journal of Computational Chemistry, Vol. 27, Issue 15, p. 1787-1799
  • DOI: 10.1002/jcc.20495