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Title: A comparative review of the aqueous corrosion of glasses, crystalline ceramics, and metals

Abstract

All materials can suffer from environmental degradation; the rate and extent of degradation depend on the details of the material composition and structure as well as the environment. The corrosion of silicate glasses, crystalline ceramics, and metals, particularly as related to nuclear waste forms, has received a lot of attention. The corrosion phenomena and mechanisms of these materials are different, but also have many similarities. Furthermore, this review compares and contrasts the mechanisms of environmental degradation of glass, crystalline ceramics, and metals, with the goal of identifying commonalities that can seed synergistic activities and advance the current knowledge in each area.

Authors:
ORCiD logo [1];  [2];  [3];  [4];  [5];  [2];  [6]; ORCiD logo [7];  [1]; ORCiD logo [8]
  1. The Ohio State Univ., Columbus, OH (United States)
  2. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  3. Rensselaer Polytechnic Inst., Troy, NY (United States)
  4. Univ. of Virginia, Charlottesville, VA (United States)
  5. Commissariat a l’energie Atomique et aux energies Alternatives, Marcoule (France)
  6. Louisiana State Univ., Baton Rouge, LA (United States)
  7. Pennsylvania State Univ., University Park, PA (United States)
  8. Univ. of North Texas, Denton, TX (United States)
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Performance and Design of Nuclear Waste Forms and Containers (WastePD); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1482216
Grant/Contract Number:  
AC0576RL01830
Resource Type:
Accepted Manuscript
Journal Name:
npj Materials Degradation
Additional Journal Information:
Journal Volume: 2; Journal Issue: 1; Journal ID: ISSN 2397-2106
Publisher:
Springer
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Frankel, Gerald S., Vienna, John D., Lian, Jie, Scully, John R., Gin, Stephane, Ryan, Joseph V., Wang, Jianwei, Kim, Seong H., Windl, Wolfgang, and Du, Jincheng. A comparative review of the aqueous corrosion of glasses, crystalline ceramics, and metals. United States: N. p., 2018. Web. doi:10.1038/s41529-018-0037-2.
Frankel, Gerald S., Vienna, John D., Lian, Jie, Scully, John R., Gin, Stephane, Ryan, Joseph V., Wang, Jianwei, Kim, Seong H., Windl, Wolfgang, & Du, Jincheng. A comparative review of the aqueous corrosion of glasses, crystalline ceramics, and metals. United States. doi:10.1038/s41529-018-0037-2.
Frankel, Gerald S., Vienna, John D., Lian, Jie, Scully, John R., Gin, Stephane, Ryan, Joseph V., Wang, Jianwei, Kim, Seong H., Windl, Wolfgang, and Du, Jincheng. Thu . "A comparative review of the aqueous corrosion of glasses, crystalline ceramics, and metals". United States. doi:10.1038/s41529-018-0037-2. https://www.osti.gov/servlets/purl/1482216.
@article{osti_1482216,
title = {A comparative review of the aqueous corrosion of glasses, crystalline ceramics, and metals},
author = {Frankel, Gerald S. and Vienna, John D. and Lian, Jie and Scully, John R. and Gin, Stephane and Ryan, Joseph V. and Wang, Jianwei and Kim, Seong H. and Windl, Wolfgang and Du, Jincheng},
abstractNote = {All materials can suffer from environmental degradation; the rate and extent of degradation depend on the details of the material composition and structure as well as the environment. The corrosion of silicate glasses, crystalline ceramics, and metals, particularly as related to nuclear waste forms, has received a lot of attention. The corrosion phenomena and mechanisms of these materials are different, but also have many similarities. Furthermore, this review compares and contrasts the mechanisms of environmental degradation of glass, crystalline ceramics, and metals, with the goal of identifying commonalities that can seed synergistic activities and advance the current knowledge in each area.},
doi = {10.1038/s41529-018-0037-2},
journal = {npj Materials Degradation},
number = 1,
volume = 2,
place = {United States},
year = {2018},
month = {5}
}

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A mechanistic model for understanding nuclear waste glass dissolution
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HLW glass dissolution in the presence of magnesium carbonate: Diffusion cell experiment and coupled modeling of diffusion and geochemical interactions
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The Effect of Ordinary Portland Cement on Nuclear Waste Glass Dissolution
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